ALBERT

Note: Zugl.: Bremen, Univ., Diss., 1995

Note: CONTENTS: 1. Introduction. - 1.1 Scope of Aquatic Chemistry. - 1.2 The Solvent Water. - 1.3 Solute Species. - Suggested Readings. - Appendix 1.1: Some Useful Quantities, Units, Conversion Factors, Constants, and Relationships. - 2. Chemical Thermodynamics and Kinetics. - 2.1 Introduction. - 2.2 Chemical Thermodynamic Principles. - 2.3 Systems of Variable Composition: Chemical Thermodynamics. - 2.4 Gibbs Energy and Systems of Variable Chemical Composition. - 2.5 Chemical Potentials of Pure Phases and Solutions. - 2.6 Chemical Potentials of Aqueous Electrolytes. - 2.7 The Equilibrium Constant. - 2.8 The Gibbs Energy of a System. - 2.9 Driving Force for Chemical Reactions. - 2.10 Temperature and Pressure Effects on Equilibrium. - 2.11 Equilibrium Tools. - 2.12 Kinetics and Thermodynamics: Time and Reaction Advancement. - 2.13 Rate and Mechanism. - 2.14 Concentration Versus Time. - 2.15 Theory of Elementary Processes. - 2.16 Elementary Reactions and ACT. - 2.17 Equilibrium Versus Steady State in Flow Systems. - Suggested Readings. - Problems. - Answers to Problems. - 3. Acids and Bases. - 3.1 Introduction. - 3.2 The Nature of Acids and Bases. - 3.3 The Strength of an Acid or Base. - 3.4 Activity and pH Scales. - 3.5 Equilibrium Calculations. - 3.6 pH as a Master Variable; Equilibrium Calculations Using a Graphical Approach. - 3.7 Ionization Fractions of Acids, Bases, and Ampholytes. - 3.8 Titration of Acids and Bases. - 3.9 Buffer Intensity and Neutralizing Capacity. - 3.10 Organic Acids. - Suggested Readings. - Problems. - Answers to Problems. - 4. Dissolved Carbon Dioxide. - 4.1 Introduction. - 4.2 Dissolved Carbonate Equilibria (Closed System). - 4.3 Aqueous Carbonate System Open to the Atmosphere. - 4.4 Alkalinity and Acidity, Neutralizing Capacities. - 4.5 Alkalinity Changes. - 4.6 Analytical Considerations: Gran Plots. - 4.7 Equilibrium with Solid Carbonates. - 4.8 Kinetic Considerations. - 4.9 Carbon Isotopes and Isotope Fractionation. - Suggested Readings. - Problems. - Answers to Problems. - 5. Atmosphere-Water Interactions. - 5.1 Introduction. - 5.2 Anthropogenic Generation of Acidity in the Atmosphere. - 5.3 Gas-Water Partitioning: Henry's Law. - 5.4 Gas-Water Equilibria in Closed and Open Systems. - 5.5 Washout of Pollutants from the Atmosphere. - 5.6 Fog. - 5.7 Aerosols . - 5.8 Acid Rain - Acid Lakes. - 5.9 The Volatility of Organic Substances. - 5.10 Gas Transfer Across Water-Gas Interface. - Suggested Readings. - Problems. - Answers to Problems. - 6. Metal Ions in Aqueous Solution: Aspects of Coordination Chemistry. - 6.1 Introduction. - 6.2 Protons and Metal Ions. - 6.3 Hydrolysis of Metal Ions. - 6.4 Solubility and Hydrolysis: Solid Hydroxides and Metal Oxides. - 6.5 Chelates. - 6.6 Metal Ions and Ligands: Classification of Metals. - 6.7 Speciation in Fresh Waters. - 6.8 Seawater Speciation. - 6.9 Kinetics of Complex Formation. - Suggested Readings. - Problems. - Answers to Problems. - Appendix 6.1: Stability Constants. - Appendix 6.2: The Various Scales for Equilibrium Constants, Activity Coefficients, and pH. - 7. Precipitation and Dissolution. - 7.1 Introduction. - 7.2 The Solubility of Oxides and Hydroxides. - 7.3 Complex Formation and Solubility of (Hydr)oxides. - 7.4 Carbonates. - 7.5 The Stability of Hydroxides, Carbonates, and Hydroxide Carbonates. - 7.6 Sulfides and Phosphates. - 7.7 The Phase Rule: Components, Phases, and Degrees of Freedom. - 7.8 Solubility of Fine Particles. - 7.9 Solid Solutions. - Suggested Readings. - Problems. - Answers to Problems. - 8. Oxidation and Reduction; Equilibria and Microbial Mediation. - 8.1 Introduction. - 8.2 Redox Equilibria and the Electron Activity. - 8.3 The Electrode Potential: The Nernst Equation and the Electrochemical Cell. - 8.4 p[Epsilon]-pH, Potential-pH Diagrams. - 8.5 Redox Conditions in Natural Waters. - 8.6 Effect of Complex Formers on the Redox Potential. - 8.7 Measuring the Redox Potential in Natural Waters. - 8.8 The Potentiometric Determination of Individual Solutes. - Suggested Readings. - Problems. - Answers to Problems. - Appendix 