ALBERT

Notes: Abstract Because fluid flow in porous media is opaque to most observational techniques simulations of the processes occurring in porous media have become important. Typical reservoir simulations treat the flow as taking place in some averaged (Darcy-scale) medium but simulations can also be carried out at the level of the network of pores and throats of the porous medium. We report the results of a pore-scale investigation of mechanisms for the alteration of mobility by foam lamella blockage in a network of these spaces and channels of porous media. Saturation and relative permeability curves are obtained using well-known power-law expressions of percolation theory and a rescaling of the percolation parameter readily permits a number of lamella-blocking mechanisms to be treated. An explanation of the shift in breakthrough gas saturation and the deformation of the shape of permeabilityvs saturation curves upon introduction of foam is provided for a variety of blocking mechanisms. The qualitatively different features seen in experimental studies of modification of gas mobility by foam can be rationalized using only two parameters which characterize the throat-size at which blockage commences and the degree of blockage.

Notes: A broad continuum exists between two distinct end-member types of mountain building. Alpine-type orogenic belts develop during subduction of an ocean basin between two continental blocks, resulting in collision. They are characterized by an imbricate sequence of oceanward verging nappes; some Alpine belts exhibit superimposed late-stage backthrusting. Sediments are chiefly platform carbonates and siliciclastics, in some cases associated with minor amounts of bimodal volcanics; pre-existing granitic gneisses and related continental rocks constitute an autochthonous–parautochthonous basement. Metamorphism of deeply subducted portions of the orogen ranges from relatively high-pressure (HP) to ultrahigh-pressure (UHP). Calcalkaline volcanic–plutonic rocks are rare, and have peraluminous, S-type bulk compositions. In contrast, Pacific-type orogens develop within and landward from long-sustained oceanic subduction zones. They consist of an outboard oceanic trench–accretionary prism, and an inboard continental margin–island arc. The oceanic assemblage consists of first-cycle, in-part mélanged volcaniclastics, and minor but widespread cherts ± deep-water carbonates, intimately mixed with disaggregated ophiolites. The section recrystallized under HP conditions. Recumbent fold vergence is oceanward. A massive, slightly older to coeval calcalkaline arc is sited landward from the trench complex on the stable, non-subducted plate. It consists of abundant, dominantly intermediate, metaluminous, I-type volcanics resting on old crust; both assemblages are thrown into open folds, intruded by comagmatic I-type granitoids, and metamorphosed locally to regionally under high-T, low-P conditions. In the subduction channel of collisional and outboard Circumpacific terranes, combined extension above and subduction below allows buoyancy-driven ascent of ductile, thin-aspect ratio slices of HP–UHP complexes to midcrustal levels, where most closely approached neutral buoyancy; exposure of rising sheets caused by erosion and gravitational collapse results in moderate amounts of sedimentary debris because exhumed sialic slivers are of modest volume. At massive sialic buildups associated with convergent plate cuSPS (syntaxes), tectonic aneurysms may help transport HP–UHP complexes from mid- to upper-crustal levels. The closure of relatively small ocean basins that typify many intracratonic suture zones provides only limited production of intermediate and silicic melts, so volcanic–plutonic belts are poorly developed in Alpine orogens compared with Circumpacific convergent plate junctions. Generation of a calcalkaline arc mainly depends on volatile evolution at the depth of magma generation. Phase equilibrium studies show that, under typical subduction-zone P–T trajectories, clinoamphibole ± Ca–Al hydrous silicates constitute the major hydroxyl-bearing phases in deep-seated metamorphic rocks of MORB composition; other hydrous minerals are of minor abundance. Ca and Na clinoamphiboles dehydrate at pressures of above approximately 2 GPa, but low-temperature devolatilization may be delayed by pressure overstepping; thus metabasaltic blueschists and amphibolites expel H2O at melt-generation depths, and commonly achieve stable eclogitic assemblages. Partly serpentinized mantle beneath the oceanic crust dehydrates at roughly comparable conditions. For reasonable subduction-zone geothermal gradients however, white micas ± biotites remain stable to pressures 〉3 GPa. Accordingly, attending descent to depths of 〉100 km, mica-rich quartzofeldspathic lithologies that constitute much of the continental crust fail to evolve substantial amounts of H2O, and transform incompletely to stable eclogite-facies assemblages. Underflow of amphibolitized oceanic lithosphere thus generates most of the deep-seated volatile flux, and the consequent partial melting to produce the calcalkaline suite, along and above a subduction zone; where large volumes of micaceous intermediate and felsic crustal materials are carried down to great depths, volatile flux severely diminishes. Thus, continental collision in general does not produce a volcanic–plutonic arc whereas in contrast, the long-continued contemporaneous underflow of oceanic lithosphere does.

