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Chloro[1-(dimethylaminoethyl)indenyl](triphenylphosphine)nickel(II) (2001)

Groux, Laurent F. ; Zargarian, Davit

Copenhagen : International Union of Crystallography (IUCr)

Acta crystallographica 57 (2001), S. m547-m548

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ISSN: 1600-5368

Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001

Topics: Chemistry and Pharmacology , Geosciences , Physics

Notes: The title compound, [η5:η0–Ind(CH2)2NMe2](PPh3)NiCl or [NiCl(C13H16N)(C18H15P)], is a precatalyst for the polymerization of olefins. The present structure differs from a previously published polymorph of the same compound in the conformation of the amino tether (disordered over two positions with occupation factors 0.54/0.46) and in the cell parameters.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1107/S1600536801017925

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