ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Elsevier  (5,804,698)
Collection
Language
Years
  • 1
    Publication Date: 2024-04-25
    Description: Highlights • Development of an autonomous DIC analyzer based on Conductometric technique using a cell with 4 hollow brass electrodes. • CO2 extraction from seawater using a gas diffusion cell with a “Tube In A Tube” configuration and a gas permeable membrane. • Formulation of mathematical temperature and salinity correction to determine accurate DIC concentration. • Demonstration of the analyzer performance in the southwest Baltic Sea. Abstract Background The increase in anthropogenic CO2 concentrations in the Earth's atmosphere since the industrial revolution has resulted in an increased uptake of CO2 by the oceans, leading to ocean acidification. Dissolved Inorganic Carbon (DIC) is one of the key variables to characterize the seawater carbonate system. High quality DIC observations at a high spatial-temporal resolution is required to improve our understanding of the marine carbonate system. To meet the requirements, autonomous DIC analyzers are needed which offer a high sampling frequency, are cost-effective and have a low reagent and power consumption. Results We present the development and validation of a novel analyzer for autonomous measurements of DIC in seawater using conductometric detection. The analyzer employs a gas diffusion sequential injection approach in a “Tube In A Tube” configuration that facilitates diffusion of gaseous CO2 from an acidified sample through a gas permeable membrane into a stream of an alkaline solution. The change in conductivity in the alkaline medium is proportional to the DIC concentration of the sample and is measured using a detection cell constructed of 4 hollow brass electrodes. Physical and chemical optimizations of the analyzer yielded a sampling frequency of 4 samples h−1 using sub mL reagent volumes for each measurement. Temperature and salinity effects on DIC measurements were mathematically corrected to increase accuracy. Analytical precision of ±4.9 μmol kg−1 and ±9.7 μmol kg−1 were achieved from measurements of a DIC reference material in the laboratory and during a field deployment in the southwest Baltic Sea, respectively. Significance This study describes a simple, cost-effective, autonomous, on-site benchtop DIC analyzer capable of measuring DIC in seawater at a high temporal resolution as a step towards an underwater DIC sensor. The analyzer is able to measure a wide range of DIC concentrations in both fresh and marine waters. The achieved accuracy and precision offer an excellent opportunity to employ the analyzer for ocean acidification studies and CO2 leakage detection in the context of Carbon Capture and Storage operations.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2024-04-23
    Description: Preface of a special issue.
    Description: Published
    Description: 3365-3366
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2024-04-22
    Description: Highlights: • The interactions between vortices in a four-vortex flow field using a rotating water tank. • Driven by the strain field, non-ideal vortices stretch along the centerline, and manifest an asymmetric stretching pattern. • Non-ideal vortices disperse vorticity, accumulate filaments, and exhibit distinctive variations in anti-symmetric vorticity distribution, impacting respective merging efficiency. Abstract: Oceanic vortex merging is an important physical process for the vortex evolution and its impact on marine environment. However, limitation of the in-situ oceanic observational data of vortex merging inhabits its better understanding. This study investigates the interactions between non-ideal vortices in a four-vortex flow field in a rotating tank. We examine the merging stages of anticyclonic vortices, influenced by two other cyclonic vortices and their respective dynamical behaviors and quantify the effects of merging on vortex characteristics. The results indicate a strong shear flow between two counter-rotating vortices, which accelerates the motion of the anticyclonic vortex, while cyclonic ones exhibit greater stability. Subsequently, different stages of non-ideal vortex merging in a co-rotating framework are defined, primarily the encircling stage, rapid approaching stage, and merging vortex stage. In addition, we quantify and compare variations in morphological parameters and anti-symmetric vorticity distribution of non-ideal vortices across these stages. The stretching of vortices primarily occurs along the line connecting their centers due to the strain field exerted by neighboring vortices, resulting in an asymmetric stretching pattern in the interactions among non-ideal vortices. Furthermore, during the merging process, non-ideal vortices disperse vorticity outward and accumulate vortex filaments in the surrounding environment, leading to distinctive variations in anti-symmetric vorticity distribution, affecting their respective merging efficiency.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2024-04-22
    Description: In the past three decades, altimeter-based remote sensing has been a widely used system to estimate ocean surface currents. However, it remains a great challenge to effectively resolve scales below ∼100 km at high latitudes and ∼ 300 km at mid-latitudes. In this study, we propose a scheme that utilizes geostrophic equilibrium and surface quasigeostrophy theory (SQG) to improve surface current resolution by incorporating remote sensing sea surface temperature (SST), sea surface height (SSH), and sea surface salinity (SSS) observations. The scheme separately characterizes the larger-scale flows and smaller-scale motions of surface currents. A case study encompassing the Agulhas surface current demonstrates that the smaller-scale motions associated with temperature fronts are well captured by introducing high spatial-temporal resolution SST data. Furthermore, the reconstructed surface current is systemically evaluated by using surface drogued drifters and a Lagrangian synthetic particle tracking tool throughout the South Indian Ocean (SIO) for 2011–2015. Notably, the reconstructed zonal velocity component is closer to the drifter observations than the meridional counterpart and corresponding velocity phase. Regionally, the Antarctic Circumpolar Current (ACC) showcases superior reconstruction performance, with higher skill scores and lower Lagrangian separation distances. However, a relatively large uncertainty is observed around the Agulhas Retroflection (AR) and Greater Agulhas System (GAS), which are linked to complicated regional dynamic regimes. We finally conduct four simulation experiments to explore the effect of different SST products on surface current reconstruction within the subdomain AR. The results indicate the varying potentials of the four evaluated SST products for informing surface current applications. Specifically, the MWIRSST enhances the likelihood of particles reaching the target field, while DMI OI shortens the average deviation distance of the arrived particles.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2024-04-22
    Description: Marine imaging studies have unique constraints on the data collected requiring a tool for defining the biological scope to facilitate data discovery, quality evaluation, sharing and reuse. Defining the ‘target population’ is way of scoping biological sampling or observations by setting the pool of organisms to be observed or sampled. It is used in survey design and planning, to determine statistical inference, and is critical for data interpretation and reuse (both images and derived data). We designed a set of attributes for defining and recording the target population in biological studies using marine photography, incorporating ecological and environmental delineation and marine imaging method constraints. We describe how this definition may be altered and recorded at different phases of a project. The set of attributes records the definition of the target population in a structured metadata format to enhance data FAIRness. It is designed as an extension to the image FAIR Digital Objects metadata standard, and we map terms to other biological data standards where possible. This set of attributes serves a need to update ecological metadata to align with new remotely-sensed data, and can be applied to other remotely-sensed ecological image data.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2024-04-22
    Description: The Arctic is greatly impacted by climate change. The increase in air temperature drives the thawing of permafrost and an increase in coastal erosion and river discharge. This leads to a greater input of sediment and organic matter into coastal waters, which substantially impacts the ecosystems by reducing light transmission through the water column and altering the biogeochemistry, but also the subsistence economy of local people, and changes in climate because of the transformation of organic matter into greenhouse gases. Yet, the quantification of suspended sediment in Arctic coastal and nearshore waters remains unsatisfactory due to the absence of dedicated algorithms to resolve the high loads occurring in the close vicinity of the shoreline. In this study we present the Arctic Nearshore Turbidity Algorithm (ANTA), the first reflectance-turbidity relationship specifically targeted towards Arctic nearshore waters that is tuned with in-situ measurements from the nearshore waters of Herschel Island Qikiqtaruk in the western Canadian Arctic. A semi-empirical model was calibrated for several relevant sensors in ocean color remote sensing, including MODIS, Sentinel 3 (OLCI), Landsat 8 (OLI), and Sentinel 2 (MSI), as well as the older Landsat sensors TM and ETM+. The ANTA performed better with Landsat 8 than with Sentinel 2 and Sentinel 3. The application of the ANTA to Sentinel 2 imagery that matches in-situ turbidity samples taken in Adventfjorden, Svalbard, shows transferability to nearshore areas beyond Herschel Island Qikiqtaruk.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev , info:eu-repo/semantics/article
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Agricultural and Forest Meteorology, Elsevier, 339, pp. 109543-109543, ISSN: 0168-1923
    Publication Date: 2024-04-22
    Description: Tundra is primarily a habitat for shrub growth, not trees, but growth of prostrate forms of trees has been reported occasionally from the subarctic tundra region. In the light of on-going climate change, climate sensitivity studies of these unique trees are essential to predict vegetation dynamics and potential northward expansion of boreal forest tree species into tundra. Here we studied one of the northernmost Larix Mill. trees and Betula nana L. shrubs (72°N) from the Siberian tundra for the common period 1980-2017. We took advantage of the discovery of a single cohort of prostrate Larix trees within a tundra ecosystem, i.e., ca. 60 km northwards from the northern treeline, and compared climate-growth relationships of the two species. Both woody plants were sensitive to the July temperature, however this relationship was stable across the entire study period (1980-2017) only for Betula nana chronology. Additionally, radial growth of Larix trees became negatively correlated to temperatures during the previous summer. In recent period moisture sensitivity between Larix trees and Betula nana shrubs was contrasting, with generally wetter soil conditions favoring Larix trees growth and dryer conditions promoting Betula nana growth. Our study indicates that Larix trees radial growth in recent years is more sensitive to moisture than to summer air temperatures, whereas temperature sensitivity of Betula nana shrub is stable over time. We provide first detailed insight into the annual resolution on Larix tree growth sensitivity to climate in the heart of the tundra. The potentially higher Betula nana shrub resistance to warmer and drier climate versus Larix trees on a tundra revealed in our study needs to be further examined across habitats of various soil, moisture and permafrost status.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2024-04-22
    Description: Amongst other factors, topographic features can influence the genetic variability among populations of marine organisms. This applies to host species but also to their parasites, which are poorly studied regarding this aspect, as well as with regard to their use as bioindicators. In the present work, the ribosomal DNA (28S rDNA) was used to assess genetic diversity of Grillotia (Cestoda, Trypanorhyncha) larvae in one of its paratenic hosts, namely Etmopterus spinax, across five different regions (off Scotland, Celtic, Alboran and Balearic Seas and off Cyprus) belonging to three major geographic areas (Northeast Atlantic, western and eastern Mediterranean). The obtained sequences revealed a total of 18 polymorphic sites and 17 haplotypes, as well as significant values of variance throughout the five different regions. Reconstructed phylogenetic trees highlighted that all Grillotia sp. sequences formed a monophyletic group, but divergent lineages split into different main clades which were in relation to the area of origin, with a consistent cluster of sequences from the Atlantic Ocean, as well as another from the Eastern Mediterranean. In contrast, low genetic differentiation was observed between samples from Balearic and Alboran Seas, and with respect to Grillotia sp. larvae from the Gulf of Naples analysed in a previous study. Geographical differences in parasite infection descriptors (prevalence, abundance, and intensity) were assessed, revealing significant differences among the sampled regions. The present study indicates that geographical distance and submarine barriers affect not only the connectivity of hosts but also their parasite infrapopulations by limiting interpopulation dispersal. It underlines the usefulness of parasites as biological tags for the study of susceptible and data-poor host species such as deep-water sharks and its potential implications for host population management and protection measures.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Palaeogeography Palaeoclimatology Palaeoecology, Elsevier, 632, pp. 111863-111863, ISSN: 0031-0182
    Publication Date: 2024-04-22
    Description: Winter climate variations in midlatitude regions have far-reaching effects on both natural and human systems worldwide. However, most climate reconstructions focus on either annual or summer climate conditions. Here we present a stalagmite stable isotope record from Urşilor Cave (Romania) where the δ18O values are controlled by winter temperature. Because of its East-Central Europe (ECE) location, the cave site is well suited to capture variations in precipitation and temperature in response to changes in the North Atlantic region. Present day precipitation and temperature in this region are controlled by two teleconnection patterns, the Arctic Oscillation (AO) and the East Atlantic (EA). By analyzing composite maps for four different scenarios of AO and EA phase, we suggest that between 5.6 and 5.2 ka the positive phases of AO and EA became increasingly dominant. This shift led to generally warmer winters in northern Europe, but drier conditions in southern Europe and the Levant. Considering the compound effect of AO and EA on the hydroclimate of ECE, our study highlights the importance of examining the combined impact of teleconnection patterns on climate proxies influenced by various forcing mechanisms.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2024-04-22
    Description: Paleoclimate reconstructions are increasingly used to characterize climate variability and change prior to the instrumental record, in order to improve our estimates of climate extremes and to provide a baseline for climate change projections. Most of these reconstructions are focused on temperature, precipitation, and/or drought indices and, to a lesser extent, reconstruct streamflow variability. In this study, the first regional tree-ring width chronology (i.e. Quercus sp.), from the Caraorman forest (Danube Delta, Romania), was used to reconstruct the last ∼250 years of annual (from November previous year to July of the current year) streamflow of the Lower Danube River. The obtained results indicate a stable and significant correlation between the tree-ring width index from the Caraorman forest and the Danube streamflow at the Ceatal Izmail hydrologic station situated in the southeastern part of Europe. Interannual streamflow variation for the analyzed period indicates 14 extremely high flow years, with streamflow greater than 8780 m3/s (1770, 1771, 1799, 1836, 1838, 1839, 1871, 1876, 1877, 1879, 1940, 1941, 1997 and 2010) and 14 extremely low flow years, with streamflow lower than 5300 m3/s (1741, 1745, 1750, 1753, 1773, 1794, 1812, 1832, 1843, 1882, 1899, 1921, 1964 and 1994). Periods characterized by pluvials in the lower Danube Delta are associated with a low-pressure system centered over Europe, positive sea surface temperature (SST) anomalies over the Atlantic Ocean, and negative SST anomalies over the Baltic, North, and Mediterranean Seas. These large-scale conditions favor the advection of moist air from the Mediterranean and the Black Sea towards the southeastern part of Romania, which in turn leads to high precipitation rates over this region. Opposite to this, low streamflow years are associated with a high-pressure system centered over Europe, characterized by a northward shift of the storm tracks and negative SST anomalies over the Atlantic Ocean, and positive SST anomalies over the Baltic, North, and Mediterranean Seas. Based on our results, we argue that the reconstruction of river streamflow data based on the tree-ring width has important scientific and practical implications for a better understanding of the streamflow variation of the past, necessary for water resource management and environmental-hydrological protection.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 11
    Publication Date: 2024-04-22
    Description: The enhanced inertia load caused by biofouling on device components, such as the foundations of wind turbines or other structures at sea, modifies the hydrodynamic properties, and increases the stress to structures, predominantly in upper water layers with high impact from wave dynamics. This compromises the stability, functioning, operation as well as the durability of these devices especially in exposed environments. A main challenge is the quantification of the impact of hydrodynamic forces on irregular bodies being overgrown by soft- and hard-bodied biofouling organisms. Therefore, test bodies from the upper 1–5 m water depth and thus exposed to the strongest wave actions close to the surface shall be overgrown by biofouling and used in measurement trials in a wave and current flume. These measurements shall shed light on the varying roughness and its influence on the load bearing capacity of foundation piles. Consequently, the main aims of the present work were the development of two independent test stations as holding devices for artificial test bodies for the collection of biofouling organisms during field studies: a carrying unit floating at the surface in an exposed area (System A) and a sampling device with access from a land-based facility (System B). Both systems are relatively easy to access, exhibit straightforward handling, and are reasonable cost-effective. A Test Body Support Unit (TBSU, System A) was designed and mounted on a spare buoy to carry the test bodies (cylinders), which serve as substrate for the fouling. The system was sufficiently robust to withstand several periods of rough sea conditions over the first two years. This system can only be accessed by vessels. System B (MareLift) provided the robustness and functionality needed for areas exhibiting harsh conditions but can be operated from land. The here used test bodies (steel panels) exhibited a sound basis for the monitoring of succession processes in the biofouling development. System B offered the possibility to analyse two habitats (intertidal and subtidal) and revealed clear differences in the composition and development of their fouling communities. Overall, both systems provide advantages in obtaining standardized biofouling samples compared to previous approaches. Such test stations play an important role in the risk management of marine sectors as they could help characterising biofouling communities over different geographical areas. System A and B provide a sound basis for biofouling research but potentially also for other potential research approaches in exposed areas as they provide space for future developments.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 12
    Publication Date: 2024-04-19
    Type: Book chapter , PeerReviewed
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 13
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Current Opinion in Environmental Science & Health, Elsevier, 20, pp. 100231-100231, ISSN: 2468-5844
    Publication Date: 2024-04-19
    Description: Declaration of interest was missed out in the published version. The authors have confirmed in the following context: ‘The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.’ The publisher would like to apologise for any inconvenience caused.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 14
    Publication Date: 2024-04-18
    Description: The Beagle Channel is a remote subantarctic environment where mussel aquaculture initiatives have existed since the early 1990s. Here we analyze phytoplankton biomass and composition, and the occurrence of harmful microalgae species and their toxins at three sites during the period 2015–2016. The occurrence of potentially harmful algae was observed throughout the study period, including toxigenic dinoflagellates such as Alexandrium catenella (Group I of the A. tamarense complex), A. ostenfeldii, Dinophysis acuminata, Gonyaulax spinifera, Azadinium sp., and the diatoms Pseudo-nitzschia australis and P. fraudulenta. Toxic dinoflagellates were detected in low densities whereas a Pseudo-nitzschia bloom was observed in late February. Isolates of A. catenella and P. delicatissima sensu stricto were phylogenetically characterized. The toxin profile of A. catenella was dominated by GTX4, while P. delicatissima sensu stricto showed no production of the neurotoxin domoic acid in culture conditions. The results provide base-line information for the management of harmful algal blooms in this little explored subantarctic area.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 15
    Publication Date: 2024-04-17
    Description: Recent studies have highlighted the prevalence of microplastic (MP) pollution in the global marine environment and these pollutants have been found to contaminate even remote regions, including the Southern Ocean south of the polar front. Previous studies in this region have mostly focused on MPs larger than 300 μm, potentially underestimating the extent of MP pollution. This study is the first to investigate MPs in marine surface waters south of the polar front, with a focus on small MPs 500–11 μm in size. Seventeen surface water samples were collected in the southern Weddell Sea using an in-house-designed sampling system. The analysis of the entire sample using micro-Fourier transform infrared spectroscopy (μFTIR) with focal plane array (FPA) detection revealed the presence of MPs in all samples, with the vast majority of the MPs detected being smaller than 300 μm (98.3 %). The mean concentration reached 43.5 (± 83.8) MPs m−3, with a wide range from 0.5 to 267.2 MPs m−3. The samples with the highest concentrations differed from the other samples in that they were collected north of the continental slope and the Antarctic Slope Current. Sea ice conditions possibly also influenced these varying concentrations. This study reports high concentrations of MPs compared to other studies in the region. It emphasizes the need to analyze small MPs, down to a size of 11 μm or even smaller, in the Antarctic Treaty Area to gain a more comprehensive understanding of MP pollution and its potential ecological impacts.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 16
    Publication Date: 2024-04-17
    Description: Over the past decades, significant efforts have been made to understand the nature, dynamics and evolution of volcanic systems. In parallel, the continuous demographic expansion and extensive urbanization of volcanic areas have increased the exposure of our society to these natural phenomena. This increases the need to improve our capacities to accurately assess projected volcanic hazards and their potential socioeconomic and environmental impact, and Antarctica and the sub-Antarctic islands are no exception. More than a hundred volcanoes have been identified in Antarctica, some of which are entirely buried beneath the ice sheet and others as submarine volcanoes. Of these, at least eight large (basal diameters 〉 c. 20-30 km) volcanoes are known to be active and pose a considerable threat to scientific and ever-increasing tourism activities being carried out in the region. Despite the scientific and socioeconomic interest, many aspects of the past volcanic activity and magmatic processes in Antarctica, and current volcanic hazards and risks, remain unknown. Moreover, many of Antarctica’s volcanoes preserve a remarkable history of the eruptive environment, from which multiple parameters of past configurations of the Antarctic ice sheet (AIS) can be deduced. Given the critical role that the AIS plays in regulating Earth’s climate, Antarctica’s volcanoes therefore can be regarded as the ground truth for current models of past climates derived from modelling and studies of marine sediments. Here, we provide a succinct overview of the evolution of volcanism and magmatism in Antarctica and the sub-Antarctic region over the past 200 million years. Then, we briefly review the current state of knowledge of the most crucial aspects regarding Antarctica’s volcanic and magmatic processes, and the contributions volcanic studies have made to our understanding of ice sheet history and evolution, geothermal heat flow, as well as present-day and future volcanic hazard and risk. A principal objective is to highlight the problems and critical limitations of the current state of knowledge and to provide suggestions for future potential directions of volcanic-driven investigations in Antarctica. Finally, we also discuss and assess the importance and scope of education and outreach activities specifically relating to Antarctic volcanism, and within the context of broader polar sciences.
