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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
  • 04.03. Geodesy
  • 1
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    Static vs Real-Time Coseismic Offset Comparison: The test case of 30 October, 2016 Central Italy earthquake (2018)
    AUTh - School of Rural and Surveying Engineering
    Details
    Publication Date: 2020-12-15
    Description: The knowledge of coseismic deformations due to earthquakes represents the fundamentals on which studies on seismic cycle and fault source mechanism are based on. Geodetic methods, in particular the recent developments of GNSS monitoring, are the only onescapable of providing the displacements of reference sites due to the occurrence of significant seismic events. Usually the detection of seismic offsets is done by comparing coordinates estimated before and after the earthquake. Here, considering the test case of the 30 October, 2016 central Italy seismic event, we show that it is possible to achieve such offsets also in real-time through the application of the new functionalities of the VADASE (Variometric Approach for Displacements Analysis Stand-alone Engine) approach. The comparison between the seismic offsets coming from the two approaches (static and realtime) is shown and discussed; the mean overall agreement is at the level of about half centimetre.
    Description: Published
    Description: 189-198
    Description: 2T. Deformazione crostale attiva
    Keywords: Coseismic Offset ; VADASE ; Tectonic deformation ; Central Italy 2016 earthquakes ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 2
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    Carbon dioxide degassing and thermal energy release in the Monte Amiata volcanic-geothermal area (Italy) (2010)
    Elsevier
    Details
    Publication Date: 2021-01-07
    Description: The quaternary volcanic complex of Mount Amiata is located in southern Tuscany (Italy) and represents the most recent manifestation of the Tuscan Magmatic Province. The region is characterised by a large thermal anomaly and by the presence of numerous CO2-rich gas emissions and geothermal features, mainly located at the periphery of the volcanic complex. Two geothermal systems are located, at increasing depths, in the carbonate and metamorphic formations beneath the volcanic complex. The shallow volcanic aquifer is separated from the deep geothermal systems by a low permeability unit (Ligurian Unit). A measured CO2 discharge through soils of 1.8 109 mol a 1 shows that large amounts of CO2 move from the deep reservoir to the surface. A large range in d13CTDIC ( 21.07 to +3.65) characterises the waters circulating in the aquifers of the region and the mass and isotopic balance of TDIC allows distinguishing a discharge of 0.3 109 mol a 1 of deeply sourced CO2 in spring waters. The total natural CO2 discharge (2.1 109 mol a 1) is slightly less than minimum CO2 output estimated by an indirect method (2.8 109 mol a 1), but present-day release of 5.8 109 mol a 1 CO2 from deep geothermal wells may have reduced natural CO2 discharge. The heat transported by groundwater, computed considering the increase in temperature from the infiltration area to the discharge from springs, is of the same order of magnitude, or higher, than the regional conductive heat flow (〉200 mWm 2) and reaches extremely high values (up to 2700mWm 2) in the north-eastern part of the study area. Heat transfer occurs mainly by conductive heating in the volcanic aquifer and by uprising gas and vapor along fault zones and in those areas where low permeability cover is lacking. The comparison of CO2 flux, heat flow and geological setting shows that near surface geology and hydrogeological setting play a central role in determining CO2 degassing and heat transfer patterns.
    Description: Published
    Description: 860–875
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide degassing ; Monte Amiata ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
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    Strain Pattern and Kinematics of the Canary Islands from GNSS Time Series Analysis (2021)
    MDPI
    Details
    Publication Date: 2021-01-04
    Description: Following the 2004 seismic unrest at Tenerife and the 2011–2012 submarine eruption at El Hierro, the number of Global Navigation Satellite System (GNSS) observation sites in the Canary Islands (Spain) has increased, offering scientists a useful tool with which to infer the kinematics and present-day surface deformation of the Canary sector of the Atlantic Ocean. We take advantage of the common-mode component filtering technique to improve the signal-to-noise ratio of the velocities retrieved from the daily solutions of 18 permanent GNSS stations distributed in the Canaries. The analysis of GNSS time series spanning the period 2011–2017 enabled us to characterize major regions of deformation along the archipelago through the mapping of the 2D infinitesimal strain field. By applying the triangular segmentation approach to GNSS velocities, we unveil a variable kinematic behaviour within the islands. The retrieved extension pattern shows areas of maximum deformation west of Tenerife, Gran Canaria and Fuerteventura. For the submarine main seismogenic fault between Tenerife and Gran Canaria, we simulated the horizontal deformation and strain due to one of the strongest (mbLg 5.2) earthquakes of the region. The seismic areas between islands, mainly offshore Tenerife and Gran Canaria, seem mainly influenced by the regional tectonic stress, not the local volcanic activity. In addition, the analysis of the maximum shear strain confirms that the regional stress field influences the E–W and NE–SW tectonic lineaments, which, in accordance with the extensional and compressional tectonic regimes identified, might favour episodes of volcanism in the Canary Islands.
    Description: Published
    Description: 3297
    Description: 2T. Deformazione crostale attiva
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: GNSS time series ; kinematics and ground deformation ; Canary Islands ; 04.02. Exploration geophysics ; 04.03. Geodesy ; 04.07. Tectonophysics ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 4
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    The Christmas 2018 Eruption at Mount Etna: Enlightening How the Volcano Factory Works Through a Multiparametric Inspection (2021)
    John Wiley & Sons, Inc
    Details
    Publication Date: 2021-01-07
    Description: The 24–27 December 2018 flank eruption at Mount Etna (Southern Italy) has been investigated through a multidisciplinary approach in which olivine chemical zoning and diffusion chronometry data were integrated with models inferred by GNSS (Global Navigation Satellite System) measurements. Inspection of the olivine chemical zoning from core to rim allowed the identification of some dominant ways of transfer and interaction between magmas pertaining to different magmatic environments. Most of crystal cores are representative of crystallization at pressure of 290–230 and 160–120 MPa. Olivine rims suggest re‐equilibration at shallow pressure (≤30 MPa). Geodetic‐based models indicate pressurization of near‐vertical prolate spheroidal sources centered at ∼7.2 km below sea level (bsl) between 9 June 2017 and 28 June 2018 and later at ∼5.1 km bsl between 28 June 2018 and the eruption onset. Geodetic data also highlight a change in the inflation rate since late June 2018 and later around November 2018, which has been here related to both replenishment phases and magma uprising across the plumbing system. Timescales of magma replenishment are in agreement with prolonged recharge from deep levels upward to shallow environments started about 6 months before the eruption, with further replenishment involving the upper magmatic environments just 3–16 days before the eruption. At present, the eruptive activity at the volcano is primarily controlled by pressure imbalances affecting extensive sections of the plumbing system, with possibility to develop persistent eruptive activity at the summit versus flank eruptions depending on fortuitous interruptions of the steady magma recharge/discharge rate at shallow levels.
    Description: Università di Catania (University of Catania). Grant Numbers: Three Year Plan 2016‐18 project code 22722132140, Three Year Plan 2020‐22 project code 22722132140
    Description: Published
    Description: e2020GC009226
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: plumbing system ; volcano geodesy ; inflation ; eruption ; 04. Solid Earth ; 04.03. Geodesy ; 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 5
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    Geodetic Study of the 2006–2010 Ground Deformation in La Palma (Canary Islands): Observational Results (2021)
    MDPI
    Details
    Publication Date: 2021-01-07
    Description: La Palma is one of the youngest of the Canary Islands, and historically the most active. The recent activity and unrest in the archipelago, the moderate seismicity observed in 2017 and 2018 and the possibility of catastrophic landslides related to the Cumbre Vieja volcano have made it strongly advisable to ensure a realistic knowledge of the background surface deformation on the island. This will then allow any anomalous deformation related to potential volcanic unrest on the island to be detected by monitoring the surface deformation. We describe here the observation results obtained during the 2006–2010 period using geodetic techniques such as Global Navigation Satellite System (GNSS), Advanced Differential Synthetic Aperture Radar Interferometry (A-DInSAR) and microgravimetry. These results show that, although there are no significant associated variations in gravity, there is a clear surface deformation that is spatially and temporally variable. Our results are discussed from the point of view of the unrest and its implications for the definition of an operational geodetic monitoring system for the island
    Description: This research was mainly funded by the Spanish Ministerio de Ciencia, Innovación y Universidades research project DEEP-MAPS, grant agreement number RTI2018-093874-B-I00. It was also partially supported by the CSIC project 201530E019 and the project GEOSIR, grant agreement AYA2010-17448 from the Spanish Ministerio de Ciencia e Innovación.
    Description: Published
    Description: 2566
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: A-DInSAR ; GNSS ; gravimetry ; La Palma ; Canary Islands ; volcanic unrest ; 04. Solid Earth ; 04.03. Geodesy ; 04.02. Exploration geophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
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    Tracing thermal aquifers of El Chichón volcano-hydrothermal system (México) with 87Sr/86Sr, Ca/Sr and REE (2011)
    Elsevier
    Details
    Publication Date: 2020-11-26
    Description: The volcano–hydrothermal system of El Chichón volcano, Chiapas, Mexico, is characterized by numerous thermal manifestations including an acid lake, steam vents and boiling springs in the crater and acid and neutral hot springs and steaming ground on the flanks. Previous research on major element chemistry reveals that thermal waters of El Chichón can be divided in two groups: (1) neutral waters discharging in the crater and southern slopes of the volcano with chloride content ranging from 1500 to 2200 mg/l and (2) acid-toneutral waters with Cl up to 12,000 mg/l discharging at the western slopes. Our work supports the concept that each group of waters is derived from a separate aquifer (Aq. 1 and Aq. 2). In this study we apply Sr isotopes, Ca/Sr ratios and REE abundances along with the major and trace element water chemistry in order to discriminate and characterize these two aquifers. Waters derived from Aq. 1 are characterized by 87Sr/86Sr ratios ranging from 0.70407 to 0.70419, while Sr concentrations range from 0.1 to 4 mg/l and Ca/Sr weight ratios from 90 to 180, close to average values for the erupted rocks. Waters derived from Aq. 2 have 87Sr/86Sr between 0.70531 and 0.70542, high Sr concentrations up to 80 mg/l, and Ca/Sr ratio of 17–28. Aquifer 1 is most probably shallow, composed of volcanic rocks and situated beneath the crater, within the volcano edifice. Aquifer 2 may be situated at greater depth in sedimentary rocks and by some way connected to the regional oil-gas field brines. The relative water output (l/s) from both aquifers can be estimated as Aq. 1/Aq. 2– 30. Both aquifers are not distinguishable by their REE patterns. The total concentration of REE, however, strongly depends on the acidity. All neutral waters including high-salinity waters from Aq. 2 have very low total REE concentrations (b0.6 μg/l) and are characterized by a depletion in LREE relative to El Chichón volcanic rock, while acid waters from the crater lake (Aq. 1) and acid AS springs (Aq. 2) have parallel profile with total REE concentration from 9 to 98 μg/l. The highest REE concentration (207 μg/l) is observed in slightly acid shallow cold Ca-SO4 ground waters draining fresh and old pyroclastic deposits rich in magmatic anhydrite. It is suggested that the main mechanism controlling the concentration of REE in waters of El Chichón is the acidity. As low pH results from the shallow oxidation of H2S contained in hydrothermal vapors, REE distribution in thermal waters reflects the dissolution of volcanic rocks close to the surface or lake sediments as is the case for the crater lake.
    Description: -
    Description: Published
    Description: 55-66
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrogeochemistry ; geothermal systems ; Sr isotopes ; REE ; El Chichón Volcano ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
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    Geochemistry of groundwater from Graciosa Island (Azores): A contribution to the hydrothermal system conceptual model (2012)
    Mineralogical Magazine
    Details
    Publication Date: 2021-01-27
    Description: Graciosa island is located in the Azores Archipelago, along the so-called Terceira Rift, a major tectonic structure that makes the NE boundary of the Azores Plateau. In general terms, it includes a basaltic plataform on the NW and a silicic poligenetic volcano with caldera on the SE, the Graciosa Caldera Volcano. This volcano has produced significant tephra falls, pyroclastic flows, lahars, and lava flows, both of basaltic s.l. and trachitic s.l. composition. The hydrothermal system shows fumarolic emissions inside the volcano caldera and thermal springs located along the shoreline. This system is exploitated in a thermal building through shallow and deep (110 m) boreholes, near the coast. In Graciosa two types of Na-Cl groundwater systems can be identified: 1) a cold one emerging at springs and exploited by wells for public water supply, and 2) a hydrothermal system with temperatures around 40-44 °C. The cold groundwaters have pH higher than 7 and different degree of mineralization, according to the proximity to the sea. The thermal waters show mixing with seawater, pH varying between 6.20 and 6.94, 166 mg/L of SiO2, and significant concentration of metals, such as Mn, Fe, Co, Ni, Cu and Zn. The thermal water mineralization varies strongly, showing EC from 8.87 mS/cm (shallow water) to 47.4 mS/cm (deeper water). The higher mineralized water is rich in CO2(g), with 2130 mg/L of total dissolved CO2. Geothermometers application reveals aquifer temperature around 167 °C and immature/mixed waters, not reaching complete equilibrium with reservoir rock. The geochemistry of the thermal waters indicates the occurrence of seawater/host rock interaction processes at high temperature and slightly acid conditions, favored by CO2(g) input, and a different degrees of mixing with cold and shallow groundwaters.
    Description: Published
    Description: Prague, Czech Republic
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Hydrothermal systems ; Graciosa Island, Azores ; Grondwater chemistry ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 8
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    New Insights into Long-Term Aseismic Deformation and Regional Strain Rates from GNSS Data Inversion: The Case of the Pollino and Castrovillari Faults (2021)
    MDPI
    Details
    Publication Date: 2021-01-07
    Description: We present a novel inverse method for discriminating regional deformation and long-term fault creep by inversion of GNSS velocities observed at the spatial scale of intraplate faults by exploiting the different spatial signatures of these two mechanisms. In doing so our method provides a refined estimate of the upper bound of the strain accumulation process. As case study, we apply this method to a six year GNSS campaign (2003–2008) set up in the southern portion of the Pollino Range over the Castrovillari and Pollino faults. We show that regional deformation alone cannot explain the observed deformation pattern and implies high geodetic strain rate, with a WSW-ENE extension of 86±41×10−9/yr. Allowing for the possibility of fault creep, the modelling of GNSS velocities is consistent with their uncertainties and they are mainly explained by a shallow creep over the Pollino fault, with a normal/strike-slip mechanism up to 5 mm/yr. The regional strain rate decrease by about 70 percent and is characterized by WNW-ESE extension of 24±28×10−9/yr. The large uncertainties affecting our estimate of regional strain rate do not allow infering whether the tectonic regime of the area is extensional or strike-slip, although the latter is slightly more likely
    Description: Published
    Description: 2921
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: regional deformation ; fault creep ; GNSS velocities ; inverse theory ; 04. Solid Earth ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
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    Crustal deformation, active tectonics and seismic potential in the Sicily Channel (Central Mediterranean), along the Nubia-Eurasia plate boundary (2021)
    Nature P.G.
    Details
    Publication Date: 2021-01-07
    Description: Based on multidisciplinary data, including seismological and geodetic observations, as well as seismic reflection profiles and gravity maps, we analysed the pattern of crustal deformation and active tectonics in the Sicily Channel, a key observation point to unravel the complex interaction between two major plates, Nubia and Eurasia, in the Mediterranean Sea. Our data highlight the presence of an active ~ 220-km-long complex lithospheric fault system (here named the Lampedusa-Sciacca Shear Zone), approximately oriented N-S, crossing the study area with left-lateral strike-slip deformations, active volcanism and high heat flow. We suggest that this shear zone represents the most active tectonic domain in the area, while the NW-SE elongated rifting pattern, considered the first order tectonic feature, appears currently inactive and sealed by undeformed recent (Lower Pleistocene?) deposits. Estimates of seismological and geodetic moment-rates, 6.58 × 1015 Nm/year and 7.24 × 1017 Nm/year, respectively, suggests that seismicity accounts only for ~ 0.9% of crustal deformation, while the anomalous thermal state and the low thickness of the crust would significantly inhibit frictional sliding in favour of creeping and aseismic deformation. We therefore conclude that a significant amount of the estimated crustal deformation-rate occurs aseismically, opening new scenarios for seismic risk assessments in the region.
