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  • Inorganic Chemistry  (86)
  • Astrophysics
  • 1995-1999  (70)
  • 1985-1989  (34)
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  • 1930-1934  (18)
  • 1915-1919
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  • 1996  (70)
  • 1988  (34)
  • 1931  (18)
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  • 1995-1999  (70)
  • 1985-1989  (34)
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  • 1930-1934  (18)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 845-852 
    ISSN: 0044-2313
    Keywords: Nickel orthoperiodate ; i.r., Raman spectra ; crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: NiH3IO6 · 6 H2O  -  Crystal Structures and Vibrational SpectraThe crystal structure of NiH3IO6 · 6 H2O has been determined by X-ray single-crystal diffraction (Pc, Z = 2, a = 516.74(9), b = 981.5(2), c = 1052.5(2) pm, β = 116.496(8)°) on the basis of 4169 unique reflections (R = 1.96%). The structure is built up of distorted Ni(H2O)62+ and H3IO62- octahedra linked by hydrogen bonding. IR and Raman spectra of both the title compound and isostructural MgH3IO6 · 6 H2O as well as of deuterated specimens are given. There are up to 14 different OH(OD) modes in the spectra of isotopically dilute samples due to the 15 different hydrogen positions of the structure. The internal modes of the meridional H3IO62- ions (pseudo C2v symmetry) are discussed with respect to that double T-shaped entity, which gives rise to only two instead of 3I—O, I—O(H), and OH stretches in the IR and Raman spectra, i.e. the same as for facial (C3v) structured ions.
    Notes: Die Kristallstruktur (Pc, Z = 2) von NiH3IO6 · 6 H2O wurde mittels Röntgen-Einkristallmessungen auf der Basis von 4169 symmetrieunabhängigen Reflexen bestimmt (R = 1,96%). IR- und Raman-Spektren von NiH3IO6 · 6 H2O und der isotypen Verbindung MgH3IO6 · 6 H2O sowie von deuterierten Präparaten werden mitgeteilt. Die Spektren isotypenverdünnter Proben zeigen bis zu 14 OH(OD)-Streckschwingungen entsprechend den 15 verschiedenen Wasserstoff-Positionen der Struktur. Die meridionalen H3IO62--Ionen (Pseudosymmetrie C2v) besitzen wegen der T-förmigen Anordnung der je 3 IO-und IOH-Gruppen nur je 2 IO-, IO(H)- und OH-Streckschwingungen in den IR- und Raman-Spektren und können daher schwingungsspektroskopisch nicht von H3IO62--Ionen mit facialer Struktur (C3v) unterschieden werden.
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  • 2
    Publication Date: 2019-08-16
    Description: Volatile compounds in comets are the most pristine materials surviving from the time of formation of the Solar System, and thus potentially provide information about conditions that prevailed in the primitive solar material. Moreover, comets may have supplied a substantial fraction of the volatiles on the terrestrial planets, perhaps including organic compounds that played a role in the origin of life on Earth. Here we report the detection of hydrogen isocyanide (HNC) in comet Hyakutake. The abundance of HNC relative to hydrogen cyanide (HCN) is very similar to that observed in quiescent interstellar molecular clouds, and quite different from the equilibrium ratio expected in the outermost solar nebula, where comets are thought to form. Such a departure from equilibrium has long been considered a hallmark of gas-phase chemical processing in the interstellar medium, suggesting that interstellar gases have been incorporated into the comet's nucleus, perhaps as ices frozen onto interstellar grains. If this interpretation is correct, our results should provide constraints on the temperature of the solar nebula, and the subsequent chemical processes that occurred in the region where comets formed.
    Keywords: Astrophysics
    Type: NASA-TM-110471 , NAS 1.15:110471 , Nature
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  • 3
    Publication Date: 2019-07-10
    Description: The remarkably strong radio gravitational lens PKS 1830-211 consists of a one arcsecond diameter Einstein ring with two bright compact (milliarcsecond) components located on opposite sides of the ring. We have obtained 22 GHz VLBA data on this source to determine the intrinsic angular sizes of the compact components. Previous VLBI observations at lower frequencies indicate that the brightness temperatures of these components are significantly lower than 10(exp 10) K (Jauncey, et al. 1991), less than is typical for compact synchrotron radio sources and less than is implied by the short timescales of flux density variations. A possible explanation is that interstellar scattering is broadening the apparent angular size of the source and thereby reducing the observed brightness temperature. Our VLBA data support this hypothesis. At 22 GHz the measured brightness temperature is at least 10(exp 11) K, and the deconvolved 2 size of the core in the southwest compact component is proportional to upsilon(sup -2) between 1.7 and 22 GHz. VLBI observations at still higher frequencies should be unaffected by interstellar scattering.
