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  • Polymer and Materials Science  (123)
  • AIRCRAFT
  • 1980-1984
  • 1960-1964  (130)
  • 1962  (79)
  • 1961  (51)
Collection
Publisher
Years
  • 1980-1984
  • 1960-1964  (130)
Year
  • 1
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Investigations of the viscoelastic aspects of the mechanical behavior of polymers have been limited almost exclusively to relatively simple conditions of homogeneous stress, that is, to tension or shear loadings. In the present work a study has been made from the viscoelastic standpoint of the response of several elastomers to a much more complex type of stress distribution arising from penetration up to failure by a cylindrical indentor for a range of temperatures and rates of penetration. The failure or “puncture point” was determined by a dip in the recorded curve of load versus depth of penetration. The puncture strength values were reduced to 25°C. by applying the ratio of absolute temperatures and plotted against the logarithm of the reciprocal of the rate of penetration. These curves were then shifted on the time scale to give a master curve after the manner of Tobolsky and of Ferry. The logarithms of the shift factors thus obtained were related to the reciprocal of the absolute temperature over the range studied. The results indicate a broader generality for the viscoelastic principle of time-temperature equivalence than has usually been supposed.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 5 (1961), S. 527-533 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A system is described for automatic collection of stress-strain data for polymeric films on magnetic tape for subsequent automatic data reduction and computation of a variety of stress-strain parameters. Two shaft analog-to-digital encoders attached to a conventional tensile tester feed digital information to an incremental pulse recorder which stores all stress and strain data in two channels on 0.625-in. magnetic tape. Specimen information and test constants are inserted by the operator through a keyboard located at the tensile tester. The tape is subsequently fed into a standard digital computer through a special incremental pulse magnetic tape reader. The data pulses are internally stored and converted by means of a special program into eight significant stress-strain parameters for polymeric film samples, plus averages and standard deviations for groups of replicate determinations. These parameters include: corrected length of specimen, initial maximum tensile modulus, offset yield stress, strain at break, strain at maximum stress, maximum tensile stress, tensile stress at break, and work to break. While the program described applies to polymer film testing, both it and the digital recording equipment accessories are applicable with suitable modification, to any analog experimental data. Significant savings in man-hours and increased information output result from use of this system.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 6 (1962), S. S46 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 1 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 51 (1961), S. 527-539 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Through x-ray and infrared examinations of stereoregular polymers and copolymers of vinylaromatic monomers, the occurrence of chain isomorphism phenomena, together with many cases of a new type of isomorphism between monomeric units, have been proved. Isomorphism of macromolecules, allowing true solid solutions, has been observed when melting and crystallizing mixtures of homopolymers (i.e., isotactic polystyrene) and of crystalline copolymers (i.e., styrene-p-methylstyrene) having the same identity period and differing very little in lattice constants. Isomorphism among monomeric units occurs in copolymerizing monomers that have a chemical nature and shape slightly different one from the other, e.g., styrene and o-fluorostyrene. This allows the formation of crystallizable copolymers in the entire composition range. They show physical properties (lattice constants, melting temperatures, etc.) continuously varying between those of the pure homopolymers. The occurrence of isodimorphism phenomena has been observed in crystalline copolymers obtained from monomers the homopolymers of which have different crystalline structures (e.g., styrene-p-fluorostyrene), and also in copolymerizing styrene with monomers (e.g., p-methyl, p-chlorostyrene) giving only amorphous homopolymers. In the latter case, of course, the copolymers show crystallinity only in a limited composition range.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 58 (1962), S. 869-880 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The polymerization of acrylonitrile initiated by diethyl sodiomalonate in dimethylformamide has been investigated. The degree of polymerization was found to be independent of the monomer conversion but was dependent on the extent of polymerization. The polymers produced were examined for functional groups by infrared spectroscopy. An anionic mechanism involving hydride ion transfer to monomer has been suggested. The kinetics of the reaction can be followed because of the slow initiation step and are found to be governed by the rate expression -d[M]/dt = k[M]2[C]. The decrease in DP with increasing conversion is due to degradation of the polyacrylonitrile by basic ions. The ratios of the rate constants for both the monomer and polymer transfer reactions to the rate constant for propagation have been determined. The coloration of the polymers appears independent of the degradation reaction.
    Additional Material: 1 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 49 (1961), S. 533-541 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The preparation of a completely isopropylated polystyrene by polymerization of p-isopropylstyrene monomer is described. This polymer was autoxidized in cyclohexane with lauroyl peroxide to give a material of good reproducibility and high purity. Methyl methacrylate was successfully grafted to the polymeric hydroperoxide by using a sugar-containing recipe. Homopolymer was separated from the graft copolymer by extraction. Evidence for grafting was obtained from solubility and fractionation behavior, as well as from light-scattering and viscosity measurements.
    Additional Material: 5 Ill.
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  • 7
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 1 Ill.
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  • 8
    Publication Date: 2019-05-11
    Description: Project fire - space and reentry vehicle static stability
    Keywords: AIRCRAFT
    Type: NASA-TN-D-1497
    Format: application/pdf
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  • 9
    Publication Date: 2019-05-29
    Description: Aerodynamic heating analysis of X-15 aircraft in flight
    Keywords: AIRCRAFT
    Type: NASA-TM-X-638
    Format: application/pdf
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  • 10
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The cellulose of cotton yarns was reacted with acrylonitrile under conditions preventing their longitudinal contraction. Changes taking place in the fine structure of the fiber were studied by means of optical microscopy, density measurements, x-ray diffraction, and thermal stress behavior measurements. The results indicate that in spite of the strong tensions developed in the yarns, the reaction proceeds in both the accessible and the crystalline regions with considerable volume expansion and eventual disappearance of crystalline structure. Suggestions of a glass transition temperature appear at substitutions slightly above D.S. = 1. Annealing becomes possible at substitutions above D.S. = 2 with the development of the cyanoethyl cellulose crystal structure and over 40% increase in tensile strength. Changes in tenacity, ultimate elongation, energy of rupture, and immediate elastic recovery were also observed.
    Additional Material: 6 Ill.
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