    Description: Published
    Description: 21238
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.02. Exploration geophysics ; 04.03. Geodesy ; 04.06. Seismology
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  • 10
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    Four Years of Continuous Seafloor Displacement Measurements in the Campi Flegrei Caldera (2021)
    Frontiers
    Details
    Publication Date: 2021-01-05
    Description: We present 4 years of continuous seafloor deformation measurements carried out in the Campi Flegrei caldera (Southern Italy), one of the most hazardous and populated volcanic areas in the world. The seafloor sector of the caldera has been monitored since early 2016 by the MEDUSA marine research infrastructure, consisting of four instrumented buoys installed where sea depth is less than 100 m. Each MEDUSA buoy is equipped with a cabled, seafloor module with geophysical and oceanographic sensors and a subaerial GPS station providing seafloor deformation and other environmental measures. Since April 2016, the GPS vertical displacements at the four buoys show a continuous uplift of the seafloor with cumulative measured uplift ranging between 8 and 20 cm. Despite the data being affected by environmental noise associated with sea and meteorological conditions, the horizontal GPS displacements on the buoys show a trend coherent with a radial deformation pattern. We use jointly the GPS horizontal and vertical velocities of seafloor and on-land deformations for modeling the volcanic source, finding that a spherical source fits best the GPS data. The geodetic data produced by MEDUSA has now been integrated with the data flow of other monitoring networks deployed on land at Campi Flegrei.
    Description: Published
    Description: 615178
    Description: 4V. Processi pre-eruttivi
    Description: JCR Journal
    Keywords: Seafloor geodesy, volcanic caldera ; 04.08. Volcanology ; 04.03. Geodesy ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
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    A deformation study of Anthemountas graben (northern Greece) based on in situ data and new InSAR results (2021)
    Springer
    Details
    Publication Date: 2021-05-12
    Description: The focus of this study is Anthemountas basin in northern Greece, where land subsidence phenomena had been previously identified. The basin has a NNW-SSE orientation, which is optimal to the currently acting ~ N-S extension field in the back-arc Aegean area and is bordered to its north and south edge by two, well-pronounced faults. The region of study is located close to the greater metropolitan city of Thessaloniki and comprises a number of critical facilities including the city’s international airport. The research object is the monitoring of the evolution of the displacement at Anthemountas graben, using InSAR time-series and the investigation of the dominant driving mechanism. We show new surface displacement results from the ENVISAR satellite, and overall, an enhanced dataset of SAR time-series is presented, spanning the period 1992 to 2010, by using the satellites ERS1, ERS2 and ENVISAT. Results indicate a continuously deforming environment in both decades, with an increasing magnitude. The detailed study of the deformation pattern together with the analysis of in situ data defines aquifer overpumping as the main cause of the detected displacement of both decades. Critical regions are examined in detail, as for example: an area close to Thermi, the town of Perea and the Thessaloniki’s international airport, a major hub of the Balkans. The latter was subjected to an increasing deforming velocity during the monitoring period. Overall, we conclude that a water management plan should be of high priority for the area.
    Description: Published
    Description: 518
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Aquifer activity ; InSAR time-series ; 04.03. Geodesy ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
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    The structure of a hydrothermal system from an integrated geochemical, geophysical, and geological approach: The Ischia Island case study (2011)
    AGU Geochemical Society
    Details
    Publication Date: 2020-11-26
    Description: The complexity of volcano-hosted hydrothermal systems is such that thorough characterization requires extensive and interdisciplinary work. We use here an integrated multidisciplinary approach, combining geological investigations with hydrogeochemical and soil degassing prospecting, and resistivity surveys, to provide a comprehensive characterization of the shallow structure of the southwestern Ischia's hydrothermal system. We show that the investigated area is characterized by a structural setting that, although very complex, can be schematized in three sectors, namely, the extra caldera sector (ECS), caldera floor sector (CFS), and resurgent caldera sector (RCS). This contrasted structural setting governs fluid circulation. Geochemical prospecting shows, in fact, that the caldera floor sector, a structural and topographic low, is the area where CO2-rich (〉40 cm3/l) hydrothermally mature (log Mg/Na ratios 〈 −3) waters, of prevalently meteoric origin (δ18O 〈 −5.5‰), preferentially flow and accumulate. This pervasive hydrothermal circulation within the caldera floor sector, being also the source of significant CO2 soil degassing (〉150 g m−2 d−1), is clearly captured by electrical resistivity tomography (ERT) and transient electromagnetic (TEM) surveys as a highly conductive (resistivity 〈 3 Ω·m) layer from depths of ~100 m, and therefore within the Mount Epomeo Green Tuff (MEGT) formation. Our observations indicate, instead, that less-thermalized fluids prevail in the extra caldera and resurgent caldera sectors, where highly conductive seawater-like (total dissolved solid, TDS 〉 10,000 mg/l) and poorly conductive meteoric-derived (TDS 〈 4,000 mg/l) waters are observed, respectively. We finally integrate our observations to build a general model for fluid circulation in the shallowest (〈0.5 km) part of Ischia's hydrothermal system.
    Description: Published
    Description: Q07017
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: restricted
    Keywords: ERT ; TEM ; Ischia ; fluid geochemistry ; hydrothermal systems ; resurgent caldera ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
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    Insights into the fragmentation of the Adria Plate (2018)
    Details
    Publication Date: 2020-11-30
    Description: This study gives an interpretation of the current tectonics and kinematics of the Adria Plate, a region mostly coinciding with Italy and its surroundings. We have examined the spatial distribution and kinematics of seismicity by using an updated dataset obtained integrating the available catalogues of earthquakes and focal mechanisms. Moreover, to highlight the distribution of seismicity and of the asso- ciated strain patterns, we have elaborated a seismic flux map of the Italian region, which is a map of the energy released per unit time and per unit area. Seismic flux represents the energy released and provides a synthetic and continuous view of areas with greater seismicity and associated strain patterns with respect to the plot of earthquakes only. The seismic data, and the results of some elaborations car- ried out using these datasets have been compared with the present-day state of stress and slip rates of the major active faults of some sectors of Italy, as well as with the horizontal kinematics highlighted by GPS observations. The distribution and kinematics of earthquakes and active faults, the seismic flux, and GPS velocities, suggest that the Adria Plate is currently behaving as an ensemble of independent blocks rather than as a unique rigid plate. The Adria Plate can be thus subdivided into three major blocks and a number of smaller blocks moving independently under the action of a first-order mechanism related to the ongoing, roughly N-S, Europe-Africa convergence vector. This complicated setting may promote the occurrence of mutual relationships between blocks, and generate peculiar local kinematics causing seis- mic activity. We infer that the great majority of the seismic events occur at the boundaries of the main or minor blocks, and therefore the alignments of seismicity allows the individuation of the different blocks and the main seismogenic belts. A major crustal structure subdivides the Adria Plate into a western and two eastern blocks, and approximately coincides with the axial zone of the Apennines along which most of the seismicity is concentrated.
    Description: Published
    Description: 121-138
    Description: 1T. Deformazione crostale attiva
    Description: 1IT. Reti di monitoraggio
    Description: 4IT. Banche dati
    Description: JCR Journal
    Keywords: Adria plate ; Apennines ; Active tectonics ; Seismicity ; Seismic flux ; GPS ; 04.06. Seismology ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
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    Combined Seismic and Geodetic Analysis Before, During, and After the 2018 Mount Etna Eruption (2021)
    Wiley Agu
    Details
    Publication Date: 2021-01-05
    Description: In December 2018, Etna volcano experienced one of the largest episodes of unrest since the installation of geophysical monitoring networks in 1970. The unrest culminated in a short eruption with a small volume of lava erupted, a significant seismic crisis and deformation of the entire volcanic edifice of magnitude never recorded before at Mount Etna. Here we describe the evolution of the 2018 eruptive cycle from the analysis of seismic and geodetic data collected in the months preceding, during, and following the intrusion. We model the space‐time evolution of high‐rate deformation data starting from the active source previously identified from deformation data and the propagation of seismicity in a 3‐D velocity model. The intrusion model suggests emplacement of two dikes: a smaller dike located beneath the eruptive fissure and a second, deeper dike between 1 and 5 kmbelow sea level that opened ~2 m. The rise and eruption of magma from the shallower dike did not interrupt the pressurization of a long‐lasting deeper reservoir (~6 km) that induced continuous inflation and intense deformation of the eastern flank. Shortly after the intrusion, on 26 December 2018, aML4.8 earthquake occurred near Pisano, destroying buildings and roads in two villages. We propose a time‐dependent intrusion model that supports the hypothesis of the inflation inducing flank deformation and that this process has been active since September 2018.
    Description: Published
    Description: e2020GC009218
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 2018 Mount Etna Eruption, time‐dependent intrusion model, modelling of high‐rate deformations ; 04.08. Volcanology ; 04.03. Geodesy ; 04.06. Seismology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
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    Geodetic Deformation versus Seismic Crustal Moment-Rates: Insights from the Ibero-Maghrebian Region (2021)
    MDPI
    Details
    Publication Date: 2021-01-07
    Description: Seismic and geodetic moment-rate comparisons can reveal regions with unexpected potential seismic hazards. We performed such a comparison for the Southeastern Iberia—Maghreb region. Located at the western Mediterranean border along the Eurasia–Nubia plate convergence, the region has been subject to a number of large earthquakes (M ≥ 6.5) in the last millennium. To this end, on the basis of available geological, tectonic, and seismological data, we divided the study area into twenty-five seismogenic source zones. Many of these seismogenic source zones, comprising the Western Betics, the Western Rif mountains, and the High, Middle, and Saharan Atlas, are characterized by seismic/geodetic ratio values lower than 23%, evidencing their prevailing aseismic behavior. Intermediate seismic/geodetic ratio values (between 35% and 60%) have been observed for some zones belonging to the Eastern Betics, the central Rif, and the Middle Atlas, indicating how crustal seismicity accounts only for a moderate fraction of the total deformation-rate budget. High seismic/geodetic ratio values (〉 95%) have been observed along the Tell Atlas, highlighting a fully seismic deformation.
    Description: The research performed in this study was partially supported by the Spanish CGL2015-65602-R, CGL2016-80687-R and RTI2018-093874-B-100 projects, and the Programa Operativo FEDER Andalucía 2014-2020 – call made by the University of Jaén 2018.
    Description: Published
    Description: 952
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: earthquake catalogs ; seismic/aseismic behavior ; GNSS ; earthquake hazards ; Eurasia-Nubia plate ; 04. Solid Earth ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 16
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    Use of CORS Time Series for Geodynamics Applications in Western Sicily (Italy) (2021)
    Springer
    Details
    Publication Date: 2021-01-05
    Description: In the last few decades, the use of GNSS Continuously Operating Reference Station (CORS) networks allowed improving the accuracy of realtime positioning and post-processing positioning. In this way, several applications have been performed including remote sensing, agriculture, cultural heritage and geodynamics studies. The latter have been developed analysing CORS time-series and consistent data over long periods were needed to validate the results. In Italy, specifically in Sicily, two CORS networks were be used to monitor the geodynamics motions: the Istituto Nazionale di Geofisica e Vulcanologia (INGV) GNSS CORS network in the eastern part and the University of Palermo (UNIPA) GNSS CORS network in the western part. In this research, preliminary results of time series about geodynamics motions of the western part of Sicily have been presented. In particular, the time series of the UNIPA GNSS CORS network have been analyzed over time by using the static positioning, over a period of approximately 5 years. Results showed a linear trend for all CORS time series, according to literature. An innovative methodology, the static Precise Point Positioning (PPP) has been also tested, to determine the time series of one CORS and compare the results with the static solution. The comparison between the two methodologies (static and PPP) demonstrated the capabilities of PPP technique with benefits in terms of costs and time.
    Description: Published
    Description: 61-76
    Description: 2T. Deformazione crostale attiva
    Keywords: GNSS time series analysis ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 17
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    Chemical and isotopical characterisation of fluid manifestations of Ischia Island (Italy) (2021)
    Elsevier Science Limited
    Details
    Publication Date: 2021-03-01
    Description: Between 1994 and 1995, gas samples from fumaroles and thermal waters were collected on Ischia Island. The chemical composition of the shallow and deep natural hydrothermal fluids discharged is related to the main hydrological and lithological characteristics of the rock formations present in the reservoir. A biphase reservoir (liquid 1 gas) is identified, where the dominant liquid has a temperature of about 2808C. On the basis of d 13CTDC values it was possible to hypothesize a deep source characterised by carbon isotopic values varying from 0 to 23d‰. These values are noticeably more positive with respect to those attributed to magmatic CO2 d13CCO2 ranging from 25 to 28d ‰), thus suggesting a magmatic source modified by crustal contamination. This hypothesis is supported by the carbon isotopic composition of CO2 in sampled gases, which varied from 0 to 25d‰. The inferred isotopic value of carbon of magmatic CO2 would then be about 22d‰. The observed differences in C isotopic composition between fumarolic and magmatic gases would be caused by kinetic and/or equilibrium fractionation processes. These processes would cause a fractionation of d 13C of deep CO2 towards more negative values (down to 25‰). Actually, CO2 removal or addition processes caused by the interaction between deep gases and shallow hydrothermal waters are likely to be responsible for the different chemical and isotopic compositions of gaseous emissions. For these reasons, and on the basis of the homogeneity of geothermometric values, the existence of a single, large reservoir that feeds all of the fluids discharged at Ischia Island can be hypothesised. Based on acquired data, a new geochemical model of the geothermal system of Ischia Island is proposed.
    Description: Published
    Description: 151-178
    Description: 6V. Pericolosità vulcanica e contributi alla stima del rischio
    Description: JCR Journal
    Keywords: gas thermometers; water geothermometer; dissolved gases; geothermal system; Ischia Island ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 18
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    Degassing pathways through the shallow magmatic-hydrothermal system of Poás (2010)
    Details
    Publication Date: 2021-06-21
    Description: We report results from a multidisciplinary campaign carried out at Poás crater-lake (Costa Rica) on 17-18 March 2009. Thermal imagery of fumaroles on the north side of the dome and the lake surface revealed mean apparent temperatures of 25-40°C (maximum of 80°C), and 30-35°C (maximum of 48°C), respectively. Mean radiative heat output of the lake, uncorrected for downwelling flux, was estimated as ~230 MW. The mean SO2 flux emitted by the crater measured by walking-traverses was 76 tonnes day-1, with approximately equal contributions from both the dome and the lake and fumarole plumes. Gas measurements by active open-path FTIR spectroscopy indicated molar ratios of H2O/SO2 = 151 and CO2/SO2 = 1.56. HCl and HF were not detected in measured spectra but based on the detection limits of these species, we calculate SO2/HCl 〉 40, and SO2/HF 〉 200. Particles were sampled from the plume by air filtration. The filters were analysed using ion chromatography, which revealed an abundance of K+ and SO42-, with smaller amounts of Ca2+, Mg2+ and Cl-. We discuss here the implications of the results for degassing pathways through the shallow magmatic-hydrothermal system.
    Description: Published
    Description: San Francisco, USA
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: open
    Keywords: Thermal imagery, SO2 flux traverses, FTIR measurements, Particle composition, ; Poás volcano ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 19
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    Il Monitoraggio dei Vulcani Campani - Primo semestre 2019 (2021)
    Details
    Publication Date: 2021-05-12
    Description: L'Istituto Nazionale di Geofisica e Vulcanologia (INGV) è componente del Servizio Nazionale di Protezione Civile, ex articolo 6 della legge 24 febbraio 1992 n. 225 ed è Centro di Competenza per i fenomeni sismici, vulcanici e i maremoti per il Dipartimento della Protezione Civile Nazionale (DPC). L’Osservatorio Vesuviano, Sezione di Napoli dell’INGV, ha nei suoi compiti il monitoraggio e la sorveglianza H24/7 delle aree vulcaniche attive campane (Vesuvio, Campi Flegrei e Ischia). Tali attività sono disciplinate dall’Accordo-Quadro (AQ) sottoscritto tra il DPC e l’INGV per il decennio 2012-2021 e sono dettagliate negli Allegati A e B del suddetto AQ. Il presente Rapporto sul Monitoraggio dei Vulcani Campani rappresenta l’attività svolta dall’Osservatorio Vesuviano e dalle altre Sezioni INGV impegnate nel monitoraggio dell’area vulcanica campana nel primo semestre 2019.
