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  • 1
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The coupling between the constituent reactions of a burning process, namely pyrolysis, combustion of volatiles, and (possibly) oxidation of char, is on the whole quite different for fires occurring in the open and for those that develop in an enclosure. Consequently, knowledge of the characteristics of free burning fires is of only limited value in studies related to compartment fire. Since the singe-rout communication between the fire compartment and its environment, always assumed in classical fire studies, is not at all common in real world fires, great sophistication in the mathematical modeling of classical fires is rarely warranted. An examination of pool-like fires and pile fires of noncharring fuels has shown that the severity of such fires in the fire compartment, as characterized by the so-called ‘fire severity product’, decreases slightly with an increase in ventilation. The principal danger presented by these fires, however, is not so much to the fire compartment itself as to the surrounding spaces.An interesting feature of fires involving charring fuels, cellulosies in particular, is that the rate of consumption of fuel, the so-called ‘rate of burning’, is practically independent of all process variables except ventilation. The severity of fires of cellulosics is, as a rule, much higher than that of fires of noncharring fuels. It exhibits a maximum at relatively low ventilations. From the point of view of spread of fire to the surrounding spaces, cellulosics are generally less dangerous than noncharring plastics. Fires involving cellulosics mixed with smaller amounts of noncharring plastics can be characterized as basically cellulosics fires, with a superimposed initial period of very high spread liability.
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  • 2
    Electronic Resource
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 218-222 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Glass reinforced polyesters (GRP), or the resins used, have to pass a wide variety of tests which vary considerably from country to country and from industry to industry. Some of these tests are carried out on a scale outside the capabilities of most laboratories and the results leave much to be desired in the matter of reproducibility. All these factors lead to problems for the formulator of fire-retardant unsaturated polyester resins.
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  • 3
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 202-210 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The Australian Standard ‘Test for Early Fire Hazard Properties of Materials’ (AS 1530 Part 3, 1976) has been studied in detail as a method of assessing the fire performance of plastics wall linings under the conditions of early fire development in a room. A particular feature of the standard test is that four parameters characterizing the reaction to fire are measured concurrently. Results from the standard test have been compared to corner-wall burns involving the same parameters as in the standard test. The suitability of these parameters and the ability of the standard test to rank the behaviour of the materials in the same order as indicated by corner-wall burns is discussed. A general relationship between ignition time and flame spread was observed and is discussed as support for the concept of concurrent measurement of different reaction-to-fire parameters under the one test procedure and condition.
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  • 4
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 3 (1979), S. 211-217 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Over a six-year period, 530 fire fatalities resulting from 398 fires were studied in the State of Maryland. The study had two major objectives: (1) to determine the specific cause of death by a detailed autopsy stud of fire victims, and (2) to determine the specific cause of fatality-producing fire by an on-the-scene fire investigation. The fire fatality study was limited to residential fires and to fatalities that occurred within 6 h of the fire. The results of the toxicological analysis show that (1) 60% of the victims had a carboxyhemoglobin value greater than or equal to 50% carbon monoxide saturation, (2) an additional 20% had elevated carboxyhemoglobin with preexisting cardiovascular disease, (3) 11% of the victims had severe burns, (4) 9% were unexplained and (5) 40% of the victims had positive blood alcohol levels with 30% of these meeting the legal definition of intoxication (blood alcohol ≥0.1%). The fire investigations confirmed that the predominant fatal scenario is the cigarette ignition of upholstered furniture or bedding. This scenario accounted for 47% of the fires and 44% of the victims. Alcohol also appears to be significant factor in this scenario.
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  • 5
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    Fire and Materials 4 (1980), S. 60-60 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 6
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 4 (1980) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 7
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Measurement of the rate of oxygen consumption provides a simple, versatile and powerful tool for estimating the rate of heat release in fire experiments and fire tests. The method is based on the generalization that the heats of combustion per unit of oxygen consumed are approximately the same for most fuels commonly encountered in fires. A measurement of the rate of oxygen consumption can then be converted to a measure of rate of heat release. Data on heats of combustion are presented to support this generalization. The applicability of the technique to combustion under fire conditions is examined, possible sources of error in the measurements are discussed, and applications of the method are reviewed. It is concluded that the accuracy of oxygen consumption based rate of heat release measurements should compare favorably with those derived from conventional calorimetric measurements.
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  • 8
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    Fire and Materials 4 (1980), S. 77-82 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Experiments using a thermobalance, a hot-plate and a moving furnace have all shown that polymers can evolve oxidation products in air even at moderate temperatures. These gases can include carbon monoxide, formaldehyde and acrolein. The amounts are generally low except near the very top of the temperature range used in some processes. Tests in the vicinity of three different extruders have confirmed some of these small-scale findings but also showed that the evolved gases were adequately handled by the ventilation installed. The evolution of other gases in certain cases has also been briefly studied. Some measure of the heat evolved in oxidative pyrolysis has also been obtained for polyethylene. The polymers investigated were low density and high density polyethylene, poly(ethylene vinylacetate), polypropylene, poly(vinylonitrille) polypropylene, poly(vinylchloride), polystyrene, poly(methylmethacrylate), polycarbonate, poly(ethylene terephthalate), nylon 6-6, acrylonitrile/butadiene/styrene and one nature material (wood).
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  • 9
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    Fire and Materials 4 (1980), S. 83-86 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An important observation during full-scale fires was that burning behaviour is often determined by softening characteristics as well as ignitability, flame spread, etc. Examples include stacking chairs where thermoplastics give a rapid rate of fire growth and suspended ceilings where thermoplastics reduce fire hazard. A test rig has been progressively developed at RAPRA to reproduce the mechanisms and fire growth rates of stacked chairs and to evaluate the role of softening in fire growth. Although the ignitability of fire-retarded materials is less than that of non-fire-retarded grades, the fire growth rate in stacks is similar and may be related to the softening behaviour determined by exposing sheets of material to radiant heat. The rate of fire growth in stacks may be significantly reduced by modifying the softening behaviour of materials, e.g. by using asbestos-reinforced thermoplastics which can form an integral, non-melting felt or by using non-melting materials such as SMC or wood.
