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Resonant two-photon ionization spectra of the van der Waals complexes: C6H5X⋅⋅⋅N2 (X=F, Cl, Br) (1996)

Hu, Yihua ; Lu, Wenyun ; Yang, Shihe

College Park, Md. : American Institute of Physics (AIP)

The Journal of Chemical Physics 105 (1996), S. 5305-5312

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ISSN: 1089-7690

Source: AIP Digital Archive

Topics: Physics , Chemistry and Pharmacology

Notes: The one-color resonant two-photon ionization technique is employed to study jet-cooled van der Waals (vdW) clusters of halobenzene and nitrogen through the S0→S1 transition around the 0¯00 band. The spectra obtained exhibit rich information about the clusters' intermolecular vdW vibrational modes and their solvent internal rotation. We have tentatively assigned all the observed spectral features to a single isomer of C6H5X⋅⋅⋅N2 (X=F, Cl, Br). The influence of X on the vdW vibrations and the internal rotation of N2 in the complex is investigated. The analysis of the influence of X on the 0¯00 spectral shift suggests that the change in vdW interaction energy upon electronic excitation is mainly due to the dispersion term. © 1996 American Institute of Physics.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1063/1.472408

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