    Keywords: Astrophysics
    Type: JPL ASTROPHYSICS PREPRINT-96-008 , ; 1-11
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  • 4
    Publication Date: 2019-07-17
    Description: Previous studies have shown that many individual grains within the dark phase of the Kapoeta howardite were irradiated with energetic particles while residing on the surface of the early HED regolith. Particle tracks in these grains vary in density by more than an order of magnitude and undoubtedly were formed by energetic heavy (Fe) ions associated with early solar flares. Early Irradiation of HED Regolith: Concentrations of excess Ne alone are not sufficient to decide between competing galactic and solar irradiation models. However, from recent studies of depth samples of oriented lunar rocks, we have shown that the cosmogenic 21-Ne/22-Ne ratio produced in feldspar differs substantially between Galactic Cosmic Radiation (GCR) and solar protons, and that this difference is exactly that predicted from cross-section data. Using Ne literature data and new isotopic data we obtained on acid-etched, separated feldspar from both the light and dark phases of Kapoeta, we derive 21-Ne/22-Ne = 0.80 for the recent GCR irradiation and 21-Ne/22-Ne = 0.68 for the early regolith irradiation. This derived ratio indicates that the early Ne production in the regolith occurred by both galactic and solar protons. If we adopt a likely one-component regolith model in which all grains were exposed to galactic protons but individual grains had variable exposure to solar protons, we estimate that this early GCR irradiation lasted for about 3-6 m.y. More complex two-component regolith models involving separate solar and galactic irradiation would permit this GCR age to be longer. Higher-energy solar protons would permit the GCR to be longer. Higher-energy solar protons would permit the GCR age to be shorter. Further, cosmogenic 126(Xe) in Kapoeta dark is no more than a factor of about 2 higher than that observed in Kapoeta light. Because 126(Xe) can only be formed by galactic protons and not solar protons, these data support a short GCR irradiation for the HED regolith. This would also be the maximum time peRiod for the solar irradiation. Various asteroidal regolith models, based on Monte Carlo modeling of impact rates as a function of size and on irradiation features of meteorites, predict surface exposure times of about 0.1 to 10 m.y., and depend on such factors as gravity, rock mechanical properties, and micrometeoroid flux. Because the depth at which solar Fe tracks are produced (is much less than 1 micrometer) is much less than the depth at which Solar Cosmic Rays (SCR) Ne is produced (about 1 cm), for a reasonably well-stirred HED regolith the "surface exposure time" for SCR 21-Ne production should be significantly longer than that for solar tracks and some other surface irradiation features. Enhanced Solar Proton Irradiation: For bulk samples of Kapoeta dark feldspar and a one-component regolith model, the derived ratio of 21-Ne/22-Ne = 0.68 implies that the early production ratio of SCR 21-Ne to GCR 21-Ne was about 0.5-1.5. This ratio is independent of any assumptions about the fraction of dark grains that are irradiated or of the variability in the degree of solar irradiation among grains. The 21-Ne SCR/GCR ratio indirectly derived from bulk Kapoeta pyroxene is somewhat larger, as is the ratio derived for simple two-component regolith models. Individual feldspar grains that were extensively solar irradiated would require even larger 21-Ne SCR/GCR production ratios. In contrast, the theoretical SCR/GCR production ratio for lunar feldspar with 0 g/CM2 shield ing is is less than or equal to 2, and the lowest ratio observed in near-surface samples of lunar anorthosites is less than or equal to 1. Considering the greater solar distance of Vesta (compared to the Moon), the likelihood that SCR 21-Ne was acquired under some shielding where production rates are lower, and the likelihood that the exposure time to galactic protons exceeded the exposure time to solar protons because of their very different penetration depths, the 21-Ne SCR/GCR production ratio on the HED parent body was probably 〈 0.1. The relatively large difference between the derived 21-Ne SCR/GCR ratio in Kapoeta dark feldspar and the estimated production ratio strongly indicates that the early solar irradiation involved a flux -20-50x the recent solar flux. This enhanced proton flux was probably associated with an overall greater solar activity in the first approximately 10(exp 7) to 10(exp 8) years of solar history.
