ISSN:
0887-6266
Keywords:
furfuryl alcohol resins
;
crosslinking reactions
;
hexamethylenetetramine
;
high-resolution solid-state NMR
;
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The reactions between furfuryl alcohol (FA)/poly(furfuryl alcohol) (PFA) and hexamethylenetetramine (HMTA) have been studied by 13C and 15N high-resolution solid-state NMR techniques. Highly crosslinked polymer networks similar to those obtained from the thermal curing of FA resins under acidic condition are formed. Possible reaction pathways are postulated on the basis of changes of chemical structures during the curing; α-substituted furfurylamines are shown to be the initial intermediates. Their further reactions with FA/PFA, together with thermal decomposition, produce methylene linkages between furan rings, resulting in chain extension and crosslinking, which occurs at both the methylene linkages and the 3- or 4-C of furan rings. Various side-products such as amines, imines, amides, imides, and nitriles are also formed during the reactions, and some of these can remain in the resins up to 205°C. The crosslinked network can be heterogeneous with different structures on nanometer scales when higher oligomers of FA resins react with HMTA. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 2233-2243, 1997
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