8.1: Activity Ratio Diagrams for Redox Systems. - 9. The Solid-Solution Interface. - 9.1 Introduction. - 9.2 Adsorption. - 9.3 Adsorption Isotherms. - 9.4 Hydrous Oxide Surfaces; Reactions with H+, OH-, Metal Ions, and Ligands. - 9.5 Surface Charge and the Electric Double Layer. - 9.6 Correcting Surface Complex Formation Constants for Surface Charge. - 9.7 Sorption of Hydrophobic Substances on Organic Carbon-Bearing Particles. - 9.8 Ion Exchange. - 9.9 Transport of (Ad)sorbable Constituents in Groundwater and Soil Systems. - Suggested Readings. - Problems. - Appendix 9.1: The Gouy-Chapman Theory. - Appendix 9.2: Contact Angle, Adhesion and Cohesion, the Oil-Water Interface. - 10. Trace Metals: Cycling, Regulation, and Biological Role. - 10.1 Introduction: Global Cycling of Metals. - 10.2 Analytical Approaches to Chemical Speciation. - 10.3 Classification of Metal Ions and the Inorganic Chemistry of Life. - 10.4 Organometallic and Organometalloidal Compounds. - 10.5 Bioavailability and Toxicity. - 10.6 Metal Ions as Micronutrients. - 10.7 The Interaction of Trace Metals with Phytoplankton at the Molecular Level. - 10.8 Regulation of Trace Elements by the Solid-Water Interface in Surface Waters. - 10.9 Regulation of Dissolved Heavy Metals in Rivers, Lakes, and Oceans. - 10.10 Quality Criteria in Fresh Waters: Some Aspects. - Suggested Readings. - 11. Kinetics of Redox Processes. - 11 1 Introduction. - 11.2 How Good an Oxidant Is O2?. - 11.3 Can p[Epsilon] Be Defined for a Nonequilibrium System?. - 11.4 Kinetics of Redox Processes: Case Studies. - 11.5 Oxidants Used in Water and Waste Technology: A Few Case Studies. - 11.6 Linear Free Energy Relations (LFERs). - 11.7 The Marcus Theory of Outer-Sphere Electron Transfer: An Introduction. - 11.8 Nucleophile-Electrophile Interactions and Redox Reactions Involving Organic Substances. - 11.9 Corrosion of Metals as an Electrochemical Process. - Suggested Readings. - 12. Photochemical Processes. - 12.1 Introduction. - 12.2 Absorption of Light. - 12.3 Photoreactants. - 12.4 Photoredox Reactions: Photolysis of Transition Metal Complexes. - 12.5 Photochemical Reactions in Atmospheric Waters: Role of Dissolved Iron Species. - 12.6 Heterogeneous Photochemistry. - 12.7 Semiconducting Minerals. - Suggested Readings. - 13. Kinetics at the Solid-Water Interface: Adsorption, Dissolution of Minerals, Nucleation, and Crystal Growth. - 13.1 Introduction. - 13.2 Kinetics of Adsorption. - 13.3 Surface-Controlled Dissolution of Oxide Minerals: An Introduction to Weathering. - 13.4 Simple Rate Laws in Dissolution. - 13.5 Rates of CaCO3 Dissolution (and of CaCO3 Crystal Growth). - 13.6 Inhibition of Dissolution. - 13.7 Nucleation and Crystal Growth. - Suggested Readings. - 14. Particle-Particle Interaction: Colloids, Coagulation, and Filtration. - 14.1 Colloids. - 14.2 Particle Size Distribution. - 14.3 Surface Charge of Colloids. - 14.4 Colloid Stability: Qualitative Considerations. - 14.5 Effects of Surface Speciation on Colloid Stability. - 14.6 Some Water-Technological Considerations in Coagulation, Filtration, and Flotation. - 14.7 Filtration Compared with Coagulation. - 14.8 Transport in Aggregation and Deposition. - Suggested Readings. - Appendix 14.1: A Physical Model (DLVO) for Colloid Stability. - 15. Regulation of the Chemical Composition of Natural Waters. - 15.1 Introduction. - 15.2 Weathering and the Proton Balance. - 15.3 Isothermal Evaporation. - 15.4 Buffering. - 15.5 Interactions Between Organisms and Abiotic Environment: Redfield Stoichiometry. - 15.6 The Oceans: Relative Constancy of the Composition and Chemical Equilibria. - 15.7 Constancy of Composition: Steady State. - 15.8 Hydrothermal Vents. - 15.9 The Sediment-Water Interface. - 15.10 Biological Regulation of the Composition. - 15.11 Global Cycling: The Interdependence of Biogeochemical Cycles. - 15.12 The Carbon Cycle. - 15.13 Nitrogen Cycles:

Note: Teilw. zugl.: Bremen, Univ., Diss., 1995