    Description: Istituto Nazionale di Geofisica e Vulcanologia
    Description: Unpublished
    Description: 4V. Processi pre-eruttivi
    Description: 6SR VULCANI – Servizi e ricerca per la società
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Keywords: Campi Flegrei ; Vesuvio ; Ischia ; Volcano Monitoring ; 04.06. Seismology ; 04.03. Geodesy ; 04.08. Volcanology ; 05.04. Instrumentation and techniques of general interest
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: report
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  • 20
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    Magma-derived gas influx and water-rock interactions in the volcanic aquifer of Mt. Vesuvius, Italy (2005)
    Elsevier
    Details
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 21
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    The importance of multi-parametric analysis in long- term submarine gas emission monitoring: the SN4 ob- servatory at the North Anatolian Fault (Marmara Sea, Turkey) (2016)
    Details
    Publication Date: 2021-06-07
    Description: Methane-rich fluid vents have been widely observed and associated to active faults in the Sea of Marmara, along the submerged portion of the North Ana- tolian Fault (NAF). Episodic gas seepage also occurs in the Izmit Gulf, along the NAF segment that ruptured during the 1999 Izmit earthquake. This site is thus a unique area to test the hypothesis on the relation between strike-slip deforma- tion, seismic activity and gas expulsion within an active fault zone. A long-term multi-parametric experiment can be an effective way to study the irregular dy- namics of gas emission from seafloor and to understand its possible relation with seismic activity. A benthic seafloor observatory (SN-4) was deployed in the Izmit Gulf in 2009 using the R/V Urania as a demonstration mission in the framework of the EC ES- ONET (European Seas Observatory NETwork) project. Instrumental redundancy and specific cross-correlation of data from different sensors, proves to be funda- mental to distinguish actual seepage events from other signals related to ocean- ographic behaviour or even sensor biases. The observatory was equipped with a three component broad-band seismometer, a CTD with turbidity meter, two methane detectors, an oxygen sensor and a current-meter. All sensors installed on the observatory were managed by dedicated low-power electronics, which can manage a wide set of data streams with quite different sampling rates. A unique reference time, set by a central high-precision clock, is used to tag each datum. After six months of continuous monitoring, SN-4 was recovered in March 2010 in order to download the data and replace the batteries for a further six month mission period and finally recovered in October 2010. The data analysis clearly shows frequent degassing events, recorded as methane anomalies in seawater and as high-frequency short-duration signals recorded by the seismometer.. The time series of other oceanographic parameters (tempera- ture, oxygen concentration, turbidity and salinity) shows patterns that seem to be linked to both local gas seepage and to the circulation of water masses in the Gulf of Izmit. A comparative analysis of the various observables and their mutual correlation, can be a key tool to understand actual degassing events along the NAF. This analysis is first attempt in finding possible correlations be
    Description: Published
    Description: Cadiz, Spain
    Description: 3A. Ambiente Marino
    Description: restricted
    Keywords: seafloor observatory ; methane seepage ; multi-parametric ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 22
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    Present-day uplift of the European Alps: Evaluating mechanisms and models of their relative contributions (2020)
    Elsevier
    Details
    Publication Date: 2021-06-25
    Description: Recent measurements of surface vertical displacements of the European Alps show a correlation between vertical velocities and topographic features, with widespread uplift at rates of up to ~2–2.5 mm/a in the North-Western and Central Alps, and ~1 mm/a across a continuous region from the Eastern to the South-Western Alps. Such a rock uplift rate pattern is at odds with the horizontal velocity eld, characterized by shortening and crustal thickening in the Eastern Alps and very limited deformation in the Central and Western Alps. Proposed me- chanisms of rock uplift rate include isostatic response to the last deglaciation, long-term erosion, detachment of the Western Alpine slab, as well as lithospheric and surface de ection due to mantle convection. Here, we assess previous work and present new estimates of the contributions from these mechanisms. Given the large range of model estimates, the isostatic adjustment to deglaciation and erosion are su cient to explain the full observed rate of uplift in the Eastern Alps, which, if correct, would preclude a contribution from horizontal shortening and crustal thickening. Alternatively, uplift is a partitioned response to a range of mechanisms. In the Central and Western Alps, the lithospheric adjustment to deglaciation and erosion likely accounts for roughly half of the rock uplift rate, which points to a noticeable contribution by mantle-related processes such as detachment of the European slab and/or asthenospheric upwelling. While it is di cult to independently constrain the patterns and magnitude of mantle contributions to ongoing Alpine vertical displacements at present, future data should provide additional insights. Regardless, interacting tectonic and surface mass redistribution processes, rather than an individual forcing, best explain ongoing Alpine elevation changes.
    Description: Published
    Description: 589-604
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.03. Geodesy ; 04.07. Tectonophysics
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  • 23
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    Changes in prokaryotic community composition accompanying a pronounced temperature shift of a shallow marine thermal brine pool (Panarea Island, Italy) (2015)
    Springer Verlag Tokyo
    Details
    Publication Date: 2021-07-13
    Description: Hot Lake is a recently described thermal brine pool off Panarea Island (Eolian Islands, Italy) where emitted fluids are highly saline and rich in CO2 and H2S. The prokaryotic community composition in surface sediment samples was analyzed by high-throughput Illumina sequencing targeting the V3 region of the 16S rRNA at two time points that differed mainly with respect to temperature conditions, high-temperature (94 °C, HT09) and low-temperature (28.5 °C, LT10). Bacterial richness and diversity were greater than those of Archaea under both temperature conditions. In contrast to Bacteria, diversity and evenness of Archaea greatly increased at LT10. While the phylogenetic analysis indicated the presence of members mostly affiliated with the same taxonomic groups, their relative abundances differed from HT09 to LT10, resulting in different bacterial and archaeal assemblages. Both HT09 and LT10 were dominated by members of the Epsilonproteobacteria. Within this subphylum, bacteria of the genus Sulfurimonas were most frequently detected at HT09, while Arcobacter prevailed at LT10. The abundance of other dominant taxonomic groups (≥1 % of Illumina reads) also correlated with temperature conditions. Members assigned to hyperthermophilic Euryarchaeota (Thermococci) or to thermophilic (Caldiserica) and thermoresistant (Firmicutes) bacterial taxa were dominant at HT09, while those related to non-thermophilic Bacteroidetes, Fusobacteria and Actinobacteria were dominant at LT10. Several, probably photosynthetic, members of the Alphaproteobacteria, Chlorobi, Cyanobacteria and Chloroflexi were recovered under both temperature conditions. The co-occurrence of photosynthetic and chemolithotrophic microorganisms represents a unique feature of shallow vents such as Hot Lake
    Description: Published
    Description: 547-559
    Description: 3A. Ambiente Marino
    Description: JCR Journal
    Description: restricted
    Keywords: Microbial diversity ; Shallow Idrthermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
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    Geochemistry of REE, Zr and Hf in a wide range of pH and water composition: The Nevado del Ruiz volcano-hydrothermal system (Colombia) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2021-07-14
    Description: The geochemical behaviour of Rare Earth Elements, Zr and Hf was investigated in the thermal waters of Nevado del Ruiz volcano system. A wide range of pH, between 1.0 and 8.8, characterizes these fluids. The acidic waters are sulphate dominatedwith different Cl/SO4 ratios. The important role of the pH and the ionic complexes for the distribution of REE, Zr and Hf in the aqueous phase was evidenced. The pH rules the precipitation of authigenic Fe and Al oxyhydroxides producing changes in REE, Zr, Hf amounts and strong anomalies of Cerium. The precipitation of alunite and jarosite removes LREE from the solution, changing the REE distribution in acidic waters. Y–Ho and Zr–Hf (twin pairs) have a different behaviour in strong acidic waterswith respect to the water with pH near-neutral. Yttrium and Ho behave as Zr and Hf in waters with pH near neutral-to-neutral, showing superchondritic ratios. The twin pairs showed to be sensitive to the co-precipitation and/or adsorption onto the surface of authigenic particulate (Fe-, Al-oxyhydroxides), suggesting an enhanced scavenging of Ho and Hf with respect to Y and Zr, leading to superchondritic values. In acidic waters, a different behaviour of twin pairs occurs with chondritic Y/Ho ratios and sub-chondritic Zr/Hf ratios. For the first time, Zr and Hf were investigated in natural acidic fluids to understand the behaviour of these elements in extreme acidic conditions and different major anion chemistry. Zr/Hf molar ratio changes from 4.75 to 49.29 in water with pH b 3.6. In strong acidic waters the fractionation of Zr and Hf was recognized as function of major anion contents (Cl and SO4), suggesting the formation of complexes leading to sub-chondritic Zr/Hf molar ratios.
    Description: Published
    Description: 125–133
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Zirconium ; Hafnium ; Rare earth elements ; Ionic complexes ; Acidic waters ; Fe–Al oxyhydroxides ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
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    New insights into active tectonics and seismogenic potential of the Italian Southern Alps from vertical geodetic velocities (2020)
    Copernicus
    Details
    Publication Date: 2020-09-07
    Description: This study presents and discusses horizontal and vertical geodetic velocities for a low strain rate region of the south Alpine thrust front in northeastern Italy obtained by integrating GPS, interferometric synthetic aperture radar (InSAR) and leveling data. The area is characterized by the presence of subparallel, south-verging thrusts whose seismogenic potential is still poorly known. Horizontal GPS velocities show that this sector of the eastern Southern Alps is undergoing ∼1 mm a−1 of NW–SE shortening associated with the Adria–Eurasia plate convergence, but the horizontal GPS velocity gradient across the mountain front provides limited constraints on the geometry and slip rate of the several subparallel thrusts. In terms of vertical velocities, the three geodetic methods provide consistent results showing a positive velocity gradient, of ∼ 1.5 mm a−1, across the mountain front, which can hardly be explained solely by isostatic processes. We developed an interseismic dislocation model whose geometry is constrained by available subsurface geological reconstructions and instrumental seismicity. While a fraction of the measured uplift can be attributed to glacial and erosional isostatic processes, our results suggest that interseismic strain accumulation at the Montello and the Bassano–Valdobbiadene thrusts it significantly contributing to the measured uplift. The seismogenic potential of the Montello thrust turns out to be smaller than that of the Bassano–Valdobbiadene fault, whose estimated parameters (locking depth equals 9.1 km and slip rate equals 2.1 mm a−1) indicate a structure capable of potentially generating a Mw〉6.5 earthquake. These results demonstrate the importance of precise vertical ground velocity data for modeling interseismic strain accumulation in slowly deforming regions where seismological and geomorphological evidence of active tectonics is often scarce or not conclusive.
    Description: Published
    Description: 1681–1698
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Southern Alps ; Vertical Velocities ; GPS and InSAR integration ; Interseismic Deformation ; Dislocation Model ; Seismic Potential ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
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    Mantle-derived carbon in Hercynian granites. Stable isotopes signatures and C/He associations in the thermomineral waters, N-Portugal (2010)
    Elsevier
    Details
    Publication Date: 2021-01-27
    Description: Na–HCO3–CO2-rich thermomineral waters issue in the N of Portugal, within the Galicia-Trás-os-Montes region, linked to a major NNE-trending fault, the so-called Penacova-Régua-Verin megalineament. Along this tectonic structure different occurrences of CO2-rich thermomineral waters are found: Chaves hot waters (67 °C) and also several cold (16.1 °C) CO2-rich waters. The δ2H and δ18O values of the thermomineral waters are similar to those of the local meteoric waters. The chemical composition of both hot and cold mineral waters suggests that water–rock reactions are mainly controlled by the amount of dissolved CO2 (g) rather than by the water temperature. Stable carbon isotope data indicate an external CO2 inorganic origin for the gas. δ13CCO2 values ranging between −7.2‰ and −5.1‰ are consistent with a two-component mixture between crustal and mantle-derived CO2. Such an assumption is supported by the 3He/4He ratios measured in the gas phase, are between 0.89 and 2.68 times the atmospheric ratio (Ra). These ratios which are higher than that those expected for a pure crustal origin (≈0.02 Ra), indicating that 10 to 30% of the He has originated from the upper mantle. Release of deep-seated fluids having a mantle-derived component in a region without recent volcanic activity indicates that extensive neo-tectonic structures originating during the Alpine Orogeny are still active (i.e., the Chaves Depression).
    Description: Published
    Description: 49-56
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: CO2-rich thermomineral waters ; mantle volatiles ; isotopes ; Chaves geothermal system ; N-Portugal ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 27
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    Precise Topographic Model Assisted Slope Displacement Retrieval from Small Baseline Subsets Results: Case Study over a High and Steep Mining Slope (2021)
    MDPI
    Details
    Publication Date: 2021-01-07
    Description: Due to the intrinsic side-looking geometry of synthetic aperture radar (SAR), time series interferometric SAR is only able to monitor displacements in line-of-sight (LOS) direction, which limits the accuracy of displacement measurement in landslide monitoring. This is because the LOS displacement is only a three dimensional projection of real displacement of a certain ground object. Targeting at this problem, a precise digital elevation model (DEM) assisted slope displacement retrieval method is proposed and applied to a case study over the high and steep slope of the Dagushan open pit mine. In the case study, the precise DEM generated by laser scanning is first used to minimize topographic residuals in small baseline subsets analysis. Then, the LOS displacements are converted to slope direction with assistance of the precise DEM. By comparing with ground measurements, relative root mean square errors (RMSE) of the estimated slope displacements reach approximately 12-13% for the ascending orbit, and 5.4-9.2% for the descending orbit in our study area. In order to validate the experimental results, comparison with microseism monitoring results is also conducted. Moreover, both results have found that the largest slope displacements occur on the slope part, with elevations varying from -138 m to -210 m, which corresponds to the landslide area. Moreover, there is a certain correlation with precipitation, as revealed by the displacement time series. The outcome of this article shows that rock mass structure, lithology, and precipitation are main factors affecting the stability of high and steep mining slopes.
    Description: Published
    Description: 6674
    Description: 7SR AMBIENTE – Servizi e ricerca per la società
    Description: JCR Journal
    Keywords: digital elevation model; high and steep slope; landslide monitoring; open-pit mine; small baseline subsets analysis ; 04.03. Geodesy
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  • 28
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    Geopositioning time series from offshore platforms in the Adriatic Sea (2021)
    Nature P.G.
    Details
    Publication Date: 2021-01-07
    Description: We provide a dataset of 3D coordinate time series of 37 continuous GNSS stations installed for stability monitoring purposes on onshore and offshore industrial settlements along a NW-SE-oriented and ~100-km-wide belt encompassing the eastern Italian coast and the Adriatic Sea. The dataset results from the analysis performed by using different geodetic software (Bernese, GAMIT/GLOBK and GIPSY) and consists of six raw position time series solutions, referred to IGb08 and IGS14 reference frames. Time series analyses and comparisons evidence that the different solutions are consistent between them, despite the use of different software, models, strategy processing and frame realizations. We observe that the offshore stations are subject to significant seasonal oscillations probably due to seasonal environmental loads, seasonal temperature-induced platform deformation and hydrostatic pressure variations. Many stations are characterized by non-linear time series, suggesting a complex interplay between regional (long-term tectonic stress) and local sources of deformation (e.g. reservoirs depletion, sediment compaction). Computed raw time series, logs files, phasor diagrams and time series comparison plots are distributed via PANGAEA ( https://www.pangaea.de ).
    Description: This research was financed by the Italian Economic Development Ministry in the”CLYPEA-Innovation Network for Future Energy” framework, “subsoil deformations” project.