    Keywords: Astrophysics
    Type: Workshop on Evolution of Igneous Asteroids: Focus on Vesta and the HED Meterorites; Pt. 1; 2-3; LPI-TR-96-02-Pt-1
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  • 5
    Publication Date: 2019-07-13
    Description: This report summarizes science analysis activities by the SAMPEX mission science team during the period during the period July 1, 1995 through July 1, 1996. Bibliographic entries for 1995 and 1996 to date (July 1996) are included. The SAMPEX science team was extremely active, with 20 articles published or submitted to refereed journals, 18 papers published in their entirety in Conference Proceedings, and 53 contributed papers, seminars, and miscellaneous presentations. The bibliography at the end of this report constitutes the primary description of the research activity. Science highlights are given under the major activity headings of anomalous cosmic rays, solar energetic particles, magnetospheric precipitating electrons, trapped H and He isotopes, and data analysis activities.
    Keywords: Astrophysics
    Type: NASA-CR-201539 , NAS 1.26:201539
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  • 6
    ISSN: 0044-2313
    Keywords: Sn(P2)3Sn cage system ; NMR data, crystal structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Structure of Hexa-t-butyl-1,4-dichloro-1,4-distanna-2,3,5,6,7,8-hexaphosphabicyclo[2.2.2]octane - a New Cage Compound with the Sn(P2)3Sn SkeletonThe reaction of the diphosphide K2[(tBuP)2] 1 with SnCl4 leads by a redox process mainly to (tBuP)3,4 and other sideproducts. However, at the same time a threefold [2 + 1]-cyclocondensation reaction takes place yielding the new cage compound hexa-t-butyl-1,4-dichloro-1,4-distanna-2,3,5,6,7,8-hexaphosphabicyclo[2.2.2]octane, ClSn(tBuP—PtBu)3SnCl 2. 2 could be obtained in a pure form and characterized 31P and 119Sn NMR spectroscopically; 2 was also characterized by a single crystal structure analysis.
    Notes: Bei der Reaktion zwischen dem Diphosphid K2[(tBuP)2] 1 und SnCl4 finden überwiegend Redoxreaktionen statt, die zu (tBuP)3,4 und weiteren Nebenprodukten führen. Gleichzeitig findet aber auch eine dreifache [2 + 1]-Cyclokondensation statt, bei der die neuartige Käfigverbindung Hexa-t-butyl-1,4-dichloro-1,4-distanna-2,3,5,6,7,8-hexaphospha-bicyclo[2.2.2]octan, ClSn(tBuP—PtBu)3SnCl 2 gebildet wird. 2 konnte in reiner Form isoliert und 31P- und 119Sn-NMR-spektroskopisch sowie durch eine Einkristallstrukturanalyse charakterisiert werden.
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 566 (1988), S. 90-102 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Preparation and Reactions of Methylene-bridged Phosphorus(III)-Phosphorus(V) CompoundsThe synthesis of methylene-bridged diphosphorus compounds of the type Y2PCH2P(S)X2 (with Y = F, Cl, OPri, NMe2, Ph) is reported. Reactions of these compounds with bicycloheptadiene-metaltetracarbonyls to form complexes of the type (L—L′)M(CO)4 and (L—L′)2M(CO)4, respectively, as well as some oxidation reactions and the conversion of the phosphine F2PCH2P(S)F2 to the cyclotetraphosphine [PCH2P(S)F2]4 are described.
    Notes: Über die Darstellung von methylenverbrückten Diphosphorverbindungen der Zusammensetzung Y2PCH2P(S)X2 (mit Y = F, Cl, OPri, NMe2, Ph; X = F, OPri, NMe2, Ph) wird berichtet. Umsetzungen der erhaltenen Verbindungen mit Bicycloheptadien-Metalltetracarbonylen zu Komplexen des Typs (L—L′)M(CO)4 bzw. (L—L′)2M(CO)4 (mit M = Cr, Mo, W), einige Oxidationsreaktionen und die Umwandlung des Phosphans F2PCH2P(S)F2 zum Cyclotetraphosphan [PCH2P(S)F2]4 werden beschrieben.