Note: Contents Editor's note Acknowledgements page xu Notes on translations and definitions Abstract Preface Introduction 1 Geocryology as part of planetary cryology 2 Frozen rocks as natural-historical geological formations 3 History of research of the zone of permafrost and the frozen materials composing this zone 4 Structure, problems and scientific themes of geocryology 5 Methodological basis of geocryology I Thermal-physical, physico-chemical and mechanical processes in freezing, frozen and thawing ground and their manifestation in the permafrost regions 1 Thermal-physical processes in freezing and thawing ground 1.1 Heat transfer and temperature field in ground 1.2 Freezing (crystallization) of water and melting of ice in the ground 1.3 Sublimation and desublimation of moisture in frozen rocks 1.4 Freezing and thawing of ground 1.5 Methods for solving soil freezing (thawing) problems and approximate formulae for freezing and thawing depth calculations 2 Water transfer and ice formation in soils 2.1 Nature and mechanism of moisture migration in soils 2.2 Water transfer and ice formation in frozen soil 2.3 Water transfer and ice formation in freezing and thawing soils 3 Physico-chemical and mechanical processes in freezing and thawing ground 3.1 Chemical reactions and processes in freezing and thawing soils 3.2 Physico-chemical and mechanical processes in freezing and thawing soils 3.3 Physical-mechanical processes in frozen soils caused by changes in temperature 3.4 Physical and chemical processes in frozen soils caused by an external load 4 Structure and texture of freezing and thawing soils 4.1 Thermal-physical and physical-mechanical conditions of development of migrational-segregated ice interlayers 4.2 Basic types of cryogenic structure 4.3 Formation of structure in freezing and thawing soils 4.4 Structural associations and types of contact in frozen soils 5 Cryogenic geological processes and phenomena 5.1 Classification of processes and phenomena 5.2 Frost heaving of soils 5.3 Frost cracking (fissuring) and polygonal formations, surface and underground 5.4 Thermokarst 5.5 Slope processes and phenomena 5.6 Processes and effects associated with the activity of water, glaciers and other geological agents II Composition, cryogenic structure and properties of frozen rocks 6 Formation of sedimentary materials in the permafrost regions (cryolithogenesis) 6.1 Sediment genesis in the permafrost regions 6.2 Transformation of loose deposits of the permafrost regions into rock 6.3 Formation of useful mineral deposits at different stages of cryogenesis 7 Composition and structure of frozen earth materials 7.1 Characteristics of organic, mineral and chemical composition of frozen earth materials 7.2 Unfrozen water and ice in ground 7.3 Textural characteristics of the frozen material 7.4 Microstructure of frozen soils 8 Properties of frozen soils 8.1 Physical properties of the frozen materials 8.2 Thermal-physical properties of rocks 8.3 Moisture exchange properties of soils 8.4 Mechanical properties of frozen ground 9 Characteristics of the basic genetic types of frozen ground 9.1 Features of the cryogenic types of frozen strata 9.2 Composition and cryogenic structure of the principal geologic-genetic types of sedimentary materials in the permafrost regions 9.3 Natural ice as a monomineral rock III Principles of the formation and development of the frozen strata and layers of seasonal freezing and thawing 10 Thermodynamic and climatic conditions for formation of the frozen layers 10.1 Energy balance of the Earth 10.2 Thermodynamic conditions for development of seasonally and perennially frozen ground 10.3 Frozen ground as a result of zonation of thermal- and mass-exchange processes on the Earth's surface and in the atmosphere 11 Seasonal freezing and thawing of ground 11.1 Formation of the layer of seasonal freezing and thawing of soil 11.2 Types of seasonal freezing and thawing of the ground 11.3 The influence oflandscape-climatic factors on the temperature regime and depth of seasonal freezing and thawing of the ground 12 Development of the temperature regime and the thickness of the permafrost 12.1 Present-day knowledge of the development of permafrost 12.2 The effect of boundary conditions on the permafrost thickness and temperature