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  • Chemical Engineering  (76)
  • 1980-1984
  • 1975-1979  (76)
  • 1935-1939
  • 1979  (39)
  • 1975  (37)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 200-202 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 773-781 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A series of seven coals of different ranks and from various locations were heated in air under relatively mild conditions to measure the rates of oxidation and the production of carbonic gases in the effluent stream. The gas flow rate, coal particle size, and reactor temperature were changed as independent variables. Each sample was exposed for from 6 to 9 hr under atmospheric pressure at temperatures in the range of 200° to 250°C. The results show two kinds of rate behavior depending primarily on the relative porosity of the coal under study. The small pore coals followed the expectations of the earlier Kam-Hixson-Perlmutter (KHP) model, but the large pore coals gave rates sensitive to transport effects. Correlations were also obtained on the ratio of carbon dioxide and carbon monoxide produced and on the relationship between the carbon content of an exposed coal and its heating value.
    Additional Material: 19 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 1210-1213 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 298-306 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A population balance approach is used to model solid phase reactions in terms of nuclei of the product phase dispersed in the reactant matrix. A conversion-time relationship is obtained by the solution of a set of moment equations derived from the population balance. Some previously known solutions for both homogeneous and heterogeneous nucleation are developed by this approach to demonstrate the relative ease of solution when compared with previously used integral techniques. A model for nucleus impingement at low conversions is formulated and applied to published data on the oxidation of cuprous iodide to illustrate the practical use of this technique. The classical Avrami model (Avrami, 1939, 1940, 1941) is modified to include the initial volume of a nucleus, and it is shown that insensitivities in the original model are removed by this improvement. The need for direct measurements of nucleation and growth rates is emphasized.
    Additional Material: 3 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 15 (1975), S. 70-72 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A crosslinked polybutadiene containing a cyclic depsipeptide (Valinomycin) has been synthesized in which there is some possibility of threading to produce a catenated structure (polymeric catenane). Unthreaded rings were removed by extraction with toluene. An elemental analysis indicated the yield of threaded rings to be greater than the calculated expected yield. The total amount of threaded Valinomycin present was 0.37 percent. The rings showed no effect on the calorimetric glass transition temperature, but did result in an increase in the tensile modulus.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 160-167 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liquid membranes containing a macrocyclic polyether can move or pump a specific cation against its concentration gradient. The cation flux is not proportional to the difference of the cation concentration but to the difference of the product of cation and anion concentrations across the membrane. The results are inconsistent with existing theories of ion transport, but can be explained in terms of ion pairs.
    Additional Material: 7 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 184-187 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 4 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 507-510 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: An expression has been derived for predicting the penetration depth of vertical jets into fluidized beds based on the experimental observations of several workers. The expression correlates a wide range of data with reasonable accuracy and is suggested as a useful working equation for design purposes.
    Additional Material: 3 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 501-506 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The concept of the effectiveness, factor, commonly used as a means of accounting for diffusional effects in gas-solid catalytic and noncatalytic reactions, is extended to gas-liquid reactions. The relevant differential equations for an isothermal system with appropriate boundary conditions are solved for the case of (1) a simple first-order irreversible reaction, (2) a consecutive reaction, and (3) a parallel reaction. The results are presented in terms of effectiveness factor plots, and methods of delineating the controlling regimes are discussed. It is shown that gas-liquid reactions represent perhaps the most general case which reduces to gas-solid reactions under appropriate limiting conditions.
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 25 (1979), S. 160-170 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The feasibility of new solid/liquid separation processes, such as solids removal from oil and certain tertiary oil recovery techniques, can be evaluated by a thermodynamic stability analysis of possible liquid-liquid-particle configurations. The thermodynamic stability and hence feasibility of two possible liquid-liquid-particle separation process is predicted by use of a free energy analysis. Stability is shown to depend primarily on droplet/particle size ratio (n) and three phase contact angle (θ). Stability criteria are presented which can be applied to many particle and liquid separation processes.
    Additional Material: 10 Ill.
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