    Description: Published
    Description: 107941
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 17
    Publication Date: 2024-04-17
    Description: We present the results of the tephrochronology study of a 14.49 m long marine sediment core (TR 17–08) collected in the Edisto Inlet, Ross Sea (Antarctica). The core contains four cryptotephra layers at 55–56, 512–513, 517–518, and 524–525 cm of depth, which have been characterised by a detailed description of the texture, mineral assemblage, and single glass shards major and trace element geochemistry. The age model of the investigated sedimentary sequence, based on radiocarbon dating, indicates that the topmost cryptotephra correlates with the widespread 1254 CE tephra erupted by a historical eruption (696 ± 2 cal yrs BP) of Mount Rittmann, in northern Victoria Land. Deeper cryptotephra layers were derived from previously unknown explosive eruptions of Mount Melbourne volcano and were emplaced between 1615 cal yrs BP and 1677 cal yrs BP, e.g. between the 3rd and 4th centuries CE. This discovery demonstrates that the Mount Melbourne volcanic complex has been highly active in historical times allowing significant progress in the current understanding of regional eruptive history. Moreover, from a tephrochronological point of view, the detected cryptotephra provide new regional isochron markers to facilitate high-precision correlations and help stratigraphically constrain changes in environmental and climatic conditions that are identified by multidisciplinary studies.
    Description: Published
    Description: 100079
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 18
    Publication Date: 2024-04-16
    Description: Phototrophic protists are a fundamental component of the world's oceans by serving as the primary source of energy, oxygen, and organic nutrients for the entire ecosystem. Due to the high thermal seasonality of their habitat, temperate protists could harbour many well-adapted species that tolerate ocean warming. However, these species may not sustain ecosystem functions equally well. To address these uncertainties, we conducted a 30-day mesocosm experiment to investigate how moderate (12C) and substantial (18C) warming compared to ambient conditions (6C) affect the composition (18S rRNA metabarcoding) and ecosystem functions (biomass, gross oxygen productivity, nutritional quality – C:N and C:P ratio) of a North Sea spring bloom community. Our results revealed warming-driven shifts in dominant protist groups, with haptophytes thriving at 12 C and diatoms at 18 C. Species responses primarily depended on the species' thermal traits, with indirect temperature effects on grazing being less relevant and phosphorus acting as a critical modulator. The species Phaeocystis globosa showed highest biomass on low phosphate concentrations and relatively increased in some replicates of both warming treatments. In line with this, the C:P ratio varied more with the presence of P. globosa than with temperature. Examining further ecosystem responses under warming, our study revealed lowered gross oxygen productivity but increased biomass accumulation whereas the C:N ratio remained unaltered. Although North Sea species exhibited resilience to elevated temperatures, a diminished functional similarity and heightened compositional variability indicate potential ecosystem repercussions for higher trophic levels. In conclusion, our research stresses the multifaceted nature of temperature effects on protist communities, emphasising the need for a holistic understanding that encompasses trait-based responses, indirect effects, and functional dynamics in the face of exacerbating temperature changes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 19
    Publication Date: 2024-04-15
    Description: Fishes occur in a wider range of habitats than any other vertebrate or invertebrate group, from the upper reaches of streams in high mountain ranges to the mouths of temperate and tropical rivers, and from the intertidal zone to the ocean's abyss. Fish grow in size, spawn and die, either from natural causes (predation, diseases, ageing) or from being caught in fishing nets if the population is exploited. These dynamical processes are expressed with mathematical equations and are used in population models to estimate fisheries reference points (stock assessment), which in turn provide the basis for fisheries management. Fish populations subjected to fisheries exploitation are called fish “stocks”. Fishing has been increasingly affecting fish stocks and ecosystems both directly and indirectly, and along with the human-induced climate change they pose major threats to fish biodiversity worldwide. Using the available data stored in local or global databases to assess the status of all stocks, even the data-poor fish stocks, and following an ecosystem approach to fisheries management that incorporates effort reduction through marine protected areas, may contribute to the sustainable exploitation of fisheries resources.
    Type: Book chapter , NonPeerReviewed
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 20
    Publication Date: 2024-04-15
    Description: Cadmium (Cd) has a nutrient-like distribution in the ocean, similar to the macronutrient phosphate. Significant isotope fractionation induced by the biological cycling of Cd makes it a potential tracer for nutrients and productivity. However, the Cd flux and Cd isotope composition of marine sediments can also be influenced by local redox conditions and partial remineralization of organically hosted Cd. These confounding factors are under-constrained and render it challenging to use Cd as a reliable paleoproxy. To understand the relative importance of each of these processes, we examined the Cd isotope systematics of 69 modern sediments deposited across a wide range of environments. We complement these data with four profiles of particulate Cd isotope compositions from the Southern Ocean. We report three main results. First, we show that the sedimentary flux of Cd is tightly coupled to that of organic matter. Second, most Cd burial occurs in regions with some bottom-water oxygen, and the flux of CdS to anoxic regions is, globally, minor. Finally, we find that remineralization can substantially modify sedimentary Cd isotope compositions, though it is challenging to relate pelagic and sedimentary processes. For example, we find that the relationship between sedimentary Cd isotope compositions and surface seawater [Cd] is the reverse of that predicted by isotope reactor models. Likewise, sedimentary Cd isotope compositions are anti-correlated with bottom-water oxygen. While this pattern is consistent with preferential remineralization of isotopically heavy Cd, profiles of marine particulate matter reveal the reverse, whereby the Cd isotope composition of large particles, which are most likely to reach the seafloor, becomes increasingly ‘heavy’ with depth. These results highlight how productivity, redox, and remineralization all influence the flux and isotope composition of Cd to marine sediments. While our study suggests that there is no simple way to relate sedimentary Cd isotopes to surface nutrient utilization, our data point toward several potential controls that could form the basis of novel proxies for local redox conditions and remineralization.
    Type: Article , PeerReviewed
    Format: other
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 21
    Publication Date: 2024-04-11
    Description: Interactions between minerals and organic carbon (OC) in soils are key to stabilize OC and mitigate greenhouse gas emissions upon permafrost thaw. However, changes in soil water pathways upon permafrost thaw are likely to affect the stability of mineral OC interactions by inducing their dissolution and precipitation. This study aims to assess and quantify how mineral OC interactions are affected by dissolution and precipitation in thawed relative to unthawed layers. We hypothesize that a change in the radiogenic strontium (Sr) isotopic ratio (87Sr/86Sr) involved in mineral OC interactions upon changing water saturation conditions implies a destabilization of the mineral OC interaction. We quantified mineral OC interactions using selective extractions in soils facing gradual thaw (Eight Mile Lake, AK, USA) and in sediments with a thawing history of abrupt thaw (Duvanny Yar, Russia), and we measured the 87Sr/86Sr ratio of the selective extracts targeting the Sr associated to mineral OC interactions. Firstly, for water saturated layers with a higher proportion of mineral OC interactions, we found a difference in the 87Sr/86Sr ratio relative to the surrounding layers, and this supports the preservation of a Sr “stable” pool in these mineral OC interactions. We estimated that a portion of these mineral OC interactions have remained undissociated since their formation (between 4% and 64% by Sr isotope mass balance). Secondly, we found no difference in 87Sr/86Sr ratio between layers accumulating Fe oxides at redox interfaces regularly affected by water table changes (or upon thermokarst processes) relative to surrounding layers. This supports the dominance of a Sr “labile” pool inherited from processes of dissolution and precipitation of the mineral OC interactions. Thirdly, our estimations based on a Sr isotope mass balance support that, as a consequence of permafrost thaw, a larger proportion of Sr from primary mineral weathering (〉80%) controls the Sr in mineral OC interactions in the saturated zone of deeply thawed soils relative to poorly thawed soils (~50%). In conclusion, we found that the radiogenic Sr isotope method, applied for the first time in this context, is promising to trace dissolution-precipitation processes of mineral OC interaction in thawing permafrost.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 22
    Publication Date: 2024-04-11
    Description: Fluid induced fault reactivation experiments will take place as part of the “Fault Activation and Earthquake Rupture” project (FEAR) at the BedrettoLab, an underground laboratory for geosciences and geo-energy excavated within the Rotondo massif (Swiss Alps). The aim of this publication is to characterize frictional properties and permeability of the main segment of the fault zone selected for limited fluid-induced fault reactivation experiments. Firstly, we characterized fault zone microstructures in the field and in thin sections. Secondly, we assessed fault gouge mineralogy by X-ray powder diffraction analysis, yielding a composition in agreement with similar fault gouges in the same area. Finally, we performed a detailed frictional and permeability characterization in laboratory, using BRAVA (Brittle Rock deformAtion Versatile Apparatus). We performed five frictional experiments, run at the actual in-situ conditions: four experiments for frictional properties characterization; and one further experiment where we stimulated the experimental fault by fluid pressurization applying a similar injection protocol designed for the in-situ hydraulic stimulation experiment. Additionally, we performed microstructural analysis on experimental samples to link frictional and permeability properties with fault fabric evolution. The integration of experimental results with field investigations suggests that the selected fault is potentially seismogenic and can be dynamically reactivated and controlled with hydraulic stimulation. This study highlights the importance of bridging the gap between laboratory and in-situ fault characterization, where experimental results become instrumental for the correct design of injection protocols such as those of FEAR project.
    Description: Published
    Description: 229987
    Description: OST3 Vicino alla faglia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 23
    Publication Date: 2024-04-10
    Description: Trace metals (TMs) manganese (Mn), cobalt (Co), and aluminium (Al) have important geochemical and biological roles in the ocean. Here, we present full depth profiles of dissolved (d) and particulate Al, Mn, and Co along the latitude of 40 °S in the South Atlantic Ocean from the GEOTRACES GA10 cruises that operated in austral spring 2010 and summer 2011. The region is characterized by enhanced primary productivity and forms a key transition zone between the Southern Ocean and South Atlantic Subtropical Gyre. The mean concentrations of dAl, dCo, and dMn (±standard deviation) were 3.36 ± 2.65 nmol kg−1, 35.3 ± 17.6 pmol kg−1, and 0.624 ± 1.08 nmol kg−1, respectively. Their distributions in surface waters were determined by external sources and complex internal biogeochemical processes. Specifically, surface ocean dCo was controlled by the interplay between phytoplankton uptake, remineralization and external inputs; dMn was likely determined by the formation and photoreduction of Mn-oxides; and dAl was supplied by atmospheric deposition and removed by scavenging onto particles. Fluvial and sedimentary inputs near the Rio de La Plata estuary and benthic sources from the Agulhas Bank resulted in elevated dTM concentrations in near-shore surface waters. These externally sourced dTMs were effectively delivered to the open ocean by offshore diffusion and/or advection, and potentially facilitated enhanced primary productivity along the transect. The distributions of dTMs at depth were predominantly controlled by the mixing of North Atlantic Deep Water (NADW) and waters of Antarctic origin (e.g., Upper Circumpolar Water (UCDW) and Antarctic Bottom Water (AABW)). The calculated endmember concentrations of dAl and dCo in NADW showed minor decreases in the SASTG following north–south transport, suggesting removal rates of 0.064 nM/year and 0.035–0.075 pM/year, respectively. The endmember concentration of dCo in AABW was maintained at ∼30 pmol kg−1 without evidence for scavenging removal in the Southern Ocean and SASTG (time frame 〉400 years). The concentrations of dMn in NADW and AABW were between 0.1 and 0.16 nmol kg−1, and any elevated dMn concentrations were ascribed to local external inputs (e.g., from sediments in the Argentine Basin and hydrothermal activity near the Mid-Atlantic Ridge). Hence, four controlling factors (sources, internal cycling, water mass mixing and time) need to be considered when assessing TM distributions in the global ocean, even for TMs that are vulnerable to scavenging removal processes. Because the deep waters formed in high latitude oceans are crucial components of the global thermohaline overturning system, any processes (e.g., glacier melting, upwelling and sinking, and biological activity) that impact the preformed dTM concentrations in high latitude oceans will determine the downstream dTM distributions. Therefore, the sources and sinks of TMs and associated biological activity in high latitude oceans could engender basin to global scale impacts on seawater distributions of Al, Co, and Mn and their stoichiometric relationships with macronutrients, and the global biogeochemical cycles of these scavenged-type TMs.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 24
    Publication Date: 2024-04-10
    Description: Phytoplankton play a central role in the planetary cycling of important elements and compounds. Understanding how phytoplankton are responding to climate change is consequently a major question in Earth Sciences. Monitoring phytoplankton is key to answering this question. Satellite remote sensing of ocean colour is our only means of monitoring phytoplankton in the entire surface ocean at high temporal and large spatial scales, and the continuous ocean-colour data record is now approaching a length suitable for addressing questions around climate change, at least in some regions. Yet, developing ocean-colour algorithms for climate change studies requires addressing issues of ambiguity in the ocean-colour signal. For example, for the same chlorophyll-a concentration (Chl-a) of phytoplankton, the colour of the ocean can be different depending on the type of phytoplankton present. One route to tackle the issue of ambiguity is by enriching the ocean-colour data with information on sea surface temperature (SST), a good proxy of changes in three phytoplankton size classes (PSCs) independent of changes in total Chl-a, a measure of phytoplankton biomass. Using a global surface insitu dataset of HPLC (high performance liquid chromatography) pigments, size-fractionated filtration data, and concurrent satellite SST spanning from 1991 to 2021, we re-tuned, validated and advanced an SST-dependent three-component model that quantifies the relationship between total Chl-a and Chl-a associated with the three PSCs (pico-, nano- and microplankton). Similar to previous studies, striking dependencies between model parameters and SST were captured, which were found to improve model performance significantly. These relationships were applied to 40 years of monthly composites of satellite SST, and significant trends in model parameters were observed globally, in response to climate warming. Changes in these parameters highlight issues in estimating long-term trends in phytoplankton biomass (Chl-a) from ocean colour using standard empirical algorithms, which implicitly assume a fixed relationship between total Chl-a and Chl-a of the three size classes. The proposed ecological model will be at the centre of a new ocean-colour modelling framework, designed for investigating the response of phytoplankton to climate change, described in subsequent parts of this series of papers.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 25
    Publication Date: 2024-04-10
    Description: EnMAP (Environmental Mapping and Analysis Program) is a high-resolution imaging spectroscopy remote sensing mission that was successfully launched on April 1st, 2022. Equipped with a prism-based dualspectrometer, EnMAP performs observations in the spectral range between 418.2 nm and 2445.5 nm with 224 bands and a high radiometric and spectral accuracy and stability. EnMAP products, with a ground instantaneous field-of-view of 30 m×30 m at a swath width of 30 km, allow for the qualitative and quantitative analysis of surface variables from frequently and consistently acquired observations on a global scale. This article presents the EnMAP mission and details the activities and results of the Launch and Early Orbit and Commissioning Phases until November 1st, 2022. The mission capabilities and expected performances for the operational Routine Phase are provided for existing and future EnMAP users.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 26
    Publication Date: 2024-04-09
    Description: The overriding physicochemical controls in seawater discussed here are the chemical composition and the state of master variables including temperature, pressure, salinity, pH and redox status. Dissolved Organic Matter also plays a major role, but since its properties are not sufficiently well quantified it is described as an emergent master variable at this stage. The theoretical basis for the treatment of equilibrium chemistry and kinetics is presented, together with projections of the future development of seawater chemistry resulting from climate change. Key points • Composition of seawater • Master variables (temperature, pressure, pH, oxygen/redox state) • The role of Dissolved Organic Matter • Equilibrium chemistry • Kinetics • The consequences of ongoing global changes
    Type: Book chapter , NonPeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 27
  • 28
    Publication Date: 2024-04-09
    Description: Highlights • Developed an innovative weighted outlier detection function that adaptively selects the best outlier detection technique, markedly improving precision and robustness in multibeam echosounder data analysis. • Demonstrated superior performance of the weighted function over traditional methods, achieving higher precision, recall, and F1 scores, pivotal for accurate seafloor mapping. • Enhanced data quality for geoscientific applications by effectively identifying and removing outliers without introducing data voids, preserving the integrity of multibeam sonar data. • The function’s significance extends to supporting sustainable environmental and resource management practices through improved accuracy in seabed mapping. • Discussed the adaptability of the method to various outlier patterns and its limitations, highlighting the need for further research and validation across different marine environments and data types. Abstract Multibeam sonar data are a valuable tool for seafloor mapping and geological studies. However, the presence of outliers in multibeam data can distort the results of analyses and reduce the accuracy of seafloor maps. In this paper, we define a weighting function based on the performance of various outlier detection techniques (OTDs) for detecting outliers in multibeam data, which calculates an outlier probability score for each sounding. Our results show that each OTD has its own strengths and weaknesses, and that a combination of outlier detection techniques is promising to improve reproducibility, explainability and the accuracy of the detection process. To address the challenge of detecting outliers in multibeam data, we propose a weighted outlier detection function that outperforms individual outlier detection techniques in terms of precision, recall and F1 scores by considering their strengths and combining them in a way that accounts for variations in the data. The function detects various types of outliers with high precision and recall values, resulting in valuable improvements in outlier detection performance for multibeam data. Overall, our proposed workflow has the potential to significantly improve the way multibeam data cleaning is performed, with the weighted outlier detection function being applied first, detecting most of the outlier automatically, followed by a domain-expert review of a small group of soundings whose automatic outlier labelling is not unequivocal.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 29
    Publication Date: 2024-04-09
    Description: We contribute transcriptomic data for two species of Ostracoda, an early-diverged group of small-sized pancrustaceans. Data include new reference transcriptomes for two asexual non-marine species (Dolerocypris sinensis and Heterocypris aff. salina), as well as single-specimen transcriptomic data that served to analyse gene expression across four developmental stages in D. sinensis. Data are evaluated by computing gene expression profiles of the different developmental stages which consistently placed eggs and small larvae (at the stage of instar A-8) similar to each other, and apart from adults which were distinct from all other developmental stages but closest to large larvae (instar A-4). We further evaluated the transcriptomic data with two newly sequenced low-coverage genomes of the target species. The new data thus document the feasibility of obtaining reliable transcriptomic data from single specimens – even eggs – of these small metazoans.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 30
    Publication Date: 2024-04-09