regime 12.3 Dependence of the permafrost thickness and temperature regime on geological factors and processes 13 Taliks and groundwater in the permafrost zone 13.1 The types and formation of taliks in the permafrost zone 13.2 Groundwater of the permafrost regions 13.3 Interaction of groundwater with the permafrost and types of cryohydrogeological structures IV Regional features and evolution of permafrost 14 Permafrost evolution in the Earth's history 14.1 History of the development of permafrost and its distribution on the planet 14.2 Reasons for the development and evolution of permafrost in the Earth's history 14.3 The history of geocryological development and the main stages of permafrost formation on the territory of the former USSR in the Late Cenozoic 15 Zonal and regional features of present-day geocryological conditions in the territories of the former USSR 15.1 Distribution of permafrost and spatial variations of its mean annual temperature 15.2 Structure of the permafrost and spatial variability of its thickness 15.3 Distribution of main types of seasonal ground thawing and freezing 16 Principles and methods for regional geocryological investigations 16.1 Geocryological survey as the basis for regional investigation of the seasonally and perennially freezing zones 16.2 The methods and carrying-out of geocryological surveys 16.3 Classification and regionalization in the course of geocryological survey 16.4 Regionalization in geocryological mapping V Rational use of frozen ground and environmental protection in the course of economic development of the permafrost regions 17 The effect of different types of development on the natural geocryological environment 17.1 The basic principles of rational use of frozen ground in the course of the economic development of the permafrost regions 17.2 Regional environmental change in the course of development of extensive areas within the permafrost zone 17.3 Economic development of the permafrost regions with various kinds of construction 17.4 Development in the permafrost regions for the mining industry and underground engineering 17.5 Types of agrobiological development in the permafrost regions 18 Ensuring the stability of engineering structures in the permafrost regions 18.1 Principles of construction on permafrost (bases and foundations) 18.2 Methods of amelioration of frozen ground for foundations 18.3 Principles of foundation design and selection of type of foundation for construction on permafrost 18.4 Normative documents for engineering design and construction in the permafrost regions 19 Engineering geology in support of design, construction and operation of structures in the permafrost regions 19.1 Engineering-geological survey in the permafrost regions 19.2 Forecasting change in the geocryological conditions in the course of development 19.3 Principles and methods of the control of cryogenic processes 19.4 The basis of the rational use and protection of the geological environment in the permafrost regions References Index

Note: Contents: Figures. - Tables. - Preface. - Illustrations. - 1. Introduction. - 1.1 Background. - 1.2 Scope of the text. - 1.3 World vegetation types. - 1.3.1 Vegetation formations and zones. - 1.3.2 Zonobiomes. - 1.3.3 Exoclimates. - 1.3.4 The Canadian vegetation classification system. - 1.3.5 Ecozones. - 1.3.6 Floristic realms. - 1.3.7 Plant species nomenclature. - 1.4 Soil classification and soil systems. - 1.5 Climatic parameters. - 1.5.1 The role of climate. - 1.5.2 Moisture indices. - 1.5.3 Climate diagrams. - 1.6 Plant strategies. - 1.6.1 Competition. - 1.6.2 Hydrature and moisture regulation. - 1.6.3 Life forms. - 1.6.4 Leaf morphology and adaptation. - 1.7 Biomass and net primary productivity. - 2. Tundra 2.1 Tundra distribution. - 2.2 Climate. - 2.3 Soils. - 2.4 Tundra in North America. - 2.4.1 Ecoclimatic sub-provinces and regions. - 2.4.2 High and mid-Arctic. - 2.4.3 Low Arctic. - 2.5 Tundra in other Northern Hemisphere locations. - 2.5.1 Arctic Tundra. - 2.5.2 Typical Tundra. - 2.5.3 Southern Tundra. - 2.5.4 Tundra on Arctic Islands. - 2.6 Tundea in the Southern Hemisphere. - 