ALBERT

Note: Contents Preface Prelude 1 The Earth-atmosphere system 1.1 Introduction 1.1.1 Descriptions of atmospheric behavior 1.1.2 Mechanisms influencing atmospheric behavior 1.2 Composition and structure 1.2.1 Description of air 1.2.2 Stratification of mass 1.2.3 Thermal and dynamical structure 1.2.4 Trace constituents 1.2.5 Cloud 1.3 Radiative equilibrium of the Earth 1.4 The global energy budget 1.4.1 Global-mean energy balance 1.4.2 Horizontal distribution of radiative transfer 1.5 The general circulation 1.6 Historical perspective: Global-mean temperature 1.6.1 The instrumental record 1.6.2 Proxy records Suggested references Problems 2 Thermodynamics of gases 2.1 Thermodynamic concepts 2.1.1 Thermodynamic properties 2.1.2 Expansion work 2.1.3 Heat transfer 2.1.4 State variables and thermodynamic processes 2.2 The First Law 2.2.1 Internal energy 2.2.2 Diabatic changes of state 2.3 Heat capacity 2.4 Adiabatic processes 2.4.1 Potential temperature 2.4.2 Thermodynamic behavior accompanying vertical motion 2.5 Diabatic processes 2.5.1 Polytropic processes Suggested references Problems 3 The Second Law and its implications 3.1 Natural and reversible processes 3.1.1 The Carnot cycle 3.2 Entropy and the Second Law 3.3 Restricted forms of the Second Law 3.4 The fundamental relations 3.4.1 The Maxwell Relations 3.4.2 Noncompensated heat transfer 3.5 Conditions for thermodynamic equilibrium 3.6 Relationship of entropy to potential temperature 3.6.1 Implications for vertical motion Suggested references Problems 4 Heterogeneous systems 4.1 Description of a heterogeneous system 4.2 Chemical equilibrium 4.3 Fundamental relations for a mufti-component system 4.4 Thermodynamic degrees of freedom 4.5 Thermodynamic characteristics of water 4.6 Equilibrium phase transformations 4.6.1 Latent heat 4.6.2 Clausius-Clapeyron Equation Suggested references Problems 5 Transformations of moist air 5.1 Description of moist air 5.1.1 Properties of the gas phase 5.1.2 Saturation properties 5.2 Implications for the distribution of water vapor 5.3 State variables of the two-component system 5.3.1 Unsaturated behavior 5.3.2 Saturated behavior 5.4 Thermodynamic behavior accompanying vertical motion 5.4.1 Condensation and the release of latent heat 5.4.2 The pseudo-adiabatic process 5.4.3 The Saturated Adiabatic Lapse Rate 5.5 The pseudo-adiabatic chart Suggested references Problems 6 Hydrostatic equilibrium 6.1 Effective gravity 6.2 Geopotential coordinates 6.3 Hydrostatic balance 6.3.1 Hypsometric equation 6.3.2 Meteorological Analyses 6.4 Stratification 6.4.1 Idealized stratification 6.5 Lagrangian interpretation of stratification 6.5.1 Adiabatic stratification: A paradigm of the troposphere 6.5.2 Diabatic stratification: A paradigm of the stratosphere Suggested references Problems 7 Static stability 7.1 Reaction to vertical displacement 7.2 Stability categories 7.2.1 Stability in terms of temperature 7.2.2 Stability in terms of potential temperature 7.2.3 Moisture dependence 7.3 Implications for vertical motion 7.4 Finite displacements 7.4.1 Conditional instability 7.4.2 Entrainment 7.4.3 Potential instability 7.4.4 Modification of stability under unsaturated conditions 7.5 Stabilizing and destabilizing influences 7.6 Turbulent dispersion 7.6.1 Convective mixing 7.6.2 Inversions 7.6.3 Life cycle of the nocturnal inversion 7.7 Relationship to observed thermal structure Suggested references Problems 8 Radiative transfer 8.1 Shortwave and longwave radiation 8.1.1 Spectra of observed SW and LW radiation 8.2 Description of radiative transfer 8.2.1 Radiometric quantities 8.2.2 Absorption 8.2.3 Emission 8.2.4 Scattering 8.2.5 The Equation of Radiative Transfer 8.3 Absorption characteristics of gases 8.3.1 Interaction between radiation and molecules 8.3.2 Line broadening 8.4 Radiative transfer in a plane parallel atmosphere 8.4.1 Transmission function 8.4.2 Two-stream approximation 