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  • Chemistry  (62)
  • Analytical Chemistry and Spectroscopy  (14)
  • 61.70
  • Atomic, Molecular and Optical Physics
  • Magnetism
  • Mass Spectra
  • 2010-2014
  • 2000-2004
  • 1995-1999  (58)
  • 1955-1959
  • 1940-1944  (7)
  • 1999  (10)
  • 1998  (22)
  • 1995  (26)
  • 1944  (7)
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  • 2010-2014
  • 2000-2004
  • 1995-1999  (58)
  • 1955-1959
  • 1940-1944  (7)
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 337 (1995), S. 245-249 
    ISSN: 0941-1216
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Spectroscopic Investigations on the Acidity of O,O′-Dithiophosphoric Acid Esters in Nonpolar Aprotic Solvents
    Additional Material: 3 Tab.
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 61 (1995), S. 207-212 
    ISSN: 1432-0630
    Keywords: 61.70 ; 81.40 ; 76.00
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract The application of the perturbed γγ angular correlation technique as an analytical tool for the characterisation of atomic defect configurations is discussed. Using the radioactive probe atom111In/111Cd, recent results on the compensation of acceptor and donor atoms in different II–VI semiconductors will be discussed, in particular the role of the cation vacancy defect.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 60 (1995), S. 541-544 
    ISSN: 1432-0630
    Keywords: 61.70 ; 61.80
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract Defects induced by electron irradiation were investigated in GaP. The irradiation was performed at 15 K with an incident electron energy of 2 MeV and a fluence of 1018cm−2. Annealing experiments were carried out in the temperature range between 100 and 1000 K. Ga and P vacancies were detected after electron irradiation and the different annealing behaviour of the two types of vacancies was observed. The recovery stage between 100 and 400 K was attributed to the annealing of Ga vacancies and the recovery at temperatures above 900 K to the annealing of P vacancies. We also performed Hall measurements to determine the location of the Fermi level in the bandgap during the annealing. Two different ionization levels of the P vacancy were found which can be attributed to the transitions V P + /V P o and V P o /V P − . Temperature-dependent measurements were performed to study the effect of shallow positron traps.
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  • 4
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Macrocyclic [4n + 2]-Hückel Aromatic Systems up to n = 9 and [4n] Antiaromatic Systems up to n = 10: Homologous Sequences from Tetraepoxy[24]annulene(2.0.2.0) to Tetraepoxy[40]annulene(12.0.12.0) and from the ‘Tetraoxa[22]porphyrin(2.0.2.0)-’ to the ‘Tetraoxa[38]porphyrin(12.0.12.0’-Dication1)2)Tetraepoxy[32]annulene(8.0.8.0) 3, tetraepoxy[36]annulene(10.0.10.0) 4, and tetraepoxy[40]annulene(12.0.12.0) 5 are synthesized and oxidized to give the ‘tetraoxa[30]-’, ‘tetraoxa[34]-’, and ‘tetraoxa[38]porphyrin’ dications 8-10. The annulenes as well as the ‘porphyrins’ are mixtures of at least two different configurational isomers, which can be analyzed by 1H-NMR techniques. Together with systems described already earlier, a complete homologous sequence from tetraepoxy[24]annulene(2.0.2.0) to tetraepoxy[40]annulene(12.1.12.0) and from ‘tetraoxa[22]porphyrin(2.0.2.0)’ to ‘tetraoxa[38]porphyrin(12.0.12.0)’ dications are available for the first time. The UV/VIS-absorptionmaxima in the annulene series are shifted to longer wavelengths with an increment of 12 nm per additional C=C bonds, and the Δδ values of the 1H-NMR spectra demonstrate a decreasing paratropic character (Δδ = 5.97 (1), 2.80 (3), and 4.23 ppm (4). The averaged λmax values of the Soret bands of the ‘tetraoxaporphyrin’ dications show a linear bathochromic shift with an increment Δδ of 58 nm per two additional double bonds, the absorptions of the most intensive Q-bands also increase linearly with an increment of ca. 160 nm. The Δδ values of the 1H-NMR spectra of the ‘tetraoxaporphyrin’ dications are increasing with the ring size (Δδ = 24.04 (7a) to 25.17 (9a) ppm), respectively, decreasing (Δδ = 21.55 (6) to 21.50 (9b) ppm) with a small maximum of 22.60 ppm for 7b, depending on the configuration of the isomers. The results confirm the antiaromatic character of the annulenes with up to 40π electrons and the aromatic character of the ‘tetraoxaporphyrin’ dications with up to 38π electrons.