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  • 10
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    Fire and Materials 4 (1980), S. 87-91 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper describes work carried out on flame-retarded polypropylene comparing results on selected small-scale laboratory fire tests with those obtained on a larger-scale test designed to simulate the typical real life hazard situation. In the latter test a number of important parameters such as heat build-up, Hame spread, smoke development and gas evolution were assessed. The results indicate that there is need to use both types of tests to gain a fuller understanding prior to using new materials. An assessment based on small-scale tests alone could be misleading and allow the use of potentially hazardous material in the particular application involved.
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  • 11
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    Fire and Materials 4 (1980), S. 92-97 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Considerable concern has been expressed about the increasing number and changing pattern of fires and the fact that modern upholstered furniture is relatively easy to ignite and, once ignited, burns rapidly to produce large quantities of smoke and toxic gas. This led to a number of major research programmes and to the evolution of a number of test procedures in the UK. The first major test procedure was published in 1976 by the BPF in conjunction with RAPRA, BRMA and FIRA. An important aspect of this approach was the linking of ignition and rate of initial burning data with the application of the product and the environmental hazard. It was evolved within a short period of time to proved furniture designers and specifies with a means of avoiding products of high risk. The DOE/PSA are using a comprehensive series of Fire Retardant Specifications to control and specify their upholstered furniture and bedding. Specifications have been developed which enable individual components and sub-assemblies as well as the final product to be characterized in terms of ignitability and burning characteristics, i.e. temperatures, smoke, and carbon monoxide production. BS DD58 and BS 5852 Part1, ignitability tests for upholstered seating are essentially a combination of BPR and DOE/PSA test procedures. Cigarettes, gas flames and wooden cribs are used for the ignition sources and are positioned on a composite seat/back test rig.
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  • 12
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    Fire and Materials 4 (1980), S. 98-103 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The standard NBS/Aminco smoke test chamber is critically examined from the point of view of repeatability and reproducibility of the apparatus itself. Individual components contributing to the overall determination are examined and suggested lines for improvement are made which should result in more consistent results. Problems associated with the presentation of results are discussed and a new approach which includes time-weighted data is proposed. This attempts to consider the rate dependence of smoke production in one calculated figure rather than isolated observations such as maximum optical density. Utilizing the NBS/Aminco chamber, a novel procedure for determining the smoke evolution characteristics of materials has been developed which can be considered to simulate more closely the progress of thermal degradation that a material undergoes in a real fire.
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  • 13
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    Fire and Materials 4 (1980), S. 104-108 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The heat flux in the NBS smoke chamber has been varied from 1.0 to 5.0 W cm-2 in 0.5 W cm-2 steps for some fifteen natural and synthetic materials. These experiments confirm the results given in previous papers for a smaller heat flux range, namely that smoke density varies ove4r the temperature/heat flux range. The extended range studied ensured that a much higher proportion of the materials reached a heat flux at which ignition occurred. As before at this and higher heat fluxes, the experiments were repeated in the flaming mode to ensure better reproducibility. With a few exceptions the general shape of the specific optical density/heat flux plot was similar, with a steep rise to a peak and then a corresponding drop to a low value at high fluxes. At 5 W cm-2the drop had not been reached in some cases, but it is assumed to occur later by inference from earlier work on a smaller-scale apparatus at high temperatures. Complex materials can give unusual plots during the transition from pyrolysis to combustion. This is true of certain polymers containing fire retardant when the pyrolysis of the additive can have a separate effect.
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  • 14
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    Fire and Materials 4 (1980), S. 115-118 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of diammonium phosphate has been examined on sawdust-polymethylmethacrylate composites. It has been observed that the char formation depends on the distribution of DAP in sawdust and polymethylmethacrylate. An interesting correlation was found between the mass burning rates of the composites and the extent of char formation during thermal degradation.
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  • 15
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The internal temperature of rigid foam undergoing combustion in the DIN tubular traveling furnace using conditions previously employed for gas generation and analysis has been studied. Unexpected findings were obtained in that the material exhibited no insulating effect and temperatures within the core of the foam were up to 25% (+125°C at 500°C) greater than has been assumed or indeed aimed for. An explanation of the phenomenon has been put forward and proved by further experiment. Suggested practices to be adopted in the future to minimize the effect are described. Using these practices the gaseous combustion products from the materials studied at 500°C were found not to change in type or distribution; however, rather more accurate description of combustion temperature is achieved. With a static furnace of the ‘Potts Pot’ type a very much smaller temperature differential is observed, hence better definition of combustion temperature is allowed.
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  • 16
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    Fire and Materials 4 (1980), S. 119-126 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The evaluation of hazards from developing room fires often requires a knowledge of flame lengths developed by burning objects. Procedures for estimating flame lengths have been available only for vertical plume fires, where there is no flame impingement on the room ceiling. Calculational procedures are developed for approximate calculation of flame lengths when part of the flame flow is along the ceiling. Four common geometries are treated: unbounded ceiling, plume near corner, plume in corner and one-directional corridor spread. Ceiling flame lengths are calculated by use of the assumption that the total air entrained up to the flame tip is the same for ceiling flow as for the free fire. Comparison with limited experimental data suggests potential for prediction in full-scale room fires.
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  • 17
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    Fire and Materials 4 (1980), S. 157-162 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A theoretical approach is developed for evaluating quantitatively the heat evolved during a reaction-to-fire test. This involves determining the transfer function from two head balance equations, one concerning the walls and the other the air in the test box. A comparison between this theoretical approach and the empirical ‘area under the curve’ method has been made for 34 tests on electrical cables. It is shown that the empirical method is unacceptable.
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  • 18
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    Fire and Materials 4 (1980), S. 163-163 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 19
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    Fire and Materials 4 (1980) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 20
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    Fire and Materials 4 (1980), S. 165-172 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The development of the Australian Standard AS 1530 Part 3 ‘Test for Early Fire Hazard Properties of Materials’ from the study of the fire behavior of cellulosic wall linings in simulated room fires has been outlined. Similar studies for assessing a wider range of wall linings are now reported including various plastic facings applied to hardboard. Using similar parameters for ignitability, spread of flame, heat evolved and smoke developed, the behaviors of the linings in the standard test have been compared to the behavior in corner-wall burns. Two methods of ignition were used for the burns; (a) timber cribs; and (b) impressed radiant heat with a pilot flame. The results are discussed in terms of the validity of the standard test as a multi-parameter assessment of materials in a fire hazard situation. The test has been validated for the wider range of wall lining materials.
