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Radiation-induced cationic polymerization of ethylene (1963)

Tabata, Yoneho ; Shibano, Hiroshi ; Sobue, Hiroshi ; [et al.]

New York : Wiley-Blackwell

Journal of Polymer Science Part A: General Papers 1 (1963), S. 1049-1053

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ISSN: 0449-2951

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: Radiation-induced polymerization of liquid ethylene was investigated at -78°C. No induction period was observed. The rate of polymerization was proportional to the first power of the dose rate. Radical scavengers did not inhibit the polymerization. On the other hand, methylene chloride accelerated the polymerization appreciably. It was concluded that the polymerization of liquid ethylene at low temperature proceeds by a cationic mechanism.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1963.100010318

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