    Description: Published
    Description: 373
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GNSS ; offshore platforms ; subsidence ; data processing ; oil/gas exploiting ; 04. Solid Earth ; 04.03. Geodesy
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  • 29
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    Temporal trends and matrix-dependent behaviors of trace elements closed to a geothermal hot-spot source (Aeolian Archipelago, Italy) (2012)
    Elsevier
    Details
    Publication Date: 2021-04-07
    Description: Degassing activity from marine shallow-water hydrothermal vents represents a natural important source of trace elements of particular ecotoxicological concern, such as Hg, Cd, Pb, and As. In 2002, on November 3rd, a submarine area of the Aeolian Archipelago (Italy) was affected by an exceptional hydrothermal activity, presumably associated to a significant trace element release. This study developed in the highest impacted area, was focused on different environmental matrices (water, sediment, primary producers, and fishes) with the aim to evaluate on a statistical basis temporal dynamics involving trace elements closed to the emission source. Results evidenced that this event produced significant changes in water column, modifying the general assessment of the chemical descriptors selected (Na, K, Mg, Ca, Cl, Br, SO4 2-, HCO3 -). Furthermore, the degassing activity represents a significant input of Hg, Cd, Pb, and As for all of the sampled matrices, being it responsible of the higher levels observed in the study area compared to controls. Concentrations measured in sediments and biota (Cystoseira compressa, Serranus cabrilla) at temporal intervals of ten months distanced, supported the occurrence of different time scale dynamics which are both element and matrix-dependent. In particular, levels of Cd and As measured in liver tissues of S. cabrilla evidenced a significant trend to increase with the time, allowing to exclude a quick recovery of the study area. Measured values in edible fishes tissues are, also, notably higher than risk limits proposed by the 2001/22/CE Directive for human consumption, so, local-based caught have to be accurately regulated to avoid the occurrence of diet over-exposure.
    Description: Published
    Description: 10-28
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: N/A or not JCR
    Description: restricted
    Keywords: trace elements ; hydrothermal vents ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 30
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    The importance of methanotrophic activity in geothermal soils of Pantelleria island (Italy) (2013)
    European Geophysical Union
    Details
    Publication Date: 2021-06-14
    Description: Methane is a major contributor to the greenhouse effect, its atmospheric concentration being more than doubled since the XIX century. Every year 22 Tg of methane are released to the atmosphere from several natural and anthropogenic sources. Natural sources include geothermal/volcanic areas but the estimation of the total methane emission from these areas is currently not well defined since the balance between emission through degassing and microbial oxidation within the soils is not well known. Microbial oxidation in soils contributes globally for about 3-9% to the removal of methane from the atmosphere and recent studies evidenced methanotrophic activity also in soils of volcanic/geothermal areas despite their harsh environmental conditions (high temperatures, low pH and high concentrations of H2S and NH3). Methanotrophs are a diverse group of bacteria that are able to metabolize methane as their only source of carbon and energy and are found within the Alpha and Gamma classes of Proteobacteria and within the phylum Verrucomicrobia. Our purpose was to study the interaction between methanotrophic communities and the methane emitted from the geothermally most active site of Pantelleria island (Italy), Favara Grande, whose total methane emission has been previously estimated in about 2.5 t/a. Laboratory incubation experiments with soil samples from Favara Grande showed methane consumption values of up to 9500 ng g-1 dry soil per hour while soils collected outside the geothermal area consume less than 6 ng g-1 h-1. The maximum consumption was measured in the shallowest part of the soil profile (1-3 cm) and high values (〉100 ng g-1 h-1) were maintained up to a depht of 15 cm. Furthermore, the highest consumption was measured at 37 C, and a still recognizable consumption (〉20 ng g-1 h-1) at 80 C, with positive correlation with the methane concentration in the incubation atmosphere. These results can be considered a clear evidence of the presence of methanotrophs that were investigated by culturing and culture-independent techniques. The diversity of proteobacterial methanotrophs was investigated by creating a clone library of the amplified methane mono-oxygenase encoding gene, pmoA. Clone sequencing indicates the presence of Gammaproteobacteria in the soils of Favara Grande. Enrichment cultures, on a mineral medium in a CH4-enriched atmosphere, led to the isolation of different strains that were identified as Methylocistis spp., which belong to the Alphaproteobacteria. The presence of Verrucomicrobia was detected by amplification of pmoA gene using newly designed primers. Soils from Favara Grande show therefore the largest spectrum of methanotrophic microorganisms until now detected in a geothermal environment. While the presence of Verrucomicrobia in geothermal soils was predictable due to their thermophilic and acidophilic character, the presence of both Alpha and Gamma proteobacteria was unexpected. Their presence is limited to the shallowest part of the soil were temperatures are lower and is probably favored by a soil pH that is not too low (pH 5) and their contribution to biological methane oxidation at Pantelleria is significant. Understanding the ecology of methanotrophy in geothermal sites will increase our knowledge of the role of soils in methane emissions in such environments.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: soil methane fluxes ; methanotrophic activity ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 31
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    Geochemical monitoring of groundwaters (1998-2001) at Vesuvius volcano (Italy) (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 32
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    Chemical and isotopic equilibrium between CO2 and CH4 in fumarolic gas discharges: generation of CH4 in magmatic-hydrothermal systems (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece,and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments. Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature. N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and 13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism.
    Description: European community
    Description: Published
    Description: 2321–2334
    Description: partially_open
    Keywords: fumarolic gases ; hydrothermal systems ; chemical and isotopic equilibrium ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 33
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    Microbial communities near the oxic/anoxic interface in the hydrothermal system of Vulcano Island, Italy (2006)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Hydrothermal fluids and sediments from subaerial and shallow submarine sites at Vulcano Island, Italy were investigated for relations between the thermophilic microbial communities, as analysed by fluorescence in situ hybridization, and their geochemical environment, as assessed by photometry, chromatography, and in situ microsensor measurements. Mixing between hydrothermal fluids and seawater in the sediment pore space was reflected in the chemical composition of the emitted fluids, in depth profiles of pore water oxygen and sulfide concentrations, and in the structure of the benthic microbial community. Organic compounds did not accumulate in the vent fluids (b10 AM fatty acids) or in the sediments (b0.1% Corg), suggesting that efficient utilization supported microbial populations on the order of 104 cells per ml fluid and 108 cells per cm3 sediment. Groups of thermophiles that typically gain metabolic energy from the fermentation of organic matter (Thermococcales, Thermotoga/Thermosipho spp., and Bacillus sp.)were detected in significant abundances at all study sites. Also abundant were thermophiles capable of oxidizing organic acids with oxygen, nitrate, or sulfate. Aerobic thermophiles (Aquificales and Thermus sp.) were more abundant at oxic sites than at anoxic sites. Increasingly oxygenated habitats were associated with decreasing abundance of anaerobic (hyper)thermophiles belonging to the order Archaeoglobales.
    Description: Published
    Description: 169– 182
    Description: partially_open
    Keywords: Biogeochemistry ; Hydrothermal system ; Marine sediment ; Microbial ecology ; Microsensor ; Thermophiles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 34
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    Chemical and isotopic composition of waters and dissolved gases in some thermal springs of sicily and adjacent volcanic islands, Italy. (2007)
    Birkhauser
    Details
    Publication Date: 2017-04-04
    Description: Hydrochemical (major and some minor constituents), stable isotope (dDH2O and d18OH2O; d13CTDIC total dissolved inorganic carbon) and dissolved gas composition have been determined on 33 thermal discharges located throughout Sicily (Italy) and its adjacent islands. On the basis of major ion contents, four main water types have been distinguished: (1) a Na-Cl type; (2) a Ca-Mg〉Na- SO4-Cl type; (3) a Ca-Mg-HCO3 type and (4) a Na-HCO3 type water. Most waters are meteoric in origin or resulting from mixing between meteoric water and heavy-isotope end members. In some samples, d18O values reflect the effects of equilibrium processes between thermal waters and rocks (positive 18O-shift) or thermal waters and CO2 (negative 18O-shift). Dissolved gas composition indicates the occurrence of gas/ water interaction processes in thermal aquifers. N2/O2 ratios higher than air-saturated water (ASW), suggest the presence of geochemical processes responsible for dissolved oxygen consumption. High CO2 contents (more than 3000 cc/litre STP) dissolved in the thermal waters indicate the presence of an external source of carbon dioxide-rich gas. TDIC content and d13CTDIC show very large ranges from 4.6 to 145.3 mmol/Kg and from )10.0& and 2.8&, respectively. Calculated values indicate the significant contribution from a deep source of carbon dioxide inorganic in origin. Interaction with Mediterranean magmatic CO2 characterized by heavier carbon isotope ratios (d13CCO2 value from )3 to 0& vs V-PDB (CAPASSO et al., 1997, GIAMMANCO et al., 1998; INGUAGGIATO et al., 2000) with respect to MORB value and/ or input of CO2-derived from thermal decomposition of marine carbonates have been inferred.
    Description: Published
    Description: 781-807
    Description: JCR Journal
    Description: reserved
    Keywords: Thermal waters, ; chemical and isotope composition, ; dissolved gases ; d13C ; Sicily. ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes
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  • 35
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    Fluid geochemistry investigations on the volcanic system of methana (2007)
    Geological Society of Greece
    Details
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey on the fluids released by the volcanic/geothermal system of Methana was undertaken. Characterization of the gases was made on the basis of the chemical and isotopic (He and C) analysis of 14 samples. CO2 soil gas concentration and fluxes were measured on the whole peninsula at more than 100 sampling sites. 31 samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of aquifers. Anomalies referable to the geothermal system, besides at known thermal manifesta-tions, were also recognized at some anomalous degassing soil site and in some cold groundwater. These anomalies were always spatially correlated to the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated in about 0.2 kg s-1. Although this value is low compared to other volcanic systems, anomalous CO2 degassing at Methana may pose gas hazard problems. Such volcanic risk, although restricted to limited areas, cannot be neglected and further studies have to be undertaken for its better assessment
    Description: Published
    Description: 712-722
    Description: N/A or not JCR
    Description: open
    Keywords: soil gases ; CO2 fluxes ; gas hazard ; groundwater chemistry ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 36
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    Thermal monitoring of hydrothermal activity by permanent infrared automatic stations: Results obtained at Solfatara di Pozzuoli, Campi Flegrei (Italy) (2008)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: A permanent automatic infrared (IR) station was installed at Solfatara crater, the most active zone of Campi Flegrei caldera. After a positive in situ calibration of the IR camera, we analyze 2175 thermal IR images of the same scene from 2004 to 2007. The scene includes a portion of the steam heated hot soils of Solfatara. The experiment was initiated to detect and quantify temperature changes of the shallow thermal structure of a quiescent volcano such as Solfatara over long periods. Ambient temperature results as the main parameter affecting IR temperatures while air humidity and rain control image quality. A geometric correction of the images was necessary to remove the effects of slow movement of the camera. After a suitable correction the images give a reliable and detailed picture of the temperature changes, over the period October 2004 – January 2007, which suggests origin of the changes were linked to anthropogenic activity, vegetation growth and to the increase of the flux of hydrothermal fluids in the area of the hottest fumaroles. Two positive temperature anomalies were registered after the occurrence of two seismic swarms which affected the hydrothermal system of Solfatara in October 2005 and October 2006. It is worth noting that these signs were detected in a system characterized by a low level of activity with respect to systems affected by real volcanic crisis where more spectacular results will be expected. Results of the experiment show that this kind of monitoring system can be a suitable tool for volcanic surveillance.
    Description: Published
    Description: B12206
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: partially_open
    Keywords: Termal Monitoring of Hydrothermal ; Activity ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 37
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    GEOCHEMICAL CHARACTERIZATION OF THERMAL AND COLD GROUNDWATERS OF METHANA PENINSULA (PELOPONNESUS, GREECE) (2008)
    Details
    Publication Date: 2017-04-04
    Description: A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system of Methana was undertaken collecting 59 natural water samples during the period 2004-2007. Methana is a peninsula whose climatology and hydrology can be compared to the nearby small islands of the Aegean Sea. Similarly the chemical and isotopic composition of its water is dominated by the mixing of seawater with meteoric water. But the simple mixing trend is modified by water-rock interaction processes, enhanced by the dissolution of endogenous CO2, leading to strong enrichments in Alkalinity, Calcium, Barium, Iron and Manganese.
    Description: Published
    Description: Athens, Greece
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Methana ; thermal waters ; groundwaters ; hydrochemistry ; stable isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 38
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    The Albano Maar Lake high resolution bathymetry and dissolved CO2 budget (Colli Albani volcano, Italy): Constrains to hazard evaluation (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The Albano Lake is the deepest volcanic lake in Italy (−167 m) and fills the youngest maar of the quiescent Colli Albani volcano. The lake has undergone significant level changes and lahar generating overflows occurred about 5800 yrs B.P. and likely in 398 b.C., when Romans excavated a tunnel drain through the maar wall. Hazardous lake rollovers and CO2 release are still possible because the Albano volcano shows active ground deformation, gas emission and periodic seismic swarms. On November 2005, the first high resolution bathymetric survey of the Albano Lake was performed. Here we present the results provided by a Digital Elevation Model and 2-D and 3-D images of the crater lake floor, which is made by coalescent and partly overlapping craters and wide flat surfaces separated by some evident scarps. Submerged shorelines are identified at depths between −20 m and −41 m and indicate the occurrence of significant lake level changes, likely between 7.1 and 4.1 ka. The current lake volume is ~447.5×106 m3 and the total quantity of dissolved CO2 is 6850 t estimated by chemical analyses of samples collected on May 2006. A decrease of nearly one order of magnitude of the CO2 dissolved in the lake water below −120 m, observed from December 1997 to May 2006 (from 4190 to 465 t respectively), has been attributed to lake water overturn. The observed oscillations of the dissolved CO2 concentrations justify the efforts of monitoring the chemical and physical characteristics of the lake. At present the quantity of dissolved CO2 is very far from saturation and Nyostype events cannot presently occur.
    Description: DPC-INGV Project V3_1
    Description: Published
    Description: 258–268
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Albano maar ; lake bathymetry ; geochemistry ; crater lake hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 39
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    Temporal Changes in Fluid Chemistry and Energy Profiles in the Vulcano Island Hydrothermal System (2008)
    Mary Ann Liebert Inc.
    Details
    Publication Date: 2017-04-04
    Description: In June 2003, the geochemical composition of geothermal fluids was determined at 9 sites in the Vulcano hydrothermal system, including sediment seeps, geothermal wells, and submarine vents. Compositional data were combined with standard state reaction properties to determine the overall Gibbs free energy (deltaGr) for 120 potential lithotrophic and heterotrophic reactions. Lithotrophic reactions in the H-O-N-S-C-Fe system were considered, and exergonic reactions yielded up to 120 kJ per mole of electrons transferred. The potential for heterotrophy was characterized by energy yields from the complete oxidation of 6 carboxylic acids—formic, acetic, propanoic, lactic, pyruvic, and succinic—with the following redox pairs:O2/H2O, SO4 2-/H2S, NO3 -/NH4+, S0/H2S, and Fe3O4/Fe2+. Heterotrophic reactions yielded 6–111 kJ/mol e-. Energy yields from both lithotrophic and heterotrophic reactions were highly dependent on the terminal electron acceptor (TEA); reactions with O2 yielded the most energy, followed by those with NO3-, Fe(III), SO4 2-, and S0. When only reactions with complete TEA reduction were included, the exergonic lithotrophic reactions followed a similar electron tower. Spatial variability in deltaGr was significant for iron redox reactions, owing largely to the wide range in Fe2+ and H+ concentrations. Energy yields were compared to those obtained for samples collected in June 2001. The temporal variations in geochemical composition and energy yields observed in the Vulcano hydrothermal system between 2001 and 2003 were moderate. The largest differences in deltaGr over the 2 years were from iron redox reactions, due to temporal changes in the Fe2+ and H+ concentrations. The observed variations in fluid composition across the Vulcano hydrothermal system have the potential to influence not only microbial diversity but also the metabolic strategies of the resident microbial communities.