Notes: Temperature, light and dissolved nutrients are considered the “master” abiotic properties controlling primary production in the ocean. Each of these properties, in turn, is influenced by water column stability Sustained research over the past several decades has endeavored to ascertain which of these properties is most important in regulating phytoplankton growth. In no region has this research effort been more evident than at high latitudes. For both polar regions, extremes in each of these properties is the rule in surface waters where phytoplankton grow: the lowest ocean temperatures, the greatest seasonal excursion in incident solar radiation, and the highest dissolved nutrient concentrations.Based largely on indirect evidence, early researchers speculated that polar primary production was high relative to production at lower latitudes. This was commonly attributed to the abundant surface “macronutrients” (NO3, PO4, H4SiO4) since physiological adaptations to the suboptimum temperatures and light were thought to characterise these high latitude populations. Intensification of polar research since the late 1960's has in many respects modified this view. Current perspectives are that important differences exist between the Arctic and Antarctic with regard to the availability and role nutrients play in regulating primary production. In general much less emphasis is now placed on the significance of the macronutrients in the Antarctic although there is speculation and some evidence that “micronutrients” (Fe) may be important. Macronutrient availability appears to play a more important, though secondary, role in the Arctic, that of sustaining rather than initiating phytoplankton growth.This paper reviews early, contemporary, and present research addressing the question, “What role does nutrient availability play in the distribution and magnitude of primary production in Arctic and Antarctic waters?” Emphasis is placed on new research on under-ice communities as well as on the historically studied pelagic communities.

Notes: Night-time lunar geomagnetic tides have been analysed for a set of mid-latitude European observatories, using International Quiet Sun Years (IQSY) data. It is found that the variations with longitude are consistent with those expected on the Chapman–Kendall theory for a tidally induced electric current flowing north–south in the Atlantic Ocean together with an image current induced in the solid Earth.

Notes: Samples of beach gravels were obtained from foreshore cusp deposits at Portmore Beach, near Malin Head, Republic of Ireland. Axial dimensions (A, B and C) were measured, and the maximum projection sphericity was derived, for each of 4360 clasts. Each sample was also categorized according to depositional subenvironment. Principal components analysis and cluster analysis were used to identify potential facies zonation. Results indicate that reworking of the foreshore by incident and edge waves resulted in clast size and shape segregation both parallel and perpendicular to the beach. Patterns of zonation were distinctly different from those described in earlier facies descriptions, showing a complex set of foreshore facies. The distribution of these facies was controlled primarily by location within beach cusp systems. Primary and secondary facies demonstrate alongshore variability of a magnitude comparable to across shore differences. The results have important implications for palaeoenvironmental reconstruction, morphosedimentary description and research sampling design, and provide the basis for a conceptual model of gravel beach cusp facies.

Notes: Abstract Ultrahigh-pressure (UHP) metamorphism refers to mineralogical and structural readjustment of supracrustal protoliths and associated mafic-ultramafic rocks at mantle pressures greater than ∼ 25 kbar (80-90 km). Typical products include metapelite, quartzite, marble, granulite, eclogite, paragneiss and orthogneiss; minor mafic and ultramafic rocks occur as eclogitic-ultramafic layers or blocks of various dimensions within the supracrustal rocks. For appropriate bulk compositions, metamorphism at great depths produces coesite, microdiamond and other characteristic UHP minerals with unusual compositions. Thus far, at least seven coesite-bearing eclogitic terranes and three diamond-bearing UHP regions have been documented. All lie within major continental collision belts in Eurasia, have similar supracrustal protoliths and metamorphic assemblages, occur in long, discontinuous belts that may extend several hundred kilometers or more, and typically are associated with contemporaneous high-P blueschist belts. This paper defines the P-T regimes of UHP metamorphism and describes mineralogical, petrological and tectonic characteristics for a few representative UHP terranes including the western gneiss region of Norway, the Dora Maira massif of the western Alps, the Dabie Mountains and the Su-Lu region of east-central China, and the Kokchetav massif of the former USSR. Prograde P-T paths for coesite-bearing eclogites require abnormally low geothermal gradients (approximately 7°C/km) that can be accomplished only by subduction of cold, oceanic crust-capped lithosphere ± pelagic sediments or an old, cold continent. The preservation of coesite inclusions in garnet, zircon, omphacite, kyanite and epidote, and microdiamond inclusions in garnet and zircon during exhumation of an UHP terrane requires either an extraordinarily fast rate of denudation (up to 10 cm/year) or continuous refrigeration in an extensional regime (retreating subduction zone).

