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  • Chemical Engineering  (126)
  • 1990-1994  (60)
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  • 1990-1994  (60)
  • 1980-1984  (66)
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  • 1
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 56-60 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Resin transfer molding (RTM) of advanced fiber architecture materials promises to be a cost effective process for obtaining composite parts with exceptional strength. However there are a larger number of material processing parameters that must be observed, known, and/or controlled during the resin transfer molding process. These include the viscosity both during impregnation and cure. In-situ sensors which can observe these processing properties within the RTM tool during the fabrication process are essential. This paper will discuss recent work on the use of frequency dependent electromagnetic sensing (FDMS) techniques to monitor these properties in the RTM tool. Our objective is to use these sensing techniques to address problems of RTM scaleup for large complex parts and to develop a closed loop, intelligent, sensor controlled RTM fabrication process.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: Microkinetic simulations have been carried out to describe the partial oxidation of methane over silica-supported molybdena and vanadia. The objective of this study was to formulate a physically reasonable reaction network to capture the basic aspects of the surface catalytic chemistry and to use this network to link methane oxidation kinetics with the kinetics observed for the oxidation of subsequent gaseous products, i.e., methanol, formaldehyde, and carbon monoxide. The most abundant reactive intermediates on the catalyst surface are suggested to be oxygen and hydroxyl groups. This reaction network successfully predicts the catalytic activities, selectivities, activation energies, and reaction orders observed over silica-supported molybdena and vanadia; and the microkinetic model also semiquantitatively explains the kinetic trends for related catalyst systems and is consistent with surface bonding energetics reported in the literature over various oxide catalysts. The microkinetic reaction network properly reduces to the more simple macrokinetic model reported previously for methane partial oxidation.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1-38 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: As steady-state and dynamic simulators with optimal controllers have evolved, tools for nonlinear analysis have been developed by reactor and thermophysical property specialists. Designers lag behind in developing and utilizing these tools, as many design strategies assume idealized behavior even though processes contain an increasing number of nonlinear elements. This article examines the sources of the nonlinear elements, often associated with physical and chemical interactions, in designs and their control systems. Promising methods for nonlinear analysis are reviewed.In each design activity, involving simulation, economic optimization, projections of controllability and operability, emphasis is on the sources of nonlinearities and solution methods. These are examined for the equality constraints and nonlinear programs in phase and chemical equilibria, in reactors and separators, and in the simulation and optimization of flowsheets. Also examined are the impact of non-linear predictive control in screening designs and methods to insure operability, in the face of uncertainties.
    Zusätzliches Material: 27 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 514-515 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 765-772 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A generalized mathematical model is developed to describe the process of multicomponent adsorption on activated carbon in fixed beds. Numerical, finite difference, solutions for the adsorption of binary, and ternary organic mixtures are shown to satisfactorily match previously published experimental data.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 199-207 
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A series of seven coals of different ranks and from various locations were heated in an inert atmosphere under relatively mild conditions to measure the rates of gas evaporation. Samples crushed to various fractions in the particle size range -6+50 U.S. mesh were studied at temperatures in the range of 150 to 300°C. The results show that: (1) most water is released at 100°C, evidently an evaporation process, (2) CO2 is evolved at 150°C and above, and (3) CO is evolved at 250°C and above. An interpretive model was developed to fit the CO2 production rate and kinetic constants were obtained. Gas evolution rates are independent of particle size for the most porous coals, but vary among coals, depending on both chemical composition and physical structure. A 15% loss in heating value was incurred during drying and subsequent oxidation when the pretreatment temperature was increased from 150 to 225°C.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 684-687 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Films of polyacetylene synthesized according to Akagi method present a high degree of crystallinity. A 6-7 times stretching of these films results in the orientation of the polymer fibers: The mosaic was ± 5 degrees. Such highly oriented polyacetylene (HOPA) films were chemically doped by heavy alkali metals in the vapor state and electrochemically with GaCl4- anion in nitromethane medium. The evolution of the structures and the variation of the electrical conductivity upon doping were examined in both cases.Doping with alkali metal leads to the appearance of different intercalated phases: The commensurability of these phases is discussed as a function of the nature and the concentration of the intercalated alkaline ion. The electrical maximum room temperature conductivity, which depends on the nature of the alkali metal, is maximum for K-doped materials. In the case of GaCl4- doping, the unique intercalated phase observed is poorly organized except in the chain direction where a GaCl4- ion is found every 4.5 (CH) units. The room temperature electrical conductivity measured along the chain axis is equal to 15 000 S/cm, one order of magnitude higher than the value observed in Shirakawa unoriented polyacetylene.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 1670-1673 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The rheological characteristics of a number of polymer blends, including amorphous and semi-crystalline plastic matrices, during melting or softening, are analyzed with a batch mixer. The physical changes accompanying the phase transitions taking place as the slat-and-pepper blends are heated and mixed in the region of their component melt transition temperatures are monitored visually through a transparent window with video recordings. The torque of mixing and the mixture temperature are also recorded continuously. The strong effects of additives such as filler or lower melting resin as well as rotor speed, degree of fill, and ram pressure were observed.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 31 (1991), S. 992-998 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Ultrahigh molecular weight polyethylene (UHMWPE) powder (60 micron diameter) and chopped fiber (6.5 mm length) were surface treated with a blend of reactive gases (fluorine and oxygen.) These powders and fibers were then compounded into a thermoset polyurethane matrix. Surface-treated and control reinforcements are compared at a 10 vol.% loading level. Tensile testing indicates improved stress transfer with surface treatment. Stress transfer is also improved with fibers versus powders. Fracture toughness is characterized by measuring the essential work of fracture, we. Surface-treated fiber composites exhibit work of fracture values almost three times the unfilled polyurethane values. Abrasion resistance was also measured. Surface treatment was found to significantly lower wear rates of powder composites. Fiber composites had lower wear rates than powder composites, although surface treatment had little effect. An approximate inverse relationship was found between wear rate and essential work of fracture.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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