    Description: Published
    Description: 905-932
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Hydrothermal systems ; Vulcano ; Energetics ; Geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 40
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    Carbon dioxide diffuse emission from the soil: ten years of observations at Vesuvio and Campi Flegrei (Pozzuoli), and linkages with volcanic activity (2010)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Carbon dioxide flux from the soil is regularly monitored in selected areas of Vesuvio and Solfatara (Campi Flegrei, Pozzuoli) with the twofold aim of i) monitoring spatial and temporal variations of the degassing process and ii) investigating if the surface phenomena could provide information about the processes occurring at depth. At present, the surveyed areas include 15 fixed points around the rim of Vesuvio and 71 fixed points in the floor of Solfatara crater. Soil CO2 flux has been measured since 1998, at least once a month, in both areas. In addition, two automatic permanent stations, located at Vesuvio and Solfatara, measure the CO2 flux and some environmental parameters that can potentially influence the CO2 diffuse degassing. Series acquired by continuous stations are characterized by an annual periodicity that is related to the typical periodicities of some meteorological parameters. Conversely, series of CO2 flux data arising from periodic measurements over the arrays of Vesuvio and Solfatara are less dependent on external factors such as meteorological parameters, local soil properties (porosity, hydraulic conductivity) and topographic effects (high or low ground). Therefore we argue that the long-term trend of this signal contains the “best” possible representation of the endogenous signal related to the upflow of deep hydrothermal fluids.
    Description: Published
    Description: 103-118
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Carbon dioxide ; Soil diffuse degassing ; Monitoring ; Vesuvio . Campi Flegrei ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 41
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    Carbon dixide emission in Italy: Shallow crustal sources or subduction related fluid recycling? (2010)
    Details
    Publication Date: 2017-04-04
    Description: Anomalous non-volcanic CO2 release in central and southern Italy has been highlighted by ten years of detailed investigations on Earth degassing processes. Two regional degassing structures are located in the Tyrrhenian sector where more then 200 emissions of CO2 are located and has been recently included in the first web based catalogue of degassing sites (http://googas.ov.ingv.it). The total amount of CO2 released by the two structures were evaluated to be 〉 2×1011 mol a-1 ( 〉10% of the estimated global volcanic CO2 emission). The anomalous flux of CO2 suddenly disappears in the Apennine in correspondence of a narrow band where most of the Italian seismicity concentrates. Here, at depth, the gas accumulates in crustal traps generating CO2 overpressurised reservoirs. These overpressured structures are, in our opinion, one of the main cause of Apennine earthquake activation processes. The results of these investigations suggested that Earth degassing in Italy may have an active primary role in the geodynamics of the region. What is the origin of gas? The large extension of the degassing structures and petrologic data suggested that the main source of gas is a mantle metasomatised by the fluids produced in the subdacted slabs. However, has been also hypothesised the presence of localised crustal source of the gas. This matter will be discussed on the base of unpublished isotopic data of the main gas emissions.
    Description: Unpublished
    Description: Davos,Switzerland
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: anomalous flux CO2 ; Italy ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 42
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    Estimation of the magmatic gas and heat flux through the Etnean volcanic aquifer (2010)
    Copernicus
    Details
    Publication Date: 2017-04-04
    Description: Etna volcano, Italy, hosts one of the major groundwater systems of the island of Sicily. Waters circulate within highly permeable fractured, mainly hawaiitic, volcanic rocks. Aquifers are limited downwards by the underlying impermeable sedimentary terrains. Thickness of the volcanic rocks generally does not exceed some 300 m, preventing the waters to reach great depths. This is faced by short travel times (years to tens of years) and low thermalisation of the Etnean groundwaters. Measured temperatures are, in fact, generally lower than 25 °C. But the huge annual meteoric recharge (about 0.97 kmˆ3) with a high actual infiltration coefficient (0.75) implies a great underground circulation. During their travel from the summit area to the periphery of the volcano, waters acquire magmatic heat together with volcanic gases and solutes through water-rock interaction processes. In the last 20 years the Etnean aquifers has been extensively studied. Their waters were analysed for dissolved major, minor and trace element, O, H, C, S, B, Sr and He isotopes, and dissolved gas composition. These data have been published in several articles. Here, after a summary of the obtained results, the estimation of the magmatic heat flux through the aquifer will be discussed. To calculate heat uptake during subsurface circulation, for each sampling point (spring, well or drainage gallery) the following data have been considered: flow rate, water temperature, and oxygen isotopic composition. The latter was used to calculate the mean recharge altitude through the measured local isotopic lapse rate. Mean recharge temperatures, weighted for rain amount throughout the year, were obtained from the local weather station network. Calculations were made for a representative number of sampling points (216) including all major issues and corresponding to a total water flow of about 0.315 kmˆ3/a, which is 40% of the effective meteoric recharge. Results gave a total energy output of about 140 MW/a the half of which is ascribable to only 13 sampling points. These correspond to the highest flow drainage galleries with fluxes ranging from 50 to 1000 l/s and wells with pumping rates from 70 to 250 l/s. Geographical distribution indicates that, like magmatic gas leakage, heat flow is influenced by structural features of the volcanic edifice. The major heat discharge through groundwater are all tightly connected either to the major regional tectonic systems or to the major volcanic rift zones along which the most important flank eruptions take place. But rift zones are much more important for heat upraise due to the frequent dikes injection than for gas escape because generally when dikes have been emplaced the structure is no more permeable to gases because it becomes sealed by the cooling magma.
    Description: Published
    Description: Vienna, Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: groundwaters ; volcanic surveillance ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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    Type: Oral presentation
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    Thermal and geochemical signature of Poas Volcano (Costa Rica) (2010)
    Details
    Publication Date: 2012-02-03
    Description: We report results from a multidisciplinary campaign conducted at Poás volcano (Costa Rica) in March 2009. Thermal imagery of the fumaroles sited on the north side of the pyroclastic cone revealed mean apparent temperatures ranging between 25 and 40°C with a maximum apparent temperature of 80°C. The crater lake surface was characterised by mean apparent temperatures varying between 30 and 35°C and a maximum recorded value of 48°C. Thermal profiles across the lake surface revealed steady temperatures and thus thorough convective mixing. The overall mean SO2 flux emitted from the crater was 76 Mg d-1, with approximately equal contributions from both the pyroclastic cone and the lake. Analysis of gas composition using active, open-path FTIR spectroscopy indicated molar ratios of H2O/SO2 = 151, CO2/SO2 = 1.56, SO2/HCl 〉 40, and SO2/HF 〉 200 for the lake emission. The plume was also sampled using filter packs. Ion chromatographic analysis revealed the presence of abundant K+ and SO42-, with small amounts of Ca2+, Cl-, and Mg2+. This provides a detailed picture of lake surface temperature characteristics and of gas flux and composition of the plume emitted from Poás. The results are consistent with the typical non-eruptive state of this volcano.
    Description: UK Natural Environment Research Council (NERC grant NE/F004222/1) and the NERC Field Spectroscopy Facility
    Description: Published
    Description: 171-190
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: N/A or not JCR
    Description: reserved
    Keywords: Thermal imagery ; SO2 flux ; FTIR ; particles ; Poas ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 44
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    Molecular and isotopic composition of free hydrocarbon gases from Sicily, Italy (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Chemical and isotopic data have been used as geochemical tracers for a genetic characterization of hydrocarbon gases from a total of eleven manifestations located in Eastern and Central-Southern Sicily (Italy). The molecular analysis shows that almost all the samples are enriched in methane (up to 93.2% Vol.), with the exception of four gas samples collected around Mt. Etna showing high mantle-derived CO2 content. Methane isotope signatures suggest that these are thermogenic gases or a mixture between thermogenic gases and microbial gases. Although samples from some mud volcanoes in Southern Sicily (Macalube di Aragona) show isotope signatures consistent with a mixing model between thermogenic and microbial, by combining the molecular compositions (C1/(C2 + C3))and the methane isotope ratios (d13C1), such a process seems to be excluded. Therefore, the occurrence of secondary post-genetic processes should be invoked. Two main hypotheses have been considered: the first hypothesis includes that the gas is produced by microbial activity and altered post-genetically by microbial oxidation of methane, while according to the second hypothesis thermogenic gas have modified their molecular ratios due to vertical migration.
    Description: Published
    Description: L06607
    Description: partially_open
    Keywords: Isotopic composition/chemistry ; Organic geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 45
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    The aquatic geochemistry of arsenic in volcanic groundwaters from southern Italy (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper discusses the abundance, speciation and mobility of As in groundwater systems from active volcanic areas in Italy. Using literature data and new additional determinations, the main geochemical processes controlling the fate of As during gas–water–rock interaction in these systems are examined. Arsenic concentrations in the fluids range from 0.1 to 6940 mg/l, with wide differences observed among the different volcanoes and within each area. The dependence of As content on water temperature, pH, redox potential and major ions is investigated. Results demonstrate that As concentrations are highest where active hydrothermal circulation takes place at shallow levels, i.e. at Vulcano Island and the Phlegrean Fields. In both areas the dissolution of As-bearing sulphides is likely to be the main source of As. Mature Cl-rich groundwaters, representative of the discharge from the deep thermal reservoirs, are typically enriched in As with respect to SO4-rich ‘‘steam heated groundwaters’’. In the HCO3 groundwaters recovered at Vesuvius and Etna, aqueous As cycling is limited by the absence of high-temperature interactions and by high-Fe content of the host rocks, resulting in oxidative As adsorption. Thermodynamic modelling suggests that reducing H2S-rich groundwaters are in equilibrium with realgar, whereas in oxidising environments over-saturation with respect to Fe oxyhydroxides is indicated. Under these oxidising conditions, As solubility decreases controlled by As co-precipitation with, or adsorption on, Fe oxy-hydroxides. Consistent with thermodynamic considerations, As mobility in the studied areas is enhanced in intermediate redox environments, where both sulphides and Fe hydroxides are unstable.
    Description: Published
    Description: 1283–1296
    Description: partially_open
    Keywords: Hydrogeochemistry ; Arsenic ; volcanic groundwaters ; speciation ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 46
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    Geophysical and hydrogeological experiments from a shallow hydrothermal system at Solfatara Volcano, Campi Flegrei, Italy: Response to caldera unrest (2007)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Integration of high-resolution geophysical and hydrogeological investigations at Solfatara Volcano, Campi Flegrei, Italy, allowed us to (1) image the shallow and intermediate subsurface to the crater, (2) elucidate patterns in the shallow subsurface degassing, and (3) refine and upgrade volcano-monitoring strategies for this dynamic area. Our results show that the subsurface to the crater can be divided roughly into two zones: a dry, outcropping layer overlying a horizon saturated by hydrothermal fluids. Within this saturated zone, intersections of dominant NW- and ENE-striking structural lineaments act as preferential escape conduits for the fluids which generate high microseismic noise amplitudes in the southeastern part of the crater. Hydrogeological data suggest an uprising of the isotherms below Solfatara crater, and a marked increment of fluid degassing, over the last 40 years. Sudden variations of both seismic noise level and noise cycling are positively correlated with early stages of ground inflation during the AD 2000 uplift. We believe therefore that monitoring of seismic noise can be used for upgrading early warning strategies in this sector of the Campi Flegrei volcanic system.
    Description: Published
    Description: B06201
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Geophysical ; hydrogeological ; experiments ; Solfatara ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 47
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    Hydrothermal Fluid Circulation and its Effect on Caldera Unrest (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper focuses on the role that hydrothermal systems may play in caldera unrest. Changes in the fluid chemistry, temperature, and discharge rate of hydrothermal systems are commonly detected at the surface during volcanic unrest, as hydrothermal fluids adjust to changing subsurface conditions. Geochemical monitoring is carried out to observe the evolving system conditions. Circulating fluids can also generate signals that affect geophysical parameters monitored at the surface. Effective hazard evaluation requires a proper understanding of unrest phenomena and correct interpretation of their causes. Physical modeling of fluid circulation allows quantification of the evolution of a hydrothermal system, and hence evaluation of the potential role of hydrothermal fluids during caldera unrest. Modeling results can be compared with monitoring data, and then contribute to the interpretation of the recent caldera evolution. This paper: 1) describes the main features of hydrothermal systems; 2) briefly reviews numerical modeling of heat and fluid flow through porous media; 3) highlight the effects of hydrothermal fluids on unrest processes; and 4) describes some model applications to the Phlegrean Fields caldera. Simultaneous modeling of different independent parameters has proved to be a powerful tool for understanding caldera unrest. The results highlight the importance of comprehensive conceptual models that incorporate all the available geochemical and geophysical information, and they also stress the need for high-quality, multi-parameter monitoring and modeling of volcanic activity.
    Description: Published
    Description: 393-416
    Description: 3.6. Fisica del vulcanismo
    Description: 4.3. TTC - Scenari di pericolosità vulcanica
    Description: reserved
    Keywords: hydrothermal fluids ; unrest ; modeling ; caldera ; monitoring ; volcanic hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 48
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    Stable isotope feature of groundwaters from Graciosa volcanic Island (Azores) – preliminary results (2012)
    Akadémiai Kiadò
    Details
    Publication Date: 2012-02-03
    Description: The Azores archipelago is made of nine islands all of volcanic origin and a few islets located in the North Atlantic Ocean, about 1800 km west of Portuguese mainland at the triple junction of the Eurasian, North American and Nubian plates (Azores Triple Junction = ATJ). Graciosa Island is part of the Central Group of Azores archipelago and is located on the Terceira Rift, a major tectonic feature of the ATJ. The main hydrothermal manifestations at Graciosa Island occur in the Caldeira volcano (SE part of the island), and particularly inside the huge (150 m wide, 80 m high) Furna do Enxofre lava cave located in the Caldeira, where a bubbling mud pool releases steam and gases, leading to the accumulation of CO2 at the bottom of the cave, filled by a coldwater subterranean lake. Three field work campaigns were carried out at Graciosa Island and 14 water samples have been collected, from boreholes, springs and the subterranean lake for isotopic (18O, 2H and 3H) and chemical analysis. The groundwater samples were plotted along the GMWL, and two water groups were identified in the 18O vs. 2H diagram. The splitting up of the samples is even more visible when the O-18 content is plotted as a function of the temperature or as a function of the electrical conductivity. Besides the differences in mineralization and temperature observed in the groundwater samples from Graciosa Island, an isotopic shift towards more enriched values is also observed. The salinity and isotopic content seems to indicate not a simple mixture between two end-members, i.e. seawater – fresh water: another process of mineralization and isotope enrichment must be considered in this active volcanic environment. A hypothesis to be formulated is that the source of salts could be associated to mixing with boiling seawater, that by evaporation will be able to: i) increase groundwater salinity, ii) strongly change the 2H content to more enriched values, and iii) absent or limited variation in d18O content.
    Description: Published
    Description: Budapest, Hungary
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: restricted
    Keywords: Water isotope ; Graziosa Island ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 49
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    Hydrothermal fluids vented at shallow depths at the Aeolian islands: relationships with volcanic and geothermal systems. (2009)
    Freiberg Online Geology FOG - ISSN 1434-7512
    Details
    Publication Date: 2013-01-31
    Description: Scuba diving investigations carried out over the last two decades at the Aeolian islands revealed the existence of submarine magmatic and late-magmatic hydrothermalism at all the islands, despite the absence of on-shore activity at some of the islands. The results gained by diving activities provided useful information to evaluate the volcanic and geothermal activity and to manage the volcanic crisis occurred on November 2002 off the island of Panarea.
    Description: Published
    Description: Freiberg-Germany
    Description: open
    Keywords: submarine ; hydrothermal ; vents ; Aeolian islands ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 50
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    Nitrogen isotopes in thermal fluids of a forearc region (Jalisco Block, Mexico): evidence for heavy nitrogen from continental crust (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The Jalisco Block (JB) is a geologically and tectonically complex part of northwestern Mexico characterized by active subduction-type volcanism, rifting, and old stable structures. Thermal springs and groups of springs are widely distributed over JB. Bubbling gas from seven thermal springs located within different tectonic environments of the JB was analyzed for He, 20Ne, and N2 concentrations and d15N ratios. All gases are N2-dominant (〉84%) with the exception of one sample (Rio´ Purificacio´n), which has a significant CH4 content (about 50%). All collected gas samples are relatively high in He, up to 1500 ppm vol and with 3He/4He values ranging from 0.6 to 4.5 Ra. All measured nitrogen isotope ratios are heavier than air with d15N values ranging from 0.5 to 5.0%. The relative N2 excess with respect to air-saturated water computed on the basis of N2 and 20Ne contents indicates the contribution of a nonatmospheric N2 source. All the samples show a good correlation between d15N and the relative excess of N2 with d15N +5.3% for the maximum N2 excess of 100%. Due to a presumed lack of seafloor sediment involved in the subduction process, such a d15N positive value seems to reflect the addition to the fluids of a heavy nitrogen originating from metamorphism processes of rocks occurring within the overlying continental crust.