    Description: Epibenthic dinoflagellates occur globally and include many toxin-producing species of concern to human health and benthic ecosystem function. Such benthic harmful algal blooms (BHABs) have been well described from tropical and sub-tropical coastal environments, but assessments from north temperate waters, e.g., northern Europe, and polar regions are scarce. The present study addressed the biodiversity and distribution of potentially toxic epibenthic dinoflagellate populations along the west coast of Sweden (Kattegat-Skagerrak) by morphological and molecular criteria. Morphological analysis conducted by light- and electron-microscopy was then linked by DNA barcoding of the V4 region of 18S rRNA gene sequences to interpret taxonomic and phylogenetic relationships. The presence of two potentially toxigenic epibenthic dinoflagellates, Prorocentrum lima (Ehrenberg) F.Stein and Coolia monotis Meunier was confirmed, along with a description of their spatial and temporal distribution. For P. lima, one third of the cell abundance values exceeded official alarm thresholds for potentially toxic BHAB events (〉1000 cells gr–1 of macroalgae fresh weight). The same species were recorded consecutively for two summers, but without significant temporal variation in cell densities. SEM analyses confirmed the presence of other benthic Prorocentrum species: P. fukuyoi complex, P. cf. foraminosum and P. cf. hoffmannianum. Analyses of the V4 region of the 18S rRNA gene also indicated the presence P. compressum, P. hoffmannianum, P. foraminosum, P. fukuyoi, and P. nanum. These findings provide the first biogeographical evidence of toxigenic benthic dinoflagellates along the west coast of Sweden, in the absence of ongoing monitoring to include epibenthic dinoflagellates. Harmful events due to the presence of Coolia at shellfish aquaculture sites along the Kattegat-Skagerrak are likely to be rather marginal because C. monotis is not known to be toxigenic. In any case, as a preliminary assessment, the results highlight the risk of diarrhetic shellfish poisoning (DSP) events caused by P. lima, which may affect the development and sustainability of shellfish aquaculture in the region.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 31
    Publication Date: 2024-04-09
    Description: The marine dinoflagellate Alexandrium Halim represents perhaps the most significant and intensively studied genus with respect to species diversity, life history strategies, toxigenicity, biogeographical distribution, and global magnitude and consequences harmful algal blooms (HABs). The socioeconomic impacts, environmental and human health risks, and mitigation strategies for toxigenic Alexandrium blooms have also been explored in recent years. Human adaptive actions based on future scenarios of bloom dynamics and shifts in biogeographical distribution under climate-change parameters remain under development and not yet implemented on a regional scale. In the CoCliME (Co-development of climate services for adaptation to changing marine ecosystems) project these issues were addressed with respect to past, current and anticipated future status of key HAB genera and expected benefits of enhanced monitoring. Data on the distribution and frequency of Alexandrium blooms related to paralytic shellfish toxin (PST) events from key CoCliME Case Study areas, comprising the North Sea and adjacent Kattegat-Skagerrak, Norwegian Sea, and Baltic Sea, and eastern North Atlantic marginal seas, were evaluated in a contemporary and historical context over the past several decades. The first evidence of possible biogeographical expansion of Alexandrium taxa into eastern Arctic gateways was provided from DNA barcoding signatures. Various key climate change indicators, such as salinity, temperature, and water-column stratification, relevant to Alexandrium bloom initiation and development were identified. The possible influence of changing variables on bloom dynamics, magnitude, frequency and spatial and temporal distribution were interpreted in the context of regional ocean climate models. These climate change impact indicators may play key roles in selecting for the occurrence and diversity of Alexandrium species within the broader microeukaryote communities. For example, shifts to higher temperature and lower salinity regimes predicted for the southern North Sea indicate the potential for increased Alexandrium blooms, currently absent from this area. Ecological and socioeconomic impacts of Alexandrium blooms and effects on fisheries and aquaculture resources and coastal ecosystem function are evaluated, and, where feasible, effective adaptation strategies are proposed herein as emerging climate services.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 32
    Publication Date: 2024-04-09
    Description: A bloom of the fish-killing haptophyte Chrysochromulina leadbeateri in northern Norway during May and June 2019 was the most harmful algal event ever recorded in the region, causing massive mortalities of farmed salmon. Accordingly, oceanographic and biodiversity aspects of the bloom were studied in unprecedented detail, based on metabarcoding and physico-chemical and biotic factors related with the dynamics and distribution of the bloom. Light- and electron-microscopical observations of nanoplankton samples from diverse locations confirmed that C. leadbeateri was dominant in the bloom and the primary cause of associated fish mortalities. Cell counts by light microscopy and flow cytometry were obtained throughout the regional bloom within and adjacent to five fjord systems. Metabarcoding sequences of the V4 region of the 18S rRNA gene from field material collected during the bloom and a cultured isolate from offshore of Tromsøy island confirmed the species identification. Sequences from three genetic markers (18S, 28S rRNA gene and ITS region) verified the close if not identical genetic similarity to C. leadbeateri from a previous massive fish-killing bloom in 1991 in northern Norway. The distribution and cell abundance of C. leadbeateri and related Chrysochromulina species in the recent incident were tracked by integrating observations from metabarcoding sequences of the V4 region of the 18S rRNA gene. Metabarcoding revealed at least 14 distinct Chrysochromulina variants, including putative cryptic species. C. leadbeateri was by far the most abundant of these species, but with high intraspecific genetic variability. Highest cell abundance of up to 2.7 × 107 cells L − 1 of C. leadbeateri was found in Balsfjorden; the high cell densities were associated with stratification near the pycnocline (at ca. 12 m depth) within the fjord. The cell abundance of C. leadbeateri showed positive correlations with temperature, negative correlation with salinity, and a slightly positive correlation with ambient phosphate and nitrate concentrations. The spatio-temporal succession of the C. leadbeateri bloom suggests independent initiation from existing pre-bloom populations in local zones, perhaps sustained and supplemented over time by northeastward advection of the bloom from the fjords.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 33
    Publication Date: 2024-04-09
    Description: The diatom Pseudo-nitzschia H. Peragallo is perhaps the most intensively researched genus of marine pennate diatoms, with respect to species diversity, life history strategies, toxigenicity, and biogeographical distribution. The global magnitude and consequences of harmful algal blooms (HABs) of Pseudo-nitzschia are particularly significant because of the high socioeconomic impacts and environmental and human health risks associated with the production of the neurotoxin domoic acid (DA) among populations of many (although not all) species. This has led to enhanced monitoring and mitigation strategies for toxigenic Pseudo-nitzschia blooms and their toxins in recent years. Nevertheless, human adaptive actions based on future scenarios of bloom dynamics and proposed shifts in biogeographical distribution under climate-change regimes have not been implemented on a regional scale. In the CoCliME (Co-development of climate services for adaptation to changing marine ecosystems) program these issues were addressed with respect to past, current and anticipated future status of key HAB genera such as Pseudo-nitzschia and expected benefits of enhanced monitoring. Data on the distribution and frequency of Pseudo-nitzschia blooms in relation to DA occurrence and associated amnesic shellfish toxin (AST) events were evaluated in a contemporary and historical context over the past several decades from key northern CoCliME Case Study areas. The regional studies comprised the greater North Sea and adjacent Kattegat-Skagerrak and Norwegian Sea, eastern North Atlantic marginal seas and Arctic gateways, and the Baltic Sea. The first evidence of possible biogeographical expansion of Pseudo-nitzschia taxa into frontier eastern Arctic gateways was provided from DNA barcoding signatures. Key climate change indicators, such as salinity, temperature, and water-column stratification were identified as drivers of upwelling and advection related to the distribution of regional Pseudo-nitzschia blooms. The possible influence of changing variables on bloom dynamics, magnitude, frequency and spatial and temporal distribution were interpreted in the context of regional ocean climate models. These climate change indicators may play key roles in selecting for the occurrence and diversity of Pseudo-nitzschia species within the broader microeukaryote communities. Shifts to higher temperature and lower salinity regimes predicted for the southern North Sea indicate the potential for high-magnitude Pseudo-nitzschia blooms, currently absent from this area. Ecological and socioeconomic impacts of Pseudo-nitzschia blooms are evaluated with reference to effects on fisheries and mariculture resources and coastal ecosystem function. Where feasible, effective adaptation strategies are proposed herein as emerging climate services for the northern CoCLiME region.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 34
    facet.materialart.
    Unknown
    Elsevier
    In:  Comment to “Shallow portion of an active geothermal system revealed by multidisciplinary studies: The case of Le Biancane (Larderello, Italy)” by Granieri D., Mazzarini F., Cerminara M., Calusi B., Scozzari A., Menichini M., and Lelli M. (2023) Luca Bolognesi Geothermics 113 (2023) 102753 https://doi.org/10.1016/j.geothermics.2023.102753
    Publication Date: 2024-04-09
    Description: Reply to the comment by Luca Bolognesi
    Description: Reply to the comment by Luca Bolognesi
    Description: Published
    Description: 102754
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 35
    Publication Date: 2024-04-09
    Description: The natural park of Le Biancane is located in the southern sector of the Larderello-Travale geothermal field (LTGF). It extends over an approximately 100,000 m2 area where the impermeable caprock is locally absent and deep fluids may directly reach the surface. Through a multidisciplinary approach including measurements of soil CO2 flux (total output of 11.5 t day􀀀 1), soil temperature (average 34.4 ◦C), stable isotope and chemical data on fluids from fumaroles (dominated by a mixture of geothermal gases and air or gases from air-saturated meteoric water), and structural analysis of the formation outcropping, we found that anomalous CO2 emissions are positively correlated with shallow temperature anomalies. These are in restricted locations adjacent to vents and fumaroles, where a network of well-connected fractures (preferentially NW-SE and NE-SW orientated and with steep dips) drains efficiently allowing upward migration of the deep fluids and the energy toward the surface.
    Description: INGV Project RL 2021 - AGEREMUS
    Description: Published
    Description: 102616
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: Larderello geothermal field ; Fracture network connectivity ; Diffuse CO2 soil degassing ; Thermal infrared images ; Hydrothermal gas ; 04. Solid Earth
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 36
    Publication Date: 2024-04-08
    Description: For the past 50 years it has been assumed that the principal pathway for the deep limb of the Atlantic Meridional Overturning Circulation (AMOC) is the Deep Western Boundary Current (DWBC). However, recent observations of Lagrangian floats have shown that the DWBC is not necessarily a unique, dominant, or continuous pathway for these deep waters. A significant portion of the deep water export from the subpolar to the subtropical gyres follows a pathway through the interior of the Newfoundland and subtropical basins, which is constrained by the western boundary and the western flank of the Mid-Atlantic Ridge. The hypothesis that deep eddy-driven recirculation gyres are a mechanism for partitioning the deep limb of the AMOC into the DWBC and this interior pathway is investigated here. Eulerian and Lagrangian analyses of the output of ocean general circulation models at eddy-resolving, eddy-permitting, and non-eddy permitting resolutions are used to test this hypothesis. Eddy-driven recirculation gyres, simulated in the eddy-resolving and eddy-permitting models and similar to recirculations inferred from hydrographic data, are shown to shape the export pathways of deep water from the subpolar to the subtropical gyres.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 37
    Publication Date: 2024-04-08
    Description: The formation and growth mechanisms of Mid-Ocean Ridges (MOR) are relatively well known, whereas those of back-arc spreading ridges are comparatively less known because geophysical, geochemical, and morphological data are scarce and of low density. Here we present a high-resolution bathymetry of the Marsili Seamount (MS; 1Ma 3 ka), which represents the inflated spreading ridge of the 2Ma old Marsili back-arc basin associated to the subduction of the Ionian Sea below the Calabrian Arc and Tyrrhenian Sea. MS is 70 km long, 30 km wide, and its height reaches about 3000 m from surrounding seafloor. Our new digital bathymetric model has a 5 m grid cell size resolution and covers the MS bathymetry from 1670 mbsl to the top at 491 mbsl. We conduct morphometric and morphological analyses of the bathymetry and recognize landforms due to volcanic, tectonic, hydrothermal and gravity processes. MS consists of volcanoes related to fissural and central-type activity, this latter located at the northern and southern tips of the main dike swarms. Dike swarms represent the surface expression of different ridge segments whose strikes are controlled by the larger scale back-arc spreading processes and by the local occurrence of an active hydrothermal field. This latter develops in a flat area between two partly overlapping ridge segments where historical volcanism and extensional processes concentrate. Such ridges represent the embryonic stage of the formation of transform-like faults. Central volcanoes, the northern of which is characterized by a caldera, form at the tips of MS because the decrease in width of the major volcanic fissures promotes vent localization associated with the formation of sill-like reservoirs from which central-type vents may develop. Gravity processes affecting the MS flanks are due to shallow seafloor sliding. Caldera collapses affecting the northernmost central-type polygenic volcano must be included in the evaluation of the hazard related to potential tsunami. Inward dipping faults characterize the MS eastern flank suggesting a moderately asymmetric growth of the spreading ridge possibly associated with the eastward opening of the Marsili back-arc. The Marsili back-arc spreading rate is similar to those of MOR slow spreading ridges. However, the MS morphology resembles that of fast spreading ridges. These two features also characterize more extended back-arc spreading ridges (e.g. the Mariana in Western Pacific). We conclude that, independently from the spatial scale, the increase in the ridge accretion rate is related to the progressive addition of a subduction-related component to a pure spreading mantle source.
    Description: Published
    Description: 101723
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 38
    Publication Date: 2024-04-08
    Description: This work aims at identifying and modelling statistical dependencies between empirical amplification functions of sites in central Italy and the main geological and geophysical characteristics of the region, within a geostatistical analysis framework. The empirical functions, named δS2S, are estimated by decomposing the re siduals of the median predictions of a non-ergodic ground motion model of elastic acceleration response spectra developed for the reference region. To select the model that best describes the spatial variability of the data, the performance of stationary and non-stationary spatial models is compared, the latter being able to constrain the prediction of the empirical functions to physical quantities available in the region and descriptive of the geology, topography and geographical location of the site. Finally, we obtain optimal models of δS2S, for each spectral ordinate, parameterised as a function of geographical coordinates and an input map of shear wave velocity in the upper 30 m (Vs30) constructed ad hoc by combining information gathered from two high-resolution maps available for the region. The methodology allows the development of a new practice-oriented framework for the empirical estimation of site amplification, which can be adopted for the gen eration of shaking scenarios in the context of regional hazard and seismic risk assessment.
    Description: Published
    Description: 108496
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 39
    Publication Date: 2024-04-08
    Description: The Castelnuovo village is placed on a small NW-SE trending ridge, approximately 60 m higher than the valley floor, occupying a portion of the larger continental L'Aquila Basin (Central Italy). During the April 6, 2009 L'Aquila earthquake (Mw 6.3), the village suffered heavy damage. Several studies investigated the local seismic amplification of the Castelnuovo area employing geotechnical, geophysical, and geological surveys, together with 1D, 2D and 3D numerical models. However, all these studies relied on shallow geotechnical and geophysical surveys, which do not reach the engineering bedrock and do not constrain the presence of an impedance contrast at depth. To date, no detailed study has been carried out to assess the depth of the engineering bedrock. In this work, we fill this gap by executing two deep boreholes reaching the engineering bedrock, tied with an extensive campaign of microtremor measurements all over the Castelnuovo ridge and the surrounding plain. The interpretation of such new data, together with analytical, numerical, and geostatistical techniques, demonstrates that local seismic amplification is linked to a strong impedance contrast at more than 200-m depth beneath the Castelnuovo village associated with the lithological transition between clayey silts and breccias. Such results differ from those provided by previous studies, where such impedance contrast was considered shallower, and represent a milestone for assessing the local seismic hazard of the area.
    Description: Published
    Description: 106506
    Description: OST4 Descrizione in tempo reale del terremoto, del maremoto, loro predicibilità e impatto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 40
    Publication Date: 2024-04-08
    Description: Although Deep-Seated Gravitational Slope Deformations are well-known in the literature, their evolution and kinematics are still poorly understood. Their behavior is often complex and characterized by small movements associated with steady-state creep, alternating with periods of stasis, or accelerating downslope movements that, in some cases, could result in sudden and catastrophic failure events. Therefore, a multidisciplinary approach is often required. In this work, we shed light on the complex geometry and kinematics of the Pisciotta DSGSD, a deep-seated roto-translational sliding involving structurally complex turbiditic rock mass and interacting with man-made infrastructures. To reveal the geometrical features and the spatial and temporal behavior of the analyzed phenomenon, a multidisciplinary investigation was performed. Typical DSGSD landforms were mapped employing in-situ surveys, aided by stereoscopic analysis of historical aerial images and high-resolution drone-based mapping. Structural data and ancillary ground-based surveys revealed the presence of a highly weathered and folded turbiditic sequence, with competent sandstone and calcarenite units alternated by tectonically disrupted, weak argillite and mudrock layers. Remote sensing measurements from optical imagery and Synthetic Aperture Radar satellite data assessed the DSGSD's past and current kinematics, allowing to distinguish a pre-failure period with accelerating displacement rates, a failure period with maximum displacement rates, and a current post-failure period with decelerating displacement rates. Analytical modeling established the deep reach (up to 85 m) of the studied DSGSD as it allowed the estimation of its bottom surface and volume, as verified by available boreholes and inclinometric measurements. Furthermore, numerical modeling outcomes highlighted how the progressive weakening and alteration of the DSGSD material, in conjunction with changes in groundwater dynamics, serve as the primary mechanisms driving the observed kinematics. The models also revealed the intricate interaction between the DSGSD and the neighboring infrastructures.
    Description: Published
    Description: 113751
    Description: OST5 Verso un nuovo Monitoraggio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 41
    Publication Date: 2024-04-08
    Description: Continental rifts result from the simultaneous action of shallow processes such as the thinning of the lithosphere, and deeper processes related to the dynamics of the mantle. The role of these deeper processes may change over time as a function of the type of rifting, e.g., subduction-related rift vs plume-related rifts, and the pre-rift geodynamics. During the Cretaceous, the Songliao Basin (NE China) was affected by continental rifting accompanied by discontinuous stages of volcanism. The relative role of the asthenospheric and lithospheric mantle associated with the Songliao Basin rift volcanism, its evolution with time, and the origin of the felsic rocks are still debated problems due to the lack of comprehensive studies. Here, we present a critical review of the available geochronological and geochemical data (major, trace elements, and Sr-Nd isotopes) and show that the Songliao rift Cretaceous volcanism developed between 133 Ma and 102 Ma in five main stages: Stage I (133–129 Ma), Stage II (124–118 Ma), Stage III (117–113 Ma), Stage IV (115–106 Ma), and Stage V (105–102 Ma). While magmas with an alkaline, intraplate affinity characterize all the Stages, magmas with a subalkaline (calc-alkaline) signature erupted in Stages II and III. Mafic and intermediate rocks are always present, whereas felsic magmas have been found in the last three Stages. Based on the major, trace elements and Nd-Sr isotopic compositions, the general evolution of volcanism is dominated by crystal fractionation processes. Evidence of assimilation of upper crust material is restricted to the more evolved rocks (SiO2 〉 57 wt%). The alkaline mafic rocks derived from a veined asthenospheric mantle modified by melts deriving from the sediments of the Paleo- Pacific slab or associated with pre-rifting, Jurassic, collisional subduction processes related to the closing of the Mongol–Okhotsk Ocean. The source of the Songliao rift subalkaline rocks is the sub-continental lithospheric mantle metasomatized by fluids released from the dehydration of the subducting Paleo-Pacific slab. The release of fluids from the sediments subducted during the Jurassic Mongol–Okhotsk collision may also have played a role. The Songliao Basin Cretaceous rift may be classified as a subduction-related rift caused by the eastward rollback of the west-dipping Paleo-Pacific slab, a process initiated after the Jurassic collisional phase in NE China. Within the wider geodynamic frame of the eastern Asian block, the 133–102 Ma volcanism of the Songliao rift suggests a transition from a lithospheric mantle responsible for the pre-140 Ma NE China, Mongolia, and Russia volcanism to an asthenospheric mantle source of the post-107 Ma magmatism. This is also suggested by the fact that the Songliao rift magmatism shows compositional features consistent with the contribution of both the lithospheric and asthenospheric mantle. The Songliao rift volcanism would be therefore associated with a passive rifting process, where the progressive removal of the lithosphere below East Asia, which is due to eastward rollback of the Pacific oceanic plate, caused an upwelling of asthenospheric material, finally involved in the post- 102 Ma magmatism in the NE China block.
