Weitere Messungen zur Anisotropie der intermolekularen Wechselwirkung durch Streuung von Molekülen in definiertem Quantenzustand

Abstract

In a previous paper the anisotropy parameter of the attractive part of the intermolecular potential has been determined from total cross sections measured by scattering of TlF-molecules in selected rotational states by rare gases. In this series of papers, further measurements on the systems TlF-He, Ne, Ar, Xe, CH₄, and CsF-He, Ar will be described. In the case of CsF-He, it has been possible to determine the anisotropy parameter of the repulsive part of the potential additionally, by comparing cross sections related to different rotational states over a large velocity range and by using the high energy approximation.

The determination of the anisotropy parameter for the repulsive potential requires knowledge of the parameters of the angle averaged potential. Part I describes the determination of these parameters for a Lennard-Jones-potential from measurements of the velocity dependence and the absolute value of the total cross section by scattering of not state selected CsF-molecules by He and Ar. Since these systems show no glory undulations in the experimentally accessible velocity range, they require an evaluation procedure, which is independent of the appearance of such undulations. The procedure described below only uses the velocity dependence of the cross section itself by fitting of quantum mechanically calculated cross sections. The finite resolving power of the apparatus and the influence of velocity distributions are taken into account. The results are communicated, the parallel evaluation of an experiment on K-Ar serves as a test for the procedure described.