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  • Articles  (5)
  • Other Sources
  • Articles: DFG German National Licenses  (5)
  • 1970-1974
  • 1965-1969  (5)
  • 1960-1964
  • 1925-1929
  • 1969  (5)
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  • Articles  (5)
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  • 1970-1974
  • 1965-1969  (5)
  • 1960-1964
  • 1925-1929
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Astrophysics and space science 4 (1969), S. 3-43 
    ISSN: 1572-946X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The type I carbonaceous chondrites, with volatiles between 24 and 30% (at 1000 C, N2 atm.), contain the maximum percentage of the low-temperature ground mass, in which the high-temperature minerals are dispersed as ‘microchondrules’. In the type II carbonaceous chondrites (vol. 12–24%), the loosely cohering aggregates of microchondrules, ‘grape-bunch chondrules’, reach a maximum. The type III carbonaceous chondrites and some enstatite chondrites (vol. 2–12%) contain the maximum of the ‘partly coalesced chondrules’, in which microchondrules of olivine and nickel-iron appear. The ureilites are interpreted as impact shocked aggregates of microchondrules in differing states of coalescence. The ‘fully coalesced chondrules’ are characteristic for the ordinary chondrites with volatiles below 1%. It appears that the evolution of chondrules with the decrease of volatiles in meteorites subdivides into: (A) primary condensation of microchondrules with diameters of 0.01 mm; (B) secondary accretion of the former into the chondrules of diameter range ±1 mm. The observations may be explained through the hypothesis that at the highest-temperature stage of condensation of the asteroid-type parent body was an incandescent cloud (preserved through the solidification of chondrules at an early stage of degassing) covered with cosmic dust. The carbonaceous chondrites orginate from the marginal incandescent fog and the correspondingly deeper zones of the incandescent cloud mantle. The absence of typical chondritic rocks on earth may be explained by the slower cooling rate of this celestial body of relatively greater mass.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In a previous paper the anisotropy parameter of the attractive part of the intermolecular potential has been determined from total cross sections measured by scattering of TlF-molecules in selected rotational states by rare gases. In this series of papers, further measurements on the systems TlF-He, Ne, Ar, Xe, CH4, and CsF-He, Ar will be described. In the case of CsF-He, it has been possible to determine the anisotropy parameter of the repulsive part of the potential additionally, by comparing cross sections related to different rotational states over a large velocity range and by using the high energy approximation. The determination of the anisotropy parameter for the repulsive potential requires knowledge of the parameters of the angle averaged potential. Part I describes the determination of these parameters for a Lennard-Jones-potential from measurements of the velocity dependence and the absolute value of the total cross section by scattering of not state selected CsF-molecules by He and Ar. Since these systems show no glory undulations in the experimentally accessible velocity range, they require an evaluation procedure, which is independent of the appearance of such undulations. The procedure described below only uses the velocity dependence of the cross section itself by fitting of quantum mechanically calculated cross sections. The finite resolving power of the apparatus and the influence of velocity distributions are taken into account. The results are communicated, the parallel evaluation of an experiment on K-Ar serves as a test for the procedure described.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Improved measurements of the ratio of scattering cross sections for various molecular rotational states are reported for scattering of TlF in rotational states ¦J, M〉=¦1, 0〉 and ¦1, 1〉, and CsF in rotational states ¦2, 0〉 and ¦2, 2〉 by rare gases. The results are interpreted in terms of an angle dependent attractive potentialV=−2ε(r m /r) 6(1+q 6 P 2(cosΘ) in which the repulsive part of the interaction is neglected. The “high energy” approximation is used to calculate the cross section, which contains the velocity dependence and the state dependence as factors. The experiments show for all scattering partners with the exception of He and Ne, that the state dependence is velocity independent. In those cases this result provides a justification for the neglect of the repulsive potential term. The results for the anisotropy parameterq 6, which to a good approximation depends only on properties of the moleculus, are:q 6=0.23±0.01 for TlF,q 6=0.28±0.02 for CsF.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 311 (1969), S. 118-129 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wird die Benzonitriloxid-Addition an die semicyclische CC-Doppelbindung der 2-Methylen-cycloalkanone-(1), der benzokondensierten und bicyclischen α-Methylenketone sowie der α,α′-Dimethylen-cycloalkanone beschrieben. Die erhaltenen Spiro-isoxazoline wurden NMR-spektroskopisch untersucht und daraus die Additionsrichtung festgelegt. Die LiAlH4-Reduktion vom Benzonitriloxid-Addukt des 2-Methylen-cycloheptanons-(1) liefert 1,2-Dihydroxy-2-(β-amino-β-phenyl-äthyl)-cycloheptan.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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