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  • Polymer and Materials Science  (119)
  • Analytical Chemistry and Spectroscopy  (68)
  • AERODYNAMICS  (43)
  • SPACECRAFT DESIGN, TESTING AND PERFORMANCE
  • 2020-2024
  • 1975-1979  (245)
  • 1977  (245)
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  • 2020-2024
  • 1975-1979  (245)
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  • 1
    Publikationsdatum: 2019-06-27
    Beschreibung: A preliminary assessment of possible means for improving the low speed aerodynamic characteristics of advanced supersonic cruise arrow wing configurations and to extend the existing data base of such configurations has been made. Principle configuration variables included wing-leading and trailing-edge flap deflection, fuselage nose strakes, and engine exhaust nozzle deflection. Results showed that deflecting the wing leading edge apex flaps downward provided improved longitudinal stability but resulted in reduced directional stability. The model exhibited relatively low values of directional stability over the operational angle of attack range and experienced large asymmetric yawing moments at high angles of attack. The use of nose strakes was found to be effective in increasing the directional stability and eliminating the asymmetric yawing moment.
    Schlagwort(e): AERODYNAMICS
    Materialart: NASA-TM-74043
    Format: application/pdf
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 28 (1977), S. 809-816 
    ISSN: 0947-5117
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Maschinenbau
    Beschreibung / Inhaltsverzeichnis: Pitting corrosion susceptibility of the heat treatable steel X20Cr13 in sodium chloride solutionsFor blades in steam trubines it is common to use the heat-treatable steels with 13% Cr (X20Cr13). Cracking of blades in the region of the turbine, where the steam starts to get wet, have often been referred to be caused by corrosion fatigue. The fatigue cracks sometimes start at inclusions in the material, but more often at pits caused by pitting corrosion. Pitting is brought about by chloride containing blade deposits. To examine the pitting behaviour of the steel in NaCl-solutions we measured the mixed-potential, the potentiostatic piting potential, the mass-loss and the pits per area as depending on temperature (20-80°C), pH (5-7-9), oxygen content (20 μg/kg up to saturation with oxygen) and chloride content (8×10-5 mole/l up to saturation with NaCl 5,4 mole/l). The results show that steel X20Cr13 suffers pitting corrosion because of it's low Cr content in all technical possible NaCl solutions down to a Cl content of 10-5 mole/l at the mixed potential.
    Notizen: Als schaufelwerkstoff für Dampfturbinen wendet man überwiegend Vergütungsstähle mit 13% Cr (X 20 Cr 13) an. Schaufelbrüche im Gebiet beginnender Dampfnässe der Turbine ließen sich häufig auf Schwingungsrißkorrosion zurückführe, die ihren Ausgang von Werkstoffinhomogenitäten, im allgemeinen jedoch von durch Lochkorrosion entstandenen löchern nahm. Ursache der Lochkorrosion sind festgestellte chloridhaltige Schaufelbeläge. Um das Lochkorrosionsverhalten dieses Stahles zu untersuchen, wurden in Natriumchlloridlösungen das Ruhe- und Lochkorrosionspotential, Massenverlust und Lochzahldichte und das Redoxpotential der Lösungen in Abhängigkeit von der temperatur (20-80°C), pH-Wert (5-7-9), Sauerstoffgehalt (20 μg/l bis sauerstoffgesättigt) und Chloridkonzentration (8 × 10-5 m/l bis 5,4 m/l (ges.)) bestimmt. Es ergab sich, daß der Stahl X20Cr13 wegen seiner nur gering ausgeprägten Passivität in praktisch allen technisch möglichen chloridhaltigen Elektrolyten bis hinab zu 10-5m/l Cl anfällig gegen Lochkorrosion ist.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 1052-9306
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The antitumour agent cyclophosphamide - {2-[bis(2-chloroethyl)amino]-tetrahydro-2H -1,3,2-oxaza-phosphorine 2-oxide} - is chiral owing to asymmetry at phosphorus. The differential metabolism of the enantiomers [(+)-cyclophosphamide and (-)-cyclophosphamide] can be monitored by mass spectrometry if pseudoracemates consisting of either unlabelled [2H0] (+)- and tetradeuterated [2H4] (-)-cyclophosphamide or of [2H0](-) and [2H4](+) enantiomers are administered. Using this principle, methodology has been developed for determining the enantiomer ratios of cyclophosphamide and two metabolites, 4-ketocyclophosphamide {2-[bis(2-chloroethyl)amino] tetrahydro-2H-1,3,2-oxazaphosphorin-4-one 2-oxide} and carboxyphosphamide [2-carboxyethyl N,N-bis(2-chloroethyl)phosphorodiamidate] recovered from the urine of mice. The drug and the two metabolites were quantified using [2H10]cyclophosphamide, 4-keto-[2H8]cyclophosphamide and [2H6]carboxyphosphamide respectively, as internal standards. The amount of cyclophosphamide excreted was small and neither enantiomer preponderated markedly, but the minor metabolite, 4-ketocyclophosphamide, was markedly depleted in the enantiomer derived from (-)-cyclophosphamide, whereas the major metabolite, carboxyphosphamide, was slightly depleted in the enantiomer derived from (+)-cyclophosphamide.
