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  • Articles  (13)
  • Polymer and Materials Science  (13)
  • Biochemistry and Biotechnology
  • 1980-1984  (13)
  • 1960-1964
  • 1983  (6)
  • 1981  (4)
  • 1980  (3)
  • 1960
  • Architecture, Civil Engineering, Surveying  (13)
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  • Articles  (13)
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  • 1980-1984  (13)
  • 1960-1964
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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 79-88 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: There are two major fire processes, an understanding of which is essential for effective fire safety design: (1) the conditions under which a combustible material may become involved in flaming combustion, and (2) the rate at which such a material, once involved, will provide an output of heat, smoke, toxic gases, etc., which can endanger people and property. The first process may be regarded as covering both ignition and spread of fire on materials; its complement is the way in which fire may become extinguished. It is necessary for such processes to bring in a characteristic of the basic combustion reaction which, directly or indirectly, expresses the reactivity of the combustion process. Thus pilot ignition is usually associated with an approximate surface fuel temperature. More basically, it is associated with a critical flow rate of volatiles and a critical heat loss from the flame, the latter being influenced by ambient oxygen and temperatures conditions as well as heat lost and gained by the fuel itself. The most important factor governing the production of dangerous product is the rate at which volatiles first (fuel controlled fires) and later air (air controlled fires) are fed into the flames. The reactivity is of less importance, although it may be one of the factors which control combustion efficiency. In general, the more efficient is the combustion the more heat is produced, but the less smoke and toxic gases are produced. Some of the main advances in the above areas are reviewed in this paper.
    Additional Material: 2 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 185-192 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Detailed quantitative studies are reported on the kinetics of acetonitrile pyrolysis using an isothermal quartz tubular flow reactor at 720-1033 K and 1 atm. Pressure using flow rates, in nitrogen, of 2-200 ml min-1. The pyrolysis of several other nitriles (acrylonitrile, propionitrile, methacrylonitrile and benzonitrile) has also been investigated qualitatively by pyrolysis-gas chromatography.
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 177-178 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 175-176 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 1 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 5 (1981), S. 180-181 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 150-156 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A device constructed and used to determine the flammability limits of pyrolysate-air mixtures as a function of percentage weight loss on pyrolysis has been employed to investigate the pyrolysate gases generated from poly (ethylene terephthalate) both in the presence and absence of chemical flame retardants. The chemicals tripropyl phosphate (TPP), dibromopropanol (DBP) and tris (2, 3 dibromopropyl) phosphate (TRIS) all influenced both the lower and upper flammability limits, with the largest effects being obtained when both phosphorus and bromine were present, followed by bromine only and then phosphorus only. The results indicate TPP has negligible condensed phase activity with only small gas phase action. DBP has no condensed phase activity but is a very active gas phase inhibitor. In contrast, TRIS has a detrimental effect upon the condensed phase reactions in that it is responsible for the formation of a more flammable pyrolysate gas mixture. Fortunately, its gas phase inhibition reaction is capable of reducing the overall flammability.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 216-218 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Additional Material: 6 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 28-36 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper deals with legislation enacted in the United Kingdom for the control of the hazard form fire in buildings of public resort such as hotels, boarding houses, factories, offices and shops as well as domestic dwellings. It gives background to why the various Acts were deemed necessary, why subsequent Regulations under the Acts were introduced, an impression on the effect their enforcement has had and an introduction into what is envisaged for the future. The legislation is not the product of any one Government department nor is it enforced by any single agency. Much of it is enforced by local authority fire brigade fire prevention departments and other sections by local authority Building Control Officers. It is the view of the author that more controls are required by way of Regulations and that certain of the Regulations at present in force are in need of revision. Included in the paper are tables of the latest statistics available (1976) together with other data, previously unpublished, which in the author's opinion justify his claim that more controls are needed. In the final part of the paper the author recommends most strongly that the gap in the present British Standard fire tests produced by the lack of an effective means of evaluating the smoke-producing qualities and the toxicity of the produced by the lack of an effective means of evaluating the smoke-producing qualities and the toxicity of the products of combustion of different materials should be urgently studied with an amended priority.
    Additional Material: 4 Tab.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 7 (1983), S. 62-66 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The conversion of fuel-N species to NOx in diffusion flames has been studied by adding acetonitrile to the fuel flow for a methane-Oxygen-argon diffusion flame burning in excess oxygen. It is shown that the conversion is significantly lower than that obtained in a ‘corresponding’ pre-mixed flame, although the observed concentrations of NOx are still much higher than the appropriate thermodynamic equilibrium concentrations. The effect of initial concentration of acetonitrile, flame temperature and amount of excess oxygen on the conversion can all be explained in terms of the basic structure of a diffusion flame. This enables molecular nitrogen to be formed in the reducing atmosphere which exists on the fuel side of the flame through reaction of cyanide radicals with nitric oxide. The latter diffuses back from the oxygen side of the flame where it is formed, but the overall result is that a proportion of the fuel-N is converted to molecular nitrogen before it can be converted to nitric oxide.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980), S. 50-58 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The toxicological end-points used in a method for the assessment of the toxicity of combustion products are described. The evaluation considers three areas of toxicological interaction: incapacitation, death, and post-exposure involvement. The model of incapacitation described is the leg-flexion avoidance response of the rat. Additional end-points to assist in the determination of the causality of the observed toxicity are included. The effects of the combustion products of Douglas fir, a phenolic foam, a urea formaldehyde foam and a flexible polyurethane foam on these endpoint are described. The wide range of types of potential toxicities resulting form exposure of animals to the combustion products of materials is discussed. Additionally discussed are the relative merits of the leg-flexion avoidance response as a model of incapacitation. Conclusions as to the important components of a first-tier toxicological evaluation of combustion products are drawn.
    Additional Material: 3 Ill.
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