    Additional Material: 18 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 49-54 
    ISSN: 0887-624X
    Keywords: polymer membranes ; poly(vinyl pyrrolidone) ; hypochlorite ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Sodium hypochlorite solutions are used to treat membranes prepared from a polymeric blend containing poly(vinyl pyrrolidone) (PVP) to increase their water permeability. Sodium hypochlorite affects the membrane material in such a way that PVP is selectively removed from the membrane matrix. The mechanism of the reaction between hypochlorite and PVP is investigated by several chemical analysis techniques of the reaction products. Strong indications are found that the reaction involves chain scission of PVP according to a radical mechanism. © 1995 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
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  • 6
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Influence of mean stresses and mean strains on the cyclic deformation behavior and the plasticity-induced martensite formation of X6CrNiTi1810 stainless steelThis paper describes some aspects of the fatigue behavior of the metastable austenitic stainless steel X6CrNiTi1810 (German material number 1.4541). The aim of the present investigation is to determine the influence of plasticity-induced martensite formation on the cyclic deformation behaviour at room temperature and T = 300°C. Several specimen batches were tested under stress and total strain control with different R-values, a frequency of 5 Hz and triangular load-time functions, s̰-hysteresis and nondestructive magnetic measurements are used to characterize the fatigue behavior. Characteristic results are presented and discussed.
    Notes: Anhand von einstufigen spannungs- und totaldehnungskontrollierten Versuchen werden Zusammenhänge zwischen dem zyklischen Verformungsverhalten und der verformungsinduzierten Martensitbildung des metastabilen austenitischen Stahls X6CrNiTi1810 (Werkstoff-Nr. 1.4541) bei Raumtemperatur und T = 300°C untersucht. Besondere Beachtung findet hierbei der Einfluß von Mittelbeanspruchungen. Alle Versuche wurden mit einem dreieckförmigen Beanspruchung-Zeit-Verlauf und einer Frequenz von 5 Hz durchgeführt. Zur Charakterisierung des Wechselverformungsverhaltens dient neben den aus σ-Hysteresen ermittelten mechanischen Kennwerten, der on-line mittels eines Wirbelstromsensors gemessene magnetische Phasenanteil. Ausgewählte Versuchsergebnisse werden vorgestellt und diskutiert.
    Additional Material: 20 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 26 (1995), S. 553-559 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Bestimmung der Spannungstensoren in dünnen, texturierten Kupferschichten mittels Röntgenbeugung bei streifendem EinfallIonenplattierte Kupferschichten wurden mittels Röntgenbeugung hinsichtlich Texturen und Eigenspannungen untersucht. Die vollständigen Orientierungsverteilungsfunktionen wurden bestimmt und scharfe (111)-Fasertexturen gefunden. Die Messung der Dehnungen erfolgte unter streifendem Strahleinfall. Zur Berechnung der Spannungstensoren wurden sowohl texturgewichtete elastische Moduln als auch texturunabhängige elastische Moduln verwendet. Die Bedeutung der Texturmessung für die Spannungstensorbestimmung wird diskutiert. Die gefundenen Spannungen können als thermisch verursacht verstanden werden.
    Notes: Ion-platted thin copper films were examined for residual stresses and texture by X-ray diffraction. The complete orientation distribution functions were determined and sharp (111)-fibre textures were found. The strains were measured by grazing incidence diffraction. The stress tensors were calculated using both texture-weighted elastic compliances and texture-independent X-ray elastic constants. The importance of the texture measurement for the stress tensor determination is discussed. The found stresses can be interpreted as thermally induced.
    Additional Material: 5 Ill.