    Zusätzliches Material: 2 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 1383-1394 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The preparation and properties of sodium carbonate and sodium hydroxide-catalyzed phenolic resins polymerized in 1-liter glass reactors over a broad range of F/P mole ratios are described. Laminates produced from selected sodium carbonate-catalyzed resins coated on kraft paper are discussed and compared with laminates prepared from standard sodium hydroxide-catalyzed resins. Several apparent advantages of the sodium carbonate-catalyzed resin systems over the sodium hydroxide-catalyzed resins are presented. The superior performance is attributed to the high degree of crosslinking resulting from the high concentration of methylolated phenols present in the sodium carbonate-catalyzed resin.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 1267-1272 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A method of multipeak resolution and computation of background scatter in x-ray diffraction from fiber has been applied to jute fibers. While crystallinity as determined by this method in raw and delignified jute fibers remains unchanged, perfection of the crystalline regions improves on delignification.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 11 (1977), S. 811-838 
    ISSN: 0021-9304
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: The present status of skeletal fixation of permanent orthopedic implants by poly(methyl methacrylate) (PMMA) is discussed. It is proposed that alternatives to the acrylic cement can improve the skeletal fixation. The present paper is concerned with the fixation method by bone ingrowth into pores of the implant surface.Two different implantation models have been designed to investigate the influence of load bearing upon ingrowth in surface pores of the implant: intramedullary nails as a means of fixation of a femoral pseudarthrosis and hinged knee prostheses. In each animal, implants with identical material characteristics (pore size, density, and thickness of the porous layer) but different loading conditions were used: one implant was “statically” loaded, the other “dynamically.” This procedure allows the evaluation of ingrowth with regard to load bearing only.Two different mean pore sizes, viz., 87 and 110 μm, have been used with the two models. After an 8 week implantation period, bone ingrowth was evident for the statically loaded implants. Calcified tissue ingrowth was, however, not observed in the dynamically loaded implants. The discrepancy in bone ingrowth behavior between the statically and the dynamically loaded implants has been attributed to 1) the gross movement or the micromovement existing at the bone prosthesis interface and 2) the fact that the critical mean pore size for ingrowth with static loading is smaller than the one with dynamic loading.The experimental implantations allow still another conclusion: the results suggest that designs of present clinical prostheses fixed by bone cement cannot be used with the alternative fixation by bone ingrowth unless the deisgn has been changed in a fundamental way. Mechanical factors as well as the phenomenology of bone ingrowth fixation account for this conclusion.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 15 (1977), S. 379-384 
    ISSN: 0098-1273
    Schlagwort(e): Physics ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The photoelectret charge in the aluminum-poly(vinylcarbazole) (PVK) conducting-glass (NESA), sandwich cell configuration has been observed to decrease with voltage above some critical voltage, depending on the intensity of illumination. This critical voltage corresponds to the value at which a time-independent photocurrent is observed and also to the “knee-point” voltage in the current voltage plot. The results are explained on the basis of field-assisted detrapping setting in at high field.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The determination and complete assignment of the 13C—19F coupling constants and 13C chemical shifts for 15 monofluoro derivatives of nine polycyclic aromatic hydrocarbons are reported. Fluorine substitutent effects on the 13C chemical shifts are given and their regular behaviour, making comparisons between different compounds possible, is discussed. The numerical values of the 13C—19F long range coupling constants are found, with a few exceptions, to decrease in an alternating manner along the periphery of the molecules. In several cases the signs of the coupling constants have been determined. It appears that the signs alternate, but additional evidence is required. The magnitudes of different types of coupling constants are discussed in terms of steric and electronic effects. CNDO/2 and INDO calculations of the 13C—19F coupling constants in the fluoronaphthalenes have been performed using the ‘sum-over-states’ method with the aim of examining the orbital and spin-dipole contributions to the various couplings.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    ISSN: 0030-4921
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The vanadium IV ion in vanadyl acetylacetonate (VIV) forms labile paramagnetic complexes with organic phosphites in the first coordination sphere. The enthalpy of complex formation between VIV and triphenyl phosphite was 2.6 kcal mol-1. Complex formation enthalpies ΔH and the activation energies E of ligand (hydroperoxide) escape from the metal ion sphere were determined from the temperature dependence of paramagnetic broadening of the n.m.r. lines of hydroperoxides in the presence of vanadyl acetylacetonate. At low temperatures the phosphite sharply weakens the bond between the metal ion and hydroperoxide in the second coordination sphere (ΔH decreases fivefold). Taken in excess, phosphite displaces the hydroperoxide molecules from the coordination sphere of the VIV ion and thus blocks it. The observed n.m.r. characteristics of the paramagnetic complexes explain, on the model level, the kinetic regularities of the reaction of hydroperoxides with phosphite catalysed by transient metal ions.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Propellants, Explosives, Pyrotechnics 2 (1977), S. 81-84 
    ISSN: 0721-3115
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: An improved gas comparison pycnometer has been developed, based on precise differential pressure measurements coupled with a sample volume compensator. Using helium gas, volumes of solid and powdered explosives can be measured to a precision approaching one part in lo4. Coupled with a precise mass measurement, these volumes allow densities with an uncertainty of ∼± 0.002 g/ml to be inferred. Measurements performed on various explosives have allowed assessment of the purity and homogeneity of individual samples. It is also possible to infer void percentage or porosity in pressed explosive pellets.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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