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  • 1
    Electronic Resource
    Electronic Resource
    Limitations of the optimization of the resolution by the buffer pH in capillary zone electrophoresis (1994)
    Springer
    Fresenius' Zeitschrift für analytische Chemie 348 (1994), S. 576-582 
    Details
    ISSN: 1618-2650
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The model which enables the prediction of the resolution as a function of the buffer pH for capillary zone electrophoresis described elsewhere has two main limitations. One limitation is linked to the accuracy of the data necessary for the calculation, namely actual mobilities, pK values and effective charge numbers of the separands. The other is given by the fact that only longitudinal diffusion is taken as the source of peak dispersion in the model. Examples for deviations from the predicted resolution are discussed, with wall adsorption of small ions contributing significantly to migration and distorsion.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00323936
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