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  • 8
    ISSN: 0044-2313
    Keywords: Phosphorus tin heterocycles ; syntheses ; crystal structure ; NMR ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis of the Stannatetraphospholanes (tBuP)4SnR2 (R = tBu, nBu, C6H5) and (tBuP)4Sn(Cl)nBu Molecular and Crystal Structure of (tBuP)4Sn(tBu)2The reaction of the diphosphide K2[tBuP-(tBuP)2-PtBu] 4 with the halogenostannanes (tBu)2SnCl2, (nBu)2SnCl2, (C6H5)2SnCl2 or nBuSnCl3 in a molar ratio of 1 : 1 leads via a [4 + 1]-cyclocondensation reaction to the stannatetraphospholanes (tBuP)4SnR2 3 b-3 d and (tBuP)4Sn(Cl)nBu 3 e, respectively, with the binary 5-membered P4Sn ring system. 3 b was characterized by a single crystal structure analysis; the 5-membered ring exists in a planar conformation. The compounds 3 b-3 e were identified by NMR and also by mass spectroscopy; the 31P{1H}-NMR spectra of 3 b-3 d showed an AA′MM′ (AA′MM′X), 3 e on the other hand an ABCD (ABCDX) spin system.
    Notes: Bei der Reaktion zwischen dem Diphosphid K2[tBuP-(tBuP)2-PtBu] 4 und den Halogenstannanen (tBu)2SnCl2, (nBu)2SnCl2, (C6H5)2SnCl2 bzw. nBuSnCl3 im Molverhältnis 1 : 1 findet eine [4 + 1]-Cyclokondensationsreaktion statt, bei der die Stannatetraphospholane (tBuP)4SnR2 3b-3d bzw. (tBuP)4Sn(Cl)nBu 3 e mit dem binären Fünfringgerüst P4Sn gebildet werden. Von 3 b wurde eine Einkristallstrukturanalyse durchgeführt; das Fünfringgerüst zeigt eine planare Konformation. Die Verbindungen 3 b-3 e wurden Massen- und NMR-spektroskopisch charakterisiert; 3 b-3 d liefern im 31P{1H}-NMR-Spektrum ein AA′MM′-(AA′MM′X)-, 3 e dagegen ein ABCD- (ABCDX)-Spinsystem.
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  • 9
    ISSN: 0044-2313
    Keywords: Trifluoromethyl tellurium compounds ; crystal structure ; NMR spectra ; metathesis reactions ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Crystal Structure of CF3TeTeCF3. Synthesis, Characterization, and Properties of CF3TeITe2(CF3)2 crystallizes in the monoclinic space group P21/a with four formular units in the unit cell. The lattice constants are a = 10.13(1) Å, b = 11.489(7) Å, c = 6.822(8) Å and β = 101.20(8)°. CF3TeI is prepared by a quantitative reaction of Te2(CF3)2 with equimolar amounts of iodine. This compound is very instable, no isolation is possible. NMR spectra have been registrated. From metathesis reactions CF3TeX (X = C≡CC6H5, t-C4H9, SCN, SC6F5) are prepared.
    Notes: Te2(CF3)2 kristallisiert in der monoklinen Raumgruppe P21/a mit vier Formeleinheiten in der Elementarzelle. Die Gitterkonstanten betragen a = 10,13(1) Å, b = 11,489(7) Å, c = 6,822(8) Å und β = 101,20(8)°. Bei der Umsetzung von Te2(CF3)2 mit der äquimolaren Menge Iod entsteht CF3TeI in quantitativer Ausbeute, eine Isolierung gelingt nicht. Die NMR-Spektren zeigen eine starke Lösungsmittelabhängigkeit. Durch Metathesereaktionen werden die Verbindungen CF3TeX (X = C≡CC6H5, t-C4H9, SCN, SC6F5) synthetisiert.
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  • 10
    Publication Date: 2018-06-08
    Keywords: Astrophysics
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