2.6.1 The Antarctic Subregion. - 2.6.2 The Sub-Antarctic Subregion. - 2.7 Alpine Tundra. - 2.7.1 Temperate-latitude alpine Tundra. - 2.7.2 Low-latitude (equatorial) alpine Tundra. - 2.8 Primary production and phytomass in Tundra. - 3. Forest-Tundra or Boreal-Tundra Ecotone. - 3.1 Definitions. - 3.2 Distribution. - 3.3 Climate. - 3.4 Soils. - 3.5 Forest-Tundra in Canada. - 3.5.1 Ecoclimatic sub-provinces. - 3.5.2 The shrub subzone (Northern Forest-Tundra). - 3.5.3 The forest subzone (Southern Forest Tundra). - 3.6 Eurasian Forest-Tundra. - 3.7 Primary production and phytomass in forest-Tundra. - 4. Boreal Forest (Taiga) and Mixed Forest Transition. - 4.1 Distribution. - 4.2 Climate. - 4.3 Soils. - 4.4 Boreal forest in North America. - 4.4.1 Open Lichen Woodland. - 4.4.2 Northern Coniferous Forest. - 4.4.3 Mixed-Forest (Boreal-Broadleaf ecotone). - 4.4.4 Mixed-Forest transition to grassland (Northern Mixedwoods). - 4.5 Eurasian Boreal. - 4.5.1 The European Boreal. - 4.5.2 The Siberian Boreal. - 4.5.3 Northwest Pacific Fringe Boreal. - 4.6 Primary production and phytomass in boreal forest. - 5. Prairie (Steppe). - 5.1 Distribution. - 5.2 Climate. - 5.2.1 North America. - 5.2.2 Climate in Eurasia and elsewhere. - 5.3 Soils. - 5.4 Prairie in North America. - 5.4.1 The Canadian Prairie. - 5.4.2 Prairie in the USA. - 5.5. Eurasian Steppe. - 5.6 Southern Hemisphere Grasslands. - 5.6.1 The High Veldt. - 5.6.2 The Pampas/Campos Grasslands. - 5.7 Primary production and biomass. - 6. Cordilleran Environments in Western North America. - 6.1 Canada's Cordilleran ecoclimatic provinces. - 6.1.1 Distribution. - 6.1.2 Climate. - 6.1.3 Soils. - 6.1.4 Pacific Coastal Mesothermal Forest. - 6.1.5 Pacific Coastal Subalpine Forest. - 6.1.6 Cordilleran Forest Region. - 6.1.7 Cordilleran Cold Steppe and Savanna Forst. - 6.1.8 Canadian Cordilleran Subalpine Forest. - 6.1.9 Alpine Tundra and Boreal Forest. - 6.2 The Cordilleran Region in the USA. - 6.2.1 Distribution. - 6.2.2 Northwest Coast Conifer-Hardwood Forests. - 6.2.3 Montane Pine Forests. - 6.2.4 Sagebrush and Grasslands. - 6.2.5 Interior Hemlock-Douglas-Fir-Larch. - 6.2.6 Subalpine Forest. - 6.3 Primary Production and Phytomass. - 7. Temperate Deciduous Forests. - 7.1 Distribution. - 7.2 Climate. - 7.3 Soils. - 7.4 Temperate Deciduous Forest in North America. - 7.4.1 Canada. - 7.4.2 United States of America. - 7.4.3 Southern Mexico and South America. - 7.5 Europe. - 7.5.1 Atlantic Deciduous Forest. - 7.5.2 Central European Deciduous Forest. - 7.5.3 East European Deciduous Forest. - 7.6 Asia. - 7.7 Southern Hemisphere. - 7.8 Primary Production and Phytomass. - 8. Wetlands. - 8.1 Introduction. - 8.2 Climate. - 8.3 Soils. - 8.4 Canadian Wetland Classification. - 8.4.1 Canadian Wetland Classification System. - 8.4.2 Wetland classes. - 8.4.3 Wetland forms and types. - 8.5 Canadian Wetlands. - 8.5.1 Arctic Wetlands. - 8.5.2 Subarctic Wetlands. - 8.5.3 Boreal Wetlands. - 8.5.4 Prairie Wetlands. - 8.5.5 Temperate Wetlands. - 8.5.6 Oceanic Wetlands. - 8.5.7 Mountain Wetlands. - 8.6 Wetlands in the USA. - 8.7 Eurasian Wetlands. - 8.7.1 European Wetlands. - 8.7.2 Asian Wetlands. - 8.8 Central and South American Wetlands. - 8.9 African Wetlands. - 8.10 Austromalesian and Pacific Wetlands. - 8.11 Phytomass and Primary Production. - 9. Conclusion. - Appendix: Biomials and their local names as used in the text. - Bibliography. - Index.

Note: Contents: Preface. - 1 Getting Started. - 2 Essentials of the R Language. - 3 Data Input. - 4 Dataframes. - 5 Graphics. - 6 Tables. - 7 Mathematics. - 8 Classical Tests. - 9 Statistical Modelling. - 10 Regression. - 11 Analysis of Variance. - 12 Analysis of Covariance. - 13 Generalized Linear Models. - 14 Count Data. - 15 Count Data in Tables. - 16 Proportion Data. - 17 Binary Response Variables. - 18 Generalized Additive Models. - 19 Mixed-Effects Models. - 20 Non-linear Regression. - 21 Tree Models. - 22 Time Series Analysis. - 23 Multivariate Statistics. - 24 Spatial Statistics. - 25 Survival Analysis. - 26 Simulation Models. - 27 Changing the Look of Graphics. - References and Further Reading. - Index.