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  • 21
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: It is submitted that the development of a set of complementary performance test standards and of an algorithm for calculating from the test results the inherent potential of products for harm is the prerequisite of any progress towards a coherent fire risk assessment philosophy.
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  • 22
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    Fire and Materials 4 (1980), S. 185-191 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this paper the definition of heat release rate in fires is given in terms of heat of combustion and mass loss rate of the fuel. Various components of the heat of combustion are defined. The dependency of heat of combustion components and mass loss rate on factors such as fire stages, oxygen to fuel ratio, heat flux received by the fuel, chemical composition of the fuel vapors and products are enumerated. Applications of heat release rate data for relative fire hazard of fuels, for various fire conditions, for human escape potential from fires and for the operation of fire-sensing devices are discussed.
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  • 23
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    Fire and Materials 4 (1980), S. 201-202 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 24
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    Fire and Materials 5 (1981), S. vi 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 25
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 26
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    Fire and Materials 5 (1981) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 27
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    Fire and Materials 5 (1981), S. 73-76 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The dependence of the Critical Oxygen Index values of some thermoplastic materials on sample sixe is reported. The extent of melting of this class of material is shown to be important in determining the effect of sample size on the index.
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  • 28
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    Fire and Materials 5 (1981), S. 131-131 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 29
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    Fire and Materials 5 (1981) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 30
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    Fire and Materials 5 (1981), S. iii 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 31
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    Fire and Materials 5 (1981), S. 142-148 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Results of a study of time-dependent deformation of concrete over a period of five hours at room and elevated temperatures (22 to 649°C) are described. The influences of load, temperature and material variables are examined and data compared with several mathematical models commonly used to describe concrete creep behavior. Information obtained from this study will help in evaluation of the design of concrete structures to withstand fire and other high temperature environments.
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  • 32
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    Fire and Materials 5 (1981), S. 133-141 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The thermal decomposition of a number of TDI- and MDI-based biscarbamates (model compounds for polyurethane foams) between 200°C and 1000°C showed that the urethane linkage undergoes an O-acyl fission at about 300°C to generate the free isocyanate and alcohol. In the case of the flexible foam analogues, the newly generated TDI reacts further to generate volatile polyureas, termed ‘yellow smoke’. The MDI residues generated in the decomposition of a rigid foams react to yield non-volatile polycarbodiimides. Both the yellow smokes and the polycarbodiimides decompose above 600°C to give a mixture of nitriles (including HCN) as well as a number of olefinic and aromatic compounds. The use of 13C labeling indicated that HCN and all the other nitriles generated during the high temperature decompositions originate in the thermal fission of the aromatic ring, the nitrile carbon being the 2-, 4- or 6- carbon of MDI.
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    Fire and Materials 5 (1981), S. 149-152 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Gas chromatography using a column with a molecular sieve was applied to the determination of carbon monoxide in thermal degradation of polymeric materials. Attention was paid to the variance of individual determinations and conclusions were drawn regarding reproducibility of the processes studies. The carbon monoxide content in pyrolysis and thermooxidation products of the commonest polymeric materials and the effect of temperature on the amount of carbon monoxide formed were determined.
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    Fire and Materials 5 (1981), S. 153-162 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Ignitability, one of the new fire test methods for building materials developing within the International Standards Organization is compared with the national fire test methods in Austria, Britain, France, Germany and Scandinavia. Different commercial wood-based panels have been tested, including fire retardant treated panels. The International Standards Organization ignitability test measures the time to ignition at radiation intensities from 1 to 5 Wm -2; it seems to be able to distinguish between different materials in an intelligible way. An evaluation of the results of this ignitability test is discussed. One possibility which is proposed here is to calculate the mean time to ignition at different fixed radiation intensities; such a mean value simplifies the evaluation and takes into account all the test data. Agreement with the national fire test methods is rather low, since they partly measure other fire parameters; agreement with the Austrian Schlyter method, which also evaluated ignitability, is somewhat better and agreement between the national fire test methods is relatively good for wood-based panels. This is consistent with earlier experience, which has shown that mainly new types of materials behave differently according to different national test methods.
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    Fire and Materials 5 (1981), S. 177-178 
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    Fire and Materials 5 (1981), S. 175-176 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 5 (1981), S. 179-179 
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    Fire and Materials 5 (1981), S. 163-174 
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    Notes: The results of applying the tentative, high temperature, International Standards Organization test methods DP 5925 Part 3, which was developed to measure smoke leakage of door assemblies during the course of a standard fire endurance test, are reported. A critical analysis reveals that the basic objective of the test method is limited in its utility in that fire scenarios in high-rise buildings may not be adequately simulated. Independent of this limitation, the analysis then identifies certain theoretical problems with the test method and its procedures. These lead to a conclusion that the test method is not generally reliable. An alternative test concept which appears to remove this limitation and all of its problems is described, and its development is advocated.
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    Fire and Materials 5 (1981), S. 180-181 
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    Fire and Materials 5 (1981), S. iii 
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  • 41
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    Fire and Materials 6 (1982) 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 6 (1982), S. 16-22 
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    Notes: The fire risk posed by soft furnishings such as bedding materials and upholstered furniture and the strategies being developed to reduce the number of fire-related casualities are reviewed from a Canadian point of view. Statistics from Canada, the United States and the United Kingdom indicate that a substantial reduction in the number of fire deaths would be possible if the ability of assemblies of materials to resist ignition by smokers' materials, such as cigarettes and matches, could be improved. The post-ignition performance of furnishings that results in generation of heat, smoke and toxic gases is also important from a safety point of view. A need exists for both full-scale and small-scale fire tests, and for mathematical modelling for present and future control strategies.