Notes: Abstract Mineral equilibria in the system CaO–MgO–Al2O3–SiO2–H2O provide a basis for mapping of four reaction isograds and one bathograd in the low-pressure transition from subgreenschist to greenschist facies. Most of the Matachewan area of the Abitibi greenstone belt is in the lower-pressure bathozone, as indicated by the widespread occurrences of the subassemblage Prh–Chl. The higher-pressure bathozone is indicated by two occurrences of Pmp–Act–Ep–Qtz, but in these samples the bathograd is displaced to anomalously low pressure by the high Fe content of the coexisting minerals. This illustrates the need to analyse coexisting minerals, calculate activities of end-member species, and compute P–T curves for individual samples before interpreting the isograd/bathograd pattern.Petrographic and microprobe analysis indicates that great care must be taken in the selection of ‘equilibrium’ assemblages. Pyroxene phenocrysts in one sample are replaced by the assemblage Pmp–Act–Ep–Chl–Qtz, whereas Prh–Act–Ep–Chl–Qtz occurs in the groundmass. Compositional variation may be more cryptic, as in a sample of metabasaltic hyaloclastite that contains two spatially distinct ‘univariant’ assemblages, Prh–Pmp–Ep–Chl–Qtz and Prh–Act–Ep–Chl–Qtz, within the devitrified matrix. Whereas chlorite compositions are similar in both assemblages, prehnite and epidote in the latter assemblage are significantly richer in Fe and poorer in Al. Accordingly, the rock is interpreted to contain two distinct ‘univariant’ assemblages, rather than one ‘invariant’ assemblage (Prh–Pmp–Act–Ep–Chl–Qtz). The displaced ‘univariant’ curves for this sample intersect at 2.2 kbar and 250°C.Taking account of all thermobarometric implications, the low-grade limit of the greenschist facies is at 250–270°C and 2–2.5 kbar, corresponding to depths of 7–8 km. Comparison of apparent P–T conditions on both sides of the Larder Lake – Cadillac break, a regional CO2-metasomatized fault zone that is spatially associated with many Archaean gold deposits, provides an upper limit of not more than c. 1 km for post-metamorphic south-side-up, dip-slip displacement.

Notes: Abstract The Qinling–Dabie accretionary fold belt in east-central China represents the E–W trending suture zone between the Sino-Korean and Yangtze cratons. A portion of the accretionary complex exposed in northern Hubei Province contains a high-pressure/low-temperature metamorphic sequence progressively metamorphosed from the blueschist through greenschist to epidote–amphibolite/eclogite facies. The ‘Hongan metamorphic belt’can be divided into three metamorphic zones, based on progressive changes in mineral assemblages: Zone I, in the south, is characterized by transitional blueschist–greenschist facies; Zone II is characterized by greenschist facies; Zone III, in the northernmost portion of the belt, is characterized by eclogite and epidote–amphibolite facies sequences. Changes in amphibole compositions from south to north as well as the appearance of increasingly higher pressure mineral assemblages toward the north document differences in metamorphic P–T conditions during formation of this belt. Preliminary P–T estimates for Zone I metamorphism are 5–7 kbar, 350–450°C; estimates for Zone III eclogites are 10–22 kbar, 500 ± 50°C.The petrographic, chemical and structural characteristics of this metamorphic belt indicate its evolution in a northward-dipping subduction zone and subsequent uplift prior to and during the final collision between the Sino-Korean and Yangtze cratons.

Notes: Metabasaltic rocks in the Klamath Mountains of California with ‘komatiitic’ major element concentrations were investigated in order to elucidate the origin of the magnesian signature. Trace-element concentrations preserve relict igneous trends and suggest that the rocks are not komatitic basalts, but immature arc rocks and within-plate alkalic lavas. Correlation of ‘excess’ MgO with the volume per cent hornblende (±clinopyroxene) suggests that the presence of cumulus phases contributes to the MgO-rich compositions. Early submarine alteration produced regional δ18O values of +10±1.5%° and shifts in Al2O3, Na2O, and K2O concentrations. Regional metamorphic grade in the study area varies from biotite-zone greenschist facies (350–550°C, c. 3 kbar) southward to prehnite–actinolite facies (200–400°C, ≤3 kbar), but little isotopic or elemental change occurred during the regional recrystallization. The greenschist facies assemblage is actinolitic hornblende + phengite + epidote + sodic plagioclase + microcline + chlorite + titanite + hematite + quartz in Ti-poor metabasaltic rocks; in addition to these phases biotite is present in Ti-rich analogues. Lower grade greenstones contain prehnite and more nearly stoichiometric actinolite. The moderate to low pressures of regional metamorphism are compatible with P–T conditions in a magmatic arc. Later contact metamorphism at 2–2.9±0.5 kbar and at peak temperatures approaching 600° C around the English Peak and Russian Peak granodiorites produced 3–4–km-wide aureoles typified by gradual, systematic increases in the pargasite content of amphibole, muscovite content of potassic white mica, and anorthite content of plagioclase compositions. Metasomatism during contact metamorphism produced further increases in bulk-rock δ18OSMOW of as much as +6%°. Thus, the unusually MgO-rich nature of the Sawyers Bar rocks may be attributed at least partly to metasomatism and the presence of magnesian cumulus phases.

Notes: The compositional variation of calciturbidites (Pedata/Pötschen Formation), deposited adjacent to the Dachstein Formation carbonate platform in the Triassic Hallstatt Basin, was analysed using detailed field measurements and point-counting of thin sections. The 35 m long section is located in the Northern Calcareous Alps of Austria. Six point-count groups were distinguished separating basinal from platform-derived input. Summary statistics, cluster and correspondence analysis of the point-count data reveals a close relationship between the biota present on the Dachstein carbonate platform and the calciturbidite composition. The variations in turbidite composition are attributed to fluctuations in sea level and resulting flooding and exposure of the platform, which alternately created and destroyed shallow-water habitats on the platform top.