    Description: Published
    Description: 1-9
    Description: partially_open
    Keywords: bubbling gases ; forearc region ; Jalisco Block-Mexico ; nitrogen isotopes ; subduction-related volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
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  • 51
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    The buried caldera of Misti volcano, Peru, revealed by combining a self-potential survey with elliptic Fourier function analysis of topography (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 52
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    Ubinas: the evolution of the historically most active volcano in southern Peru (2005)
    Springer-Verlag
    Details
    Publication Date: 2017-04-04
    Description: Ubinas volcano has had 23 degassing and ashfall episodes since A.D. 1550, making it the historically most active volcano in southern Peru. Based on fieldwork, on interpretation of aerial photographs and satellite images, and on radiometric ages, the eruptive history of Ubinas is divided into two major periods. Ubinas I (Middle Pleistocene 376 ka) is characterized by lava flow activity that formed the lower part of the edifice. This edifice collapsed and resulted in a debris-avalanche deposit distributed as far as 12 km downstream the Rio Ubinas. Non-welded ignimbrites were erupted subsequently and ponded to a thickness of 150 m as far as 7 km south of the summit. These eruptions probably left a small collapse caldera on the summit of Ubinas I. A 100-m thick sequence of ash-and-pumice flow deposits followed, filling paleo-valleys 6 km from the summit. Ubinas II, 376 ky to present comprises several stages. The summit cone was built by andesite and dacite flows between 376 and 142 ky. A series of domes grew on the southern flank and the largest one was dated at 250 ky; block-and-ash flow deposits from these domes filled the upper Rio Ubinas valley 10 km to the south. The summit caldera was formed between 25 and 9.7 ky. Ash-flow deposits and two Plinian deposits reflect explosive eruptions of more differentiated magmas. A debris-avalanche deposit (about 1.2 km3) formed hummocks at the base of the 1,000-m-high, fractured and unstable south flank before 3.6 ka. Countless explosive events took place inside the summit caldera during the last 9.7 ky. The last Plinian eruption, dated A.D.1000-1160, produced an andesitic pumice-fall deposit, which achieved a thickness of 25 cm 40 km SE of the summit. Minor eruptions since then show phreatomagmatic characteristics and a wide range in composition (mafic to rhyolitic): the events reported since A.D. 1550 include many degassing episodes, four moderate (VEI 2-3) eruptions, and one VEI 3 eruption in A.D. 1667. Ubinas erupted high-K, calc-alkaline magmas (SiO2=56 to 71%). Magmatic processes include fractional crystallization and mixing of deeply derived mafic andesites in a shallow magma chamber. Parent magmas have been relatively homogeneous through time but reflect variable conditions of deep-crustal assimilation, as shown in the large variations in Sr/Y and LREE/HREE. Depleted HREE and Y values in some lavas, mostly late mafic rocks, suggest contamination of magmas near the base of the 〉60-km-thick continental crust. The most recently erupted products (mostly scoria) show a wide range in composition and a trend towards more mafic magmas. Recent eruptions indicate that Ubinas poses a severe threat to at least 5,000 people living in the valley of the Rio Ubinas, and within a 15-km radius of the summit. The threat includes thick tephra falls, phreatomagmatic ejecta, failure of the unstable south flank with subsequent debris avalanches, rain-triggered lahars, and pyroclastic flows. Should Plinian eruptions of the size of the Holocene events recur at Ubinas, tephra fall would affect about one million people living in the Arequipa area 60 km west of the summit.
    Description: Published
    Description: 557-589
    Description: partially_open
    Keywords: Andes ; Ubinas ; Radiometric dating ; Geochemistry ; Fractional crystallization ; Mafic magma ; Hazards ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 53
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    Fluid circulation at Stromboli volcano (Aeolian Islands, Italy) from self-potential and CO2 surveys (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This work addresses the study of fluid circulation of the Stromboli island using a dense coverage of self-potential (SP) and soil CO2 data. A marked difference exists between the northern flank and the other flanks of the island. The northern flank exhibits (1) a typical negative SP/altitude gradient not observed on the other flanks, and (2) higher levels of CO2. The general SP pattern suggests that the northern flank is composed of porous layers through which vadose water flows down to a basal water table, in contrast to the other flanks where impermeable layers impede the vertical flow of vadose water. In the Sciara del Fuoco and Rina Grande-Le Schicciole landslide complexes, breccias of shallow gliding planes may constitute such impermeable layers whereas elsewhere, poorly permeable, fine-grained pyroclastites or altered lava flows may be present. This general model of the flanks also explains the main CO2 patterns: concentration of CO2 at the surface is high on the porous north flank and lower on the other flanks where impermeable layers can block the upward CO2 flux. The active upper part of the island is underlain by a well-defined hydrothermal system bounded by short-wavelength negative SP anomalies and high peaks of CO2. These boundaries coincide with faults limiting ancient collapses of calderas, craters and flank landslides. The hydrothermal system is not homogeneous but composed of three main subsystems and of a fourth minor one and is not centered on the active craters. The latter are located near its border. This divergence between the location of the active craters and the extent of the hydrothermal system suggests that the internal heat sources may not be limited to sources below the active craters. If the heat source strictly corresponds to intrusions at depth around the active conduits, the geometry of the hydrothermal subsystems must be strongly controlled by heterogeneities within the edifice such as craters, caldera walls or gliding planes of flank collapse, as suggested by the correspondence between SP^CO2 anomalies and structural limits. The inner zone of the hydrothermal subsystems is characterized by positive SP anomalies, indicating upward movements of fluids, and by very low values of CO2 emanation. This pattern suggests that the hydrothermal zone becomes self-sealed at depth, thus creating a barrier to the CO2 flux. In this hypothesis, the observed hydrothermal system is a shallow one and it involves mostly convection of infiltrated meteoric water above the sealed zone. Finally, on the base of CO2 degassing measurements, we present evidence for the presence of two regional faults, oriented N41‡ and N64‡, and decoupled from the volcanic structures.
    Description: Published
    Description: 1^18
    Description: partially_open
    Keywords: Stromboli ; hydrothermal system ; self-potential ; soil gas ; carbon dioxide ; Aeolian islands ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 54
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    Energetics of chemolithoautotrophy in the hydrothermal system of Vulcano Island, Southern Italy (2006)
    Blackwell
    Details
    Publication Date: 2017-04-04
    Description: The hydrothermal system at Vulcano, Aeolian Islands (Italy), is home to a wide variety of thermophilic,chemolithoautotrophic archaea and bacteria. As observed in laboratory growth studies, these organisms may use an array of terminal electron acceptors (TEAs), including O 2, NO-3,Fe(III),elemental sulphur and CO2; electron donors include H2,Fe2+,H2S and CH4. Concentrations of inorganic aqueous species and gases were measured in 10 hydrothermal fluids from seeps, wells and vents on Vulcano. These data were combined with standard Gibbs free energies ( ) to calculate overall Gibbs free energies (DGr) of 90 redox reactions that involve 16 inorganic N-, S-, C-, Fe-, H- and O-bearing compounds. It is shown that oxidation reactions with O2 as the TEA release significantly more energy (normalized per electron transferred) than most anaerobic oxidation reactions, but the energy yield is comparable or even higher for several reactions in which, or Fe(III) serves as the TEA. For example, the oxidation of CH4 to CO2 coupled to the reduction of Fe(III) in magnetite to Fe2+ releases between 94 and 123 kJ/mol e– , depending on the site. By comparison, the aerobic oxidation of H2 or reduced inorganic N-, S-, C- and Fe-bearing compounds generally yields between 70 and 100 kJ/mol e–. It is further shown that the energy yield from the reduction of elemental sulphur to H2 S is relatively low (8–19 kJ/mol e–) despite being a very common metabolism among thermophiles. In addition,for many of the 90 reactions evaluated at each of the 10 sites, values of DGr tend to cluster with differences 〈 20 kJ/mol e–. However, large differences in DGr up to ~ 60 kJ/mol e–) are observed in Fe redox reactions, due largely to considerable variations in Fe 2+, H + and H2 concentrations. In fact, at the sites investigated, most variations in DGr arise from differences in composition and not in temperature.
    Description: Published
    Description: 37–58
    Description: partially_open
    Keywords: hydrothermal system ; Vulcano Island ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 55
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    Mineral control of arsenic content in thermal waters from volcano-hosted hydrothermal systems: insights from island of Ischia and Phlegrean Fields (Campanian Volcanic Province, Italy) (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: This paper documents arsenic concentrations in 157 groundwater samples from the island of Ischia and the Phlegrean Fields, two of the most active volcano-hosted hydrothermal systems from the Campanian Volcanic Province (Southern Italy), in an attempt to identify the environmental conditions and mineral-solution reactions governing arsenic aqueous cycling. On Ischia and in the Phlegrean Fields, groundwaters range in composition from NaCl brines, which we interpret as the surface discharge of deep reservoir fluids, to shallow-depth circulating fluids, the latter ranging from acid-sulphate steam-heated to hypothermal, cold, bicarbonate groundwaters. Arsenic concentrations range from 1.6 to 6900 μg·l−1 and from 2.6 to 3800 μg·l−1 in the Phlegrean Fields and on Ischia, respectively. They increase with increasing water temperature and chlorine contents, and in the sequence bicarbonate groundwatersbsteam-heated groundwatersbNaCl brines. According to thermochemical modeling, we propose that high As concentrations in NaCl brines form after prolonged water–rock interactions at reservoir T, fO2 and fH2S conditions, and under the buffering action of an arsenopyrite+pyrite+pyrrhotite rock assemblage. On their ascent toward the surface, NaCl brines become diluted by As-depleted meteoric-derived bicarbonate groundwaters, giving rise to hybrid water types with intermediate to low As contents. Steam-heated groundwaters give their intermediate to high As concentrations to extensive rock leaching promoted by interaction with As-bearing hydrothermal steam.
    Description: Published
    Description: 313–330
    Description: reserved
    Keywords: Arsenic geochemistry ; Hydrothermal systems ; Water–rock interaction ; Hydrogeochemistry ; Arsenopyrite ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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    Type: article
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  • 56
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    Human fluorosis related to volcanic activity: a review (2007)
    WIT Press - Southampton, Boston
    Details
    Publication Date: 2017-04-04
    Description: Fluorosis is a widespread disease related to ingestion of high levels of fluorine through water and food. Although sometimes of anthropogenic origin, high levels of fluorine are generally related to natural sources. One of the main sources is represented by volcanic activity, which releases magmatic fluorine generally as hydrogen fluorine through volcanic degassing. For example, Mt. Etna in Italy is considered the greatest point source at the global scale, releasing on average 70 Gg of HF each year. But the impact of fluorine on human health is highly dependent on its chemical state, which means that high rates of release not necessary point to high impacts. The major pathway of magmatic fluorine to humans is in the form of fluoride ion (F-), through consumption of contaminated vegetables and drinking water. Contamination can happen either through direct uptake of gaseous HF or through rainwaters and volcanic ashes. Furthermore hydrogen fluoride, being one of the most soluble gases in magmas, exsolves only partially (〈 20%) during volcanic activity. Volcanic rocks thus contain high levels of fluorine, which are transferred to groundwaters through water-rock interaction processes in the aquifers. Large magmatic provinces, like for example the East African Rift Valley, are therefore endemic for fluorosis. Finally a literature review of volcanic related fluorosis is given.
    Description: Published
    Description: 21-30
    Description: open
    Keywords: Fluorosis ; magmatic fluorine ; volcanic activity ; groundwater ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.08. Risk::05.08.01. Environmental risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 57
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    Methana, the westernmost active volcanic system of the south Aegean arc (Greece): insight from fluids geochemistry (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 58
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    Geochemical evaluation of observed changes in volcanic activity during the 2007 eruption at Stromboli (Italy) (2009)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
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  • 59
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    Mantle-derived carbon in Hercynian granites. 1 Stable isotopes signatures 2 and C/He associations in the thermomineral waters, N-Portugal (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Na–HCO3–CO2-rich thermomineral waters issue in the N of Portugal, within the Galicia-Trás-os-Montes region, linked to a major NNE-trending fault, the so-called Penacova-Régua-Verin megalineament. Along this tectonic structure different occurrences of CO2-rich thermomineral waters are found: Chaves hot waters (67 °C) and also several cold (16.1 °C) CO2-rich waters. The δ2H and δ18O values of the thermomineral waters are similar to those of the local meteoric waters. The chemical composition of both hot and cold mineral waters suggests that water–rock reactions are mainly controlled by the amount of dissolved CO2 (g) rather than by the water temperature. Stable carbon isotope data indicate an external CO2 inorganic origin for the gas. δ13CCO2 values ranging between −7.2‰ and −5.1‰ are consistent with a two-component mixture between crustal and mantle-derived CO2. Such an assumption is supported by the 3He/4He ratios measured in the gas phase, are between 0.89 and 2.68 times the atmospheric ratio (Ra). These ratios which are higher than that those expected for a pure crustal origin (≈0.02 Ra), indicating that 10 to 30% of the He has originated from the upper mantle. Release of deep-seated fluids having a mantle-derived component in a region without recent volcanic activity indicates that extensive neo-tectonic structures originating during the Alpine Orogeny are still active (i.e., the Chaves Depression).
    Description: In press
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: open
    Keywords: CO2-rich thermomineral waters ; mantle volatiles ; isotopes ; Chaves geothermal 9 system ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 60
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    Long term variations of the Campi Flegrei (Italy) volcanic system as revealed by the monitoring of hydrothermal activity (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long duration time-series of the chemical composition of fumaroles and of soil CO2 flux reveal that important variations in the activity of the Solfatara fumarolic field, the most important hydrothermal site of Campi Flegrei, occurred in the 2000-2008 period. A continuous increase of the CO2 concentrations, and a general decrease of the CH4 concentrations are interpreted as the consequence of the increment of the relative amount of magmatic fluids, rich in CO2 and poor in CH4, hosted by the hydrothermal system. Contemporaneously, the H2O-CO2-He-N2 gas system shows remarkable compositional variations in the samples collected after July 2000 with respect to the previous ones, indicating the progressive arrival at the surface of a magmatic component different from that involved in the 1983-84 episode of volcanic unrest (1983-1984 bradyseism). The change starts in 2000 concurrently with the occurrence of relatively deep, long-period seismic events which were the indicator of the opening of an easy-ascent pathway for the transfer of magmatic fluids towards the shallower, brittle domain hosting the hydrothermal system. Since 2000, this magmatic gas source is active and causes ground deformations, seismicity as well as the expansion of the area affected by soil degassing of deeply derived CO2. Even though the activity will most probably be limited to the expulsion of large amounts of gases and thermal energy, as observed in other volcanoes and in the past activity of Campi Flegrei, the behavior of the system in the future is, at the moment, unpredictable.
    Description: Published
    Description: B03205
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; CO2 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 61
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    Long term variations at Campi Flegrei (Italy) volcanic system highlighted by the monitoring of hydrothermal activity (2010)
    Geophysical Research Abstracts; Vol. 11, EGU2009-2419, 2009
    Details
    Publication Date: 2017-04-04
    Description: Long time-series of chemical composition of fumaroles and of soil CO2 flux reveal that important variations in the activity of Solfatara fumarolic field, the most important hydrothermal site of Campi Flegrei, occurred in the 2000- 2008 period. A continuous increase of the CO2 concentration and a general decrease of the CH4 concentration are interpreted as the consequence of the increment of the relative amount of magmatic fluids, rich in CO2 and poor in CH4, hosted by the hydrothermal system. Contemporaneously the H2O-CO2-He-N2 gas system shows remarkable compositional variations in the samples collected after July 2000 with respect to the previous ones, indicating the progressive arrival at the surface of a magmatic component different from that involved in the 1983-84 bradyseism. The change starts in 2000 concurrently with the occurrence of relatively deep long periods seismic events which, in our interpretation, were the indicator of the opening of an easy pathway for the transfer of magmatic fluids towards the shallower, brittle domain hosting the hydrothermal system. Since 2000 this magmatic gas source is active and causes ground deformations, seismicity as well as the expansion of the area interested by diffuse soil degassing of deeply derived CO2.
