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The Highly Selective Oxidation of a Tricarbonyliron Complex (1999)

Fischer, Jürgen ; Jones, Peter G. ; Nippert, Uwe ; [et al.]

Weinheim : Wiley-Blackwell

Liebigs Annalen 1999 (1999), S. 3455-3458

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ISSN: 1434-193X

Keywords: Stereoselectivity ; Carbonyliron Complex ; Oxidation ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The tricarbonyliron complex 2a underwent selective and diastereoselective oxidation with tert-butyl hydroperoxide at room temperature to provide, after decomplexation, the peroxyether 5 which, on reduction, yielded the corres-ponding secondary alcohol 7.

Additional Material: 1 Ill.

Type of Medium: Electronic Resource

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