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  • Wiley-Blackwell  (471)
  • Cambridge University Press  (162)
  • 1980-1984
  • 1975-1979  (633)
  • 1965-1969
  • 1977  (633)
Collection
Keywords
Publisher
Years
  • 1980-1984
  • 1975-1979  (633)
  • 1965-1969
Year
  • 1
    Electronic Resource
    Electronic Resource
    Evaluation of wound-covering materials (1977)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 11 (1977), S. 489-502 
    Details
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Physical and in vivo (burned rat model) evaluations as wound coverings were performed for 1) a freeze-dried collagen/poly (∊-caprolactone) (PCL) film laminate, 2) a freeze-dried PCL “foam”/PCL film laminate, and 3) a heat-dried collagen/PCL film laminate. Porcine skin and cadaver skin were also evalulated in vivo for the purpose of comparison. Water-vapor transmission rates and Young's moduli were measured. The degrees of adherence of the coverings to the wound were measured. Grafts which became significantly adherent (〉150 dyne/cm2) to the wound within 1 day were most successful in promoting the formation of a viable tissue bed which appeared ready to accept further grafting. The force required to remove the PCL foam laminate from a full-thickness excision wound was found to increase from 170 dyne/cm2 on the first day postgraft to 1500 dyne/cm2 by the tenth day. The force required to remove freeze-dried collagen laminate remained constant at 200 dyne/cm2 over the 10 day test period. For the heat-dried collagen laminate, a force of only 50 dyne/cm2 was required on day 1, increasing to 200 dyne/cm2 on day 6. Insensible water-loss rates of animals grafted with the laminates were found to be similar to those from animals with human cadaver skin grafts and less than that from animals with porcine skin grafts. When moistened, the laminates prepared using the freeze-dried materials were flexible and somewhat transparent permitting observation of the wound.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jbm.820110405
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  • 2
    Electronic Resource
    Electronic Resource
    D2-m-carborane-siloxanes. III. Preparation and properties of trifluoropropyl-modified polymers (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 973-981 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Linear D2-m-carborane-siloxanes with one, two, and three trifluoropropyl moieties per repeat unit were prepared by the condensation reaction between bisureidosilanes and carborane disilanol. Molecular weights between 100,000 and 220,000 were obtained. Compared to fluorosilicones, the trifluoropropyl-modified carborane-siloxanes exhibited greater thermal and oxidative stability and in certain cases comparable solvent resistance. The swelling index for carborane-siloxane elastomers decreased with increasing trifluoropropyl content, although this fluorocarbon moiety did compromise the thermal stability of the carborane system.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150418
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  • 3
    Electronic Resource
    Electronic Resource
    Photoinitiation and electroinitiation in the polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 2673-2684 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The zinc chloride-catalyzed polymerization of 2-vinylnaphthalene (VN) with both photoinitiation and electronitiation methods was examined. Good yields were obtained with both methods, the electroinitiated process being somewhat faster. The mechanism for polymerization initiation was investigated through a detailed comparison of the kinetics. Both initiation methods show a similar response to increasing input energy and to change in salt to monomer mole ratio. Both methods indicate formation of a ZnCl2-(2-VN)2 complex as intermediate with the formation of the species being rate-determining. These results, together with other similar investigations, are then used to deduce a mechanism that involves the formation of an electronically excited donor-acceptor complex. It is argued that in certain salt-stabilized, electron-delocalized, aromatic systems, such excitation is possible in electroinitiation.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170151112
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  • 4
    Electronic Resource
    Electronic Resource
    Electroinitiated polymerization of 2-vinylnaphthalene (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1563-1571 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As part of a program to extend the range of donor-acceptor-initiated polymerization processes, the electroinitiation of 2-vinylnaphthalene in a zinc chloride-sulfolane solution has been studied. Good conversion yields of well-characterized (NMR, IR, GPC, elemental analysis) poly(vinylnaphthalene) were obtained with the process showing several mechanistic similarities to other donor-acceptor salt electropolymerization systems.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150704
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  • 5
    Electronic Resource
    Electronic Resource
    Electrochemically initiated polymerization of styrene with tetraalkyl and -aryl group VA halide support electrolytes (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 15 (1977), S. 1555-1562 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The electrochemically initiated polymerization of styrene in methylene chloride solvent with the use of platinum electrodes and tetraalkyl and -aryl group VA halides (i.e., quaternary ammonium, phosphonium, and arsonium compounds) as electrolyte has been investigated. The order of reactivity of the electrolytes with respect to polymerization rate and initiation efficiency was found to be: arsonium 〉 phosphonium 〉 ammonium. Mechanisms involving the electroreduction of the group VA quaternary halides to species capable of electroinitiating polymerization are postulated. The observed losses in solution conductivities during polymerization with the quaternary phosphonium and arsonium electrolytes indicate possible interaction between the initiating radical-ionic species and the supporting electrolyte. In an attempt to further elucidate the mechanism of initiation in these systems, a separate series of experiments, employing the nonpolymerizing monomer, 1,1-diphenylethylene, has been carried out.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.170150703
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  • 6
    Electronic Resource
    Electronic Resource
    Ionic and zwitterionic polymerization of n-alkyl 2-cyanoacrylates (1977)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 15 (1977), S. 399-405 