Note: Contents Preface 1 The evidence for cryospheric change 1.1 Introduction 1.2 The geomorphic and hydrologic effects of cryospheric change 1.3 Sub-arctic and alpine hydrology 1.4 Glacier loss and mountain permafrost 1.5 Permafrost 1.6 The carbon balance of the cryosphere 1.7 River and lake ice break-up and freeze-up 1.8 Ocean circulation 1.9 The mass balance of the polar ice sheets 1.10 Sea level 1.11 Importance of sea ice. 1.12 Ecological impacts 1.13 Socio-economic effects 1.14 Conclusions (Text word count-including figure captions and tables but excluding references- 9,015) 2 The monitoring of cryospheric change 2.1 Introduction 2.2 In situ measurements 2.2.1 Land surface air temperature 2.2.2 Terrestrial snow and snow on sea ice 2.2.3 Sea ice 2.2.4 Ice sheets and alpine glaciers 2.2.5 Permafrost and seasonally frozen ground 2.2.6 River runoff 2.2.7 River and lake ice freeze-up and break-up 2.3 Conclusions 3 Processes of cryospheric change 3.1 Introduction 3.2 Snow and ice as energy regulators 3.2.1 The energetics of the snow surface 3.2.2 The energetics of the snowpack 3.2.3 The energetics of glaciers 3.2.4 The energetics of sea ice and various terrain types 3.2.5 Permafrost 3.3 Snow and ice reservoir functions 3.3.1 Mass budget for snow 3.3.2 Mass balance for glacier ice 3.3.3 The mass balance of an ice sheet 3.3.4 Mass balance of sea ice 3.4 Snowfall 3.4.1 Interception by vegetation 3.4.2 Snow accumulation 3.4.3 Snow cover structure 3.5 Snow avalanches 3.6 Snow melt, runoff and streamflow generation 3.7 Snow chemistry 3.8 Snow ecology 3.9 Glacier melt 3.10 Formation of an ice cover 3.11 River and lake ice 3.12 Sediment budgets 4 Patterns of the contemporary cryosphere at local to global scales 4.1 Introduction 4.2 Remote sensing observations 4.3 Land and sea surface temperature 4.3.1 Terrestrial snow and snow on sea ice 4.3.2 Sea ice 4.3.3 Ice sheets & glaciers: estimation of volume 4.3.4 Ice sheets & glaciers: mass balance components 4.3.5 Permafrost 4.3.6 River runoff 4.3.7 River and lake ice freeze-up/break-up 4.4 Numerical Models 4.5 Conclusions: validation, coordinated projects and climate data records 5 The evidence for past cryospheric changes 5.1 Introduction 5.2 The uniqueness of the Quaternary Period 5.3. Initiation of glacial ages 5.4 Reconstructing extent of glacial environments 5.5 Extreme events 5.6 Ice sheet modelling 5.6.1 The Antarctic Ice Sheet 5.6.2 Greenland 5.6.3 North America: Innuitian, Laurentide and Cordilleran ice sheets 5.6.4 British Isles, Scandinavian and Barents ice sheets 5.6.5 The Patagonian and New Zealand ice caps 5.7 Non-glacial Quaternary environments 5.7.1 Late Quaternary permafrost in North America and Europe 5.7.2 Treeline variations 5.7.3 Climatic snowline 5.7.4 Glacier fluctuations 5.7.5 Paraglaciation 6 The transience of the cryosphere and transitional landscapes 6.1 Introduction 6.1.1 The landscape as palimpsest 6.2 Glacial landscapes: macro scale 6.2.1 Cirque landscapes 6.2.2 Fjord and strandflat landscapes 6.3 Periglacial landscapes: macro-scale 6.4 Paraglacial landscapes: macro-scale 6.5 Glacial landscapes: medium-scale 6.5.1 The transition from glacial to fluvial dominance 6.6 Proglacial landscapes: medium-scale 6.6.1 Glacifluvial landforms 6.6.2 The Channeled Scablands 6.6.3 Sub-glacial channels 6.6.4 Sub-glacial, ice-marginal and supraglacial sediment-landform associations 6.7 Periglacial landscapes: medium scale 6.7.1 The transition from periglacial to fluvial dominance 6.8 Paraglacial landscapes: medium-scale 6.9 Glacial landscapes: local-scale 6.9.1 Primary glacigenic deposits 6.9.2 Small scale erosional forms 6.10 Proglacial landscapes: local-scale 6.11 Periglacial landscapes: local