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  • Articles  (7)
  • 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks  (4)
  • Coral Sr/Ca  (3)
  • American Geophysical Union  (5)
  • Elsevier  (2)
  • American Meteorological Society
  • Annual Reviews
  • 2020-2023
  • 2010-2014  (7)
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  • 2012  (3)
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  • 1
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    Carbonate-derived CO2 purging magma at depth: Influence on the eruptive activity of Somma-Vesuvius, Italy (2012)
    Elsevier
    Details
    Publication Date: 2020-11-30
    Description: Mafic phenocrysts from selected products of the last 4 ka volcanic activity at Mt. Vesuvius were investigated for their chemical and O-isotope composition, as a proxy for primary magmas feeding the system. 18O/16O ratios of studied Mg-rich olivines suggest that near-primary shoshonitic to tephritic melts experienced a flux of sedimentary carbonate-derived CO2, representing the early process of magma contamination in the roots of the volcanic structure. Bulk carbonate assimilation (physical digestion) mainly occurred in the shallow crust, strongly influencing magma chamber evolution. On a petrological and geochemical basis the effects of bulk sedimentary carbonate digestion on the chemical composition of the near-primary melts are resolved from those of carbonate-released CO2 fluxed into magma. An important outcome of this process lies in the effect of external CO2 in changing the overall volatile solubility of the magma, enhancing the ability of Vesuvius mafic magmas to rapidly rise and explosively erupt at the surface.
    Description: Published
    Description: 84-95
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: stable-isotope ; magma geochemistry ; CO2-degassing ; Vesuvius ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
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    Vesiculation in magmas from Stromboli and implications for normal Strombolian activity and paroxysmal explosions in basaltic systems (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We performed a series of X-ray tomographic experiments and lattice Boltzmann permeability simulations on pyroclastic products from explosive activity at Stromboli between December 2004 and May 2006. We reconstructed the 3-D textures of vesicles to investigate the relationship between the nature of vesiculation in the erupted products and the dynamics of gas transport in the shallow conduit in order to derive implications for the eruptive behavior of basaltic volcanoes. Scoriae from normal Strombolian explosions display remarkably consistent vesicle volume distributions fit by power laws with an exponent of 1 (±0.2). We ascribe the origin of such distributions to the combined effect of coalescence and continuous nucleation events in the steady state, shallow magma system that supplies normal Strombolian activity. Volume distributions and textures of vesicles in pumice clasts from the 5 April 2003 and 15 March 2007 paroxysmal activity are markedly different from those in the scoriae. Besides a power law function with a higher exponent, portions of these distributions can be also fit by an exponential function, suggesting the attempt of the system to reach near-equilibrium conditions. The investigated pumice clasts also lack the large, connecting vesicles responsible for the development of degassing pathways in the Stromboli magma that erupts the scoriae. This testifies to a decreased degassing efficiency of the magma associated with paroxysmal explosions and potential overpressure buildup at depth. By comparison with degassing experiments on basaltic melts, we derive a time constraint on the order of minutes to hours for the incubation of paroxysms at Stromboli.
    Description: Published
    Description: B01206
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: JCR Journal
    Description: reserved
    Keywords: basaltic explosions ; vesicle textures ; third dimension ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 3
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    In-situ degassing study on crystal-bearing Stromboli basaltic magmas: Implications for Stromboli explosions (2012)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Three-dimensional crystal and bubble sizes and distributions in experimentally produced vesicular crystal-bearing Stromboli basalts and natural scoria were studied with X-ray microtomography (μCT) at high (1.85 μm) and low (5.46–9.0 μm) resolution. The permeabilities from lattice Boltzmann (LB) simulations and experimental measurements are about 1–2 orders of magnitude higher than in aphyric Stromboli basalts at porosity 31.6–55.3%. We propose that the higher permeability in crystal-bearing samples results in highly efficient degassing in shallow, highly porphyritc (HP) magma as opposed to the deeper, aphyric (LP) magma. In paroxysmal explosions, the LP magma flows up in a cylindrical conduit due to the density and viscosity difference between the two magmas. This type of convection can cause the LP magma with exsolved gas to be efficiently transferred through the overlying HP magma, potentially resulting in the more-violent paroxysmal explosions.
    Description: Published
    Description: L17309
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: Experimental volcanism ; Stromboli ; degassing ; crystal-bearing magmas ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
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    Texture analysis of volcanic rock samples: Quantitative study of crystals and vesicles shape preferred orientation from X-ray microtomography data (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: In the texture analysis of volcanic rocks, the preferred orientation of the constituents can provide useful information for the interpretation of the processes involved in the rock formation. We present here a new data analysis technique, based on X-ray microtomography measurements and on shape preferred orientation analysis, to obtain the orientation distribution functions of the constituents of volcanic rocks. This procedure proved to be very suitable for volcanic samples, where diffraction-based techniques, developed for crystallographic preferred orientation studies, are of limited utilization, in addition to the fact that they cannot provide any information about vesicles or bubbles. Moreover the analysis performed directly in three dimensions (3D) overcomes the problems that usually occur when employing stereological methods for the analysis of the images obtained via microscopy-based techniques. In this study, two scoriae (from Stromboli and Etna) and a tube pumice (from Campi Flegrei) were measured via X-ray microtomography and then the resulting volumes were analyzed following the proposed procedure. Results highlight little preferred orientation for the vesicles in the two scoria samples, whereas the pumice shows a marked preferred orientation. Crystals (also divided by mineral species) were taken into account as well and in the two scoria samples there is no crystal preferred orientation, in contrast with the pumice, where crystal preferred orientation features are very similar to the ones found for the vesicles. Overall we found strong differences in preferred orientation: weak for vesicles in scoriae, showing an axial symmetry with the axis parallel to the elongation axis of the sample, and a stronger and more complex orientation texture in the pumice sample for both crystals and vesicles. The promising results obtained suggest that this procedure is potentially very useful for the analysis of preferred orientation in volcanic rocks and geomaterials in general.
