ISSN:
0009-2940
Keywords:
Chelates
;
P ligands
;
Phosphaferrocene
;
Carbonyl complexes
;
Heterocycles
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Dicyclohexyl-acid diphenylphosphanyl-substituted phosphaferrocenes 2 and 3 were synthesized by substitution of the amino group in 2-dimethylaminomethyl-3,4,-dimethylphosphaferrocene 1 · Homologization of 2-formyl-3,4-dimethylphosphaferrocene 4 by one CH2 unit via Wittig olefination provided access to the phosphanylethyl derivative 9. Ligands 2, 3 and 9 formed P, P-chelate complexes with tetracarbonyl metal fragments in good yield. X-ray crystal structure determinations were carried out for the five-ring chelate complex 2. Mo(CO)4 (≡ l0), and the six-ring chelate complex 9 . Mo(CO)4, (≡ 13).
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19971301211