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  • 8
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Characterization of the Fatigue of Cyclically Loaded Welded Joints by X-Ray Diffraction and Micromagnetic TestingThe fatigue behaviour of welded Joints is influenced by the state of the material, its microstructure and residual stresses. By means of the micromagnetic Barkhausen-noise testing method in connection with x-ray diffraction the behaviour of cyclically loaded welded joints of the steel S355 is investigated. Proved by the results of the present investigations, the macro-and micro-residual stresses, micromagnetic and strain characteristic values are strongly connected with each other. Plastic deformations in the HAZ and base material during cyclic loading were identifies by a significant relaxation of the micro-residual stresses and a characteristic change in the micro-residual stresses determined by X-ray profile analysis. Analogous to the growing plastic strain amplitude an advancing damage process in the material is accompained by a significant change in the micromagnetic parameters. As a conclusion the micromagnetic testing method can be suited for the identification of fatigue processes in the material before a final damager of the specimen.
    Notes: Das Ermüdungsverhalten von Schweißnähten wird durch den Werkstoffzustand, die Gefüge-und Mikrostruktur und Eigenspannungen beeinflußt. Mit Hilfe des mikromagnetischen Meßverfahrens in Verbindung mit röntgenographischen Verfahren wurde das Werkstoffverhalten von zyklisch beanspruchten Schweißnähten des Baustahls S355 mit der Absicht einer Restlebensdauervorhersage untersucht. Die Vorliegenden Ergebnisse bestätigen die Auffassung, daß hierbei Makro- und Mikroeigenspannungen, magnetische Kennwerte und Dehnungskennwerte eng miteinander verknüpft sind. Die bei zyklischer Beanspruchung mit hinreichen großen Spannungsamplituden in Naht, WEZ und Grundwerkstoff eintretenden mikostrukturellen Veränderungen kamen einerseits in starken Veränderungen der Makroeigenspannungen zum Ausdruck und in Bereichen stärkerer Plastizierungen auch in Veränderungen der Mikroeigenspannungen, die sich aus der Röntgeninterferenzlinien-Profilanalyse ergaben. Andererseits waren die Mikrostrukturänderungen schon frühzeitig im Verlauf der zyklischen Beanspruchungen anhand z.T. sehr ausgeprägter Veränderungen der mikromagnetischen Kennwerte nachweisbar. Diese Ergebnisse lassen erwarten, daß sich die mit den mikrostrukturellen Werkstoffveränderungen verknüpfte fortschreitende Schädigung bis zur Entstehung von Makrorissen mit Hilfe des mikromagnetischen Meßverfahrens nachweisen läßt und so Aussagen über den Ermüdungszustand schwingbeanspruchter Bauteile möglich werden.
    Additional Material: 10 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 26 (1995), S. 386-393 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Lattice Constant Determination in Cubic Thin Films under Thermal StrainAn X-ray diffraction procedure is presented to determine the lattice constant of a cubic thin film which is thermally strained. The procedure also gives the thermal strain. As application examples, the lattice constants of thin aluminium and copper films deposited by ion-platting are evaluated from grazing incidence diffraction data.
    Notes: Ein Verfahren zur röntgenographischen Bestimmung der Gitterkonstanten einer kubischen dünnen Schicht, die herstellungsbedingt unter thermischer Dehnung steht, wird angegeben. Das Verfahren liefert zudem die wirksame-thermische Dehnung. Als Anwendungsbeispiele werden die Gitterkonstanten von ionenplattierten Aluminium- und Kupferschichten aus röntgenographischen Messungen mittels eines Seemann-Bohlin Diffraktometers mit streifendem Strahleinfall ermittelt.
    Additional Material: 11 Ill.
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  • 10
    ISSN: 0935-6304
    Keywords: On-line extraction ; Large volume introduction ; Capillary gas chromatography ; Atomic emission detection ; Solvent venting ; Pesticides ; Ground water ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The on-line coupling of a liquid-liquid extraction system with capillary gas chromatography using atomic emission detection (GC-AED) has been studied. The required large volumes of about 100 μl of an iso-octane solution can be introduced into the GC-AED system by using the AED solvent vent and a solvent vapor exit in front of the capillary analytical column. Test solutions containing several pesticides were detected using the carbon, chlorine, nitrogen and sulfur channels. Analyte detectability (in concentration units) was improved significantly and low concentractions of the test compounds could be determined (1-5 ng/ml). Aqueous samples were on-line extracted and analyzed. The precision of the large-volume injection itself as well as the total extraction-GC-AED system was satisfactory (RSD of ca. 2 and 4%, respectively). As a real-life application, several ground water samples were screened.
    Additional Material: 6 Ill.
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