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    Fire and Materials 6 (1982), S. 23-26 
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    Notes: An apparatus has been designed and a procedure adopted for studing the oxygen index of materials over a range of pressures. It has been found that the oxygen index falls with increase in pressure so that materials become more flammable, the effect being more marked with the less flammable materials. An empirical method has been devised for predicting the oxygen index at varying pressures.
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    Fire and Materials 6 (1982), S. 27-31 
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    Notes: It is demonstrated that he normalized heat load is a suitable parameter for ranking various enclosure fires on a ‘potential for destruction’ scale. This parameter is convertible to the familiar fire resistance.
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    Fire and Materials 6 (1982), S. 32-37 
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    Notes: Concentrations of elements were determined in tracheal specimeans of fatal fire casualties and of non-fire fatalities. Elevated concentrations of antimony, bromine, zinc, chromium, cobalt, iron, lead, cadmium and gold found in the group exposed to the fire environment were associated with deposition of soot. The presence of raised concentrations of antimony in fatalities was found to occur in association with increased content of carboxyhaemoglobin in blood and was greatest in fires involving major destruction of property. A relationship between the increased concentration of this element and the use of antimony containing fire-retardants in construction materials could not be demonstrated.
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    Fire and Materials 6 (1982), S. i 
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    Fire and Materials 6 (1982), S. 65-67 
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    Notes: Estimates of the errors in light extinction measurements of smoke resulting from forward scattered light entering the detector and from the spectral width of the light source are presented. It is shown for specific examples that each of these effects can lead to an error of about 25% in typical applications. A potential method for calibrating extinction instruments is described.
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    Fire and Materials 6 (1982), S. 68-71 
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    Notes: The development, construction, and testing of a gas-fired radiant heat source for use as part of a fire test method is described. The unit has been shown capable of operation over extended periods at surface temperatures yielding radiance corresponding to that of a black body at 935 °C. This permits a 60% increase of specimen irradiance over that possible with a burner previously used, without modifying the specimen-burner configuration factor. One such application of this burner allows operation with specimen irradiance levels at 5 W cm-2 or for short periods at levels approaching 7 W cm-2 at higher temperatures. This performance is achieved while maintaining effective spatial separation between specimen and heat source. This assists in avoiding imposition of vitiated air near the surface of a burning specimen. Some performance data are provided on its behavior when supplied with natural gas. The unit can burn propane but only with a significant reduction of thermal output.
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    Fire and Materials 6 (1982), S. 76-79 
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    Notes: In making fire safety decisions the designer often finds that some input variables concerning his problems are chance variables. As detailed statistical data are rarely available the designer must rely largely on his expert judgment. With the application of the Delphi method such decisions can be optimized and formalized. The essence of the Delphi method is described and its use illustrated through an example related to the assessment of fire resistance requirements.
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    Fire and Materials 6 (1982), S. 72-75 
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    Notes: A study of the 1979 UK fire statistics and the Annual Report of the Office of Population Censuses and Surveys shows that only 1 death per 1000 is attributable to toxic gases from combustion. However, of the ‘deaths by violence’ it rises to 30 (3%). As 37% of all fires in occupied buildings were confined to the first item ignited and 53% to the area of origin it is postulated that such fires (and the consequent deaths) largely concerned substances which will burn on their own. From experience these are largely materials with limiting oxygen indices below 22 or 22-28 for restricted burning only. Those with limiting oxygen indices 〉28 cannot on their own sustain combustion. These considerations suggest the mode in which toxic gas tests should be conducted, i.e., horizontally or vertically and vertically only for the first two groups, respectively, and in the presence of a fire sustainer for the limiting oxygen index 〉28 group. Wood in the form of a wooden crib is suggested as suitable. To this end some experiments are described with PVC placed on top of a No. 5 crib (PSA). These latter show that, making the best assumption possible from the existing data, the wood contributes about 63% to the toxicity and the PVC 37%. On the large scale, other work has shown that wooden cribs alone will give lethal concentrations of carbon monoxide for significant periods. Thus difficult-to-burn substances need to evolve gases of exceptional toxicity for their contribution to be worth considering.
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    Fire and Materials 6 (1982), S. 80-95 
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    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: NBS burned eleven mattresses made up with bedding in two different rooms, typical of a residential bedroom and a nursing home patient room, respectively. Seven of the mattresses flamed and burned vigorously, the other four were of a construction or so heavily flame-inhibited that they only smoldered. The burning behavior of the seven that flamed was modeled with the Harvard Mark V fire simulation. The experimental burn behavior for tests conducted in one room was well reproduced using only total weight of combustible, surface area and heat of combustion. Smoke production values were found to have little effect on the predicted behavior except for the smoke production itself. Fires in a second room, whose ventilation was intentionally restricted by the configuration of the adjoining space, could not be as well reproduced by the present, single-room fire model. During this study several changes were made to the simulation. The most significant change was the inclusion of mixing of the hot exiting fire gases with the cold incoming air. As a part of this, the inter-layer radiation exchange was reformulated to include the effect of smoke contamination of the lower layer. The reformulation of the radiation model has a marked effect on the predicted upper layer gas temperatures, generally improving the quality of the simulation.
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    Fire and Materials 6 (1982), S. 111-118 
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    Notes: A fire test device suitable for small-scale, comparative testing as a first step in investigating the performance of fire retardant materials is described. The procedure developed is not intended to predict the performance of a given material in a real fire, since the local conditions can be extremely variable. However, the parameters in the device can be varied over a wide range to screen the performance of various materials in given situation. Typical results for an intumescent mastic consisting of epoxy resin, hardener and melamine phosphate are quoted, together with appropriate calibration curves. A method of estimating the thermal resistance of the developing char is also discussed.
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    Fire and Materials 7 (1983), S. 99-99 
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    Fire and Materials 7 (1983), S. 101-110 
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    Notes: The smoke propensity of plastics as measured in the NBS Smoke Chamber method has been rationalized in terms of the influence of specimen thickness and resolved in a relation between mass optical density (MOD) and mass loss, which gives two parameters for characterizing behaviour, a maximum MOD for thin specimens and an asymptotic MOD for thicker ones. Data have been obtained for unplasticized piolyvinylchloride formulations and compared to that obtained by the Arapahoe Smoke Chamber and the Australian Standard method (AS 1530 Part 3). Although correlation coefficients between the methods were generally poor, the same formulations were ranked as the best performers in each method and the improvement over a standard formulation was potentially important in terms of wider acceptance under Australian building regulations.