    Description: Published
    Description: Vienna,Austria
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: Long term variations ; Campi Flegrei ; monitoring ; hydrothermal activity ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 62
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    Active geodynamics of the central Mediterranean Sea: Tensional tectonic evidences in western Sicily from mantle-derived helium (2005)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: We report results on the measured high 3He/4He isotope ratio in western Sicily, interpreted together with the heat data. The study of this sector of the Europe-Africa interaction is crucial to a better understanding of the tectonics and the geodynamical evolution of the central Mediterranean area. The estimated mantle-derived helium fluxes in the investigated areas are up to 2–3 orders of magnitude greater than those of a stable continental area. The highest flux, found in the southernmost area near the Sicily Channel, where recent eruptions of the Ferdinandea Island occurred 20 miles out to sea off Sciacca, has been associated with a clear excess of heat flow. Our results indicate that there is an accumulation of magma below the continental crust of western Sicily that is possibly intruding and out-gassing through roughly N-S trending deep fault systems linked to the mantle, that have an extensional component. Although the identification of these faults is not sufficiently constrained by our data, they could possibly be linked to the pre-existing faults that originated during the Mesozoic extensional-transtensional tectonic phases.
    Description: Published
    Description: L04312
    Description: partially_open
    Keywords: helium isotopes ; heat production ; tectonics ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics
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  • 63
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    Dissolved helium isotope ratios in ground-waters: a new technique based on gas–water re-equilibration and its application to Stromboli volcanic system (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Here, a new technique for the determination of dissolved He isotope ratios in ground-waters is presented. This method is based on the extraction and subsequent equilibrium of dissolved gases in an added ‘‘host’’ gas phase. Ultra pure N2 is placed in glass flasks (250 cc), containing water samples, that were hermetically sealed after their collection. After shaking in an ultrasonic bath for 10 min, an aliquot of the separated gas phase was removed from the flask for MS analysis. 3He/4He ratios are measured by using a modified double collector mass spectrometer (VG 5400-TFT). Helium and Ne concentrations are calculated by comparing the partial pressures of masses 4 and 20 of the samples with those of the air-standard measured by a quadrupole mass spectrometer (QMS;VG Quartz). Using He and Ne equilibrium partitioning coefficients, it is possible to calculate the amount of gas originally dissolved in the water. The technique was tested on both air-saturated waters (ASW) and thermal waters from Stromboli (Aeolian Islands, South Italy), the results of which confirmed good reproducibility (ffi5%) and accuracy (ffi3%) of the data. The method was then applied to three thermal water samples collected from the same volcanic area and the results compared with those of a fumarolic and a soil gas. The isotope ratios for dissolved He gave values of 4.06–4.23 Ra, which are significantly higher than those previously reported in the literature (3.0, 3.5 and 2.9 Ra) and that measured at the fumarole (3.09 Ra), suggesting a newer and higher isotopic signature for the volcanic system. The proposed method appears to be a useful tool in the determination of 3He/4He ratios in ground-water systems, especially when free gases are not available or are dangerous to collect.
    Description: Published
    Description: 665–673
    Description: partially_open
    Keywords: dissolved helium isotopes ; gas water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 64
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    Isotopic, chemical and dissolved gas constraints on spring water from Popocatepetl volcano (Mexico): evidence of gas–water interaction between magmatic component and shallow fluids (2005)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Geochemical research was carried out on cold and hot springs at Popocatepetl (Popo) volcano (Mexico) in 1999 to identify a possible relationship with magmatic activity. The chemical and isotopic composition of the fluids is compatible with strong gas–water interaction between deep and shallow fluids. In fact, the isotopic composition of He and dissolved carbon species is consistent with a magmatic origin. The presence of a geothermal system having a temperature of 80–1008 C was estimated on the basis of liquid geothermometers. A large amount of dissolved CO2 in the springs was also detected and associated with high CO2 degassing.
    Description: Published
    Description: 91– 108
    Description: partially_open
    Keywords: Popocatepetl volcano ; helium isotope composition ; carbon isotope composition ; dissolved gases ; gas–water interaction ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 65
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    Eddy covariance measurements of geothermal heat flux at Solfatara Volcano, Naples, Italy (2007)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The first measurements of volcanic/hydrothermal water vapor and heat flux using eddy covariance (EC) were made at Solfatara crater, Italy, June 8–25, 2001. Deployment at six different locations within the crater allowed areas of focused gas venting to be variably included in the measured flux. Turbulent (EC) fluxes of water vapor varied between 680 and 11200g H2O m−2 d−1. Heat fluxes varied diurnally with the solar input, and the volcanic component of sensible heat ranged from ∼25 to 238W m−2. The highest measurements of both sensible and latent heat flux were made downwind of hot soil regions and degassing pools and during mid-day. The ratio of average volcanic heat (both latent and sensible) to CO2 flux resulted in an equivalent H2O/CO2 flux ratio of 2.2 by weight, which reflects the deep source H2O/CO2 gas ratio. The amount latent heat flux/evaporation was determined to be consistent both with what would be expected from the magnitude of CO2 fluxes and the fumarolic H2O/CO2 ratio, as well as with observed surface temperatures and wind speeds given a moist soil. This suggests that the water vapor that condenses in the shallow subsurface is remobilized at the soil–atmosphere interface through variable evaporation dependent on the deep heat flux and surface temperature. The results suggest that EC provides a quick and easy method to monitor average H2O/CO2 ratios continuously in volcanic regions, providing another important tool for volcanic hazards monitoring.
    Description: Published
    Description: 72–82
    Description: reserved
    Keywords: eddy covariance ; volcanic ; heat flux ; water vapor ; hydrothermal ; degassing ; flux ; emissions ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 66
    facet.materialart.
    Unknown
    Geochemistry of the submarine gaseous emissions of Panarea (Aeolian Islands, Southern Italy): magmatic vs. hydrothermal origin and implications for volcanic surveillance (2007)
    Birkhauser Verlag
    Details
    Publication Date: 2017-04-04
    Description: Abstract—The marine sector surrounding Panarea Island (Aeolian Islands, South Italy) is affected by widespread submarine emissions of CO2 -rich gases and thermal water discharges which have been known since the Roman Age. On November 3rd, 2002 an anomalous degassing event affected the area, probably in response to a submarine explosion. The concentrations of minor reactive gases (CO, CH4 and H2) of samples collected in November and December, 2002 show drastic compositional changes when compared to previous samples collected from the same area in the 1980s. In particular the samples collected after the November 3rd phenomenon display relative increases in H2 and CO and a strong decrease in the CH4 contents, while other gas species show no significant change. The interaction of the original gas with seawater explains the variable contents of CO2, H2S, N2, Ar and He which characterize the different samples, but cannot explain the large variations of CO, CH4 and H2 which are instead compatible with changes in the redox, temperature and pressure conditions of the system. Two models, both implying an increasing input of magmatic fluids are compatible with the observed variations of minor reactive species. In the first one, the input of magmatic fluids drives the hydrothermal system towards atypical (more oxidizing) redox conditions, slowly pressurizing the system up to a critical state. In the second one, the hydrothermal system is flashed by the rising high-T volcanic fluid, suddenly released by a magmatic body at depth. The two models have different implications for volcanic surveillance and risk assessment: In the first case, the November 3rd event may represent both the culmination of a relatively slow process which caused the overpressurization of the hydrothermal system and the beginning of a new phase of quiescence. The possible evolution of the second model is unforeseeable because it is mainly related to the thermal, baric and compositional state of the deep magmatic system that is poorly known.
    Description: Published
    Description: reserved
    Keywords: NONE ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 67
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    Geochemical and biochemical evidence of lake overturn and fish-kill at Lake Averno, Italy. (2007)
    Details
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumable, as a result of lake overturn. This fish-kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic composition of Lake Averno waters suggests an origin by mixing of shallow waters with a Na-Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14-22 μmol.m-2.day-1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7°C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Submitted
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: open
    Keywords: Lake Averno ; dissolved gases ; stable isotopes ; fish kill event ; Sulfate Reduction Bacterial ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 68
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    Unknown
    Carbon isotopic composition of soil CO2 efflux, a powerful method to discriminate different sources feeding soil CO2 degassing in volcanic-hydrothermal areas (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A new method combining measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux was developed in order to qualitatively and quantitatively characterise the CO2 source feeding the soil CO2 diffuse degassing. The method was tested in March 2007 at the Solfatara of Pozzuoli volcano degassing area (Naples, Italy) where more than 300 measurements of soil CO2 flux and determinations of the carbon isotopic composition of soil CO2 efflux were performed, surveying Solfatara crater and its surroundings. The wide range of CO2 flux and CO2 isotopic composition values (from 8.4 g m−2 d−1 to 28,834 g m−2 d−1, and from 0.73‰ to −33.54‰, respectively), together with their statistical distributions suggests the occurrence of multiple CO2 sources feeding soil degassing. The combined interpretation of flux and isotopic data allows us to identify and characterise two distinct gas sources: a hydrothermal and a biogenic source. The soil CO2 from the hydrothermal source is characterised by a mean δ13CCO2 of −2.3‰±0.9‰, hence close to the isotopic composition of the fumarolic CO2 (δ13CCO2=−1.48‰± 0.22‰) and by a mean CO2 flux of 2875 g m−2 d−1. The CO2 from the biogenic source is characterised by a mean δ13CCO2 of −19.4‰±2.1‰, and by a mean CO2 flux of 26 g m−2 d−1, which are both in the range of the typical values for biologic CO2 soil degassing. This reliable characterisation of the biogenic CO2 flux would not have been possible by solely applying a statistical analysis of the CO2 flux values, which is commonly applied in volcanological studies for the partitioning between background fluxes and anomalous CO2 fluxes. A map of the Solfatara diffuse degassing structure was derived from the estimated threshold for the biogenic CO2 flux, highlighting that soil degassing of hydrothermal CO2 mixed in different proportion with biogenic CO2 occurs over a large area (~0.8 km2), which extends over the inner part of the Solfatara crater as well as the eastern periphery, corresponding with a NW–SE fault system. The presented method and data analysis are important means of surveillance of the volcanic activity.
    Description: Published
    Description: 372–379
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: CO2 soil degassing ; CO2 flux ; carbon dioxide ; carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 69
    facet.materialart.
    Unknown
    Geochemical and biochemical evidence of lake overturn and fish kill at Lake Averno, Italy (2008)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Lake Averno is situated in the homonymous crater in the northwestern sector of the Campi Flegrei active volcanic system in Campania region, Italy. In February 2005 a fish kill event was observed in the lake, prompting a geochemical survey to ascertain the possible cause. In February 2005 a geochemical survey revealed that the lake water was unstratified chemically and isotopically, presumably, as a result of lake overturn. This fish kill phenomenon was recorded at least two other times in the past. In contrast to the February 2005 results, data collected in October 2005, shows the Lake Averno to be stratified, with an oxic epilimnion (surface to 6 m) and an anoxic hypolimnion (6 m to lake bottom at about 33 m). Chemical and isotopic compositions of Lake Averno waters suggest an origin by mixing of shallow waters with a Na–Cl hydrothermal component coupled with an active evaporation process. The isotopic composition of Dissolved Inorganic Carbon, as well as the composition of the non-reactive dissolved gas species again supports the occurrence of this mixing process. Decreasing levels of SO4 and increasing levels of H2S and CH4 contents in lake water with depth, strongly suggests anaerobic bacterial processes are occurring through decomposition of organic matter under anoxic conditions in the sediment and in the water column. Sulfate reduction and methanogenesis processes coexist and play a pivotal role in the anaerobic environment of the Lake Averno. The sulfate reducing bacterial activity has been estimated in the range of 14–22 μmol m−2 day−1. Total gas pressure of dissolved gases ranges between 800 and 1400 mbar, well below the hydrostatic pressure throughout the water column, excluding the possibility, at least at the survey time, of a limnic eruption. Vertical changes in the density of lake waters indicate that overturn may be triggered by cooling of epilimnetic waters below 7 °C. This is a possible phenomenon in winter periods if atmospheric temperatures remain frosty for enough time, as occurred in February 2005. The bulk of these results strongly support the hypothesis that fish kill was caused by a series of events that began with the cooling of the epilimnetic waters with breaking of the thermal stratification, followed by lake overturn and the rise of toxic levels of H2S from the reduced waters near the lake bottom.
    Description: Published
    Description: 305–316
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: lake Averno ; dissolved gases ; stable isotopes ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 70
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    Water chemistry, fluid-rock interaction processes and new estimates of deep temperatures in the Colli Albani volcano, central Italy (2008)
    Details
    Publication Date: 2017-04-04
    Description: In the framework of a multidisciplinary project funded by the Italian “Dipartimento della Protezione Civile”, focused on the Alban Hills volcanic district (Central Italy), a detailed geochemical survey in groundwater was carried out in 2006-2007 in the Alban Hills area (central Italy), sampling a total of 183 water sites (springs and wells), Figure 1. Physical-chemical parameters and, on selected samples, main chemistry, minor and trace element contents, as well as dissolved gases were analyzed. The study had the main goals to: i) characterise the chemical background of the discharging fluids, gathered in a period with low seismicity; ii) define the main gas-water-rock interaction processes presently ongoing and iii) give reliable estimates of the deep aquifer temperatures, only partially performed till now. The bulk of the samples fall in the field of the earth (alkaline)- bicarbonate waters, while some of them show alkaline-bicarbonate and acid-sulphate chemistry. Earth (alkaline)-bicarbonate waters have a relatively fast circulation in the volcanic rocks in a low temperature environment; in some sectors of the volcano they receive a huge gas input from below (mainly CO2). Waters with longer interaction with volcanic rocks and/or clays, in presence of CO2, evolve towards the alkaline-bicarbonate field. Acid-sulphate waters are formed by dissolution of acid and reducing gases (CO2, H2S) into oxygen-rich shallow aquifers. CO2 and N2 are the principal dissolved gases. Nitrogen, in particular, characterises shallow waters (atmospheric component), while carbon dioxide has a prevalent deep origin. H2S, He and H2 show very low contents, while methane was found both in same CO2-rich waters and shallow samples. The main gas-water-rock interaction processes and their extent were assessed by means of activity plots. Waters can be divided into two main groups: i) earth (alkaline)- bicarbonate waters fall prevalently in the field of kaolinite, representing the early stage of the silicate weathering. They show under-saturation with respect to the main rock-forming minerals, and are considered as “immature” ii) alkaline-bicarbonate show a partial equilibrium with the main clay minerals, representing an evolution towards more “mature” terms. Acid-sulphate waters are out of any equilibrium with the host rocks and were not considered. Physical-chemical parameters and observed chemistry fully fit this chemical scenario. Statistical assessment (Factor Analysis) was used to emphasise the main geochemical processes affecting groundwater, accounting for their observed different chemical evolutions. Geothermometric estimations allowed to define the geothermal system beneath the volcano as characterised by a medium-low enthalpy, with temperatures comprised in the range 110-140°C.
    Description: Unpublished
    Description: Iceland
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: gas and water geochemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 71
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    Geochemistry of gas and water at the CA1 borehole (Alban Hills volcano, central Italy): new insights on deep fluids circulation and origin (2008)
    Details
    Publication Date: 2017-04-04
    Description: In the framework of a multidisciplinary project funded by the Italian “Dipartimento della Protezione Civile”, focused on the Alban Hills volcanic district (Central Italy), a 350 m deep borehole (named CA1) was drilled for geophysical and petrographic explorations (Mariucci et al., 2008). The borehole is located near Santa Maria delle Mole village (onwards SMM), adjacent to the western rim of the Tuscolano-Artemisio caldera, where several phenomena of unrest recently occurred (i.e. seismicity, episodes of gas exhalation from soil and/or gas burst, Figure 1). Gas exhalation can occurs due to i) human activity (removal of the shallow impermeable fine-grained sediments that discontinuously cover the area) and drillings (mainly for water supply) intercepting pressurised gas pockets that form at depth (the last episode occurred few kilometres from the CA1 well in June 2008) and ii) natural causes (i.e. opening of new cracks and variation of the fracture networks in the pervious shallow sediments, mainly clays) due to changes in the local/regional stress field and/or local seismic activity. All these phenomena caused in the past illness and casualties among local inhabitants and animals, marking the considered area as exposed to a high Natural Gas Hazard. During the phase of hydraulic fracturing tests at the CA1 borehole, in a sandy unit at a depth between 345 and 350m, a blow-out occurred (Figure 2), causing the collapse of its deepest part. In order to emphasise the origin of the fluids emitted from the CA1 borehole (gas mainly, with minor water) and to highlight the main gas-water-rock interaction processes that account for the observed chemistry, gas and water were collected and analysed for their chemical and isotopic characterisation. Moreover, for a general discussion on the fluid geochemistry of the Alban Hills and on the ongoing degassing processes, water and gas compositions are discussed and compared together with other new data (samples collected in 2006-2007). New geochemical data provided additional information about both the deep volcanic circulation of fluids and their possible connection to a deep-seated magma chamber. Furthermore, CA1 borehole provided very important information for identifying the depth, the thickness and the spatial location of both the fine-grained sediments and the impervious layers in order to mitigate and, possibly, prevent further harmful gas escapes. All these geological and stratigraphical data were still unknown for the SMM sector; the CA1 borehole provided very useful information and filled this gap of knowledge.