    Description: Published
    Description: 104294
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 42
    Publication Date: 2024-04-08
    Description: Dissolved organic matter (DOM) plays a crucial role in the biogeochemistry of coastal ecosystems, particularly nutrient cycling and distribution. Little is known about these processes in the highly productive Southern Patagonian shelf. This study was conducted to better understand the sources, composition, and behavior of DOM and inorganic nutrients in the sector between 51 and 56°S and 64–69°W with particular emphasis on inorganic nitrogen and DOM fractions. Surface water samples taken during late austral summer from the Beagle Channel (BCW), Subantarctic (SAW), Subantarctic Shelf (SASW), Grande Bay (GBW) and Tierra del Fuego Waters (TFW) and were analyzed for properties of fluorescent DOM (FDOM), dissolved organic carbon (DOC) and inorganic nutrients. Data were related to hydrographic and plankton conditions. Highest values of ammonium, DOC, humic-like FDOM (FDOMC and FDOMM peaks) and humification index (HIX) were found in BCW, and the lowest in SAW, suggesting that terrigenous input is a main source of ammonium and refractory carbon in this region, which is supported by a highly significant inverse correlation of these parameters with salinity. In contrast, nitrate, phosphate, silicate and the fluorescence index (FI) were positively correlated with salinity, pointing to the contribution of autochthonous FDOM from the saltier and nutrient-rich Antarctic Circumpolar Current to the Southern Patagonian shelf. In TFW and GBW, high nitrite concentrations, accompanied by elevated values of BIX (biological activity index of DOM), circulation patterns and high particle residence times computed from model results suggest the occurrence of regeneration processes that deserve further investigation of the poorly known dynamics of the nitrogen-rich water in this region.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 43
    Publication Date: 2024-04-08
    Description: Siderophores, high affinity iron chelators, play a key role in the uptake of iron by microorganisms and regulate many biological functions. Siderophores are categorized by their chelating group, e.g., catecholates, hydroxamates, α-hydroxycarboxylates. Natural concentrations of siderophores are often either too low or sample matrices are too complex for direct analysis by, e.g., liquid chromatography – mass spectrometry. Therefore, both concentration and purification are prerequisite for reliable analyses. However, a chromatographic technique that is selective for all siderophore classes and affords high levels of purification is lacking. We developed a titanium dioxide affinity chromatography (TDAC) solid-phase extraction (SPE) that affords the selective purification of these siderophore classes from complex sample matrices with recoveries up to 82%. The one-step purification removed most non-ligand sample ‘contaminants’, therefore, affording the straightforward identification of siderophore peaks in base peak chromatograms. As a proof of concept, the bioinformatic processing, dereplication of known features and selection of significant features in the TDAC eluates afforded a fast identification of six novel siderophores (woodybactines) from bacterial supernatants. We propose TDAC SPE as a fast and cost-effective methodology to screen for known or discover novel siderophores in natural samples in combination with untargeted bioinformatic processing by, e.g., XCMS. The method is scalable and yielded large amounts of highly purified siderophores from bacterial culture supernatants, providing an effective quantitative sample clean-up for, e.g., NMR structure elucidation.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 44
    Publication Date: 2024-04-06
    Description: Highlights • Accurate age model during Pliocene for site U1490 established • Co-variant nutricline depth and productivity in WPWP throughout Pliocene • Deeper nutricline and lower productivity during 4.8–3.5 Ma linked to CAS closure • Nutricline shoaling during 3.5–3.0 Ma due to restriction of Indonesian Seaway Abstract The tropical Pacific played an important role in modulating global climate change during the Pliocene. Studies of tropical Pacific sea surface temperatures covering the period from the Pliocene onwards indicate that changes in the thermal mean state over the tropical Pacific can significantly influence global climate feedbacks and connect the high- and low-latitude climates. Tropical productivity fluctuations are a significant mechanism with respect to the operation of the global carbon cycle. Yet, temporal changes in primary productivity are not well constrained in the western Pacific warm pool (WPWP), where the ocean–climate system is not dominated by upwelling systems. Furthermore, the role of nutricline dynamics in forcing productivity over tectonic timescales remains uncertain. Here we use relatively high-resolution foraminiferal carbon isotope records combined with Ba/Ti ratios obtained from International Ocean Discovery Program (IODP) Site U1490 in the WPWP to reconstruct nutricline depth and paleoproductivity over the period 5.1–2.6 Ma. Our records imply that nutricline and productivity variations were closely coupled over tectonic timescales, implying that the dynamics of the nutricline play a significant role in regulating productivity in the WPWP. The deeper nutricline and lower productivity during 4.8–3.5 Ma might have been fostered by the closure of the Central American Seaway through the thickening of the mixed layer in the WPWP. We relate the overall shallower nutricline and increased productivity during 3.5–3.0 Ma to the restriction of the Indonesian Seaway via the enhanced influence and upwelling of high-latitude southern-source waters.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 45
    Publication Date: 2024-04-05
    Description: Understanding the interactions between surface and deep Earth processes is important for research in many diverse scientific areas including climate, environment, energy, georesources and biosphere. The TOPO-EUROPE initiative of the International Lithosphere Program serves as a pan-European platform for integrated surface and deep Earth sciences, synergizing observational studies of the Earth structure and fluxes on all spatial and temporal scales with modelling of Earth processes. This review provides a survey of scientific developments in our quantitative understanding of coupled surface-deep Earth processes achieved through TOPO-EUROPE. The most notable innovations include (1) a process-based understanding of the connection of upper mantle dynamics and absolute plate motion frames; (2) integrated models for sediment source-to-sink dynamics, demonstrating the importance of mass transfer from mountains to basins and from basin to basin; (3) demonstration of the key role of polyphase evolution of sedimentary basins, the impact of pre-rift and pre-orogenic structures, and the evolution of subsequent lithosphere and landscape dynamics; (4) improved conceptual understanding of the temporal evolution from back-arc extension to tectonic inversion and onset of subduction; (5) models to explain the integrated strength of Europe's lithosphere; (6) concepts governing the interplay between thermal upper mantle processes and stress-induced intraplate deformation; (7) constraints on the record of vertical motions from high-resolution data sets obtained from geo-thermochronology for Europe's topographic evolution; (8) recognition and quantifications of the forcing by erosional and/or glacial-interglacial surface mass transfer on the regional magmatism, with major implications for our understanding of the carbon cycle on geological timescales and the emerging field of biogeodynamics; and (9) the transfer of insights obtained on the coupling of deep Earth and surface processes to the domain of geothermal energy exploration. Concerning the future research agenda of TOPO-EUROPE, we also discuss the rich potential for further advances, multidisciplinary research and community building across many scientific frontiers, including research on the biosphere, climate and energy. These will focus on obtaining a better insight into the initiation and evolution of subduction systems, the role of mantle plumes in continental rifting and (super)continent break-up, and the deformation and tectonic reactivation of cratons; the interaction between geodynamic, surface and climate processes, such as interactions between glaciation, sea level change and deep Earth processes; the sensitivity, tipping points, and spatio-temporal evolution of the interactions between climate and tectonics as well as the role of rock melting and outgassing in affecting such interactions; the emerging field of biogeodynamics, that is the impact of coupled deep Earth – surface processes on the evolution of life on Earth; and tightening the connection between societal challenges regarding renewable georesources, climate change, natural geohazards, and novel process-understanding of the Earth system.
    Description: Published
    Description: 104140
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 46
    Publication Date: 2024-04-05
    Description: The Krafla geothermal system is located within a volcanic center that periodically erupts basaltic lavas, and has recently attracted an economic interest due to supercritical fluids forming near a shallow magma intrusion (~ 2 km depth). Here, we discuss new soil CO2 flux and stable isotope data of the CO2 efflux (δ13C) and hydrothermal calcites (δ13C, δ18O) of drill cuttings to estimate both the current magmatic outgassing from soils and the thermal flows in the geothermal system. Soil CO2 emission is controlled by tectonics, following the NNE-SSW fissure swarm direction and a WSW-ENE trend, and accounts for ~62.5 t/d. While the δ18O of the H2O in equilibrium with deep calcites is predominantly meteoric, both the δ13C of the soil CO2 efflux and of the fluids from which calcite precipitated have a clear magmatic origin, overlapping the δ13C estimated for the Icelandic mantle (–2.5 ± 1.1 ‰). Estimates based on the soil CO2 emission from the southern part of the system show that these fluxes might be sustained by the ascent and depressurization of supercritical fluids with a thermal energy of ~800 MW. Such significant amount of energy might reach 1.5 GW if supercritical conditions extended below the whole investigated area. Finally, we report an increase in the soil CO2 emission of about 3 times with respect to 14 years ago, likely due to recent changes in the fluid extracted for power production or magmatic activity. Pairing the soil CO2 emission with stable isotopes of the efflux and calcite samples has important implications for both volcano monitoring and geothermal exploration, as it can help us to track magmatic fluid upflows and the associated thermal energy.
    Description: Published
    Description: 108032
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 47
    Publication Date: 2024-04-05
    Description: Risk mitigation in long-dormant volcanic provinces is a challenge due to the absence of collective memory of past disasters as well as the scarcity, and subtlety, of unrest signals that can be monitored. In this study, the impact of a potential limnic eruption is assessed at the 92-m-deep lake Pavin (French Massif Central). The lake is hosted in a maar crater formed during the last eruptive event in metropolitan France (∼7 ka) and contains dissolved CO2 in the deepest water layer, below 60 m. Carbon dioxide (CO2) emissions measured at the lake surface (0.44 km2) reach up to 10.1 tons/day during the winter. Beyond this (limited) continuous degassing of the lake, the current CO2 budget in the monimolimnion layer (at a depth of 60 m to 92 m) was estimated at 1750 tons, of which about 450 tons are available for release in case of overturn of the lake. Scenarios for CO2 dispersion in the lower atmosphere were simulated with the DISGAS and TWODEE-2 models by varying (i) meteorological conditions, (ii) the amount of CO2 released, (iii) and the mechanisms of degassing during a potential limnic eruption. The simulations allowed identification and delimitation of areas potentially impacted by hazardous CO2 levels in the air down-valley from the lake and directly around the lake. The spatio-temporal evolution of the potential CO2 cloud raises issues regarding the impacts of such a hypothetical event in the close vicinity of the lake and, given the area is populated and highly visited, needs to be considered in future risk mitigation strategies.
    Description: Published
    Description: 108024
    Description: OSV1: Verso la previsione dei fenomeni vulcanici pericolosi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 48
    Publication Date: 2024-04-05
    Description: We use geophysical data together with a recent subglacial bedrock map (BEDMACHINE model) to obtain and investigate a new three-layer sediment model for Antarctica that locally improves the global sediment model. We provide a combined, continuous, sediment model for Antarctica and surrounding oceans by joining such improved continental sedimentary model with an existing global one (GlobSed). Our results reveal large differences between sedimentary basins for Antarctica due to their age and origin. The maximum thickness of sediments is reached under Filchner-Ronne Ice Shelf and off the Weddell Sea coast (10–12 km); further offshore, towards the ocean, the thickness of sediments drops to 4–5 km. We divide the sediment cover into three layers to distinguish material with different velocities. The lower sediment layer (deeper than 7 km) with high P-wave velocities (4.0–4.9 km/s) is found only for Lambert Rift and Filchner-Ronne basin. The middle layer (2–7 km) has large variations for different sedimentary basins: 3.5–3.7 km/s for Lambert Basin; 4.0–4.3 km/s for Ross, Byrd and Bentley basins; 3.3–4.0 km/s for Filchner-Ronne Basin. The upper sediment layer (0–2 km) has large velocity variations, from 2.0 km/s for Ross and Lambert basins (young sediments) to 4.7 km/s for Dronning Maud Land basins. We suggest that P-wave velocities larger than 4 km/s represent old, compacted sediments which belong to the Beacon Supergroup; about 3 km/s refer to Mesozoic (rifted?) sediments; and less than 3 km/s relate to young Cenozoic sediments. According to this criterion, Dronning Maud Land, Bentley and Byrd basins belong to the Beacon Supergroup, while more complex and thicker Ross, Lambert and Filchner-Ronne basins contain sediments from Beacon Supergroup in the middle or lower layer, respectively. Other sedimentary basins with more moderate velocities possibly belong to the East Antarctic Rift System which formed later during Gondwana breakup.
    Description: Published
    Description: 229662
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Keywords: 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 49
    Publication Date: 2024-04-03
    Description: Highlights • Present day infiltration conditions in an monsoonal environment are studied. • Noble gas concentrations in groundwater are fixed near the soil surface. • Noble gas temperatures represent seasonal infiltration conditions in the monsoon. • Holocene and modern infiltration conditions are quite similar in southern Oman. Abstract Comparing directly measured soil temperatures with noble gas recharge temperatures (NGTs) inferred from noble gas concentrations indicates that the infiltrating soil water equilibrates with soil air near the soil surface during the rainy season. Therefore, NGTs of groundwater recently recharged by the Indian Summer Monsoon (ISM) in the Dhofar Mountains in southern Oman reflect the soil temperatures of the 3-month period and do not represent an annual mean. This finding highlights the need to account for seasonality when interpreting NGT data in regions with pronounced dry and wet seasons. We extend the observations from the southern flank of the Dhofar Mountains to three wells situated on the northern flank of the Dhofar Mountains. Two of these wells yield water of Holocene age that was recharged by the monsoon, their NGT signals are therefore classified as seasonal. The NGT calculated from a third well for recharge conditions during the Last Glacial Maximum (LGM), when the ISM was absent, is approximately 3 °C lower than that of the two Holocene wells. The lower LGM noble gas temperature corresponds well with the lower annual Sea Surface Temperature (SST) in the nearby Arabian Sea. NGTs from published studies from northern Oman are 1–3 °C higher when compared with our data of the same period in the southern Oman. We explain this regional difference of reconstructed temperatures for the LGM and Holocene groundwater with a more continental climatic influence on the infiltration conditions further to the north. The published NGTs from northern Oman show a large temperature difference between the late Holocene and the LGM. In view of our finding of seasonal NGT signals under monsoonal climate, part of this difference may reflect a change in the precipitation regime rather than in air temperature.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 50
    Publication Date: 2024-04-03
    Description: Highlights • This study simulates the sedimentation-driven development of multiple stacked BSRs in the Danube paleo-delta, Black Sea. • Formation of multiple BSRs in the Black Sea is controlled by the sequence of sedimentation events of the levees induced by sea-level changes. • Kinetics of phase transitions plays a key role in the coexistence, location, and timing of the multiple BSRs. • Development of multiple stacked BSRs is possible only under a narrow range of parameters, unique for the Danube delta setting. Abstract The gas hydrate stability zone (GHSZ) is defined by pressure-temperature-salinity (pTS) constraints of natural gas hydrate (GH) system. It refers to a depth interval which usually extends several hundred meters into the sediment column at sufficient water depths. The lower boundary of the GHSZ often coincides in seismic reflection data with a bottom simulating reflector (BSR), which indicates the transition between the underlying free gas and the overlying no-free gas zone at the thermodynamic stability boundary. The GHSZ in geological systems is dynamic and can shift in response to sedimentation processes and/or changes in environmental conditions such as bottom water temperatures, hydrostatic pressure, and water salinity. The appearance of multiple BSRs has been interpreted as remnants of former GHSZ shifts which have persisted over geological timescales. In this study, we numerically simulate the sedimentation-driven development of multiple stacked BSRs in the Danube deep-sea fan in the Black Sea. We show that in this dynamic sediment depositional regime sufficient amounts of residual gas remain trapped in the former GHSZ, given sufficiently high initial gas hydrate saturations, so that paleo-BSRs could persist over long time scales (similar to 300 kyr). In particular, the formation and persistence of multiple BSRs in the Danube Delta is controlled by the sequence of sedimentation events of the levees induced by sea-level change. The kinetics of methane phase transitions between gas hydrate, dissolved methane, and free gas plays a key role in the coexistence, location and timing of the multiple BSRs. Thus, For a given permeability, distinct multiple BSRs appear only for a narrow range of GH formation (10(-14) 〈 k(f) [mol/m(2) Pa s] 〈= 10(-12)) and dissociation rates (10(-16) 〈 k(d) [mol/m(2) Pa s] 〈 10(-14)).
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 51
    Publication Date: 2024-04-03
    Description: Multiple stressors often act concomitantly on ecosystems but detection of species responses follows the “single species-single driver” strategy, and cumulative impacts are seldom considered. During 1990–2010, multiple perturbations in the Caspian Sea, led to the decline of kilka, sturgeon and Caspian seal populations. Specific causes for their collapse were identified but a cumulative assessment has never been carried out. Using loop analysis, a qualitative modelling technique suitable in poor-data contexts, we show how multiple drivers can be combined to assess their cumulative impact. We confirm that the decline of kilka, sturgeon and Caspian seal populations is compatible with a net effect of the concomitant perturbations. Kilkas collapse was certainly due to the outburst of M. leidyi and overfishing. In addition, the excess nutrient might have conspired to reduce these populations. The interplay between concurrent drivers produces trade-offs between opposite effects and ecosystem management must face this challenge
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 52
    Publication Date: 2024-04-03
    Description: Highlights • Four rhyolitic explosive eruption events were distinguished from 13.1 Ma to 11.6 Ma. • Silicic volcanism occurred at termination of subduction in a thinning lithosphere. • Rhyolites show extreme magma differentiation and reduced-dry character. • Zircon trace element and Hf isotope fingerprint is an effective correlation tool. Abstract The Tokaj Mts. volcanism occurred in a thinning continental lithosphere regime at the final stage of the subduction process. Using high-precision zircon U-Pb dating, four major explosive eruption events were distinguished. Among them the 13.1 Ma Sátoraljaújhely and the 12.0 Ma Szerencs eruptions could have yielded large amount of volcanic material (possibly 〉 100 km3) and they were associated with caldera collapse as shown by the several hundred-metre-thick pyroclastic deposits and the long (〉100 km) runout pyroclastic flow in case of the 13.1 Ma eruption. The 12.3 Ma Hegyköz and the 11.6 Ma Vizsoly eruptions were relatively smaller. The volcanic products can be readily distinguished by zircon and glass trace elements and trace element ratios, which can be used for fingerprinting and to correlate with distal deposits. The Rb, Ba, Sr content and strong negative Eu-anomaly of the glasses reflect extreme crystal fractionation, particularly for the Szerencs rhyolitic magma. The silicic volcanic products of the Tokaj Mts. show compositional similarities with the so-called ‘dry–reduced–hot’ rhyolite type consistent with an origin in an extensional environment, where the primary magmas were formed by near-adiabatic decompression melting in the mantle with subordinate fluid flux. In contrast, some of the older Bükkalja rhyolitic magmas evolved via more hydrous evolutionary paths, where amphibole played a role in the control of the trace element budget. The significant increase of zircon ε Hf values from −8.8 to + 0.2 in the rhyolitic pyroclastic rocks of Tokaj Mts. with time implies that mantle-derived magmas became more dominant. This can be explained by the specific tectonic setting, i.e. the final stage of subduction when the descending subducted slab became almost vertical, which exerted a pull in the upper lithosphere leading to thinning and accelerated subsidence as well as asthenospheric mantle flow just before the slab detachment.