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    Fire and Materials 7 (1983), S. 111-118 
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    Notes: The influence that oxygen has on the burning behaviour of cotton single- and multilayered fabries has been determined by recording persistence of burning times as a function of oxygen concentration. For a given fabric subjected to a specified igniter application time, an extinction oxygen index parameter, EOI, may be determined. EOI is defined as the oxygen concentration expressed as a volume fraction in an oxygen-nitrogen mixture, necessary to give a persistence of burning time equal to zero. For a given fabric, EOI is found to decrease as the igniter application time increases and two limiting EOI values may be observed, one corresponding to zero inginter application conditions and one for igniter application times greater than 10 s. At any given ignition time, the extinction oxygen index increases linearly with fabric area density and decreases linearly with the logarithm of the respective air permeability. Similar results are observed for nylon 6.6 and polyester single- and multilayered fabrics. The validity of the extinction oxygen index is discussed with reference to other published works.
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    Fire and Materials 7 (1983), S. 123-127 
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    Notes: The apparatus described in DIN 4842 was used to measure the heat transmission of a series of Nomex, polyester-cotton, Proban®-Treated cotton, untreated cotton and wool workwear fabrics subjected to a radiant heat source. Heat transmission was found to be dependent on the incident heat flux, fabric weight and fabric thickness. At the heat flux levels tested, 10 KJ m-2s-1 and 20 KJ m-2s-1, heat transmission was found to be largely independent of the fibre composition of the fabric when single layers of fabric were tested. The level of heat transmission was reduced by the use of multiplayer assemblies or a reflective aluminium coating, but the greatest reduction was obtained when air spaces were interposed between the fabrics. Conbinaitons of fabrics were developed which transmitted less than 205 KJ m-2s-1 during testing at incident heat flux levels of 10 KJ m-2s-1 and 20 KJ m-2s-1.
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    Fire and Materials 7 (1983), S. 119-122 
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    Notes: A method is described by which the UK Upholstered Furniture (Safety) Regulations of 1980 may be complied with. By coating the surface of flexible polyurethane foam with vinylidene chloride copolymer latex, a fire retardant surface is obtained. This enables most fabric/foam combinations to pass both the cigarette and the match tests as laid down in BS5852. The coating process can be carried out with a brush, a roller or by spraying. Drying can be at room temperature or by using heat and/or a forced draught. Using about 350 gm-2 only certain deep-pile fabrics fail, and even hen additionally back-coating them with PVDC can ensure compliance. The presence of thin wadding or stockingette makes no difference, but thick wadding will burn with the fabric for more than the mandatory two minutes without setting fire to the PU foam. Fabrics successfully tested with the coated PU foam include cottons, polypropylene, acrylic, polyester and ‘Dralon’. After 80 000 indentations in a standard test the coating was still effective, as it was also after heating in a detergent for 4h.
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    Fire and Materials 7 (1983), S. 132-149 
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    Notes: To assess the utility of a laboratory test for smoke and fume emission from overheated materials, six materials were heated to 500°C in larger amounts in three locations in an air-conditioned aircraft fuselage on the ground. Smoke, acidic or alkaline gases and carbon monoxide were monitored. It was shown that the laboratory test results could be a basis for predicting the smoke- and fume-emission behaviour of materials subjected to overheating, e. g. in aircraft in flight.
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    Fire and Materials 7 (1983), S. 128-131 
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    Notes: Smoke toxicity test methods which determine only lethal toxicological potency under ‘worst case’ conditions do not satisfactorily address the critical issue of relative hazard, including time-to-escape and tenability limits resulting from the fire performance of materials under comparable conditions. Since threats to escape from a fire are largely time-dependent, toxic insults produced by burning materials should also be considered as rate processes. Assessment of time thresholds exhibited by burning materials under test conditions to effect performance impairment (incapacitation) of an animal model would appear to be more relevant than lethal toxicological potencies in estimating probability of successful escape from fires. A model is advanced in which intoxication rate thresholds for materials are obtained using a rodent exposure test method. Concentration-time curves, obtained from experimentally derived concentration-time-response surfaces, are the basis for estimating rate thresholds which are distinctively different for each material and which vary as a function of test conditions. it is this performance impairment response surface which is potentially a key to the modeling of toxic hazards of smoke in perspective with other hazards presented by fire.
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    Fire and Materials 1 (1976) 
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    Fire and Materials 1 (1976), S. 1-1 
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    Fire and Materials 1 (1976), S. 9-13 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: A review is presented of the nature of the potential heat test method. It is emphasized that the procedure usually yields a property-type measurement of the material or composite when applied. As a result, care must be taken to insure that necessary supplementary tests are performed by other methods to guarantee that a substantial fraction of the possible fire hazard has been considered. Suggestions for appropriate use of the procedure are included and information available on the precision of the procedure is reviewed. It is concluded that, when properly applied, the procedure can serve well as one of the tools for characterizing possible fire hazards. Suggestions are made for possible future development of the procedure to yield information on rate of heat release.
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  • 64
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    Fire and Materials 1 (1976), S. 19-23 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The course of pyrolysis, thermooxidation, flame combustion and glowing combustion has been observed with differently treated cellulose samples by means of thermoanalytical methods. The impregnation of cellulose materials by inorganic salts produces a less combustible material, less stable at relatively low temperatures, yet giving more of the solid residue resistant to pyrolysis and combustion processes. The more thermally stable cellulose derivatives, but with insufficient resistance to flame and particularly glowing combustion, have been obtained by cyanoethylation and grafting of acrylonitrile on to cellulose.