scale 6.13 Paraglacial landscapes: local-scale 6.13 Landscape resistance, collapse and recovery 6.14 Transitional landscapes at Quaternary, Holocene and Anthropocene timescales 7 Cryospheric change and vulnerability at Quaternary, Holocene and Anthropocene time scales 7.1 Introduction 7.2 Panarchy 7.2.1 Panarchy, sustainability and transformability 7.2.2 Collapse and the vulnerability of socio-economic systems 7.3 Changing ice cover and biomes since the Last Glacial Maximum 7.3.1 The Last Glacial Maximum 7.3.2 The Holocene Optimum 7.4 The first explorers in North America 7.5 Implications of cryospheric change/collapse 7.5.1 Snow quantity 7.5.2 Snow quality 7.5.3 River and lake ice 7.5.4 Permafrost 7.5.5 Glaciers 7.5.6 River basins 7.5.7 Sea ice 7.5.8 Ice sheets 7.5.9 Sea level change 7.5.10 Carbon sequestration 7.5.11 Vegetation 7.5.12 Polar bears 7.5.13 Human health 7.5.14 Persistent organic pollutants 7.5.15 Socio-cultural conditions and health status 7.5.16 Livelihoods and socio-economic conditions 7.5.17 Governance 7.6 Concluding thoughts References Index

Note: Table of Contents: Chapter 1 Randomization. - 1.1 The Idea of a Randomization Test. - 1.2 Examples of Randomization Tests. - 1.3 Aspects of Randomization Testing Raised by the Examples. - 1.3.1 Sampling the Randomization Distribution or Systematic Enumeration. - 1.3.2 Equivalent Test Statistics. - 1.3.3 Significance Levels for Classical and Randomization Tests. - 1.3.4 Limitations of Randomization Tests. - 1.4 Confidence Limits by Randomization. - 1.5 Applications of Randomization in Biology and Related Areas. - 1.5.1 Single Species Ecology. - 1.5.2 Genetics, Evolution, and Natural Selection. - 1.5.3 Community Ecology. - 1.5.4 Other Environmental Applications. - 1.6 Randomization and Observational Studies. - 1.7 Chapter Summary. - Chapter 2 The Jackknife. - 2.1 The Jackknife Estimator. - 2.2 Applications of Jackknifing in Biology. - 2.2.1 Single-Species Analyses. - 2.2.2 Genetics, Evolution, and Natural Selection. - 2.2.3 Community Ecology. - 2.3 Chapter Summary. - Chapter 3 The Bootstrap. - 3.1 Resampling with Replacement. - 3.2 Standard Bootstrap Confidence Limits. - 3.3 Simple Percentile Confidence Limits. - 3.4 Bias- Corrected Percentile Confidence Limits. - 3.5 Accelerated Bias-Corrected Percentile Limits. - 3.6 Other Methods for Constructing Confidence Intervals. - 3.7 Transformations to Improve Bootstrap-t Intervals. - 3.8 Parametric Confidence Intervals. - 3.9 A Better Estimate of Bias. - 3.10 Bootstrap Tests of Significance. - 3.11 Balanced Bootstrap Sampling. - 3.12 Applications of Bootstrapping in Biology. - 3.12.1 Single-Species Ecology. - 3.12.2 Genetics, Evolution, and Natural Selection. - 3.12.3 Community Ecology. - 3.12.4 Other Ecological and Environmental Applications. - 3.13 Further Reading. - 3.14 Chapter Summary. - Chapter 4 Monte Carlo Methods. - 4.1 Monte Carlo Tests. - 4.2 Generalized Monte Carlo Tests. - 4.3 Implicit Statistical Models. - 4.4 Applications of Monte Carlo Methods in Biology. - 4.4.1 Single-Species Ecology. - 4.4.2 Genetics and Evolution. - 4.4.3 Community Ecology. - 4.5 Chapter Summary. - Chapter 5 Some General Considerations. - 5.1 Questions about Computer-Intensive Methods. - 5.2 Power. - 5.3 Number of Random Sets of Data Needed for a Test. - 5.4 Determining a Randomization Distribution Exactly. - 5.5 The Number of Replications for Confidence Intervals. - 5.6 More Efficient Bootstrap Sampling Methods. - 5.7 The Generation of Pseudo-Random Numbers. - 5.8 The Generation of Random Permutations. - 5.9 Chapter Summary. - Chapter 6 One- and Two-Sample Tests. - 6.1 The Paired Comparisons Design. - 6.2 The One-Sample Randomization Test. - 6.3 The Two-Sample