    Type: Article , PeerReviewed
    Format: text
    Format: archive
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 53
    Publication Date: 2024-04-03
    Description: The redox speciation of iron was determined during the iron fertilization LOHAFEX and for the first time, the chemiluminescence assay of filtered and unfiltered samples was systematically compared. We hypothesize that higher chemiluminescence in unfiltered samples was caused by Fe(II) adsorbed onto biological particles. Dissolved and particulate Fe(II) increased in the mixed layer steadily 6-fold during the first two weeks and decreased back to initial levels by the end of LOHAFEX. Both Fe(II) forms did not show diel cycles downplaying the role of photoreduction. The chemiluminescence of unfiltered samples across the patch boundaries showed strong gradients, correlated significantly to biomass and the photosynthetic efficiency and were higher at night, indicative of a biological control. At 150 m deep, a secondary maximum of dissolved Fe(II) was associated with maxima of nitrite and ammonium despite high oxygen concentrations. We hypothesize that during LOHAFEX, iron redox speciation was mostly regulated by trophic interactions.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 54
    Publication Date: 2024-04-03
    Description: Marine planktonic eukaryotes play critical roles in global biogeochemical cycles and climate. However, their poor representation in culture collections limits our understanding of the evolutionary history and genomic underpinnings of planktonic ecosystems. Here, we used 280 billion Tara Oceans metagenomic reads from polar, temperate, and tropical sunlit oceans to reconstruct and manually curate more than 700 abundant and widespread eukaryotic environmental genomes ranging from 10 Mbp to 1.3 Gbp. This genomic resource covers a wide range of poorly characterized eukaryotic lineages that complement long-standing contributions from culture collections while better representing plankton in the upper layer of the oceans. We performed the first, to our knowledge, comprehensive genome-wide functional classification of abundant unicellular eukaryotic plankton, revealing four major groups connecting distantly related lineages. Neither trophic modes of plankton nor its vertical evolutionary history could completely explain the functional repertoire convergence of major eukaryotic lineages that coexisted within oceanic currents for millions of years.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 55
    Publication Date: 2024-04-03
    Description: Plasmids are extrachromosomal genetic elements that often encode fitness-enhancing features. However, many bacteria carry “cryptic” plasmids that do not confer clear beneficial functions. We identified one such cryptic plasmid, pBI143, which is ubiquitous across industrialized gut microbiomes and is 14 times as numerous as crAssphage, currently established as the most abundant extrachromosomal genetic element in the human gut. The majority of mutations in pBI143 accumulate in specific positions across thousands of metagenomes, indicating strong purifying selection. pBI143 is monoclonal in most individuals, likely due to the priority effect of the version first acquired, often from one's mother. pBI143 can transfer between Bacteroidales, and although it does not appear to impact bacterial host fitness in vivo, it can transiently acquire additional genetic content. We identified important practical applications of pBI143, including its use in identifying human fecal contamination and its potential as an alternative approach to track human colonic inflammatory states.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 56
    Publication Date: 2024-03-28
    Description: Volcanic rocks are the prominent host rocks in geothermal and volcanic systems in general, displaying heterogeneity. Although various external factors such as temperature, pressure, time, fluid chemistry, and subsurface geology have been thoroughly researched regarding the source of hydrothermal minerals in geothermal fields, the effect of hydrothermal alteration on volcanic hosts is still controversial in the literature. This review compiles data on the physical and mechanical properties of the host rocks composing volcanic environments exhibiting hydrothermal alteration or remaining unaltered. The considered data is originated from hydrothermal areas from Kuril-Kamchatka (Russia), Los Humeros (Mexico), Ngatamaraki, Rotokawa, Kawerau and Ohakuri geothermal fields and Mt. Ruapehu, Mt. Taranaki, and Whakaari volcanoes (New Zealand), Solfatara (Italy), Reykjanes, Nesjavellir, and Theistarereykir geothermal fields (Iceland), La Soufrière de Guadeloupe (Caribbean) volcano, and Merapi volcano (Indonesia). Analysis of average values displayed in several graphical representations and correlations finds that dense rocks (such as lavas and intrusive rocks) exhibit greater competence and lower porosity than fragmental rocks. However, altered dense rocks display greater variability in mechanical properties compared to pyroclastic rocks, primarily influenced by mineral dissolution leading to rock weakening. Exceptions occur for high-temperature hydrothermal alteration, such as advanced silicification and propylitic alteration, with the latter influenced by minor types of alteration. Fragmental rocks have diverse behaviour with the extent of hydrothermal alteration and welding/compaction. According to the compiled data, an overall strengthening of pyroclastic rocks develops as hydrothermal alteration increases, regardless of the type of hydrothermal alteration. The complexity of hydrothermal systems, the variability shown by different hydrothermal settings and histories in terms of temperature, fluid chemistry and secondary mineral assemblage, and the variety of rock materials with different microstructures contribute to moderate correlations between properties compared to those established in an unaltered state. However, the same trends (linear, nonlinear, positive, negative) are preserved along hydrothermal alteration. This review emphasizes the significance of the type and degree of hydrothermal alteration, along with the rock type and pre-existence of fractures, in shaping the development of alteration in volcanic environments and modifying the properties of host rocks. The relevance of the review relies on the fact that these properties are considered to enhance the productivity of geothermal fields and improve the assessment of volcanic hazards. Future research is expected to expand on this groundwork.
    Description: In press
    Description: 104754
    Description: OSV4: Preparazione alle crisi vulcaniche
    Description: JCR Journal
    Keywords: Hydrothermal alteration ; physical properties ; degree of hydrothermal alteration ; mechanical properties ; hydrothermal alteration facies ; intrusion-related geothermal systems ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 57
    Publication Date: 2024-03-26
    Description: This review has been undertaken to understand the effectiveness of ocean acidification on oceanic micronutrient metal cycles (iron, copper and zinc) and its potential impacts on marine biota. Ocean acidification will slow down the oxidation of Fe(II) thereby retarding Fe(III) formation and subsequent hydrolysis/precipitation leading to an increase in iron bioavailability. Further, the increased primary production sustains enzymatic bacteria assisted Fe(III) reduction and subsequently the binding of weaker ligands favours the dissociation of free Fe(II) ions, thus increasing the bioavailability. The increasing pCO2 condition increases the bioavailability of copper ions by decreasing the availability of free CO32− ligand concentration. The strong complexation by dissolved organic matter may decrease the bioavailable iron and zinc ion concentration. Since ocean acidification affects the bioavailability of essential metals, studies on the uptake rates of these elements by phytoplankton should be carried out to reveal the future scenario and its effect on natural environment.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 58
    Publication Date: 2024-03-26
    Description: The Red Sea is an important example of a continental rift transitioning slowly to an oceanic basin. However, structures that can inform us of how that transition occurred have been poorly reported because deep seismic reflection data capable of imaging basement under the rift sediments are generally lacking publicly. Three lines of multichannel seismic reflection data have recently been published revealing structures on the Nubian side of the central part of the basin. In this study, we reassess these data in the light of recent studies of the central Red Sea. Over continental crust, the data reveal reflection sequences likely due to strata at or near the base of the evaporites, in two cases with varied dips suggesting the presence of syn-rift growth stratigraphy. Almost all of those reflections dip downwards towards the rift axis, not away as would be expected from tilted fault blocks of bookshelf faulting types. That observation, and low relief of basement, confirm inferences made earlier based on gravity anomalies that this part of the Red Sea lacks large-relief fault escarpments and is most likely a syn-rift sag basin. In the transition to oceanic crust, an abnormally broad magnetic anomaly of estimated Chron 5 age is found not to be associated with structures such as sills, so it likely arises from deeper sources. One of the seismic lines traverses a ridge in Bouguer gravity anomalies that runs across the axis. This feature has previously been interpreted as a volcanic ridge similar to those observed at other ultra-slow spreading ridges. The seismic data reveal diffuse basement reflections and confirm that the record immediately above basement lacks reflections typical of sedimentary strata. Both observations are consistent with the presence of oceanic crust. Modelling of gravity anomalies suggests the ridge is likely underlain by igneous intrusive rocks displacing mantle rocks, as expected for a volcanic ridge. The seismic data, combined with recently updated multibeam and high-resolution sparker seismic results, further suggest how the evaporite movements have been modulated by basement topography. These results add to our knowledge of the evaporite movements and continent-ocean transition structures in the central Red Sea.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 59
    Publication Date: 2024-03-26
    Description: Mafic alkaline magmas, such as those feeding the persistent eruptive activity of Stromboli and Mt. Etna volcanoes in Italy, are dominated by the crystallization of plagioclase via cooling and degassing phenomena related to the dynamics of shallow crustal reservoirs and eruptive conduits. Because plagioclase textures and compositions are extremely sensitive to the changes of intensive variables in subvolcanic plumbing systems, the phenomenological variability of erupted crystals preserves detailed evidence of complex growth histories. From this point of view, we reappraise the textural maturation and compositional complexity of plagioclase by allying thermodynamic and kinetic principles to natural and experimental observations, with the purpose of drawing up guidelines for reconstructing magma dynamics in mafic alkaline volcanic settings. A multifaceted statistical method is adopted to parameterize the decay of crystal growth rate with increasing crystallization time, as relaxation kinetics prevails over melt supersaturation effects. This model parameterization is combined with the textural analysis of natural plagioclase crystals to quantify the residence time of phenocrysts in equilibrium with magmas at Stromboli and Mt. Etna and/or the timescale of rapid microlite growth during disequilibrium ascent of magmas within the conduit. The role played by temperature and melt-water content on plagioclase components and major cation substitution mechanisms is also evaluated under both isobaric-isothermal and decompression conditions. The emerging paradigm is that the influence of dissolved water on anorthite-albite exchange between plagioclase and melt is overwhelmingly mitigated by changes in temperature at conditions of P = 30–300 MPa, T = 1050–1150 °C, fO2 = NNO + 1.9-NNO + 2.3, and melt-H2O = 0.6–4.4 wt%. As a corollary, anorthite and albite melt activities are almost fully encapsulated in the variation of anhydrous melt components as the crystallization of plagioclase proceeds during magma cooling. Following this line of reasoning, we propose an integrated modeling approach to decipher complex zoning patterns in natural plagioclase phenocrysts from mafic alkaline eruptions. Key findings from our re-assessment of equilibrium, thermometric, and hygrometric models indicate that temperature and dissolved water can be iteratively estimated for different plagioclase textural patterns if crystals are sufficiently strongly zoned and probability-based criteria are applied to determine the maximum probability distribution from kernel density analysis.
    Description: Natural Environment research Council UK grant NE/T009292/1; INGV Progetti Ricerca Libera 2019 Grant #52/2020; INGV Departmental Strategic Project UNO; PRIN MIUR Grant #2017J277S9_004.
    Description: Published
    Description: 104399
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: Mafic alkaline magmas ; Plagioclase growth rate parameterization ; Plagioclase-based thermometry and hygrometry ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 60
    Publication Date: 2024-03-25
    Description: The impact of oxygen on the preservation of organic matter in marine surface sediments is still controversial. We revisited this long-standing debate by determining the burial efficiency of sedimentary organic matter in the Black Sea, the largest anoxic and euxinic basin in the modern ocean. Surface sediments were sampled in the Danube paleodelta on the northwestern margin of the Black Sea at 420–1550 m water depth. Steady-state modeling of solid species (particulate organic carbon and nitrogen) and solutes (ammonium, sulfate, and total alkalinity) in sediments was performed to quantify rates of mass accumulation, particulate organic matter (POM) degradation, and POM burial. We develop a novel analytical model to quantify these rates applying an inverse modelling approach to down core data accounting for molecular diffusion, sediment burial and compaction. Our model results indicate that 56.7 ± 6.6 % of the particulate organic matter deposited in the study area is not degraded in surface sediments but accumulates below 10 cm sediment depth. This burial efficiency is substantially higher than those previously derived for seafloor areas underlying oxygenated bottom waters. Hence, our study confirms previous studies showing that euxinic bottom water conditions promote the preservation of particulate organic matter in marine sediments.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 61
    Publication Date: 2024-03-25
    Description: The TetraEther indeX of 86 carbon atoms (TEX86) is widely used as a proxy to reconstruct past sea surface temperatures. Most current applications of TEX86 are primarily based on analyzing the composition of isoprenoid glycerol dialkyl glycerol tetraethers (isoGDGTs) that comprise TEX86 in sediments, with the assumption that the sedimentary isoGDGTs are mainly derived from the surface mixed layer. Here we report on the variations in the isoGDGT distribution, archaeal abundance and community through the water column of the Western Pacific Ocean, directly testing the export depth of isoGDGTs and constraining the temperature records of TEX86. Our data show that maximum isoGDGT concentrations occurred in subsurface waters (150–200 m) with maximum archaeal abundances. The ratio between isoGDGTs bearing 2 vs. 3 cyclopentane moieties, i.e. [2/3] ratio, increased with depth, which is likely related to the shift of the archaeal community from Ca. Nitrosopelagicus-dominance to norank_f__Nitrosopumilaceae-dominance. Models based on the [2/3] ratios in the water column predicted an average export depth of isoGDGTs to sediments of around 150–200 m, consistent with the robust relationship between the compiled sedimentary TEX86 and the annual mean subsurface temperature. Taken together, our findings support that TEX86 records subsurface rather than surface temperatures in the open ocean.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 62
  • 63
    Publication Date: 2024-03-25
    Description: The ocean region along the latitude of 40oS in the South Atlantic, characterized by enhanced primary productivity, forms a transition zone between the nutrient replete but iron depleted Southern Ocean, and the nitrate and iron depleted Subtropical Gyre. Here, we present distributions of nutrient-type dissolved and particulate trace metals (dTMs and pTMs) including cadmium (Cd), nickel (Ni), copper (Cu), and zinc (Zn) in the South Atlantic from the GEOTRACES GA10 cruises. Phytoplankton uptake, riverine and atmospheric inputs shaped dTM and pTM concentrations in surface waters (dCd 27.8±36.0 pmol kg-1, n=222; dCu 0.732±0.429 nmol kg-1, n=222; dNi 3.38±0.52 nmol kg-1, n=219; dZn 0.332±0.398 nmol kg-1, n=214). Subsurface nutrients and dTMs (dCd 563±184 pmol kg-1, n=335; dCu 1.819±0.773 nmol kg-1, n=334; dNi 6.19±1.06 nmol kg-1, n=330; dZn 3.71±2.10 nmol kg-1, n=333) were controlled by the mixing of Antarctic origin waters and North Atlantic Deep Waters (NADW) with negligible contributions from local remineralization. Dissolved and particulate TMs in the Argentine Basin showed elevated concentrations towards the seafloor because of benthic inputs. Direct hydrothermal inputs of dTMs and pTMs to deep waters were not observed along the transect. The Cd-Cu-Zn-phosphate stoichiometries of Antarctic origin waters were set by a combination of dynamic physical circulation and preferential uptake of Cd, Cu, and Zn relative to phosphate in surface waters because of a dominance by diatoms in the Southern Ocean. Water mass mixing subsequently produced convoluted dCu-P and dZn-P relationships and apparent linear dCd-P and dNi-P relationships in the South Atlantic. More importantly, endmember characteristics of Antarctic waters and NADW are largely fixed in their formation regions in high latitude oceans. Therefore, the highly dynamic high latitude oceans are key regions that supply nutrients and TMs at specific ratios to low latitude oceans via the thermohaline circulation. Changes to processes in the high latitude oceans may have consequences for marine primary productivity downstream, and hence the global carbon cycle.
    Type: Article , PeerReviewed
    Format: text
    Format: archive
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 64
    Publication Date: 2024-03-25
    Description: Highlights • Investigation into the potential of Porites microatolls for SST reconstruction. • Comparison between recent and more conventional coral paleoclimatology methods. • Application of Srsingle bondU and Li/Mg paleothermometer. • Accuracy and reproducibility of Sr/Ca proved to be the most suitable proxy for SST reconstruction. Abstract Massive dome-shaped coral Porites are the predominant choice for paleoclimate studies due to their consistent and reliable growth. When growing close to sea level, they become limited in their vertical growth and form so-called ‘microatolls’. Microatolls have not yet been extensively explored for paleoclimate reconstruction. Here, we investigate how reliable modern Porites microatolls are against empirical sea-surface temperature using Sr/Ca, δ18O, Li/Mg and Srsingle bondU paleothermometry methods on samples from the Society Islands, French Polynesia. Our results show Sr/Ca ratios have the lowest Standard Error of the Inverse Prediction (SEIP) at 0.415 °C (N = 41) with a calibration of Sr/Ca (mmol mol−1) = −0.082 ± 0.006 SST (°C) + 11.256 ± 0.170 and with high reproducibility across multiple corals. The reproducibility of δ18O was less good, with SEIP increasing to 0.829 °C (N = 41). Considering methods directly from the literature, Li/Mg ratio empirically corrected for Sr/Ca had the best balance between bias and precision where no local calibration could be available. This study independently evaluates and confirms the suitability of Porites microatolls from well-flushed environments for paleoclimate studies. Fossil dome-shaped Porites grow anywhere between near-surface and roughly 20 m depths which inherently incorporates uncertainty into any sea surface temperature reconstruction. This uncertainty is significantly reduced for microatolls due to their well-constrained bathymetry. The study represents a fundamental step in paleoclimate research targeting consistently near the water-air interface bringing reliability and, especially when combined with their ability to reconstruct past sea-level changes, microatolls have the potential to be central for future paleoenvironmental studies.
