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  • Springer  (40)
  • American Chemical Society  (16)
  • American Physical Society  (8)
  • 1980-1984  (64)
  • 1960-1964
  • 1984  (64)
  • 11
    Electronic Resource
    Electronic Resource
    Springer
    Computing 33 (1984), S. 353-362 
    ISSN: 1436-5057
    Keywords: 65H10 ; Nonlinear systems ; Quasi-Newton methods
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Description / Table of Contents: Zusammenfassung Wir stellen ein neues Quasi-Newton-Verfahren vor zur Lösung von nichtlinearen simultanen Gleichungen. Bei jeder Iteration wird lediglich eine Spalte vonB k verändert, umB k+1 zu erhalten. Dies erlaubt, wohlbekannte Techniken der Linearen Programmierung zur Faktorisierung vonB k zu benützen. Wir beweisen einen Satz über die lokale Konvergenz für die Methode. Der neue Algorithmus wird mit anderen bezüglich seiner numerischen Eigenschaften verglichen.
    Notes: Abstract In this paper we introduce a new Quasi-Newton method for solving nonlinear simultaneous equations. At each iteration only one column ofB k is changed to obtainB k+1 . This permits to use the well-known techniques of Linear Programming for modifying the factorization ofB k . We present a local convergence theorem for a restarted version of the method. The new algorithm is compared numerically with some other methods which were introduced for solving the same kind of problems.
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  • 12
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 14 (1984), S. 9-14 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The effects of applying voltages higher than the nominal voltageV N, for given periods of time, to miniature aluminium electrolytic capacitors has been investigated. The measurements of the current transients, theI–V characteristics, and the a.c. properties indicate that the main effect of subjecting the capacitors to the high voltages is an irreversible change in the capacitor dielectric characteristics as a consequence of a large increase in the resistance of the electrolyte and in the permanent leakage current through the anodic oxide. This current, very noticeable for voltages higher thanV N, is attributed to an electronic conduction mechanism in an avalanche regime. The measured dielectric parameters and their evolution after exposing the capacitors to stressed voltage conditions are interpreted in terms of an extension of McLean's equivalent circuit for an electrolytic capacitor.
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  • 13
    Electronic Resource
    Electronic Resource
    Springer
    Celestial mechanics and dynamical astronomy 33 (1984), S. 375-383 
    ISSN: 1572-9478
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Some of the properties of the oblate planet problem are derived. We use the technique of blowing up the singularity to study the collision orbits. We define some families of them in terms of their asymptotic behavior.
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  • 14
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 316 (1984), S. 251-254 
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Solid state effects are taken into account in an internal conversion coefficients computation by using Wigner-Seitz boundary conditions. Both the bound and free electron wave functions are calculated from an atomic Dirac-Hartree-Fock-Slater self consistent potential. These internal conversion coefficients are compared with those obtained from the usual free atom boundary conditions.
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  • 15
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 40 (1984), S. 557-559 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary The presence of 10−3 M ouabain or furosemide in the perfusate inhibited saliva secretion induced by either isoproterenol (10−5 M) or phenylephrine (10−5 M) from isolated rat submandibular glands and caused characteristic alterations in the electrolyte composition of saliva.
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  • 16
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract A zone of mylonite is commonly developed beneath the Alpujarride nappe complex. The contact with the underlying Nevado-Filabride Complex is marked by a zone of calc mylonite, dolomitic breccia, iron-rich carbonate rocks, and marble. These lie on a thin zone of ultramylonite derived from Nevado-Filabride schist. Related ductile deformation decreases downwards, but may extend up to 400 m beneath the contact. This deformation produces a characteristic platy foliation, a strong elongation lineation, and a proto-mylonitic microstructure. Kinematic analysis of these rocks may help determine the direction of nappe transport. Mylonitic or protomylonitic microstructures are not developed in the Alpujarride rocks, although these are strongly deformed adjacent to the contact. Microstructural evidence suggests that deformation occurred by pressure-solution in these rocks, and not by the crystal-plastic processes that operated in the Nevado-Filabride protomylonitic schists.
    Abstract: Resumen Bajo el complejo de mantos de los Alpujárrides se observa comunmente el desarrollo de una zona milonitica. El contacto de dicho complejo con el de Nevado-Filabride está señalado por una zona de calcomilonitas, brechas dolomiticas, rocas carbonatadas ricas en hierro y mármoles. Estos se situan en una zona estrecha de ultramilonitas que se derivan de los esquistos del Nevado-Filabride, La deformación dúctil asociada decrece en sentido descendente, pero puedo extenderse hasta 400 m por debajo del contacto. Esta deformation produce una foliación planar characterística, una lineación de extensión muy pronunciada y una microestructura protomilonítica. Los análisis cinemáticos de éstas rocas pueden ayudar a determinar la dirección de transporte de los mantos. Las microestructuras miloníticas y protomyloníticas no se desarrollan en las rocas Alpujárrides, aunque dichas rocas están fuertemente deformadas junto al contacto. Las observaciones microestructurales sugieren que la deformación tuvo lugar por «pressure-solution» y no por procesos de plasticidad cristalina como los operantes en los esquistos protomiloníticos del Nevado-Filabride.
