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  • Polymer and Materials Science  (2)
  • 2000-2004
  • 1980-1984
  • 1970-1974
  • 1965-1969  (2)
  • 1930-1934
  • 1965  (2)
Collection
Publisher
Years
  • 2000-2004
  • 1980-1984
  • 1970-1974
  • 1965-1969  (2)
  • 1930-1934
Year
  • 1
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of cooling, nucleation, and spherulitic growth rates on the properties of polypropylene is discussed briefly. A differential thermal analysis technique is described for evaluating the relative extent of heterogeneous nucleation that occurs in a particular polypropylene composition. The method is based upon a nucleating agent's ability to reduce the relatively large amount of supercooling that occurs upon crystallization of polypropylene. Compounds are shown to vary widely in their effectiveness as heterogeneous nucleating agents in polypropylene. The relationships between the degree of supercooling of a particular polypropylene composition and its relative clarity, tensile properties, density, and morphology are shown.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 3 (1965), S. 457-468 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: This paper describes some of the aspects of the thermal oxidation of deuterated isotactic polypropylenes. Several polymers of propylene, deuterated at different sites along the polymer chain, were subjected to a kinetic treatment designed to establish the comparative rates of oxidation at different temperatures. Infrared spectroscopy was used to follow the kinetics over the temperature interval 100-130°C. These experiments have shown the existence of a deuterium isotope effect for the thermal oxidation of polypropylene.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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