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  • ASTRONOMY  (234)
  • METEOROLOGY AND CLIMATOLOGY  (140)
  • Physics  (131)
  • 1995-1999
  • 1980-1984  (505)
  • 1982  (258)
  • 1981  (247)
Collection
Keywords
Publisher
Years
  • 1995-1999
  • 1980-1984  (505)
Year
  • 11
    Electronic Resource
    Electronic Resource
    Decomposition of polypropylene hydroperoxide by hindered aminesIssued as NRCC No. 19889. (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 575-582 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The hindered amine-induced decomposition of polypropylene hydroperoxide was studied in the solid state and in the presence of a liquid solvent and the polymer was compared with model hydroperoxides. The high reactivity of the macrohydroperoxides appears to be related to the adjacent, hydrogen-bonded hydroperoxide groups that occur in the polymer. The hindered amines are converted to nitroxides in the reaction via hydroxylamine intermediates. Amine-induced decomposition of polypropylene hydroperoxide is faster in the absence of a liquid solvent for the amine than in the presence of the solvent, probably because of the strong amine-hydroperoxide association that occurs in the solid state. The decomposition process in the solid state is sufficiently rapid for the reaction to contribute to the effectiveness of hindered amines in the light stabilization of polymers.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.170200231
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  • 12
    Electronic Resource
    Electronic Resource
    Photocrosslinking and thermal behavior of the polyesters containing conjugated diacetylenes (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 1155-1166 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of polyesters containing conjugated diacetylenic groups in the polymer backbone were synthesized by interfacial condensation of 3,5-hexadiyne-1,6-diol and diacid chlorides of succinic, glutaric, adipic, azealic, sebacic, terephthalic, and isophthalic acids. The polyesters were characterized by their infrared and ultraviolet absorption spectra, elemental analysis, and viscosity measurements. Powder x-ray patterns indicated high degress of crystallinity. The polyesters were found to be highly photoreactive. The relative photoreactivities of the polyester films were determined by the adhesion method. Only small differences in the reactivity have been observed despite structural changes in the R group in the polymer backbone. Differential thermal analysis behavior of all polymers in the temperature range ambient to 300°C and isothermal behavior of HGI at two different temperatures have been studied.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.170190512
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  • 13
    Electronic Resource
    Electronic Resource
    Morphology and structure of heavily deformed single crystals of a polydiacetylene. II. Resonance raman and optical spectroscopy (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 677-688 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Resonance Raman and optical spectroscopy have been used to study foils having a metallic appearance which were produced by the hammering or rolling of single crystals of toluene sulfonate diacetylene polymer. The spectroscopic properties of the bulk material in the foils were found to be almost indistinguishable from those of underformed crystals. In contrast, the blue-green surface skin of the foils appeared to consist of intact polymer chains without significant crystalline order.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190410
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  • 14
    Electronic Resource
    Electronic Resource
    Spectroscopic study of rigid-rod polymers. II. Protonation effect (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 509-521 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The protonation of a heterocyclic rigid-rod polymer poly(p-phenylene benzbisthiazole) and its model compound has been studied by UV-visible and Raman spectroscopy. Because of the two nitrogens on the heterocyclic ring, spectroscopic features of unprotonated, half-protonated, and fully protonated structures have been identified. For the fully protonated molecule, there is also an increase in conjugation between the phenyl ring and the heterocyclic ring.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.180200312
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  • 15
    Electronic Resource
    Electronic Resource
    Structure and morphology of heavily deformed single crystals of a polydiacetylene. I. Electron microscopy and x-ray diffraction (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 293-305 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The structure and morphology of heavily deformed single crystals of a diacetylene polymer have been studied using a combination of x-ray diffraction and electron microscopy. Crystals have been deformed by both rolling and hammering. The crystals remain intact during deformation and can be reduced in thickness by a factor of over 5 in directions perpendicular to their chain axes. It is found that the chain orientation is maintained during both hammering and rolling. A greenish-colored surface skin develops during both types of deformation but the structure of the interior of the crystals depends upon the type of deformation employed. The interior of the hammered crystals consists of crystal blocks ca. 50 μm thick formed by cleavage perpendicular to the chain direction whereas the rolled crystals tend to be fibrous with no evidence of molecular fracture. The possible deformation mechanisms which have given rise to the different structures have been discussed.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190210
