ALBERT — All Library Books, journals and Electronic Records Telegrafenberg

Hits per page

hit 1 - 1 | 1 hit

Select All Export

Electronic Resource

Oxidative addition of acetone to butadiene (1983)

Vinogradov, M. G. ; Pogosyan, M. S. ; Shteinshneider, A. Ya. ; [et al.]

Springer

Russian chemical bulletin 32 (1983), S. 768-772

add to mindlist on the mindlist

Details

ISSN: 1573-9171

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Conclusions 1. Oxidative addition of acetone to butadiene in the presence of the system Mn(OAc)3-Cu(OAc)2 has afforded 5-acetoxy-6-hepten-2-one, three isomeric 1-methyl-3,7-divinyl-2,8-dioxa-cis-bicyclo[3.3.0]octanes with the vinyl groups with the exo,exo, exo,endo, and endo,endo dispositions, and three diastereoisomeric 2,7-divinyl-1,6-dioxaspiro[4.4]nonanes. 2. Oxidative addition of acetopropyl alcohol and dihydrosylvan to butadiene results in the formation in both cases of identical mixtures of exo- and endo-1-methyl-3-vinyl-2,8-dioxa-cis-bicyclo[3.3.0]octanes and diastereoisomeric 2-vinyl-1,6-dioxaspiro[4.4]nonanes, indicating that the reaction proceeds via the same intermediate, probably a complex of Mn(III) with the ketoalcohol.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00953473

	Location	Call Number	Expected	Availability

Others were also interested in ...

Paper (German National Licenses)

Fulltext

hit 1 - 1 | 1 hit