    Type: Article , PeerReviewed
    Format: text
    Format: archive
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 65
    Publication Date: 2024-03-25
    Description: To date, the putative shellfish toxin azaspiracid 59 (AZA-59) produced by Azadinium poporum (Dinophyceae) has been the only AZA found in isolates from the Pacific Northwest coast of the USA (Northeast Pacific Ocean). Anecdotal reports of sporadic diarrhetic shellfish poisoning-like illness, with the absence of DSP toxin or Vibrio contamination, led to efforts to look for other potential toxins, such as AZAs, in water and shellfish from the region. A. poporum was found in Puget Sound and the outer coast of Washington State, USA, and a novel AZA (putative AZA-59) was detected in low quantities in SPATT resins and shellfish. Here, an A. poporum strain from Puget Sound was mass-cultured and AZA-59 was subsequently purified and structurally characterized. In vitro cytotoxicity of AZA-59 towards Jurkat T lymphocytes and acute intraperitoneal toxicity in mice in comparison to AZA-1 allowed the derivation of a provisional toxicity equivalency factor of 0.8 for AZA-59. Quantification of AZA-59 using ELISA and LC-MS/MS yielded reasonable quantitative results when AZA-1 was used as an external reference standard. This study assesses the toxic potency of AZA-59 and will inform guidelines for its potential monitoring in case of increasing toxin levels in edible shellfish.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 66
    Publication Date: 2024-03-23
    Description: The isotopic composition of Phanerozoic marine sediments provides important information about changes in seawater chemistry. In particular, the radiogenic strontium isotope (87Sr/86Sr) system is a powerful tool for constraining plate tectonic processes and their influence on atmospheric CO2 concentrations. However, the 87Sr/86Sr isotope ratio of seawater is not sensitive to temporal changes in the marine strontium (Sr) output flux, which is primarily controlled by the burial of calcium carbonate (CaCO3) at the ocean floor. The Sr budget of the Phanerozoic ocean, including the associated changes in the amount of CaCO3 burial, is therefore only poorly constrained. Here, we present the first stable isotope record of Sr for Phanerozoic skeletal carbonates, and by inference for Phanerozoic seawater (δ88/86Srsw), which we find to be sensitive to imbalances in the Sr input and output fluxes. This δ88/86Srsw record varies from ∼0.25‰ to ∼0.60‰ (vs. SRM987) with a mean of ∼0.37‰. The fractionation factor between modern seawater and skeletal calcite Δ88/86Srcc-sw, based on the analysis of 13 modern brachiopods (mean δ88/86Sr of 0.176±0.016‰, 2 standard deviations (s.d.)), is -0.21‰ and was found to be independent of species, water temperature, and habitat location. Overall, the Phanerozoic δ88/86Srsw record is positively correlated with the Ca isotope record (δ44/40Casw), but not with the radiogenic Sr isotope record ((87Sr/86Sr)sw). A new numerical modeling approach, which considers both δ88/86Srsw and (87Sr/86Sr)sw, yields improved estimates for Phanerozoic fluxes and concentrations for seawater Sr. The oceanic net carbonate flux of Sr (F(Sr)carb) varied between an output of -4.7x1010mol/Myr and an input of +2.3x1010mol/Myr with a mean of -1.6x1010mol/Myr. On time scales in excess of 100Myrs the F(Sr)carb is proposed to have been controlled by the relative importance of calcium carbonate precipitates during the “aragonite” and “calcite” sea episodes. On time scales less than 20Myrs the F(Sr)carb seems to be controlled by variable combinations of carbonate burial rate, shelf carbonate weathering and recrystallization, ocean acidification, and ocean anoxia. In particular, the Permian/Triassic transition is marked by a prominent positive δ88/86Srsw-peak that reflects a significantly enhanced burial flux of Sr and carbonate, likely driven by bacterial sulfate reduction (BSR) and the related alkalinity production in deeper anoxic waters. We also argue that the residence time of Sr in the Phanerozoic ocean ranged from ∼1Myrs to ∼20Myrs.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 67
    Publication Date: 2024-03-22
    Description: IODP Expedition 307 made it for the first time possible to investigate the entire body of a cold-water coral carbonate mound. Here we provide new insights into the long-term history of Challenger Mound on the European continental margin off Ireland. This study is based on age determinations (230Th/U, 87Sr/86Sr) and geochemical signals (Mg/Li and Ba/Ca) measured in the scleractinian cold-water coral Lophelia pertusa from IODP Site 1317 in the Porcupine Seabight. The paleoceanographic reconstructions reveal that coral growth in the Porcupine Seabight was restricted to specific oceanographic conditions such as enhanced export of primary production and Bottom-Water Temperatures (BWT) between ∼8–10 °C, related to the water mass stratification of the Mediterranean Outflow Water (MOW) and Eastern North Atlantic Water (ENAW). The geochemical signals from the coral skeletons can be explained by the close interaction between cold-water coral growth, sea-surface productivity and the surrounding water masses - the boundary layer between MOW and ENAW. Enhanced sea-surface productivity and the build-up of a stable water mass stratification between ENAW and MOW caused enhanced nutrient supply at intermediate water depths and facilitated a steady mound growth between∼3.0 - 2.1 Ma. With the decrease in sea-surface productivity and related reduced export productivity the food supply was insufficient for rapid coral mound growth between∼1.7 - 1 Ma. During the late Pleistocene (over the last∼0.5 Myr) mound growth was restricted to interglacial periods. During glacials the water mass boundary between ENAW/MOW probably was below the mound summit and hence food supply was not sufficient for corals to grow.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 68
    Publication Date: 2024-03-22
    Description: The aragonitic skeletons of scleractinian cold-water corals can serve as valuable archives in paleoceanographic studies. The potential of δ88/86Sr, Sr/Ca, Mg/Ca, Li/Ca and Mg/Li ratios of the cold-water coral Lophelia pertusa to record intermediate water mass properties has been investigated. Here we used samples from several locations along the European continental margin spanning a large temperature range from 6 to 14 °C. Stable strontium isotope measurements were carried out with the recently developed double spike TIMS technique and our results differ from those obtained with less precise methods. In contrast to the strong positive relationship with temperature of previous studies, our results suggest that δ88/86Sr measured in scleractinian cold-water corals is not controlled by seawater temperature, but reflects the Sr isotopic composition of seawater with an offset of Δ88/86Sr = − 0.196‰. As found in previous studies, the elemental ratios Sr/Ca, Li/Ca and Mg/Li measured in corals are significantly related to water temperature and do not correlate with salinity. Moreover, Sr/Ca ratios in L. pertusa display the expected inverse correlation with temperature. However, the variance in the Sr/Ca data severely limits the accuracy of paleotemperature estimates. The Li/Ca and Mg/Ca ratios reveal other influences besides temperature such as pH and/or growth or calcification rate. However, corresponding Mg/Li ratios in L. pertusa are more tightly related to temperature as they remove these secondary effects. In particular, the Mg/Li ratio in L. pertusa may serve as a new promising paleotemperature proxy for intermediate water masses. Our dataset represents the most extensive geochemical examination of L. pertusa to date, revealing a temperature sensitivity of 0.015 mol/mmol/°C for Mg/Li. However, using this temperature dependence and the precision of 5.3% (2SD) only temperature variations larger than ~ 1.5 °C can be resolved with 95% confidence.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 69
    Publication Date: 2024-03-22
    Description: The understanding of the paleoenvironment during initiation and early development of deep cold-water coral carbonate mounds in the NE Atlantic is currently a focus of international research. The Integrated Ocean Drilling Program (IODP) Expedition 307 drilled the 155 m high Challenger Mound in the Porcupine Seabight (SW off Ireland) in order to investigate for the first time sediments from the base of a giant carbonate mound. In this study we focus in high resolution on 12 m of sediments from Site 1317 encompassing the mound base. The mound initiation and start-up phase coincide with the intensification of the Northern Hemisphere Glaciation (INHG) at around 2.7 Ma. Further carbonate mound development seems to be strongly dependent on rapid changes in paleoceanographic and climatic conditions at the Pliocene–Pleistocene boundary, especially characterized and caused by the interaction of intermediate water masses, the Mediterranean Outflow Water (MOW), the Eastern North Atlantic Water (ENAW) and the influence of Southern Component Water (SCW). This study is based on well-established proxies such as δ18O and δ13C of planktonic (Globigerina bulloides) and benthic foraminifera (Fontbotia wuellerstorfi, Discanomalina coronata, Lobatula lobatula, Lobatula antarctica, and Planulina ariminensis) as well as grain size parameters to identify the paleoenvironmental and paleoecological setting favourable for the initial coral colonization on the mound. Stable oxygen and carbon isotope records of benthic foraminiferal species indicate that L. lobatula provides a reliable isotopic signature for paleoenvironmental reconstructions. In particular, δ18O values of L. lobatula indicate that initial mound growth started in a glacial mode with moderate excursions in δ18O values. Carbon isotope values of D. coronata are significantly offset compared to other epibenthic species. This offset may be related to vital effects. Bottom water temperatures, calculated using standard equations based on δ18O of foraminiferal tests, range between 7 and 11 °C, consistent with the known temperature range conducive for cold-water coral growth and development. Bottom currents transporting intermediate water masses of southern origin (Mediterranean and Bay of Biscay) enhanced at 2.6 Ma supporting first coral settlements with the INHG. The benthic δ13C and the sortable silt records indicate that the early Pleistocene hydrodynamic regime was characterized by weaker current intensities associated with vertical movements of MOW or its replacement by SCW at intermediate depth. After these sluggish phases enhanced MOW flow dominated again and led to stronger current intensities and most probably sediment erosion on Challenger Mound. Erosion in combination with early diagenetic (oxidation) processes overprinted the sediment layers as indicated by dissolved coral skeletons, the increase in Ca-content and sediment density, minimum δ13Cplanktonic values, as well as the occurrence of gypsum and pyrite, implying a careful evaluation of original and overprinted geochemical signals. We conclude that the Challenger Mound development was already influenced by short-term variability of water masses from southern origin and possible erosional events comparable to the late Pleistocene setting.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 70
    Publication Date: 2024-03-22
    Description: Highlights • Re-organization of the West Pacific Warm Pool at ~ 1.7 – 1.35 Ma. • West Pacific Warm Pool and South Pacific Convergence Zone located further to the NE prior to ~ 1.5 Ma. • High amplitude variations at thermocline and deep thermocline depths after ~ 1.5 Ma. • West Pacific Warm Pool thermocline dynamics linked to southern-sourced mode waters. Abstract The internal development of the tropical West Pacific Warm Pool and its interaction with high latitude ocean regions on geological timescales is only poorly constrained. Based on two newly recovered sediment cores from the southeastern margin of the West Pacific Warm Pool (northern and southern Manihiki Plateau), we provide new aspects on the dynamically interacting ocean circulation at surface, subsurface, thermocline, and deep thermocline levels during the Pleistocene (~ 2.5–0.5 Ma). Notably, the variability of thermocline and deep thermocline (~ 150–400 m water depth) foraminiferal Mg/Ca-based temperatures with up to ~ 6 °C amplitude variations exceeds those at shallower depths (down to ~ 120 m) with only ~ 2–3 °C temperature variations. A major gradual reorganization of the West Pacific Warm Pool oceanography occurred during the transitional time period of ~ 1.7–1.35 Ma. Prior to ~ 1.7 Ma, pronounced meridional and latitudinal gradients in sea-surface to subsurface ocean properties point to the eastward displacement of the West Pacific Warm Pool boundaries, with the South Pacific Convergence Zone being shifted further northeastward across Manihiki Plateau. Simultaneously, the low amplitude variations of thermocline and deep thermocline temperatures refer to an overall deep and stable thermocline. The meridional and zonal gradients in sea-surface and subsurface ocean properties within the West Pacific Warm Pool reveal a pronounced change after 1.5 Ma, leading to a more southward position of the warm South Pacific Convergence Zone between ~ 1.35–0.9 Ma and ~ 0.75–0.5 Ma. Synchronous to the changes in the upper ocean, the deeper water masses experienced high amplitude variations in temperature, most prominently since ~ 1.5 Ma. This and the dynamically changing thermocline were most likely associated to the impact of southern-sourced mode waters, which might have developed coincidently with the emergence of the East Pacific Cold Tongue and high latitude sea-surface cooling.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 71
    Publication Date: 2024-03-22
    Description: Highlights • First apparent calcification depth assessment of living foraminifera in the SE WPWP • Deep surface mixed layer causes deep apparent calcification depths. • Deep-dwelling G. hexagonus traces nutrient conditions in equatorial water masses. Abstract Insight into past changes of upper ocean stratification, circulation, and nutrient signatures rely on our knowledge of the apparent calcification depth (ACD) and ecology of planktonic foraminifera, which serve as archives for paleoceanographic relevant geochemical signals. The ACD of different species varies strongly between ocean basins, but also regionally. We constrained foraminiferal ACDs in the Western Pacific Warm Pool (Manihiki Plateau) by comparing stable oxygen and carbon isotopes (δ18Ocalite, δ13Ccalcite) as well as Mg/Ca ratios from living planktonic foraminifera to in-situ physical and chemical water mass properties (temperature, salinity, δ18Oseawater, δ13CDIC). Our analyses point to Globigerinoides ruber as the shallowest dweller, followed by Globigerinoides sacculifer, Neogloboquadrina dutertrei, Pulleniatina obliquiloculata and Globorotaloides hexagonus inhabiting increasing greater depths. These findings are consistent with other ocean basins; however, absolute ACDs differ from other studies. The uppermost mixed-layer species G. ruber and G. sacculifer denote mean calcification depths of ~ 95 m and ~ 120 m, respectively. These Western Pacific ACDs are much deeper than in most other studies and most likely relate to the thick surface mixed layer and the deep chlorophyll maximum in this region. Our results indicate that N. dutertrei appears to be influenced by mixing waters from the Pacific equatorial divergence, while P. obliquiloculata with an ACD of ~ 160 m is more suitable for thermocline reconstructions. ACDs of G. hexagonus reveal a deep calcification depth of ~ 450 m in oxygen-depleted, but nutrient-rich water masses, consistent to other studies. As the δ13C of G. hexagonus is in near-equilibrium with ambient seawater, we suggest this species is suitable for tracing nutrient conditions in equatorial water masses originating in extra-topical regions.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 72
    Publication Date: 2024-03-22
    Description: High dissolved iron (dFe) concentrations of the order of 10-100 nmol L-1 are a feature of waters influenced by sedimentary inputs in oxygen minimum zones (OMZ). However, the temporal development of dFe concentrations is poorly defined due to a general reliance on snapshot cross-shelf sections to study marine trace metal dynamics. Multiple cruise campaigns since the 1980s have investigated Fe dynamics over the Peruvian shelf, particularly between 9-17°S where the shelf is broad, extremely productive and known to feature benthic dFe effluxes which are amongst the highest measured globally. This extensive long-term dataset uniquely allows us to study the interannual variability in dFe concentrations and their response to El Niño–Southern Oscillation (ENSO) events. By combining data from 11 cruises during the period 1984-2017 we are able to evaluate dFe dynamics on interannual timescales in a major OMZ. The region where average dFe concentrations are sensitive to variations in ENSO is confined to a subsurface layer at depths between 50-150 m, particularly in the narrow coastal region within 50 km of the coastline. Subsurface dFe concentrations were generally low during El Niño events (0.7-15.4 nmol L-1) and relatively high with a wider range of variability during the cold ENSO phase (1.1-52.1 nmol L-1). Inverse relationships between wind speed and surface/subsurface dFe were evident. In the subsurface layer, this may be attributable to enhanced dFe offshore transport along isopycnals when upwelling-favorable winds relax in accordance with previously outlined theories. Surface layer (〈40 m) dFe variability was likely associated with a dilution and/or oxidation effect depending on the strength of wind driven water column mixing. Upwelling brings macronutrient-rich water into the euphotic zone, but its intensity had a limited impact on upper layer dFe concentrations possibly due to the influence of an onshore geostrophic flow. Interannual variability in surface chlorophyll-a (Chl-a) was found to correlate with dFe concentration in the offshore zone of northern Peru. This is consistent with bioassay experiments and climatological residual nitrate concentrations which both indicate proximal Fe limitation of phytoplankton growth over and beyond the northern Peruvian shelf. Overall, our work highlights the importance of physical factors driving short-term variations in Fe availability in one of the world’s most economically important fishery regions and suggests that, despite pronounced spatial and temporal variability in dFe concentrations, the ENSO phase has an impact on dFe availability.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 73
    Publication Date: 2024-03-22
    Description: High-latitude cold-water coral reefs are particularly vulnerable to climate change due to enhanced CO2 uptake in these regions. To evaluate their physiological functioning and potential application as pH archives, we retrieved both recent and fossil samples of Lophelia pertusa along the Norwegian margin from Oslofjord (59°N), over to Trondheimsfjord, Sula and Lopphavet (70.6°N). Boron isotope analyses (δ11B) were undertaken using solution-based and laser ablation multi-collector inductively coupled plasma mass spectrometry (MC-ICP-MS; LA-ICP-MS), and secondary ion mass spectrometry (SIMS). Epi-fluorescence microscopy was employed to provide a rapid pre-screening routine for structure-specific subsampling in the coral skeleton. This integrated approach enabled us to assess heterogeneities within single specimens, as well as to investigate the role of local environmental influences including recent and past variations. All three mass spectrometry methods show substantial differences in the δ11B of the theca wall (TW) and the centres of calcification (COC's). Micro-bulk subsamples milled from the theca wall of modern specimens originating from different habitats but with comparable seawater pH (8–8.16) gave consistent δ11B values averaging 26.7 (±0.2‰, 2σ, n = 4), while COC subsamples systematically deviated towards lower B/Ca (by ~40%) and depleted δ11B values (minimum 22.7 ± 0.3‰, 2σ), implying a difference of at least 4‰ between TW and COC. SIMS and LA-ICP-MS measurements identified much larger internal heterogeneities with maximum variation of ~10‰ between the distinct skeletal structures; minimal SIMS δ11B values of ~17.3 ± 1.2‰ (2σ) were associated with the pure COC material. Our findings may be interpreted in terms of the occurrence of two main, but likely different, biomineralisation mechanisms in L. pertusa, with the COC's generally exhibiting minimal pH up-regulation, potentially supporting the use of bicarbonate in the early stages of biomineralisation. Furthermore, we highlight the potential utility of L. pertusa for palaeo-proxy studies if targeting the compositionally homogenous TW zones devoid of COC admixtures, which appear to provide highly reproducible measurements.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 74
    Publication Date: 2024-03-22
    Description: Underwater image restoration has been a challenging problem for decades since the advent of underwater photography. Most solutions focus on shallow water scenarios, where the scene is uniformly illuminated by the sunlight. However, the vast majority of uncharted underwater terrain is located beyond 200 meters depth where natural light is scarce and artificial illumination is needed. In such cases, light sources co-moving with the camera, dynamically change the scene appearance, which make shallow water restoration methods inadequate. In particular for multi-light source systems (composed of dozens of LEDs nowadays), calibrating each light is time-consuming, error-prone and tedious, and we observe that only the integrated illumination within the viewing volume of the camera is critical, rather than the individual light sources. The key idea of this paper is therefore to exploit the appearance changes of objects or the seafloor, when traversing the viewing frustum of the camera. Through new constraints assuming Lambertian surfaces, corresponding image pixels constrain the light field in front of the camera, and for each voxel a signal factor and a backscatter value are stored in a volumetric grid that can be used for very efficient image restoration of camera-light platforms, which facilitates consistently texturing large 3D models and maps that would otherwise be dominated by lighting and medium artifacts. To validate the effectiveness of our approach, we conducted extensive experiments on simulated and real-world datasets. The results of these experiments demonstrate the robustness of our approach in restoring the true albedo of objects, while mitigating the influence of lighting and medium effects. Furthermore, we demonstrate our approach can be readily extended to other scenarios, including in-air imaging with artificial illumination or other similar cases.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 75