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  • 16
    Electronic Resource
    Electronic Resource
    Mesomorphic solutions of cellulose triacetate in halogenated organic acids and mixtures of trifluoroacetic acid and dichloromethane (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1449-1460 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Cellulose triacetate (CTA) forms liquid-crystalline solutions in trifluoroacetic acid, dichloroacetic acid, and mixtures of trifluoroacetic acid and dichloromethane. Brilliant iridescent coloration, high optical rotations, and birefringent regions with swirl-like fingerprint patterns suggested the formation of cholesteric liquid crystals. Trifluoroacetic acid-dichloromethane is a particularly excellent solvent mixture to form liquid-crystal solutions of cellulose acetate. Crude bulk viscosity measurements confirm the formation of an anisotropic phase, and the temperature dependence of the critical concentration for formation of the anisotropic phase, obtained by bulk viscosity measurements at various temperatures, provides confirming evidence. Viscosity decreases with aging, suggesting that CTA is slowly degraded in the solvents studied. This is also confirmed by optical rotatory measurements and by polarizing microscope observations. The miscibility gap is observed as a function of molecular weight, and the differences between the experimental data and Flory's prediction are discussed.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190916
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  • 17
    Electronic Resource
    Electronic Resource
    Investigation of molecular order in liquid-crystalline solutions of cellulose triacetate using PMR spectroscopy (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1019-1028 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Liquid-crystalline solutions of cellulose triacetate (CTA) in trifluoroacetic acid (TFA)-CH2Cl2, TFA-1.2-dichloroethane (1,2-DCE) solvent mixtures were examined by means of PMR spectroscopy. CTA forms both cholesteric and nematic phases in these solvents depending on the CTA concentration. In cholesteric solutions the CH2Cl2 signal is initially a singlet and then splits into a doublet. The time dependence of the splitting and the effect of CTA concentration are reported. The results suggest that the cholesteric phase slowly changes into a nematic phase in the magnetic field. The splitting of the CH2Cl2 proton signal into a doublet and the 1,2-DCE signal into a quartet are due to direct magnetic dipole-dipole interactions. Rotation of the sample in the magnetic field results in the disappearance of the doublet or quartet and suggests that the solvent molecules are originally oriented in the direction of the magnetic field. In the biphasic region, immediate splitting of the CH2Cl2 proton signal suggests that the anisotropic phase is nematic.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.180200610
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  • 18
    Electronic Resource
    Electronic Resource
    Lyotropic mesomorphic formation of cellulose in trifluoroacetic acid-chlorinated-alkane solvent mixtures at room temperature (1981)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 19 (1981), S. 1231-1236 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Mixtures of trifluoroacetic acid (TFA)-1,2-dichloroethane (1,2-DCE); TFA-dichloromethane (CH2Cl2); and TFA-trichloromethane (CHCl3) are excellent cellulose solvents at room temperature. TFA-1,2-DCE and TFA-CH2Cl2 are superior to pure TFA. Lyotropic cellulose mesophases were obtained in (20% w/v) solutions of cellulose in these solvent mixtures. The optical and optical rotatory powers of the solutions suggest that the lyotropic mesophase of cellulose is cholesteric. This implies that cellulose molecules are arranged in helical form in these solvent systems.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1981.180190806
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  • 19
    Electronic Resource
    Electronic Resource
    Microphase separation in sulfonated polystyrene ionomers (1982)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 1503-1509 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Small- and wide-angle x-ray scattering results for a series of un-neutralized and neutralized sulfonated polystyrenes are presented for the range of sulfonation from 0 to 7.26 mol %. From the small-angle scattering it is shown that above the 3 mol % level for both the zinc and sodium salts, a Bragg spacing (37 Å) and diameter (6.9-8.4 Å) of the scattering unit can be calculated. When the concentration of salt is increased, there is no appreciable change in the latter two measurements. The wide-angle data indicate that the cations do not influence to any large extent the basic intramolecular and intermolecular structure of polystyrene. All the data are consistent with the onset of clustering above a critical ion concentration.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1982.180200815
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  • 20
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    The wide field/planetary camera (1982)
    In:  CASI
    Details
    Publication Date: 2006-02-14
    Description: A wide site of potential astronomical and solar system scientific studies using the wide field planetary camera on space telescope are described. The expected performance of the camera as it approaches final assembly and testing is also detailed.
    Keywords: ASTRONOMY
    Type: Space Telescope Science Inst. The Space Telescope Obs.; p 28-39
    Format: text
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    NASA TECHNICAL REPORTS
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