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  • 65
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Notes: This paper describes the background information which led to the development of a technique specifically designed to test the flammability performance of coatings applied to metal substrates. Design parameters for the new test are discussed and the prototype apparatus is described in detail. The mode of operation is explained and some results are tabulated for a range of typical coating materials. Conclusions based on the behaviour of the coatings tested are drawn in the text. These conclusions are, however, biased towards the Naval environment and application, and may not be universally applicable. The main implications of this work so far are that it is possible to improve the performance of existing fire retardant paint systems by: (1) ensuring that only the minimum thickness is applied to non-flammable substrates; (2) that adequate time is allowed for solvent elimination before deliberate exposure to risk; (3) using a white coating if possible; (4) increasing the durability of the coating to reduce the need for cosmetic overcoating, (i.e. re-coating purely to improve appearance), e.g. by using a thermosetting resinous binder in place of the conventionally used alkyd resin.
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    Fire and Materials 1 (1976), S. 29-35 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: This paper present observations on the toxicity of gases produced by materials under three different combustion conditions. The difficulty of the general problem of toxicity is emphasized and the impossibility - at the present stage in the research - of satisfying the increasing pressure to establish toxicity safety regulations is stated.
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    Fire and Materials 1 (1976), S. 24-28 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An apparatus based on the BS 476 Part 7 small scale flame-spread specification, which has evolved over a number of years, is described. Many changes from the original simple gas/air furnace have been introduced, which have led to the development of a very useful flame-spread test apparatus where all known variables are precisely controlled. The work has shown that the radiometers described in the standard do not monitor all the variables which affect flame-spread results, and reported problems of reproducibility and variation on the large scale test, may be due to inadequate control of the furnace. The significance of the results is that the use of gas/air radian panels as the basis for flame-spread tests needs to be re-examined. All parameters should be carefully controlled and the entire procedure, particularly regarding the use of pilot ignition sources, needs to be reconsidered. There is an increasing need for test methods which assess materials at radiation intensities beyond that given by small ignition sources. The type of flame-spread apparatus described in the paper may help fulfil this important requirement.
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  • 68
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    Fire and Materials 9 (1985) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
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  • 69
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    Fire and Materials 8 (1984), S. 206-216 
    ISSN: 0308-0501
    Keywords: building materials ; fire tests ; heat release rate ; oxygen consumption ; spectral energy distribution ; weight measurement ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Equipment has been developed for measuring the rate of heat release from building materials in an open test arrangement. The method is based on an oxygen consumption technique. A vertical sample is placed under an open hood in which the combustion gases and a certain amount of air are collected. The decrease in oxygen concentration and the mass flow of the gases are measured in the exhaust duct. The rate of heat release is then calculated. The equipment has been calibrated with good agreement between input and measured effects. The total response time for the system is 10s. The method has been used for testing building materials at radiation intensities up to 5W Cm-2. It is able to distinguish between different board materials, and the repeatability is good, The paper describes the equipment, including the weighing of a burning sample and the selection of test condition. Smoke and gas analysis can be added when desirable. Some test results with building materials are also presented.
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    Fire and Materials 9 (1985), S. 30-35 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Smoke-obscuration of monochromatic (0.632μm) light helium-neon lasers and of broad-band continuum light a hot tungsten filament is reported. The effect of forward-scattered light is evaluated for the monochromatic source, and the degree to which the Bouguer law is obeyed for a non-monochromatic source is discussed. Practical experience with both small-scall and fire experiments is described.
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    Fire and Materials 9 (1985), S. 1-8 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A review is presented of the gaseous combustion and pyrolysis products evolved from coal, wood and PVC. Information has been collated on the range of products evolved, the temperatures of evolution and the effect of different ambient conditions (e.g. oxidizing of inert conditions). The data for coal have been subdivided into those from which rates of gas evolution have been or can be derived and those from which this is not possible. Probable decomposition routes for PVC and for wood are discussed. Although all three materials have been widely studied, the correlation between the work of different authors in not always good. The data obtained are dependent on the form of the experiment, and there are gaps in the information available, especially information on the rates of evolution of products of products as a function of temperature.
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    Fire and Materials 9 (1985), S. 23-29 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The performance of zine oxide gas large-scale experiments in an experimental underground mine roadway has been investigated. The sensors were in a simple prototype instrument and the response to products evolved from heated coal wood and PVC conveyor belt was determined. The response was measured as a function of sensor distancef from the combustion products, the ventilation rate in the roadway and the mass of coal dust used. Limited analuysis of the roadway air was also carried out. The results are compared with those obtained in laboratory studies1 and suggest that the sensors respond mainly to inorganic gases, e.g. CO, H2, H2S, HCl, and in the case of wood, acetic vapour at concentrations of about 1ppm. The experiments confirm the potential of the sensors as a means of detecting heating involving coal, wood and PVC conveyor belt.
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    Fire and Materials 1 (1976), S. 83-84 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 1 (1976), S. 63-73 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Full-scale fire tests on domestic beds fully equipped with bedding materials have been carried out in an experimental compartment-corridor facility at the Fire Research Station, Borehamwood, U. K. Mattresses made of hair, spring interior, foam rubber and polyurethane of various types, together with mattress covers of cotton, flame-retarded cotton or proofed nylon were studied. The effectiveness of protective hair or glass fibre interlining was examined. The study has shown that a rapid development of fire in bed and bedding materials can take place with certain combinations of mattresses and their covers. The types of covers extremely important in overall fire development, particularly with polyurethane mattresses. A substantial improvement in the fire behaviour of many of the principal types of beds tested can be achieved by a careful selection of bedding materials, such as the type of mattress cover, and in certain cases by the use of protective interlinings.
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    Fire and Materials 1 (1976), S. i 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 9 (1985) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Fire and Materials 9 (1985), S. 41-45 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: A series of experiments for studies of flammability characteristics of upholstered furniture is presented. The series comprises 53 experiments on a reduced scale and 11 full-scale experiments in an extensively instrumented room. Results are presented from measurements of rate of heat release and smoke production. The experiments indicate that ignitability can be considerably decreased by careful choice of the upholstery materials.
