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  • 1
    Electronic Resource
    Electronic Resource
    Solubilization of Benzene and Several Benzene Derivatives in Dilute Aqueous Solution of 18-Crown-6 (1998)
    Springer
    Journal of solution chemistry 27 (1998), S. 1097-1107 
    Details
    ISSN: 1572-8927
    Keywords: Solubilization ; hydrophobic interaction ; l8-crown-6 ; benzene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Solubilities of benzene, toluene, nitrobenzene, p-and o-nitrotoluene in dilute aqueous solutions of 18-crown-6 have been determined by UV-spectrometry at 15, 25, and 35°C. The saturation concentration of each aromatic solute depends linearly on the l8-crown-6 concentration. Experimental results show that 18-crown-6 molecules form host-guest complexes (with 1:1 stoichiometry) with the aromatic molecules, which supports the assumption that the force of combination between the crown ether and the aromatic molecules is a weak hydrophobic interaction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1022657916973
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