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  • Articles  (102)
  • Chemical Engineering  (60)
  • Inorganic Chemistry  (23)
  • Engineering  (19)
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  • 1975-1979  (102)
  • 1955-1959
  • 1979  (102)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1449-1460 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A numerical model is proposed to simulate the space-time behaviour of a low-density plasma in a linear multipole. Semi-discrete Galerkin techniques are used in conjunction with triangular finite elements. For both space and time discretizations, special techniques are developed to numerically separate the effect of rapid diffusion along the field lines from the slow perpendicular diffusion. Numerical results are exhibited to show how these techniques succeed in eliminating the problems caused by the strong anisotropy of the diffusion coefficient in the strongly curved and very inhomogeneous multipole configuration.
    Additional Material: 5 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1785-1804 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Several types of smoothing technique are considered which generate continuous approximation (i.e. nodal values) for vorticity and pressure from finite element solutions of the Navier-Stokes equations using quadrilateral elements. The simpler schemes are based on combinations of linear extrapolation and/or averaging algorithms which convert elementwise. Gauss point values to nodal point values. More complicated schemes, based on a global smoothing technique which employ the mass matrix (consistent or lumped), are also presented.An initial assessment of the accuracy of the several schemes is obtained by comparing the approximate vorticities with an analytical function. Next, qualitative vorticity comparisons are made from numerical solutions of the steady-state driven cavity problem. Finally, applications of smoothing techniques to discontinuous pressure fields are demonstrated.
    Additional Material: 14 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 759-762 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Calculation of the phase diagram for saturated aqueous multi-ion solutions of strong electrolytes, based upon use of the thermodynamic solubility products, is illustrated for the four-ion system: Na+, K+, Mg++, SO4=. Solid phases are identified along with the ion concentrations of the associated saturated solutions.
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 1046-1053 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The hot drawing of extruded composite sheets can be used to control the orientation of both matrix and reinforcing fibers. A study was made of the effect of draw ratio on the properties of an extruded polystyrene sheet containing 0 to 1 percent of short glass fibers. An increase in draw ratio resulted in an increase in fiber orientation. A model of a rigid fiber rotating in an elongational flow field was used to describe the effect of draw ratio on the final orientation distribution. An increase in draw ratio also caused an increase in the amount of fiber breakage. A shear-lag analysis was used to estimate the extent of damage as a function of draw ratio. It was also found that the mechanical properties were dependent upon both the draw ratio and fiber concentration.
    Additional Material: 14 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 19 (1979), S. 162-165 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The thermal and mechanical degradation of glassy polystyrene has been studied by Fourier Transform Infrared, FT-IR, spectroscopy. Using difference spectroscopy we have found that the products formed from these two modes of degradation were significantly different. This result is in contrast with other workers who found similar products for the thermal and mechanical degradation of polystyrene by mass spectroscopy. Our result suggests a reassessment of the thermal activation mechanism for mechanically-induced bond scission. We have also found that the distribution of oxidation products appears to depend upon the environment in which the polymer is mechanically degraded. Finally, we have demonstrated the utility of FT-IR spectroscopy for studying the mechanical degradation of polymers.
    Additional Material: 5 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 112 (1979), S. 2413-2418 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Molecular Structure of a Metal Cluster with Cubane Structure, [η5-C5H5Mo(CO)3HgMo]4(4)The compound [η5-C5H5Mo(CO)3HgMo]4 has been isolated as an additional product of the reaction between [η5-C5H5Mo(CO)3]2, 2-butenyl chloride, and sodium amalgam. The X-ray structure (R = 0·050) analysis of this novel species revealed that the compound has a slightly distorted cubane structure, for the first time the cubane unit being built up by two different metal atoms (Mo and Hg).
    Notes: Die Verbindung [η5-C5H5Mo(CO)3HgMo]4 (4) wurde als weiteres Produkt der Reaktion zwischen [η5-C5H5Mo(CO)3]2, 2-Butenylchlorid und Natriumamalgam isoliert. Die Röntgenstrukturanalyse dieser neuartigen Spezies zeigt eine leicht verzerrte Cubanstruktur, bei der das Cubangerüst erstmals aus zwei verschiedenen Metallatomen (Mo und Hg) aufgebaut ist. Der R-Wert beträgt 0·050.
    Additional Material: 1 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 81-102 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper considers the finite element analysis of the free, undamped and the forced damped vibrations of rotationally periodic structures. Associated with every natural frequency (except for those for which the deflection is the same at corresponding points on every substructure) there are a pair of orthogonal mode shapes, with eigenvectors {u} and {ü}. The complex vector {z}={u}+i{ü} is also an eigenvector of the equations of motion, and represents a rotating normal mode. The deflection of one substructure has the same amplitude as, and a constant phase difference from the deflection of the preceding substructure. It is therefore possible to analysse the complete structure by considering only one substructure, and applying appropriate complex constraints at its boundary with the following substructure, so as to and applying appropriate complex constrainsts at its boundary with the following substructure, so as to impose this phase difference. The method has been implemented in a computer program and is illustrated by analyses of an alternator end winding, a cooling tower with legs, and a wheel of turbine blades.For forced vibration, it is shown that any arbitrary oscillatory force can be decomposed into a series of rotating forces. For any one of these rotating components, there is a fixed relationship between the amplitude and phase of the force acting on one substructure, and that acting on an adjoining substructure. This relationship, which does not involve any approximation, can be used to enable a series of calculations of the response of one substructure to be performed instead of one on the whole structure. A series of calculations on an individual substructure normally requires much less computer time and storage than a single calculation on the complete structure.
    Additional Material: 5 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1141-1163 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper describes an explicit numerical method for solving transient combined heat conduction and convection problems. Applications include the cooling of many types of engineering plant; for example, stator and rotor windings of turbogenerators and high voltage underground cables. The Du Fort-Frankel and the fully implicit finite difference schemes have been used to solve the conduction and convection equations, respectively. It is shown that, with a suitable order of calculation, the overall method becomes explicit. Computational procedures are outlined and stability, accuracy and convergence are considered. Numerical examples are given to illustrate the use of the method and to validate some of the theoretical points. Results have also been obtained using existing numerical methods and have been compared with those from the proposed method. For certain problems, it is shown that the proposed method uses less overall computing time than other methods such as that devised by Crank and Nicolson.
    Additional Material: 6 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1359-1377 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: We introduce a finite element model for stress analysis of threaded connections. Instead of modelling individual threads, the thread zone is replaced by a layer of elements with orthotropic properties. The principal directions of orthotropy depend upon the thread geometry and upon the direction of load, which is not necessarily known a priori. Both conventional and tapered threads are considered. The latter problem is nonlinear, as the number of threads in contact is a function of the load. Numerical results for conventional and tapered threads agree well with theoretical and exeprimental results in the literature.
    Additional Material: 14 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 14 (1979), S. 1379-1398 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Orthogonal base functions that are complete first-order polynomials but contain higher order terms are developed for normalized rectangular and triangular elements. To obtain exact expressions for kinetic energy under rigid body rotation, an internal node is introduced at the centroid of each element. Then the corresponding mass matrix is both diagonal and consistent. A mixed variational formulation is used in the derivation of spatially discretized field equations. Central Difference time integration is utilized to provide sample results which are compared with other numerical or analytical solutions.
    Additional Material: 7 Ill.
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