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    Fire and Materials 9 (1985), S. 46-56 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A theoretical and experimental study of ceiling flows induced by both impinging fires and weak plumes on a horizontal ceiling is presented. Measurements along a ceiling radius were made of impinging diffusion flames with heat-release rates of 1.67 and 8.51 kW, resulting in convective and radiative ceiling-heat fluxes, radiant heat flux to the surroundings and profiles of mean velocity, mean temperature and mean concentrations of major species. However, only ceiling heat fluxes were obtained for weak plumes of pre-mixed flames of 0.24, 0.385 and 0.709kW. The predicted ceiling convective heat fluxes by an integral model are in good agreement with the measured values. In general, the present model also provides satisfactory predictions of flow thickness, bulk velocity, temperature and gas concentrations for both impinging fires and weak plumes.
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    Fire and Materials 9 (1985), S. 36-40 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Some early stages of compartment fires were explored experimentally using small-scale model fires. In particuylar, the flame spread on the compartment floor was investigated with various ventilation openings. The average flame-spread rate was higher than that for the free-burning condition (without a compartment),namely, 3.2 times at the maximum, and seems to depend only on the ventilation opening height and not on its width. Therefore it appears that the driving wind of the inflow air from the ventilation opening to the flame increase-spread rate. These data were compared with the flame angle data by Quintiere. The gas temperature within the compartment and the ceiling surface temperature was also measured to assess the radiation effect on flame spread. However, the radiation heat flux was unexpectedly small.
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  • 80
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    Fire and Materials 9 (1985), S. 65-74 
    ISSN: 0308-0501
    Keywords: Correlations ; flame spread ; flammability tests ; energy release rate ; room fires ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: An examination of the correlative relationship between room fire intensity (temperature) and flammability data for materials, ASTM E-84 flame ratings and energy release rate from calorimertry devices is presented for fire spread on lings. The results of the analysis show the significance of two modes of flame spread - wind-aided and opposed-flow spread. The factors important in these spread modes are considered from approximate solutions developed for turbulent flow. As the importance of energy release rate to flame spread in the tunnel test (E-84) and in upward or wind-aided spread is illustrated. The results suggest a possible reason why the ASTM E-84 and in upward or wind-aided spread is illustrated. The results suggest a possible reason why the ASTM E-84 ratings may not be applicable to the performance of low-density combustible linings in wall fires. In the analyses, flame radiation has not been considered. Also the interpretation of energy release rate data for difference scale and orientation effects has been ignored. These two factors must ultimately be addressed.
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    Fire and Materials 9 (1985), S. 176-184 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Three test methods for measuring the rate of heat release, RHR, have been compared on the same building materials. The test methods are the OSU-box modified for O2-consumption, the STFI open arrangement and the NBS cone calorimeter. All methods are based on the oxygen-consumption technique. Radiation intensities up to 50 k Wm-2 have been applied. Thirteen different materials were tested. The results obtained using the three methods seem to be quite similar in spite of the different equipment used. The minor deviations observed in the results seem to be systematic and may be due to the different testing arrangements. There is a good correlation between results, e.g. total heat release up to 1min after ignition, obtained by the different methods. Additional information about the time to ignition is obtained simultaneously. Heat-release rates in the vertical and horizontal orientations are also compared in the NBS cone calorimeter.
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    Fire and Materials 9 (1985), S. 185-191 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A technique for estimating fire-buildup in rooms with combustible interior finish is discussed. Use of the technique resulted in good agreement between fires conducted in one-quarter-scale rooms with a doorway opening and those performed in full-scale rooms. The effects of burner location and heating rate on flashover in a well-insulated room were also studied to help select a suitable ignition source size and placement for testing of interior-finish materials.
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    Fire and Materials 9 (1985), S. 192-197 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The International Conference Interflam'85 was held at the University of Surrey, Guildford, UK, on 26-8 March 1985. This third conference in the Interflam series was set up with the specific aim to bring together the 1985 state of the art of fire science and to show particularly how this information can be put to practical use in the saving of lives. Over 45 speakers, each specialists in their own field of work, some 15 different countries contributed papers. Dr Peter Allender, formerly of Metro-Cammell and now with John Allen Associates, has seen the Conference both from the lecturing platform and from the audience. He has been invited to give his views about Interflam'85.
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    Fire and Materials 9 (1985), S. 200-201 
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    Keywords: Chemistry ; Polymer and Materials Science
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    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 9 (1985), S. 201-201 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 10 (1986), S. 1-6 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A method based on exposure of mice in the CAB 4.5 smoke chamber for the evaluation of the biological toxicity of the products of flame and smoldering combustion of polumeric materials has been developed. A toxicity index, characterizing the danger from the products of combustion of the test polymer under the given conditions, was proposed on the basis of values of the concentration of carboxyhaemoglobin in the blood of the test animals, attaining charateristic critical limits (lethal limit) and LC50 values.
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    Fire and Materials 10 (1986), S. 21-28 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Large-scale fire experiments have been carried out in a special test rig to study the chemical nature of fire atmosphere using a ‘fingerprint’ sampling and analysis method. Four polymeric materials - wood, polypropylene, polymethyl methacrylate and polystyrene foam - were used separately as fuel, with both high and low ventilation. In addition to oxides of carbon the fingerprints yielded typically between twenty and forty different chemical compounds including several (e.g. aldehydes) which could contribute significantly to the irritancy of the fire gases. The change in nature of the fingerprint gases with the different ventilation conditions, different polymeric materials and with different stages of the same fire is discussed, together with the toxicological significance of the results.
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    Fire and Materials 10 (1986), S. 11-19 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Combustion gases were produced from several cable-insulation materials in separate experiments conducted in a model fire chamber. These gases were then allowed to interact with stressed metal specimens, consisting for the most part of various stainless and hardened steels as well as of carbon steel and stainless steel sheet. Thereafter the samples as exposed were stored in a humid atmosphere. As expected, PVC combustion gases caused the cracking of spring steel and also extensive pitting corrosion of stainless steel. These results confirmed that test conditions conformed to real-life fires as observed in practice. The combustion gases deriving from fluorinated polymers were much less corrosive on stainless steel and provoked only slight pitting in isolated cases. The rate of corrosion damage on carbon steel was lower by more than an order of magnitude than in the case of PVC. However, stress corrosion of sensitized 18/8 stainless steel and spring steel was found to occur. Tests on the thermal degradation of the dluorinated polymer ‘Teflon’ FEP and ‘Tefzel’ confirmed their high stability. If one compares the behaviour of these fluoroplastics with that of PVC it can generally be concluded that, although the use of fluorinated insulation materials on cables might not altogether eliminate corrosion problems in the event of fire, it does constitute a realistic contribution to fire protection and to the reeducation of fire-related damage.
