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Elektronenspinresonanz-untersuchungen an peroxydradikalen in bestrahltem polypropylen (1963)

Fischer, H. ; Hellwege, K.-H. ; Neudörfl, P.

New York : Wiley-Blackwell

Journal of Polymer Science Part A: General Papers 1 (1963), S. 2109-2117

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ISSN: 0449-2951

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Peroxide radicals are formed by oxidation of carbon radicals in irradiated isotactic polypropylene. An interpretation of their ESR-spectra is given. The recombination of the peroxide radicals follows a chain reaction mechanism, which is derived from the reversibility of formation of peroxide radicals, the time dependence of their concentration, and from the oxygen consumption of samples containing peroxide radicals. The reactions are discussed in view of the radiation induced oxidative degradation of polypropylene.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1963.100010629

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