8.5 Thermal equilibrium 8.5.1 Radiative equilibrium in a gray atmosphere 8.5.2 Radiative-convective equilibrium 8.5.3 Radiative heating 8.6 Thermal relaxation 8.7 The greenhouse effect 8.7.1 Feedback in the climate system 8.7.2 Unchecked feedback 8.7.3 Simulation of climate Suggested references Problems 9 Aerosol and cloud 9.1 Morphology of atmospheric aerosol 9.1.1 Continental aerosol 9.1.2 Marine aerosol 9.1.3 Stratospheric aerosol 9.2 Microphysics of cloud 9.2.1 Droplet growth by condensation 9.2.2 Droplet growth by collision 9.2.3 Growth of ice particles 9.3 Macroscopic characteristics of cloud 9.3.1 Formation and classification of cloud 9.3.2 Microphysical properties of cloud 9.3.3 Cloud dissipation 9.3.4 Cumulus detrainment: Influence on the environment 9.4 Radiative transfer in aerosol and cloud 9.4.1 Scattering by molecules and particles 9.4.2 Radiative transfer in a cloudy atmosphere 9.5 Roles of cloud and aerosol in climate 9.5.1 Involvement in the global energy budget 9.5.2 Involvement in chemical processes Suggested references Problems 10 Atmospheric motion 10.1 Description of atmospheric motion 10.2 Kinematics of fluid motion 10.3 The material derivative 10.4 Reynolds'transport theorem 10.5 Conservation of mass 10.6 The momentum budget 10.6.1 Cauchy's Equations of Motion 10.6.2 Momentum equations in a rotating reference frame 1 0.7 The first law of thermodynamics Suggested references Problems 11 Atmospheric equations of motion 11.1 Curvilinear coordinates 11.2 Spherical coordinates 11.2.1 The traditional approximation 11.3 Special forms of motion 11.4 Prevailing balances 11.4.1 Motion-related stratification 11.4.2 Scale analysis 11.5 Thermodynamic coordinates 11.5.1 Isobaric coordinates 11.5.2 Log-pressure coordinates 11.5.3 Isentropic coordinates Suggested references Problems 12 Large-scale motion 12.1 Ceostrophic equilibrium 12.1.1 Motion on an f plane 1 2.2 Vertical shear of the geostrophic wind 12.2.1 Classes of stratification 12.2.2 Thermal wind balance 12.3 Frictional geostrophic motion 1 2.4 Curvilinear motion 12.4.1 Inertial motion 12.4.2 Cyclostrophic motion 12.4.3 Gradient motion 12.5 Weakly divergent motion 12.5.1 Barotropic nondivergent motion 12.5.2 Vorticity budget under baroclinic stratification 12.5.3 Quasi-geostrophic motion Suggested references Problems 13 The planetary boundary layer 13.1 Description of turbulence 13.1.1 Reynolds decomposition 13.1.2 Turbulent diffusion 13.2 Structure of the boundary layer 13.2.1 The Ekman Layer 13.2.2 The surface layer 1 3.3 Influence of stratification 1 3.4 Ekman pumping Suggested references Problems 14 Wave propagation 14.1 Description of wave propagation 14.1.1 Surface water waves 14.1.2 Fourier synthesis 14.1.3 Limiting behavior 14.1.4 Wave dispersion 14.2 Acoustic waves 14.3 Buoyancy waves 14.3.1 Shortwave limit 14.3.2 Propagation of gravity waves in an inhomogeneous medium 14.3.3 The WKB approximation 14.3.4 Method of geometric optics 1 4.4 The Lamb wave 14.5 Rossby waves 14.5.1 Barotropic nondivergent Rossby waves 14.5.2 Rossby wave propagation in three dimensions 14.5.3 Planetary wave propagation in sheared mean flow 14.5.4 Transmission of planetary wave activity 14.6 Wave absorption 14.7 Nonlinear considerations Suggested references Problems 15 The general circulation 15.1 Forms of atmospheric energy 15.1.1 Moist static energy 15.1.2 Total potential energy 15.1.3 Available potential energy 1 5.2 Heat transfer in a zonally symmetric circulation 1 5.3 Heat transfer in a laboratory analogue 1 5.4 Quasi-permanent features 15.4.1 Thermal properties of the Earth's surface 1 5.4.2 Surface pressure and wind systems 1 5.4.3 Tropical circulations 15.5 Fluctuations of the circulation 15.5.1 Interannual changes 15.5.2 Intraseasonal variations Suggested references Problems 16 Dynamic stability 16.1 Inertial instability 16.2 Shear instability 16.2.1 Necessary conditions for instability 16.2.2