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    Fire and Materials 10 (1986), S. 29-39 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: Both ignition and rate of fire development tests are required to determine the fire performance of upholstered composites. Current practice uses small-model specimens for ignitability tests but rate of burning tests are usually carried out on actual furniture. This paper discuss small- and large-scale tests for upholstered furniture.
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    Fire and Materials 10 (1986) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
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    Fire and Materials 10 (1986), S. 47-55 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
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    Notes: This theoretical and experimental study, complementary to that discussed in Reference 1, examines those factors that affect the ‘test efficiency’ in fire resistance testing. Convective heat transfer in the test chamber may become an essential part of the heat transmission process if, due to small furnace size or non-luminous furnace gases, the radiative transmission is not sufficiently intense. The standard technique of measuring and controlling the temperature conditions in the furnace chamber, though not in line with strict scienctific practices, appears to provide insurance against poor test result. A calibration procedure is described for checking the adequacy of fire resistance test facilities and some solutions presented for improving the test efficiency.
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    Fire and Materials 10 (1986), S. 41-46 
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    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Studies have been carried out of the effects of (1) anhydrous tin (IV) oxide and (2)β-stannic acid {hydrous tin (IV) oxide} on the flammability and smoke production of unsaturated polyesters into which halogen may be introduced as a reactive monomer during the resin synthesis. The results obtained provide evidence for a marked falme-reatedant synergism between tin and halogen, accompanied by a significant reduction in smoke from the burning polymer. The hydrous tin compound was found to be more effective than the anhydrous SnO2 both as a flame retardant and a smoke suppressant. At a 2% incorporation level β-stannic acid gave polymers with LOIs of up to ca 30 and reductions in smoke density of 50% or more compared with the standard non-halogenated resin. The mode of action of the tin compounds appears to involve both the condensed and vapour phases. In view of the generally accepted low toxicity of inorganic tin chemicals their possible use as fire-retardant additives for polymer systems should merit serious consideration.
    Additional Material: 3 Ill.
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  • 94
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986), S. 57-62 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A sensitive method is described for the determination of hydrogen cyanide and organic nitriles in atmospheres created by the combustion or thermal degradation of nitrogen-containing polymeric materials. The technique also allows for the determination of other hydrocarbon species from the same sample using a gas chromatograph-mass spectrometer system without entailing too many divisions in the sample quantity The method utilizes an NOx analyzer will only respond to nitrogen-containing compounds and response factors for these compounds can be calculated.
    Additional Material: 6 Ill.
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  • 95
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    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986), S. 63-69 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The hazards resulting rom smoke emission were widely recognized in the early 1970s as a result of several major fire disasters. Since that time considerable interest has been shown in the development of smoke-suppressants. This paper reviews some of the very promising results that have been obtained using molybdenuem comounds as flame-retardants and smoke-suppressantes in halogenated polymers. They have been shown to be effective in both rigid and flexible grades of PVC. In the rigid grades these compounds can reduce smoke emission by at least 80%. Reductions in excess of 50% have been observed with typical plasticized formulations, although the magnitude of the effect here depends on both the type and level of plasticizer. Comparisons of the results of different smoke tests suggest that the small-scale tests commonly used do not fully reflect the true extent of the smoke-reductions that are obtainable with these combounds. Significant reductions in smoke-emission have also been obtained with halogenated polyester thermosets and chlorinated elastomer formulations. With the polyesters some of the best results occurred when molybdenum oxide was used in conjunction with alumunium trihydrate. In all cases these compounds proved to have significant flame-retardant properties. Reference has been made in the paper to their mode of activity but the actual mechanistic investigations have not been discussed in detail.
    Additional Material: 8 Tab.
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  • 96
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A two-storey test rig was used to investigate how an insulated facade would react to the impingement of a simulated room fire. In particular, whether or not a facade insulated with polyurethane foam would promote vertical flame spread. Wooden cribs weighing 40 kg were used as fire sources. One set of tests was run without any steel cladding to study the behaviour of the polyurethane foam alone. In a wall-configuration test as well as under a conrner-configuration one limited vertical and horizontal flame propagation were found. The degree of damage was to some extent, greater under the corner-test conditions than with the wall tests. A ventilated facade construction with the profiled steel cladding fixed to vertical support-work was used for the second set of tests. In order to simulate repair conditions, the outer metal cladding was completely removed from the lower 1.5 m of the facade. In Both tests a strong chimney-effect behind the cladding was observed. This intensification of the flame impingement led to a flame spread up the top of the facade. The tests indicated that the vertical flame spread would continue unless the method of construction incorporated vertical fire stops.
    Additional Material: 12 Ill.
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  • 97
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986), S. 71-77 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A series of materials were tested in a radiant furnace for their production of toxicants (carbon monoxide and hydrogen chloride) while concurrently measuring the weight remaining of the test specimen. In addition, the effect of sample form on toxicant production was considered for Douglas fir and polyvinyl chloride. The smoke-exposure profile was found to be dependent on the material's form. The specimen-irradiation time and the incident heat flux. The calculation of exposure using a Ct product based on the area under the production curve was found useful for smoke and toxicants. Concentrations of toxic gases produced were not linearly related to sample-weight loss throughout the experiments. The influence of sample form on smoke and toxicant production was greater for Douglas fir than for polyvinyl chloride. The results indicate that in toxicity tests samples should be tested in their end-use form and that a material's thermal properties may influence toxicity-value calculations.
    Additional Material: 10 Ill.
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  • 98
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    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986), S. 91-91 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 99
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986), S. 91-91 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 100
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Fire and Materials 10 (1986) 
    ISSN: 0308-0501
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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