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  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 141-146 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow of molten poly(ethylene terephthalate) in pipes is discussed. The considerations made are based on the results of previous investigations by the authors, concerning the rheological behavior of the melt which exhibits thermal degradation. A procedure is proposed which enables the design of a pipe-line system for the distribution of molten, spinnable poly(ethylene terephthalate) in a fiber plant to be made.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interactions between anions on one polymer chain with cations on another can lead to compatibilization of otherwise incompatible materials. Thus, if 5 mol% of ∼SO3H groups are attached to polystyrene, and 5 mol% of vinyl pyridine is copolymerized with ethyl acrylate, proton transfer occurs upon mixing, and the pairwise attractive interactions between the resultant ions compatibilize the blend. The same has been observed for the styrene-vinyl pyridine and sulfonated polyisoprene polymer pair. Dynamic mechanical and optical properties are used as a measure of compatibilization.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 22 (1982), S. 472-477 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The relations describing the elastic change of volume of thermoplastic cylindrical pressurized containers are presented. Discussions have been made on various cases including isotropic (i.e., un-oriented), uniaxially, and biaxially oriented materials. These relations are expected to be helpful for selecting the optimum processing conditions (i.e., draw ratio) in order to achieve the desired properties of polymeric pressurized containers.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Optimal temperature histories for the batch thermal polymerization of styrene are determined using Pontryagin's maximum principle. The theoretical predictions are compared with experimental measurements of conversion and molecular weight distribution. The excellent agreement suggests policy improvements in batch radical chain growth polymerizations.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A study was undertaken to determine the feasibility of using dielectric analysis as a means of monitoring and controlling cure of large closures during autoclave molding. In dielectric analysis, the dissipation factor (DF) and capacitance (C) of the sample are continuously monitored as a function of time, temperature, and frequency. Dissipation factor profiles were established for the suppliers' recommended cure cycle and for modified cure cycles, Good reproducibility was obtained in dissipation factor profiles on subsequent scaling up to production size (7 ft · 20 ft) autoclaves. Good correlation was also observed during production runs of fullscale closures. The effects of cure variables on the dissipation factor profiles and on the mechanical properties of the prepared laminates were analyzed for extent of correlation. Results of this study show: (1) dielectric analysis can be used to monitor autoclave cure of composites, and (2) within limits, process control may be feasible.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Publication Date: 2019-06-28
    Description: The whistler nozzle is a simple device which can induce jet self-excitations of controllable amplitudes and frequencies and appears highly promising for many applications involving turbulent transport, combustion and aerodynamic noise. The characteristics of this curious phenomenon are documented for different values of the controlling parameters and attempts to explain the phenomenon. It is shown that the whistler excitation results from the coupling of two independent resonance mechanisms: shear-layer tone resulting from the impingement of the pipe-exit shear layer on the collar lip, and organ-pipe resonance of the pipe-nozzle. The crucial role of the shear-layer tone in driving the organ-pipe resonance is proven by reproducing the event in pipe-ring and pipe-hole configurations in the absence of the collar. It is also shown that this phenomenon is the strongest when the self-excitation frequency matches the preferred mode of the jet.
    Keywords: ACOUSTICS
    Type: NASA-CR-170015 , NAS 1.26:170015 , FM-15
    Format: application/pdf
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