    Publication Date: 2024-03-21
    Description: Synchrotron-based powder diffraction measurements in combination with inductively coupled plasma optical emission spectrometry, Raman and fluorescence spectroscopy show that (Ba,Ca)2 can incorporate significant amounts (up to 6 ​mol%) of europium. This solid solution is therefore of potential interest for the solidification of nuclear waste streams involving aqueous nitrate solutions of lanthanides. Europium replaces Ba/Ca on lattice sites and is not incorporated as an interstitial defect. Charge compensation is likely due to the presence of OH−-groups as we could exclude a coupled substitution involving Na+. The Eu-containing compound is stable to at least 723 ​K. We show that the one-phase-field of (Bax,Ca(1−x))CO3 solid solutions at ambient conditions is larger (0.36 0.51) than previously thought. The synthesis routes employed here lead to compounds which have similar molar volumes than those of the naturally occurring (Ba,Ca)-double carbonates, in noted contrast to another synthetic phase, “balcite”.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 76
    Publication Date: 2024-03-21
    Description: Due to their large heat and moisture storage capabilities, the tropics are fundamental in modulating both regional and global climate. Furthermore, their thermal response during past extreme warming periods, such as super interglacials, is not fully resolved. In this regard, we present high-resolution (analytical) foraminiferal geochemical (δ18O and Mg/Ca) records for the last 1800 kyr from the shallow (487 m) Inner Sea drift deposits of the Maldives archipelago in the equatorial Indian Ocean. Considering the diagenetic susceptibility of these proxies, in carbonate-rich environments, we assess the integrity of a suite of commonly used planktonic and benthic foraminifera geochemical datasets (Globigerinoides ruber (white), Globigerinita glutinata (with bulla), Pulleniatina obliquiloculata (with cortex) and Cibicides mabahethi) and their use for future paleoceanographic reconstructions. Using a combination of spot Secondary Ion Mass Spectrometer, Electron Probe Micro-Analyzer and Scanning Electron Microscope image data, it is evident that authigenic overgrowths are present on both the external and internal test (shell) surfaces, yet the degree down-core as well as the associated bias is shown to be variable across the investigated species and proxies. Given the elevated authigenic overgrowth Mg/Ca (∼12–22 mmol/mol) and δ18O values (closer to the benthic isotopic compositions) the whole-test planktonic G. ruber (w) geochemical records are notably impacted beyond ∼627.4 ka (24.7 mcd). Yet, considering the setting (i.e. bottom water location) for overgrowth formation, the benthic foraminifera δ18O record is markedly less impacted with only minor diagenetic bias beyond ∼790.0 ka (28.7 mcd). Even though only the top of the G. ruber (w) and C. mabahethi records (whole-test data) would be suitable for paleo-reconstructions of absolute values (i.e. sea surface temperature, salinity, seawater δ18O), the long-term cycles, while dampened, appear to be preserved. Furthermore, planktonic species with thicker-tests (i.e. P. obliquiloculata (w/c)) might be better suited, in comparison to thinner-test counter-parts (i.e. G. glutinata (w/b), G. ruber (w)), for traditional whole-test geochemical studies in shallow, carbonate-rich environments. A thicker test equates to a smaller overall bias from the authigenic overgrowth. Overall, if the diagenetic impact is constrained, as done in this study, these types of diagenetically altered geochemical records can still significantly contribute to studies relating to past tropical seawater temperatures, latitudinal scale ocean current shifts and South Asian Monsoon dynamics
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 77
    Publication Date: 2024-03-21
    Description: Highlights: • Niche conservatism among reservoirs was generally higher in invertebrates. • Niche conservatism was not based on reservoir condition (i.e. presence or absence of pollution and/or invasion). • Invasion coupled with organic pollution may cause subtle yet differing effects on food web components. • Results provide baseline measure in carp invasions and organic pollution detection and response strategies. Abstract: Environmental pollution and biological invasions are key drivers of biodiversity change. However, the effects of invasion and pollution on food webs remain largely unexplored. Here, we used stable isotopes to examine the effects of common carp Cyprinus carpio and pollution on trophic dynamics in six small reservoirs. Our results revealed that the trophic niche widths of invertebrates, vertebrates, and invasive carp did not significantly differ among reservoirs with different pollution statuses. However, we found low niche conservatism among reservoirs, suggesting that while niche width may remain consistent, there is a shift in the position of the niches in isotopic space under both pollution and invasion scenarios. Niche conservatism among reservoirs was generally higher in invertebrates, but this was also regardless of reservoir condition (i.e. presence or absence of pollution and invasion). These results suggest that invasion by species coupled with organic pollution may cause subtle yet differing effects on components of a food web (basal end-members, invertebrates and vertebrates). Our findings provide a baseline measure of the potential in the development of detection and response strategies for carp invasions and organic pollution.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 78
    Publication Date: 2024-03-21
    Description: Shellfish contamination with azaspiracids (AZA) is a major and recurrent problem for the Irish shellfish industry. Amphidoma languida, a small thecate dinoflagellate of the family Amphidomataceae, is widely distributed in Irish coastal waters and is one of the identified source species of azaspiracids. Irish and North Sea strains of Am. languida have been found to produce as major metabolites AZA-38 and -39 whose structures have only been provisionally elucidated by mass spectrometry and their toxic potential is currently unknown. In order to provide pure AZA-38 and -39 for subsequent structural and toxicological analyses, we present the first successful large-scale culture of Am. languida. A 180 L in house prototype bioreactor was used for culture growth and harvesting in semi-continuous mode for two months. Two different runs of the photobiorector with different light and pH setting showed the highest toxin yield at higher light intensity and slightly higher pH. AZA-38 and -39 cell quota were measured throughout the complete growth cycle with AZA-39 cell quota increasing in proportion to AZA-38 at late stationary to senescence phase. Over two experiments a total of 700 L of culture was harvested yielding 0.45 mg of pure AZA-39. The structure of AZA-39 was elucidated through NMR data analyses, which led to a revision of the structure proposed previously by mass spectrometry. While the spirotetrahydrofuran/tetrahydrofuran of rings A and B has been confirmed by NMR for AZA-39, a methyl is still present in position C-14 and the carboxylic acid chain is different from the structure proposed initially.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 79
    Publication Date: 2024-03-21
    Description: This study describes two novel species of marine dinophytes in the genus Alexandrium. Morphological characteristics and phylogenetic analyses support the placement of the new taxa, herein designated as Alexandrium limii sp. nov. and A. ogatae sp. nov. Alexandrium limii, a species closely related to A. taylorii, is distinguished by having a shorter 2ʹ/4ʹ suture length, narrower plates 1ʹ and 6ʹʹ, with larger length: width ratios, and by the position of the ventral pore (Vp). Alexandrium ogatae is distinguishable with its metasert plate 1ʹ having almost parallel lateral margins, and by lacking a Vp. Production of paralytic shellfish toxins (PSTs), cycloimines, and goniodomins (GDs) in clonal cultures of A. ogatae, A. limii, and A. taylorii were examined analytically and the results showed that all strains contained GDs, with GDA as major variants (6–14 pg cell−1) for all strains except the Japanese strain of A. limii, which exclusively had a desmethyl variant of GDA (1.4–7.3 pg cell−1). None of the strains contained detectable levels of PSTs and cycloimines.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 80
    Publication Date: 2024-03-21
    Description: Uncertainty concerning the processes responsible for slip-rate fluctuations associated with temporal clustering of surface faulting earthquakes is a fundamental, unresolved issue in tectonics, because strain-rates accommodated by fault/shear-zone structures are the key to understanding the viscosity structure of the crust and seismic hazard. We constrain the timing and amplitude of slip-rate fluctuations that occurred on three active normal faults in central Italy over a time period of 20–30 kyrs, using in situ 36Cl cosmogenic dating of fault planes. We identify five periods of rapid slip on individual faults lasting a few millennia, separated time periods of up to 10 millennia with low or zero slip-rate. The rapid slip pulses migrated across the strike between the faults in two waves from SW to NE. We replicate this migration with a model where rapid slip induces changes in differential stress that drive changes in strain-rate on viscous shear zones that drive slip-rate variability on overlying brittle faults. Earthquakes increase the differential stress and strain-rate on underlying shear zones, which in turn accumulate strain, re-loading stress onto the overlying brittle fault. This positive feedback produces high strain-rate episodes containing several large magnitude surface faulting earthquakes (earthquake clusters), but also reduce the differential stress on the viscous portions of neighbouring fault/shear-zones slowing the occurrence of large-magnitude surface faulting earthquakes (earthquake anticlusters). Shear-zones on faults experiencing anticlusters continue to accumulate viscous strain at a lowered rate, and eventually this loads the overlying brittle fault to failure, initiating a period of rapid slip through the positive feedback process described above, and inducing lowered strain-rates onto neighbouring fault/shear-zones. We show that these patterns of differential stress change can replicate the measured earthquake clustering implied by the 36Cl data. The stress changes are related to the fault geometry in terms of distance and azimuth from the slipping structure, implying that (a) strain-rate and viscosity fluctuations for studies of continental rheology, and (b) slip-rates for seismic hazard purposes are to an extent predictable given knowledge of the fault system geometry.
    Description: Published
    Description: 105096
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Active Faults ; Central Apennines ; Fault interaction
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 81
    Publication Date: 2024-03-20
    Description: A multi-analytical approach was employed for the first time to study the stone materials, wall paintings and related degradation forms in the Cathedral of Gerace (Reggio Calabria, southern Italy). With an area of around 1898 square meters, the Gerace Cathedral is the largest in Calabria: its construction dates back to the Norman era (between 1085 and 1120), and currently displays distinct features of Greek and Latin architectural orders. Despite having undergone numerous restorations, the church perfectly preserves its original buildings materials. Following an extensive site inspection campaign, supported by the experts dealing with building restoration, several areas were selected for analyses. Both in situ investigations and laboratory tests were carried out on micro-fragments using Non-Destructive and Micro-Destructive Techniques (NDTs and MDTs). The first step involved an inspection through InfraRed Thermography (IRT) in order to map the internal walls of the Cathedral and identify zones with potential degradation phenomena. Subsequently, a more in-depth study was designed based on the thermographic results, and laboratory tests were carried out on micro-fragments and powders to characterize the different kinds of materials (i.e., stones, mortars, plasters and pigments) and decay agents (i.e., salts and efflorescences). Thirty-one samples were subjected to a complementary analytical approach which included Polarizing Optical Microscopy (POM), Ion Chromatography (IC), X-Ray Powder Diffraction (XRPD) and Scanning Electron Microscopy (SEM) coupled with microanalysis (EDS). The results allowed us to preliminarily characterize the different materials from which the Cathedral was built, determine its state of conservation and provide a better knowledge of the entire building, revealing details not visible to the naked eye which are important for future conservation interventions. As for the state of conservation, the integrated use of various techniques enabled the detection of rising damp generally correlated with the occurrence of water infiltration and migration phenomena which appear to affect a large part of the building, causing noticeable damage (i.e., loss of surface material, micro-cracks, white salt efflorescence, etc.). The characterization of the materials carried out on mortars, plasters, and pigments also confirmed the local origin of the raw materials. However, the provenance of the studied marbles and crystalline limestones, could not be established and, therefore, further in-depth studies are required.
    Description: Published
    Description: e02225
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Diagnostic ; Gerace cathedral ; Stone materials ; Pigments ; Plasters ; Restoration ; 05.04. Instrumentation and techniques of general interest ; 05.06. Methods
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 82
    Publication Date: 2024-03-20
    Description: We here present a 3D mapping of the dissolved CO2 at Lagoa das Furnas (S˜ao Miguel Island, Azores) obtained with an infrared-based probe that measures the partial pressure of CO₂ gas dissolved in liquids, and a multiparametric probe to measure pH, ORP, conductivity, dissolved O2, and temperature. We interpolated the dissolved CO2 at different depths and around the lake to calculate the total mass of CO2 dissolved as CO2 (aq) (109–176 tons). We identified different plumes of dissolved CO2 that spatially correspond to previously detected shallow anomalies of the diffusive CO2 degassing at the water-air (interface) and hydroacoustic signatures of the bubbling activity. Our result represents the first direct quantification of the total dissolved CO2 in a volcanic lake, opening new perspectives for volcanic lake monitoring and related hazard assessment.
    Description: Published
    Description: 108012
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: volcanic lake ; dissolved CO2 ; chemical tomography ; CO2 budget ; volcanic hazard
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 83
    Publication Date: 2024-03-20
    Description: In this article, volcanic lakes that have shown sedimentological evidence of limnic eruptions (i.e., Nyos-type gas bursts) are reviewed. Indeed, to better assess “Nyos-type lakes” related hazards, paleolimnology offers a promising tool to trace the evidence of potential ancient Nyos-type gas explosions. After gas bursts from Lakes Monoun and Nyos in 1984 and 1986, respectively, multiple paleolimnological approaches have been applied to several lakes assumed to be Nyos-type Around the world,. Only 3 lakes in Europe (i.e. lakes Pavin in France, Albano and Monticchio in Italy and one in Africa (i.e. Lake Kivu in D.R. Congo) evidenced markers of limnic eruptions in their sedimentary archives. These features include reworked sediments with reversed ages, brown colors of sedimentary deposits, gas-rich sediments, iron hydroxide-rich sediments, strong Ti and Fe enrichments, sedimentary hiatuses, absence of seismic evidence in the sedimentary record, and significant change in geochemical signature. The dating of these sedimentary deposits has made it possible to determine the ages of the events and their recurrence. This has led to associating these markers with evidence of limnic eruptions, eventhough some lakes are in temperate climates that favor seasonal overturning of lake waters and thus gradual release of accumulated gas. There is still no agreement on the dynamics and causes, and the scientific debate remains open since there is no concrete reference event in historical time. Lakes Monoun and Nyos, the first and only lakes exploded in recent history, could therefore be considered as natural laboratories to better understand limnic eruptions in lakes around the world. Unfortunately, the well-studied aspects of these Cameroonian “killer lakes” are based more on the dynamics of the explosions, hazard assessment based on water chemistry, and gas releases, rather than on the possible similar behavior in the recent geologic past by applying a combination of old and new limnological approaches. In addition, as the first natural laboratory, Lake Monoun features several advantages, including smaller surface area, shallower depth favorable for coring, easy access, and negligible gas content after artificial degassing since the early 2000s.
    Description: Published
    Description: 104603
    Description: OSV1: Verso la previsione dei fenomeni vulcanici pericolosi
    Description: JCR Journal
    Keywords: limnic eruption ; sediment cores ; paleolimnology ; physical limnology ; volcanic lakes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 84
    Publication Date: 2024-03-20
    Description: In active volcanic environments magmas that ascend within the conduit and erupt at the surface as lava flows experience physico-chemical perturbations related to temperature changes and variable degrees of deformation. We have conducted experimental investigations to examine the concurrent effects of undercooling and stirring on the crystallization kinetics of a leucite-bearing phonotephrite from Somma-Vesuvius (Italy). Two sets of undercooling experiments have been carried out within the same temperature range of 1300–1150 °C. The first set involved classical static undercooling (SU) experiments with no stirring applied to the melt, while the second set involved dynamic undercooling (DU) experiments with a shear strain rate of 1 s−1 applied. By comparing SU and DU results with previous data from literature obtained using the same experimental approach, we observe that the degree of crystallization and the textural evolution of leucite and clinopyroxene progress upon the effect of melt stirring by shortening the incubation time. As a result, the solidification process is markedly enhanced in DU experiments, accompanied by a substantial increase in the crystal nucleation density and growth rate. Thermorheological modeling indicates that stirring-induced crystallization increases the melt viscosity by a factor of ∼1.5–4.5 depending on the system temperature. At a given temperature, mass transport can therefore produce higher crystallinity and higher viscosity magmatic suspensions than static crystallization conditions. We document that if subsequent cooling occurs, the existing crystal cargo in such suspensions may promote the onset of non-Newtonian rheological response, causing a transition from homogeneous viscous flow to shear localization and magma/lava rupture.
    Description: Published
    Description: 121682
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: crystallization ; shear rate ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 85
    Publication Date: 2024-03-20
    Description: The frictional power per unit area (product of frictional traction τ and slip rate in MW m−2) dissipated during earthquakes triggers fault dynamic weakening mechanisms that control rupture nucleation, propagation and arrest. Although of great relevance in earthquake mechanics, cannot, with rare exceptions, be determined by geophysical methods. Here we exploit theoretical, experimental and geological constraints to estimate dissipated on a fault patch exhumed from 7-9 km depth. According to theoretical models, in polymineralic, silicate rocks the amplitude (〈 1 mm) of the grain-scale roughness of the boundary between frictional melt (pseudotachylyte) and host rock decreases with increasing . The dependence of grain-scale roughness with is due to differential melt front migration in the host rock minerals. This dependence is confirmed by friction experiments reproducing seismic slip where pseudotachylytes were produced by shearing tonalite at ranging from 5 to 25 MW m−2. In natural pseudotachylytes across tonalites, the grain-scale roughness broadly decreases from extensional to compressional fault domains where lower and higher are expected, respectively. Analysis of the natural dataset calibrated by experiments yields values in the range of 4-60 MW m−2 (16 MW m−2 average value). These values, estimated in small fault patches, are at the lower end of broad estimates of (3-300 MW m−2) obtained from frictional tractions (30-300 MPa) and fault slip rates (0.1-1 m/s) assumed as typical of upper crustal earthquakes.