    Description: Published
    Description: 83-95
    Description: 2.3. TTC - Laboratori di chimica e fisica delle rocce
    Description: JCR Journal
    Description: reserved
    Keywords: X-ray computed microtomography ; preferred orientation ; texture analysis ; volcanic scoria ; synchrotron X-rays ; pumice ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
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    Record of Little Ice Age sea surface temperatures at Bermuda using a growth-dependent calibration of coral Sr/Ca (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2005. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 20 (2005): PA4016, doi:10.1029/2005PA001140.
    Description: Strontium to calcium ratios (Sr/Ca) are reported for a massive brain coral Diploria labyrinthiformis collected from the south shore of Bermuda and are strongly correlated with both sea surface temperature (SST) and mean annual skeletal growth rate. High Sr/Ca ratios correspond with cold SSTs and slow skeletal growth rate and vice versa. We provide a quantitative calibration of Sr/Ca to extension rate and SST along the axis of maximum growth and derive a growth-dependent Sr/Ca–SST calibration equation to reconstruct western subtropical North Atlantic SSTs for the past 223 years. When the influence of growth rate is excluded from the calibration, Sr/Ca ratios yield SSTs that are too cold during cool anomalies and too warm during warm anomalies. Toward the end of the Little Ice Age (∼1850), SST changes derived using a calibration that is not growth-dependent are exaggerated by a factor of 2 relative to those from the growth-corrected model that yields SSTs ∼1.5°C cooler than today. Our results indicate that incorporation of growth rate effects into coral Sr/Ca calibrations may improve the accuracy of SSTs derived from living and fossil corals.
    Description: A Stanley Watson Foundation Fellowship (N.F.G.), and grants from NSF (OCE-0402728) and WHOI (K.A.H., A.L.C., and M.S.M.) supported this work.
    Keywords: SST ; Coral Sr/Ca ; Growth rate
    Repository Name: Woods Hole Open Access Server
    Type: Article
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  • 6
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    A multicoral calibration method to approximate a universal equation relating Sr/Ca and growth rate to sea surface temperature (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2007. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 22 (2007): PA1214, doi:10.1029/2006PA001312.
    Description: Combining strontium-to-calcium ratios (Sr/Ca) with mean annual growth rates in Bermuda Diploria labyrinthiformis (brain corals) is shown to improve sea surface temperature (SST) calibrations relative to instrumental data. Growth-corrected Sr/Ca–SST calibrations based on single-coral colonies over the same calibration interval, however, are found to be poorly suited for application to data from different coral colonies. This raises concerns about the accuracy of SST reconstructions from fossil coral measurements that involve extrapolation beyond the range of values seen during the calibration period. Here we pursue a novel approach to this problem by incorporating data from multiple coral colonies into a single growth-corrected Sr/Ca–SST calibration equation, effectively expanding the range of modern values constraining the model. The use of a multiple-colony calibration model for reconstructing SST yields greater precision and accuracy relative to instrumental data than single-colony models, providing greater confidence for applications to fossil coral samples.
    Description: A WHOI OCCI Fellowship (N.F.G.) and grants from NSF (OCE-0402728) and WHOI (N.F.G., K.A.H., A.L.C., and M.S.M.) supported this work.
    Keywords: Coral Sr/Ca ; Growth rate ; SST
    Repository Name: Woods Hole Open Access Server
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  • 7
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    Deglacial sea surface temperatures of the western tropical Pacific : a new look at old coral (2010)
    American Geophysical Union
    Details
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2004. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 19 (2004): PA4031, doi:10.1029/2004PA001084.
    Description: Using Secondary Ion Mass Spectrometry (SIMS) ion microprobe techniques, we generated annual Sr/Ca cycles with subweekly resolution from chunks of Porites coral retrieved from a Tahiti barrier reef drill core (149°W, 17°S), representing the period 13,650 to 13,100 years B.P. The centers of pristine skeletal septa were selectively targeted with a 10 μm diameter ion beam spot, avoiding adjacent pore spaces occupied by secondary aragonite needles. Applying a Sr/Ca–sea surface temperature (SST) calibration equation derived from modern Tahiti Porites having the same low growth rate as the fossil specimens, we obtained SSTs ∼0.5°–1.5°C cooler during the Bølling-Allerod relative to the present day, with no significant change in seasonality. On the contrary, we estimate that analysis of bulk samples would yield excessively cool Sr/Ca-based SST estimates due to the occupation by secondary aragonite crystals of up to 50% of the skeletal pore space in the ancient samples. We find that growth rate effects on coral Sr/Ca further depress the apparent mean annual derived SSTs (by 〉3°C) and amplify the apparent seasonality by selectively enhancing wintertime cooling. Our microscale analysis of pristine skeleton and application of an appropriate growth-dependent calibration yield Sr/Ca-derived SSTs that are in good agreement with those derived from Mg/Ca ratios of calcitic foraminifera which indicate a continuous postglacial warming of the western tropical Pacific, in phase with the warming of the tropical Atlantic.
    Description: Funds for this study were provided by NSF MG&G award number OCE-0241075.
    Keywords: Tropical Pacific ; Sea surface temperature ; Bølling-Allerod ; Coral Sr/Ca ; Ion microprobe ; Diagenesis
    Repository Name: Woods Hole Open Access Server
    Type: Article
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