    Details
    ISSN: 0360-6384
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1977.130150703
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  • 7
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    Insulin-secreting ability in Pietrain and Large White pigs (1977)
    Cambridge University Press
    Details
    Publication Date: 1977-10-01
    Description: summaryMesomorphic, stress-sensitive Pietrain pigs were found to have a lower insulin secretory response to intravenous tolbutamide, glucose and arginine, when compared with ectomorphic, stress-resistant Large White pigs. Pietrain pigs have also been observed to be insulin-insensitive in comparison with Large White pigs. The combination of a low production of and low sensitivity to insulin in the Pietrain breed could account for their enhanced sensitivity to lipolytic agents and for their reduced ability to deposit body fat.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Cambridge University Press
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  • 8
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    Effects of NaCl and NaHCO3 on food intake, growth rate and acid-base balance in calves (1977)
    Cambridge University Press
    Details
    Publication Date: 1977-02-01
    Description: SUMMARYCalves were reared on milk replacer up to 5 weeks of age and given ad libitum access to pellets and chopped straw from 1 to 10 weeks of age. Major ingredients of the pellets were ground barley (B) or ground barley and grass meal in a 6:4 ratio (G). Included in these two basal diets were NaCl or NaHCO3, each at 2, 11, 20 or 29 g Na/kg D.M.Calves on G diets ate more than those on B diets but grew at a similar rate. The replacement value of grass meal for ground barley was 1·36:1. Most responses to Na inclusions were unaffected by the basal diets.Before weaning there were linear increases in food intake and growth rate related to Na level in the diet. At 29 g Na/kg D.M., total D.M. intake/kg0.75 and growth rate were respectively 31 and 23% greater than at 2 g Na/kg D.M. After weaning there were differential responses to the two salts. With NaHC03 there were linear increases in food intake and growth rate up to 20 g Na/kg D.M., at which level total D.M. intake/kg0.75 and growth rate were respectively 36 and 44% greater than at 2 g Na/kg D.M. With NaCl the only significant response was that total D.M. intake at 11 g Na/kg D.M. was 16% higher than at 2 g Na/kg D.M.Observations on acid-base balance and water intake indicated that inclusions of NaCl or NaHCO3 up to 20 g Na/kg D.M. were well tolerated by calves. Above this level there was a sharp increase in water intake, and with NaHCO3 there was a large base excess and high pH in the blood.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Cambridge University Press
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  • 9
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    The digestion by sheep of silages made with and without the addition of formaldehyde (1977)
    Cambridge University Press
    Details
    Publication Date: 1977-02-01
    Description: SUMMARYS.24 perennial ryegrass was conserved by ensiling directly (control) and after treatment with a solution of formaldehyde at the rate of 6 g HCHO/100 g crude protein. After storage for 90 days, part of the formaldehyde-treated silage was dried in a high-temperature drier.The quantitative digestion of the energy, carbohydrate and nitrogen moieties of the three diets and the production of volatile fatty acids and microbial protein within the rumen were measured using five sheep fitted with re-entrant cannulae at the proximal duodenum and terminal ileum.Treatment with formaldehyde depressed organic matter and energy digestion within the rumen compared with untreated silage (P 〈 0·001) and a further depression was observed on the dehydrated material. Both formaldehyde-treated silages showed enhanced flows of total amino acids into the small intestine compared with the control silage and net absorption from the small intestine was elevated by 13 and 21% respectively on these two diets. On the untreated silage over 71% of the protein entering the small intestine was microbial in origin whereas, due to depressed microbial growth and increased protection of feed protein from rumen fermentation, microbial protein comprised only 17% of duodenal protein on the two formaldehyde-treated silage diets. Fifteen and 81 % of the dietary protein passed undegraded through the stomachs to the duodenum on the control and the two formaldehyde-treated silage diets respectively.Total VFA production within the rumen was not significantly influenced by the treatments imposed, but on the untreated silage only 56% of the energy apparently digested in the rumen was converted to VTA energy whilst a mean value of 74% was recorded on the other two diets.Estimates of the total energy absorbed gave values of 10·6, 11·9 and 10·7 MJ/kg D.M. for the control, formaldehyde and dried, formaldehyde silage diets with absorbed protein energy representing 21, 22 and 26% of the total absorbed energy respectively.
    Print ISSN: 0021-8596
    Electronic ISSN: 1469-5146
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Published by Cambridge University Press
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  • 10
    Electronic Resource
    Electronic Resource
    Quantitative electron microscope observations of the collagen fibrils in rat-tail tendon (1977)
    New York : Wiley-Blackwell
    Biopolymers 16 (1977), S. 1015-1031 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An electron microscope study of collagen fibrils from fixed tail tendons of rats has revealed that from some time shortly after birth until maturity, the fibril diameters have a bimodal distribution. The “two” types of fibril are indistinguishable in both transverse and longitudinal section. Unfixed specimens of eight-week-old-tail tendon showed a similar bimodal distribution of diameters though the positions of the peak values compared to fixed specimens of an eight-week-old-tail tendon were shifted upwards by about 30%. It has also been shown quantitatively that the polar collagen fibrils are directed randomly “up” and “down” with respect to their neighbors. Whilst it has been suggested by others that anastomosis is a feature of collagen structure, the results presented here do not support this hypothesis. Fibrillar units ∼ 140 Å in diameter have been observed and the possibilities that these are elastic fibers or the breakdown products of collagen fibrils have been considered.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.1977.360160506
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