    Notes: Zusammenfassung Im Liegenden des Deckengebäudes der Alpujarriden findet sich an vielen Stellen eine Mylonitzone. Der Kontakt mit den unterlagernden nevado-filabriden Gesteinen ist durch Kalkmylonite, Dolomitbrekzien, eisenreiche Karbonate und Marmore markiert. Diese liegen auf einer dünnen Zone von Ultramylonit, der sich aus nevado-filabriden Glimmerschiefern entwickelt hat. Diese plastische Verformung nimmt zum Liegenden hin ab, kann aber bis zu 400 m unterhalb des Deckenkontaktes reichen. Sie erzeugt eine charakteristische, plattige Schieferung, eine stark ausgeprägte Streckungslineation und eine protomylonitische Mikrostruktur. Mit einer kinematischen Analyse dieser Gesteine kann die Transportrichtung der Deckeneinheiten bestimmt werden. Die Glimmerschiefer und Phyllite alpujarrider Zuordnung besitzen keine mylonitische Mikrostruktur, obwohl sie stark deformiert sind. Dies deutet darauf hin, daß, im Gegensatz zum intrakristallinen Gleiten in den nevado-filabriden Protomyloniten, vor allem Drucklösung als Deformationsmechanismus anzusehen ist.
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  • 17
    Electronic Resource
    Electronic Resource
    Springer
    Letters in mathematical physics 8 (1984), S. 111-117 
    ISSN: 1573-0530
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics , Physics
    Notes: Abstract The quantum nonlinear Schrödinger equation with attractive coupling is considered through the quantum inverse scattering method. The asymptotic fields arising in this model are characterized in terms of scattering data operators.
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  • 18
    Electronic Resource
    Electronic Resource
    Springer
    Archiv der Mathematik 42 (1984), S. 307-310 
    ISSN: 1420-8938
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
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  • 19
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 29 (1984), S. 589-596 
    ISSN: 1572-8943
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Die thermische Zersetzung von Anilinoctamolybdat wurde unter nicht-isothermen Bedingungen thermogravimetrisch untersucht, um die im ersten Zersetzungsschritt der wasserfreien Verbindung verlaufenden chemischen Reaktionen aufzuklären. Die Zersetzungsprodukte wurden mittels Gas-Flüssigkeits-Chromatographie, Gaschromatographie-Massenspektrometrie (GC/MS), Infrarotspektroskopie und Röntgendiffraktometrie analysiert. Als Hauptprodukt der Zersetzung von Anilin wurde Indol gefunden, während bei isothermer Zersetzung bei gleicher Temperatur vorwiegend N-Äthylanilin entsteht. Es wird angenommen, daß beim nicht-isothermen Prozeß eine wahrscheinlich durch das Octamolybdat katalysierte Dehydrocyclisierungsreaktion verläuft.
    Abstract: Резюме В неизотермических у словиях проведено термогравиметричес кое разложение октамолибдата анили ния с целью выяснения химических реакций, протекающих на первой стадии разложения бе зводного соединения. Анализ продуктов разложени я проведен методом газо-жидкостной хром атографии, методом га зовая хроматография-масс-с пектрометрия, ИК спектроскопией и п орошковой рентгеног рафией. Основным продуктом р азложения анилина являлся индо л, тогда как при изотер мическом разложении-N-этилани лин. Для процесса обра зования индола предл ожена реакция дегидроцикл изации, которая возможно, вызвана кат алитическим действи ем октамолибдат-аниона.
    Notes: Abstract The thermogravimetric decomposition of anilinum octamolybdate has been studied under non-isothermal conditions to elucidate the chemical reactions taking place in the first step of decomposition of the anhydrous compound. The decomposition products were analyzed by gas-liquid chromatography, gas chromatography-mass spectrometry (GC/MS), infrared spectroscopy and X-ray powder diffraction. The main decomposition product of aniline turned out to be indole, which is different from the major product in the isothermal decomposition at the same temperature, i.e. N-ethyl-aniline. A dehydrocyclization reaction is suggested as the rate-dependent process. This is probably due to the catalytic effect of the octamolybdate anion.
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  • 20
    Electronic Resource
    Electronic Resource
    Springer
    Transition metal chemistry 9 (1984), S. 395-397 
    ISSN: 1572-901X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The kinetics of the anation reaction of [Co(NH3)5H2O]3+ by H3PO3/H2PO 3 − , to give [CoH2PO3(NH3)5]2+, have been studied at 60, 70 and 80°C, in the acidity range [H+](M)=1.5 · 10−1 −2.0 · 10−3. Only H2PO3 is found to be reactive. The rate data is consistent with an Id mechanism. The mean value of outer sphere association of [Co(NH3)H2O]3+ with H2PO 3 − is 1.5 M−1. Values of the interchange constants are: 1044ki(s−1)= 0.29, 1.47, 5.13, at 60, 70 and 80 °C respectively (ΔH≠= 1.4 · 102KJmol−1, ΔS≠=8.3 · 10 JK−1 mol−1). The first acidity constant of H3PO3 at I=1.0 has also been determined: 102Ka(M)=4.8, 5.2 and 5.5, at 25, 40 and 50 °C respectively.
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