    Description: Published
    Description: 118057
    Description: OST3 Vicino alla faglia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 86
    Publication Date: 2024-03-19
    Description: Ancient environmental DNA (aeDNA) data are close to enabling insights into past global-scale biodiversity dynamics at unprecedented taxonomic extent and resolution. However, achieving this potential requires solutions that bridge bioinformatics and paleoecoinformatics. Essential needs include support for dynamic taxonomic inferences, dynamic age inferences, and precise stratigraphic depth. Moreover, aeDNA data are complex and heterogeneous, generated by dispersed researcher networks, with methods advancing rapidly. Hence, expert community governance and curation are essential to building high-value data resources. Immediate recommendations include uploading metabarcoding-based taxonomic inventories into paleoecoinformatic resources, building linkages among open bioinformatic and paleoecoinformatic data resources, harmonizing aeDNA processing workflows, and expanding community data governance. These advances will enable transformative insights into global-scale biodiversity dynamics during large environmental and anthropogenic changes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 87
    Publication Date: 2024-03-19
    Description: The Qinghai-Tibet Plateau (QTP) is characterized by a vast number of frozen and unfrozen freshwater reservoirs, which is why it is also called “the third pole” of the Earth or “Asian Water Tower”. We analyzed testate amoeba (TA) biodiversity and corresponding protozoic biosilicification in lake sediments of the QTP in relation to environmental properties (freshwater conditions, elevation, and climate). As TA are known as excellent bio-indicators, our results allowed us to derive conclusions about the influence of climate warming on TA communities and microbial biogeochemical silicon (Si) cycling. We found a total of 113 TA taxa including some rare and one unknown species in the analyzed lake sediments of the QTP highlighting the potential of this remote region for TA biodiversity. 〉1/3 of the identified TA taxa were relatively small (〈30 μm) reflecting the relatively harsh environmental conditions in the examined lakes. TA communities were strongly affected by physico-chemical properties of the lakes, especially water temperature and pH, but also elevation and climate conditions (temperature, precipitation). Our study reveals climate-related changes in TA biodiversity with consequences for protozoic biosilicification. As the warming trend in the QTP is two to three times faster compared to the global average, our results provide not only deeper insights into the relations between TA biodiversity and environmental properties, but also predictions of future developments in other regions of the world. Moreover, our results provide fundamental data for paleolimnological reconstructions. Thus, examining the QTP is helpful to understand microbial biogeochemical Si cycling in the past, present, and future.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 88
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Palaeogeography Palaeoclimatology Palaeoecology, Elsevier, 612, pp. 111380-111380, ISSN: 0031-0182
    Publication Date: 2024-03-19
    Description: Relatively little is known about the relationship between the Indian summer monsoon (ISM) and the El Niño-Southern Oscillation (ENSO) on the centennial timescale during the Holocene. We present a well-dated high-resolution X-ray fluorescence (XRF) scanning record from a sediment core from Lake Qionghai on the southeastern Tibetan Plateau, which reveals the impact of ENSO activity on ISM variability. The results indicate a gradual drying of the regional climate on the sub-orbital timescale, which is in broad agreement with ISM changes controlled by Northern Hemisphere summer insolation. Additionally, centennial-scale drought events occurred at around 6230–5740, 4620–4250, 3820–3540, 3210–2440, 2180–1320, and 1000–615 cal yr B.P. and are consistent with enhanced ENSO activity, documenting the occurrence of ENSO-related drought events in the Holocene. Both ISM oscillations and ENSO variability show significant 350-yr, 500-yr, and 800-yr cyclicities, and there is a highly significant negative relationship between the ISM and ENSO at these cyclicities, indicating that a weak ISM was related to increased ENSO intensity, and vice versa. Our findings provide evidence for the modulation of ISM intensity by ENSO variability on the centennial timescale during the Holocene.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 89
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Ecological Modelling, Elsevier, 478, pp. 110278-110278, ISSN: 0304-3800
    Publication Date: 2024-03-19
    Description: With changing climate, the boreal forest could potentially migrate north and become threatened by droughts in the south. However, whether larches, the dominant tree species in eastern Siberia, can adapt to novel situations is largely unknown but is crucial for predicting future population dynamics. Exploring variable traits and trait adaptation through inheritance in an individual-based model can improve our understanding and help future projections. We updated the individual-based spatially explicit vegetation model LAVESI (Larix Vegetation Simulator), used for forest predictions in Eastern Siberia, with trait value variation and incorporated inheritance of parental values to their offspring. Forcing the model with both past and future climate projections, we simulated two areas – the expanding northern treeline and a southerly area experiencing drought. While the specific trait of ‘seed weight’ regulates migration, the abstract ‘drought resistance’ protects stands. We show that trait variation with inheritance leads to an increase in migration rate (∼ 3% area increase until 2100). The drought resistance simulations show that, under increasing stress, including adaptive traits leads to larger surviving populations (17% of threatened under RCP 4.5 (Representative Concentration Pathway)). We show that with the increase expected under the RCP 8.5 scenario vast areas (80% of the extrapolated area) of larch forest are threatened and could disappear due to drought as adaptation plays only a minor role under strong warming. We conclude that variable traits facilitate the availability of variants under environmental changes. Inheritance allows populations to adapt to environments and promote successful traits, which leads to populations that can spread faster and be more resilient, provided the changes are not too drastic in both time and magnitude. We show that trait variation and inheritance contribute to more accurate models that can improve our understanding of responses of boreal forests to global change.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 90
    Publication Date: 2024-03-19
    Description: Using pollen analysis and metabarcoding of plant sedimentary ancient DNA (sedaDNa), we infer the floristic diversity in the vicinity of Lake Balyktukel, Ulagan Plateau, the Altai Mountains, over the last 7 kyr. The SedaDNA method identified 200% more taxa than found by morphological pollen analysis. In particular, it revealed that the dominant tree for the last 7 kyr was Larix rather than Pinus, which was less frequent in the vicinity of Lake Balyktukel. About 7 ka, larch forest mixed with dwarf birch was widespread on the Ulagan Plateau. The period between 5.3 and 3.4 kyr BP was characterized by the maximal spread of larch forest with an understorey cover of Vaccinium vitis-idaea. Pollen-based annual precipitation reconstruction indicates the most humid phase was between 6.95 and 4.3 ka, and generally coincides with maximal phytodiversity. The most bioproductive period of the lake was from 7 to 6 ka. After that, the trophicity of the lake decreased until 4.5 ka. The appearance of Hippuris vulgaris and increase in Ranunculus subgen. Batrachium at about 5.3–5 ka may indicate the extension of shallow-water ecotopes. Between 3.7 and 3.5 ka, the cyanobacterium Anabaena – an indicator of increased organic matter and algal blooms – was widespread. A planktic thermophilic cladoceran Bosmina longirostris appeared after 1.8 ka and colonized the lake, suggesting an increase in lake trophicity. The last 100 years have been characterized by dramatic changes in the cladoceran community reflecting significant warming of climate.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
    Format: application/pdf
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 91
    Publication Date: 2024-03-18
    Description: Plate tectonic processes introduce oceanic crust (as eclogite) into the sources of oceanic island basalts (OIB). The fate of this recycled material in the deep mantle is still poorly understood. Here we present a systematic study of Zn isotopes on well-characterized alkaline basalts (〈5 Ma) from the Madeira Islands in the eastern North Atlantic. Our analyses show that the δ66Zn values of alkaline basalts range from 0.25‰ to 0.34‰, with an average of 0.30 ± 0.05‰ (2SD, N = 15), which is similar to the average of mid-ocean ridge basalts (MORB) (0.28 ± 0.03‰, 2SD), and ∼ 0.14‰ higher than that of the asthenospheric mantle (0.16 ± 0.06‰, 2SD). However, these alkaline basalts have higher Zn/Fe ratios (up to 14.20) than MORB (generally less than 12). Model calculations show that the partial melting of mantle peridotite cannot simultaneously produce the observed MORB-like δ66Zn values and trace element ratios. After excluding the effects of post-eruption alteration, crystal fractionation, and the assimilation of crustal materials during magma upwelling on Zn isotopic compositions of the studied samples, we suggest that the MORB-like δ66Zn values reflect the mixing of peridotite melt and eclogite/pyroxenite-derived melt in the magma source of the Madeira hotspot. This is supported by trace element ratios and radiogenic isotopes, such as high Zn/Fe and Dy/Yb ratios and 206Pb/204Pb values. Our new data provide independent evidence in support of the important role of recycled oceanic crust in the source and generation of alkaline OIBs, and also highlight that such sources are not ubiquitously carbonated.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 92
    Publication Date: 2024-03-18
    Description: Highlights: • Huidobria chilensis is an endemic shrub distributed in the south of the Atacama Desert with a disjunct population at the northern coast. • Population and genetic structure correlate with geographic distance and geological factors. • Rain fall and fog, as well as ground water, must be regarded as important factors for populations at the coast and the Andean valleys, respectively. • A combination of different software tool to analyze GBS data allowed a good understanding of the population structure and genetic diversity. Abstract: Survival in hyperarid deserts is a major challenge for life in general and for plants in particular. The Atacama Desert presents harsh conditions such as limited rainfall, crusted soils, high soil salinity, high altitude, and intense solar radiation. These conditions, together with paleoclimatic variations over the last 10 million years, have influenced the genetic structure and connectivity of plant populations, resulting in a diverse flora with high endemism. However, the diversification of most lineages appears to be relatively recent, in contrast to the reported age of the Atacama Desert and the onset and expansion of hyperarid conditions since the late Oligocene and early Miocene. A prominent exception is Huidobria chilensis (Loasaceae), which is thought to be endemic to the Atacama since the Eocene. However, it is still not understood why this plant has been successful in adapting to the harshening environmental conditions. To investigate its genetic structure in relation to the history of the Atacama Desert, we studied 186 individuals from 11 populations using genotyping-by-sequencing (GBS). A total of nearly 56 k genome-wide single nucleotide polymorphisms (SNPs) were analyzed for population structure and genetic diversity. We identified four genetic clusters corresponding to geographic regions: the coastal region south of Tocopilla, the Cordillera de la Costa around Chañaral, and the Copiapó catchment 1 and 2. Genetic diversity within and between these clusters was analyzed along with rainfall, altitude, and landscape data. Although the genetic data support `isolation by distance’ as a major factor for genetic divergence between populations, the study also reveals the influence of topography on the distribution of H. chilensis and highlights the role of hydrologically connected watersheds and rivers in plant migration and colonization. This shapes the species' evolutionary trajectory and genetic diversity. Understanding these patterns in H chilensis lets one draw general conclusions about adaptation and survival strategies of plants in extreme desert environments such as the Atacama.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 93
    Publication Date: 2024-03-15
    Description: Highlights: • Microphytobenthos contributed to the particulate organic matter in both beaches. • Allochthonous materials provide relevant contributions to the POM in surf zones. • Estuarine subsidies' availability determines changes in consumers' isotopic niches. • Higher estuarine trophic subsidies resulted in narrower niches of dominant species. Abstract: Benthic invertebrates in the surf zone of exposed sandy beaches represent important links for energy circulation between benthic and pelagic food webs. This work assesses the trophic ecology of co-occurring epi- and hyper-benthic invertebrates inhabiting the surf zone of sandy beaches located close to an estuarine mouth. It illustrates that different sources of organic matter induce changes in resource utilization. The trophic positions, and the niche width and overlap of species were described using δ13C and δ15N stable isotope analysis. The contribution of different sources to the particulate organic matter was quantified through stable isotopes analysis and fatty acids profiles. Shifts in the trophic niches of dominant species reflected a decrease in the contribution of estuarine carbon to the diets along the coast. This change in contribution of estuarine carbon also influenced trophic niche properties: more diverse resources availability resulted in narrower niches without overlap while less diverse resources resulted in broad isotopic niches and a highest overlap. Results show that spatial variations in the availability of resources can modify carbon pathways and trophic interactions in coastal food webs. Whenever resources are abundant, species display a more specialized diet while food scarcity leads to broader diets, a pattern consistent with the optimal foraging theory. This resource maximization behavior commonly observed in nature is also occurring in surf zone ecosystems.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 94
    Publication Date: 2024-03-15
    Description: The Amazon and the Pará are two major rivers that carry dissolved and suspended particulate trace metals to the Atlantic Ocean. In the dynamic mixing zone of the estuary, competing processes of trace metal sorption and release play a role, which might affect transport to the open ocean. Here we investigate the behavior of dissolved (〈0.2 μm), soluble (〈0.015 μm) and truly dissolved (〈10 kDa and 〈 1 kDa) molybdenum (Mo), uranium (U), and vanadium (V) during estuarine mixing between river water (S 〈 1) and seawater (S 〉 35) end members during the high discharge period, as well as during aging of the plume in its northward flow along the coast. Molybdenum behaved conservatively during estuarine mixing and showed no colloidal fraction, suggesting Mo is solely present in the soluble or even truly dissolved fraction. Uranium behaved mostly conservatively but showed removal in the low salinity range (ca. S 〈 9). This is potentially due to colloidal flocculation at low salinities, as indicated by colloidal (0.015–0.2 μm) fractions of up to 30% for U but decreasing with increasing salinity until no significant difference could be discerned at S 〉 10. Vanadium shows a general conservative mixing, but with more scatter in the data than for Mo and U and potential removal at low to mid-salinities. Removal of V to the sediments is also indicated by surface sediment data from the mid-salinity region of the estuary but no size fractionation in the dissolved phase could be observed. Hence, V seems to be predominantly present in the soluble or even truly dissolved phase and export to the sediments might take place through particles 〉0.2 μm. No considerable removal or release of Mo, U and V was observed in their water column depth profiles, indicating a conservative behavior in the water column of the estuaries studied here. Additionally, we present a comparison of differential pulse adsorptive stripping voltammetry and inductively coupled plasma – mass spectrometry analyses for Mo and V, which showed excellent agreement within analytical uncertainty in this challenging sample material covering the full salinity range from freshwater to seawater.
    Type: Article , PeerReviewed
    Format: text
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 95
    Publication Date: 2024-03-15
    Description: This work introduces a new Ground Motion Model (GMM) to predict the horizontal and vertical components of PGA, PGV and acceleration response spectra up to 5s for the volcanic events in Italy. The model updates the GMM for the horizontal components, recently developed by Lanzano & Luzi [1], and shows relevant amplitudes in near-source and a frequency content richer in intermediate-to-low frequencies. The comparison with an event not used for the calibration and belonging to another volcanic district in Italy is promising for the extension of the model to other areas. Finally, we present a case study of a site, in the proximity of Mount Etna in eastern Sicily region, which allows us to evaluate the impact of these models in the framework of a Probabilistic Seismic Hazard Analysis (PSHA).
    Description: Published
    Description: 108228
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 96
    Publication Date: 2024-03-15
    Description: Volcanic ash cloud detection is a crucial component of volcano monitoring and a valuable tool for investigating ash cloud dispersion, which is paramount for enhancing the safety of human settlements and air traffic. The latest generation of high-resolution satellite sensors (e.g., EUMETSAT MSG Spinning Enhanced Visible and InfraRed Imager, SEVIRI) provides radiometric estimates for monitoring volcanic clouds on a global scale efficiently and timely. However, these radiometric intensities are not always discriminative enough to detect volcanic ash clouds due to the spectral limitations of these instruments and the complex nature of some volcanic clouds, such as low concentration resulting in an averaged detected radiometric estimate comparable to the background. Here, we evaluate the ability of a Convolutional Neural Network (CNN) to detect and track the dispersion of volcanic ash clouds into the atmosphere, exploiting a variety of spatial and spectral intensity information mainly coming from SEVIRI Ash RGB images. We train a deep CNN model through transfer learning, and demonstrate that the trained models overcome the limitations of algorithms based solely on pixel intensity, whether traditional or machine learning, resulting in increased performance compared to other methods. We illustrate the operation of this model using the paroxysmal explosive events that occurred at Mt. Etna between 2020 and 2022.
    Description: Published
    Description: 108046
    Description: OSV3: Sviluppo di nuovi sistemi osservazionali e di analisi ad alta sensibilità
    Description: JCR Journal
    Keywords: Volcano explosive eruptions ; satellite remote sensing ; volcanic ash clouds ; machine learning ; deep learning ; Etna volcano ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 97
    Publication Date: 2024-03-14
    Description: Abundance and composition of beach litter and microplastics (20–5000 μm, excluding fibres) were assessed in spring and autumn 2018 at various beaches along the Baltic Sea coast of Schleswig-Holstein, Northern Germany. The beach litter survey followed the OSPAR guidelines, while microplastics were extracted from sediment samples using density separation and were then identified with Raman μ-spectroscopy. We observed seasonality in the abundance and composition, but not in the mass of beach litter. The median microplastic abundance was 2 particles per 500 g of dry sediment in spring as well as in autumn, while six different synthetic polymers (PE, PP, PS, PET, PVC, POM) were detected. We found no correlation between the abundances of beach litter and microplastics. Our data represent the first systematic co-assessment of macro- and micro beach litter along the Baltic Sea coast of Schleswig-Holstein.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 98
    Publication Date: 2024-03-14
    Description: Marine litter can be found along coasts, continental shelves and slopes, down into the abyss. The absence of light, low temperatures and low energy regimes characterising the deeper habitats ensure the persistence of litter over time. Therefore, manmade items within the deep sea will likely accumulate to increasing quantities. Here we report the litter abundance encountered at the Pacific abyssal nodule fields from the Peru Basin at 4150 m depth. An average density of 2.67 litter items/ha was observed. Litter composed of plastic was the most abundant followed by metal and glass. At least 58 % of the items observed could be linked to the research expeditions conducted in the area and appeared to be mostly accidental disposals from ships. The data gathered was used to address temporal trends in litter abundance as well as the impact of human on-site presence and return cruises in the context of future deep-sea mining efforts.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 99
    Publication Date: 2024-03-14
    Description: In this study we parameterize the textural attributes of plagioclase phenocrysts and microlites from nineteen pyroclasts ejected during mild to violent explosions at Stromboli over a timespan of ∼18 years, from 2003 to 2021. By allying kinetic and crystal size distribution principles, we document that the morphological stability of large-sized, euhedral phenocrysts is superimposed on an internal textural heterogeneity due to growth-dissolution phenomena associated with the input rate of hot, H2O-rich recharge magmas rising from depth. As a result, the volumetric plagioclase proportion, dominant size, and number of phenocrysts per unit volume decrease from mild to violent explosions responding to a more efficient magma mixing process via sustained injections of mafic magmas into the shallow reservoir. On the other hand, the crystallization of anhedral plagioclase microlites is controlled by fast growth kinetics taking place in the uppermost part of the conduit during magma acceleration towards the surface. Under such highly dynamic crystallization conditions, the microlite number density closely depends on the increase of melt liquidus temperature via magma decompression and H2O exsolution. This mutualism allows to model the degassing rate and ascent velocity of magma under open-conduit flow regimes for the different eruptive styles, thereby supporting the idea that violent explosions at Stromboli are driven by sustained influxes of recharge magmas favoring strong acceleration (∼12–27 m/s), decompression (∼0.25–0.49 MPa/s), and H2O exsolution (∼0.005–0.01 wt%/s) before magma discharge at the vent.
    Description: Published
    Description: 107143
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 100
    Publication Date: 2024-03-14
    Description: We present a scenario-based, probabilistic hazard assessment for the San Salvador volcanic complex (SSVC), a volcanic field located in the vicinity of San Salvador that includes the El Boquer´on stratovolcano and 25 monogenetic vents. We define a set of likely eruption scenarios for tephra fallout and pyroclastic density currents (PDCs). The eruption scenarios range from violent Strombolian eruptions with a significant uncertainty in source position to sub-Plinian and Plinian activity fed from the central cone. The adopted methodology is mainly based on numerical modeling using Tephra2 (adopting the software TephraProb) to study tephra fallout and the branching box model and the branching energy cone model (adopting the programs BoxMapProb 2.0 and ECMapProb 2.0) to describe inertial and frictional PDCs, respectively. Despite the dominant W-WSW-trending winds, numerical results show that Plinian eruptions at El Boquer´on volcano are able to deposit thick tephra layers in the metropolitan area of San Salvador city, likely reaching mass loads of the order of 100 kg/m2 (conditional probability of 50%). The simulated sub-Plinian events highlight the seasonal influence of wind patterns. In fact, the conditional probability of significant tephra sedimentation in San Salvador city is strongly reduced when eruptions occur during the rainy season. Numerical modeling of violent Strombolian eruptions is performed considering uncertainty in vent position. Results show that the conditional probability of depositing tephra mass loads higher than 10 kg/m2 at a given point reaches a maximum value of ~7% on the NW flank of the volcano, at about 8 km from the central crater. On the other hand, very low conditional probabilities (〈1%) are obtained for San Salvador city for any relevant threshold (10 kg/m2 or more) of tephra mass load during violent Strombolian events. Regarding PDCs, results show that those produced during large-scale Plinian eruptions are able to invade significant areas of the volcano surroundings, including San Salvador city. PDCs generated from the partial collapse of a sub-Plinian eruption column exhibit maximum inundation probabilities on the N, W and S flanks of the volcano. Cerro El Picacho exerts a significant shield effect on the propagation of these PDCs, with low inundation probabilities for San Salvador city (〈3%). Finally, coupling published vent opening probability maps and numerical modeling of small-scale PDCs yields maximum inundation probabilities on the NW flank of the volcano, reaching maximum conditional probabilities of the order of ~10% and values of about 5% near the village of Nuevo Sitio del Nino.
    Description: Published
    Description: 107809
    Description: OSV1: Verso la previsione dei fenomeni vulcanici pericolosi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...