Randomization Test. - 6.4 Bootstrap Tests. - 6.5 Randomizing Residuals. - 6.6 Comparing the Variation in Two Samples. - 6.7 A Simulation Study. - 6.8 The Comparison of Two Samples on Multiple Measurements. - 6.9 Further Reading. - 6.10 Chapter Summary. - Chapter 7 Analysis of Variance. - 7.1 One-Factor Analysis of Variance. - 7.2 Tests for Constant Variance. - 7.3 Testing for Mean Differences Using Residuals. - 7.4 Examples of More Complicated Types of Analysis of Variance. - 7.5 Procedures for Handling Unequal Variances. - 7.6 Other Aspects of Analysis of Variance. - 7.7 Further Reading. - 7.8 Chapter Summary. - Chapter 8 Regression Analysis. - 8.1 Simple Linear Regression. - 8.2 Randomizing Residuals. - 8.3 Testing for a Nonzero β Value. - 8.4 Confidence Limits for β. - 8.5 Multiple Linear Regression. - 8.6 Alternative Randomization Methods with Multiple Regression. - 8.7 Bootstrapping and Jackknifing with Regression. - 8.8 Further Reading. - 8.9 Chapter Summary. - Chapter 9 Distance Matrices and Spatial Data. - 9.1 Testing for Association between Distance Matrices. - 9.2 The Mantel Test. - 9.3 Sampling the Randomization Distribution. - 9.4 Confidence Limits for Regression Coefficients. - 9.5 The Multiple Mantel Test. - 9.6 Other Approaches with More Than Two Matrices. - 9.7 Further Reading. - 9.8 Chapter Summary. - Chapter 10 Other Analyses on Spatial Data. - 10.1 Spatial Data Analysis. - 10.2 The Study of Spatial Point Patterns. - 10.3 Mead's Randomization Test. - 10.4 Tests for Randomness Based on Distances. - 10.5 Testing for an Association between Two Point Patterns. - 10.6 The Besag-Diggle Test. - 10.7 Tests Using Distances between Points. - 10.8 Testing for Random Marking. - 10.9 Further Reading. - 10.10 Chapter Summary. - Chapter 11 Time Series. - 11.1 Randomization and Time Series. - 11.2 Randomization Tests for Serial Correlation. - 11.3 Randomization Tests for Trend. - 11.4 Randomization Tests for Periodicity. - 11.5 Irregularly Spaced Series. - 11.6 Tests on Times of Occurrence. - 11.7 Discussion on Procedures for Irregular Series. - 11.8 Bootstrap Methods. - 11.9 Monte Carlo Methods. - 11.10 Model-Based vs. Moving-Block Resampling. - 11.11 Further Reading. - 11.12 Chapter Summary. - Chapter 12 Multivariate Data. - 12.1 Univariate and Multivariate Tests. - 12.2 Sample Mean Vectors and Covariance Matrices. - 12.3 Comparison of Sample Mean Vectors. - 12.4 Chi-Squared Analyses for Count Data. - 12.5 Comparison of Variations for Several Samples. - 12.6 Principal Components Analysis and Other One-Sample Methods. - 12.7 Discriminant Function Analysis. - 12.8 Further Reading. - 12.9 Chapter Summary. - Chapter 13 Survival and Growth Data. - 13.1 Bootstrapping Survival Data. - 13.2 Bootstrapping for Variable Selection. - 13.3 Bootstrapping for Model Selection. - 13.4 Group Comparisons. - 13.5 Growth Data. - 13.6 Further Reading. - 13.7 Chapter Summary. - Chapter 14 Nonstandard Situations. - 14.1 The Construction of Tests in Nonstandard Situations. - 14.2 Species Co-Occurrences on Islands. - 14.3 Alternative Switching Algorithms. - 14.4 Examining Time Changes in Niche Overlap. - 14.5 Probing Multivariate Data with Random Skewers. - 14.6 Ant Species Sizes in Europe. - 14.7 Chapter Summary. - Chapter 15 Bayesian Methods. - 15.1 The Bayesian Approach to Data Analysis. - 15.2 The Gibbs Sampler and Related Methods. - 15.3 Biological Applications. - 15.4 Further Reading. - 15.5 Chapter Summary. - Chapter 16 Final Comments. - 16.1 Randomization. - 16.2 Bootstrapping. - 16.3 Monte Carlo Methods in General. - 16.4 Classical vs. Bayesian Inference. - References. - Appendix Software for Computer-Intensive Statistics. - Author Index. - Subject Index.