    Description: Unpublished
    Description: Iceland
    Description: 4.5. Degassamento naturale
    Description: open
    Keywords: fluid isotopes, water and gas chemistry ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 72
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    Mercury content and speciation in the Phlegrean Fields volcanic complex: Evidence from hydrothermal system and fumaroles (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Mercury is outstanding among the global environmental pollutants of continuing concern. Although degassing of active volcanic areas represents an important natural source of mercury into the atmosphere, still little is known about the amount and behaviour of Hg in volcanic aquifers, especially regarding its chemical speciation. In order to assess the importance of mercury emissions from active volcanoes, thermal waters were sampled in the area surrounding La Solfatara, Pozzuoli bay. This is the most active zone of the Phlegrean Fields complex (coastal area north–west of Naples), with intense hydrothermal activity at present day. Studied groundwaters show total Hg (THg) concentrations range from 56 to 171 ng/l and are lower than the 1000 ng/l threshold value for human health protection fixed by the World Health Organization (WHO, 1993). We also carefully discriminated the different aqueous species of Hg in the collected water samples. Besides, original data on Hg determination in gaseous manifestations at La Solfatara crater are also reported. We measured volcanogenic mercury concentration and Hg/Stot ratio both in the volcanic plume and in fumarolic condensates in order to better constrain Hg reactivity once emitted into the atmosphere. Data on Hg/Stot reveal that there is no significant difference between Hg volcanic composition at the venting source (fumaroles) and in near-vent diluted volcanic plumes (1.6×10−5 and 1.9×10−5, respectively), suggesting that there is limited Hg chemical processing in volcanic fumarole plumes, at least on the timescales of a few seconds investigated here. Combining the mean fumaroles Hg/CO2 mass ratio of about 1.3×10−8 (molar ratio: 2.1×10−9) with the hydrothermal soil diffuse CO2 degassing of the area, the annual Hg flux from La Solfatara is estimated as 7 kg y−1 (0.007 t y−1). Current mercury emission from La Solfatara volcano represents a very small contribution to the estimated global volcanic budget for this element, and the estimated Hg flux is considerably lower than that estimated from open-conduit active basaltic volcanoes.
    Description: Published
    Description: 250–260
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal waters ; total mercury ; mercury speciation ; fumaroles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 73
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    CO2/CH4 ratio in fumaroles a powerful tool to detect magma degassing episodes at quiescent Volcanoes (2010)
    American Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: Long time series of fumarolic compositions at Campi Flegrei (Italy), Mammoth Mountain (California), Panarea (Italy) and Nisyros (Greece) show rapid increases, up to orders of magnitude, of the CO2/CH4 ratio systematically with the occurrence of volcanic unrest periods. These easily detected anomalies originate with the arrival of CH4-poor magmatic fluids in the shallower levels of the volcanoes. The data suggest that volcanoes are characterized by magmatic activity at depth also in periods of apparent quiescence. The activity is constituted by the pulsing release of large amount of fluids which either cause unrest periods (seismicity and ground deformation) or possibly could precede volcanic eruption. This type of volcanic activity can be monitored trough the classical geophysical techniques together with the systematic sampling and analysis of fumaroles.
    Description: Published
    Description: L02302
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: reserved
    Keywords: CO2/CH4 ; magma degassing ; quiescent volcanoes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
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  • 74
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    Magma degassing episodes and volcanic unrest periods in quiescent volcanoes (2010)
    Details
    Publication Date: 2017-04-04
    Description: Long time series of fumarolic chemical and isotopic compositions, at Solfatara (Campi Flegrei) and Vulcano highlight the occurrence of mixing processes among magmatic and hydrothermal fluids. At Solfatara temperatures of about 360°C of the hydrothermal system are inferred by methane chemical-isotopic geoindicators and by the H2/Ar geothermometer. These high temperatures are representative of a deep zone where magmatic gases flash hydrothermalliquid forming a gas pIume where the kinetically fast reactive species (H2 and CO) re-equilibrate at temperatures of 200240°C. The stable isotope compositions of the two dominant species, i.e, H20 and C02, shows that sampled effluents are mixture between magmatic fluids and the vapor generated at about 360°C by the vaporization of hydrothermalliquids of meteotic origino Similar mixing processes between magmatic fluids and a hydrothermal component of marine origin have been recognized at Vulcano high temperature fumaroleso In both the system a typical 'andesitic' water type composition and high C02 contents characterizes the magmatic component. Our hypothesis is that pulsing injections of these C02-rich magmatic fluids at the bottom of the hydrothermal systems trigger the bradyseismic crises, periodically affecting Campi Flegrei, and the periodical volcanic unrest periods of Vulcano. At Campi Flegrei a strong increase of the fraction of the magmatic component, marked in fact the bradyseismic crisis of 1982-84 and four minor episodes occurred in 1989, 1994 and 2000 and 2006. Increases of the magmatic component in the fumaroles of Vulcano were recorded in 1979-1981, 1985, 1988, 1996, 2004 and 2005 concurrently with anomalous seismic activity localized in the erater area. Physical-numerical simulations of the injection of hot, C02 rich fluids at the base of a hydrothermal system, asses the physical feasibility the processo Ground deformations, gravitational anomalies and seismic crisis can be well explained by the complex fluid dynamic processes caused by magma degassing episodes. Data on the fumaroles of other volcanoes, for example Vesuvio, Panarea, Nisyros (Greece), Mammoth (California), suggest that magma degassing episodes frequently occur in dormant volcanoes causing volcanic unrest processes not necessarily linked to magma movement but rather to pulsating degassing processes from deep pressurized, possibly stationary, magma bodies.
    Description: INGV; AIV; Comune di Nicolosi(POrta dell'Etna)
    Description: Unpublished
    Description: Nicolosi(Catania)
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: magma degassing ; fumarolic ; methane ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Abstract
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  • 75
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    CO2 degassing at La Solfatara volcano (Phlegrean Fields): Processes affecting d13C and d18O of soil CO2 (2010)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: The soil CO2 degassing is affected by processes of isotope exchange and fractionation during transport across the soil, which can deeply modify the pristine isotope composition. This has been observed in the Solfatara volcano, upon a field survey of 110 points, where the CO2 flux was measured, together with temperature, CO2 concentration and oxygen and carbon isotopes within the soil. Furthermore, in some selected sites, the measurements were made at different depths, in order to analyze vertical gradients. Oxygen isotope composition appears controlled by exchange with soil water (either meteoric or fumarolic condensate), due to the fast kinetic of the isotopic equilibrium between CO2 and water. Carbon isotope composition is reliably controlled by transport-driven fractionation, due to the differences in diffusion coefficients between 13C16O2 and 12C16O2. We model the processes affecting CO2 transport across the soil in La Solfatara volcano by means of the Dusty Gas Model applied to a multicomponent system, to evaluate the reciprocal effect on diffusion of involved gases, i.e. 12C16O2, 13C16O2, N2 and O2 in our case. Both numerical and simplified analytical solutions of the equations based on the Dusty Gas Model are given. The modeling results fit well with the experimental data and put in evidence an isotope fractionation of carbon up to about þ4:4& with respect to the source value in the soil gas. This fractionation is independent from the entity of the CO2 flux, and occurs as long as a concentration gradient exists within the soil. On these grounds, the Dusty Gas Model can be applied to whichever diffusing gas mixture to evaluate the extent of chemical and/or isotopic fractionation that can affect ascending gases upon diffusion in any geothermal, volcanic or tectonic area.
    Description: Published
    Description: 3521-3528
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: isotope exchange ; degassing ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 76
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    THE HISTORICAL INVESTIGATIONS OF CAMPANIAN VOLCANOES: CONSTRAINS FOR MAGMA SOURCE LOCATION AND GEOTHERMAL POTENTIAL ASSESSMENT (2011)
    Details
    Publication Date: 2017-04-04
    Description: xxxx
    Description: Published
    Description: Trieste
    Description: 3.6. Fisica del vulcanismo
    Description: open
    Keywords: Geotherm ; Geothermal Potential ; Campi Flegrei ; Vesuvio ; Ischia ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 77
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    Secondary hydrothermal minerals in buried rocks at the campi flegrei caldera, Italy: a possible tool to understand the rock-physics and to assess the state of the volcanic system (2012)
    Edizioni Nuova Cultura
    Details
    Publication Date: 2017-04-04
    Description: The distribution of the alteration assemblages and the related physico-chemical changes induced in the rocks with depth, may provide useful information on the state of the system. Drillholes are the only way to define hydrothermal alteration depth-profiles in variable geological contexts. Deep drillings exploiting programs were conducted since the 1970’s by the Agip-Enel Joint Venture in the Quaternary Campi Flegrei caldera (southern Italy), where a geothermal system has been active since at least historical times. New macroscopic and microscopic investigations were performed on selected samples made available by Agip in order to: 1) define the precursor lithology, 2) describe the relationships among texture, mineralogy and depth of the studied core samples and 3) examine the character of the secondary minerals and their distribution with depth and temperature. The new data are integrated with physical properties and elastic parameters of cored rocks, as well as structural information and field data, all available from the physical, seismological, geodetical and volcanological literature. The depth-related multi-parameters profiles provide evidence on the different behavior of the buried rocks beneath the Licola 1, Mofete and San Vito 1 areas, sited in three structurally different sectors of the caldera. The features of the hydrothermally altered rocks are a key to interpret the heterogeneities of the Campi Flegrei substratum, as deduced by velocity, attenuation and scattering P- and S- waves tomography. The time and space distribution of both the eruptive vents and the extruded magma volumes are consistent with the results of our analysis. Therefore, we interpret the observed Campi Flegrei geothermal system as a response to the distribution of volcanic activity in two structurally distinct sectors of the caldera. The central-eastern sector, where the San Vito 1 well was drilled, represents the preferential pathways for both gas escape and magma ascent at least since 8 kyrs, in contrast with the other sites of the caldera where eruptions occurred with minor frequency and magnitude.
    Description: EU-VIIFP GEISER project (ENERGY.2009.2.4.1)
    Description: Published
    Description: 385-406
    Description: 3.5. Geologia e storia dei vulcani ed evoluzione dei magmi
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; elastic proprieties ; geothermal system ; hydrothermal minerals ; volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 78
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    Detection of fresh and thermal waters over an island with extinct volcanism: the island of Salina (Aeolian arc, Italy) (2012)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: A geochemical prospection of the fluids circulating over a volcanic island highlighted the existence of reservoirs of both fresh and thermal water although only a few natural manifestation, mainly occurring in submarine environment, provide clues of their existence. Coupling the information provided by the diffuse gas bubbling and the low-salinity waters discharged from the sea floor off the Island with those from the low-salinity and thermal waters collected from in-land wells drilled in recent times we found that a large amount of fresh and thermal waters are continuously discharged at the sea level. The thermal waters, collected at a temperature of 32-36°C, show a typical marine recharge with equilibrium temperatures estimated to be in the range of 120-160°C. As matter of fact, the small island holds relatively large reservoirs of both fresh and thermal waters. The geochemical features of the circulating fluids are driven by water-rock and gas-water interaction processes, while the heat supplied to the geothermal reservoir comes from volcanic rocks that are still cooling down after the end of the last volcanic activity supposed to be not older than 13ky.
    Description: Published
    Description: 39-49
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: N/A or not JCR
    Description: restricted
    Keywords: geochemistry ; thermal fluids ; volcanism ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 79
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    Societal need for improved understanding of climate change, anthropogenic impacts, and geo-hazard warning drive development of ocean observatories in European Seas (2011)
    Elsevier
    Details
    Publication Date: 2017-04-04
    Description: Society’s needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised.
    Description: Published
    Description: 1-33
    Description: 3.7. Dinamica del clima e dell'oceano
    Description: JCR Journal
    Description: reserved
    Keywords: Seafloor and water columnobservatories ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 80
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    Active hydrothermal discharge on the submarine Aeolian Arc (2011)
    AGU
    Details
    Publication Date: 2017-04-04
    Description: In November 2007 we conducted a water column and seafloor mapping study of the submarine volcanoes of the Aeolian Arc in the southern Tyrrhenian Sea aboard the R/V Urania. On 26 conductivity‐temperature‐depth casts and tows we measured temperature, conductivity, pressure, and light scattering and also collected discrete samples for helium isotopes, methane, and pH. The 3He/4He isotope ratio, an unambiguous indicator of hydrothermal input, showed a clear excess above background at 6 of the 10 submarine volcanoes surveyed. Marsili seamount had the highest anomaly, where the 3He/4He ratio reached a d3He value of 23% at 610 m depth compared with background values of ∼5%. Smaller but distinct d3He anomalies occurred over Palinuro, Enarete, Eolo, Sisifo, and Secca del Capo. Although hydrothermal emissions are known to occur offshore of some Aeolian subaerial volcanoes, and hydrothermal deposits have been sampled throughout the arc, our results are the first to confirm active discharge on Marsili, Enarete, Eolo, Sisifo, and Secca del Capo. Samples collected over Lametini, Filicudi North, Alicudi North, and Alcione had d3He near the regional background values, suggesting either absence of, or very weak, hydrothermal activity on these seamounts. Hydrocasts between the volcanoes revealed a consistent d3He maximum between 11% and 13% at 2000mdepth throughout the SE Tyrrhenian Sea. The volcanoes of the Aeolian arc and the Marsili back arc, all 〈1000 m deep, cannot contribute directly to this maximum. This deep 3He excess may be a remnant of tritium decay or may have been produced by an unknown deep hydrothermal source.
    Description: Published
    Description: B02102
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: hydrothermal systems ; helium ; Tyrrhenian sea ; seamounts ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 81
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    The geothermal potential of Campanian volcanoes: evaluation and opportunities. (2011)
    Details
    Publication Date: 2017-04-04
    Description: xx
    Description: Published
    Description: Vienna Austria
    Description: 3.6. Fisica del vulcanismo
    Description: open
    Keywords: Campanian volcanoes ; Ischia ; Vesuvio ; Campi Flegrei ; Geothermal potential ; geothermic ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 82
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    THE CAMPI FLEGREI DRILLING PROJECT "CFDDP": UNDERSTANDING THE MAGMA-WATER INTERACTION AT LARGE COLLAPSE CALDERAS (2011)
    Details
    Publication Date: 2017-04-04
    Description: x
    Description: Published
    Description: Trieste
    Description: 3.6. Fisica del vulcanismo
    Description: open
    Keywords: Campi Flegrei Deep Drilling Project ; Campi Flegrei ; Magma-water interaction ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 83
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    The fluids’ geochemistry along the "Sperchios Basin - Northern Evoikos Gulf" Graben, a geodynamically complex area of Central Greece (2013)
    European Geophysical Union
    Details
    Publication Date: 2017-04-04
    Description: The study area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence at depth of a subduction slab responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). Its high geothermal gradient is evidenced by the presence of many thermal springs with temperatures from 19 to 82 C, issuing along the normal faults bordering the graben. In the period 2004-2012 about 50 gas and water samples have been collected and their chemical and isotopic analysis revealed a wide range of compositions. Going from west to east the gas composition changes from CH4- to CO2-dominated passing through mixed N2- CH4 and N2-CO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (0.05 R/Ra) up to 0.87 R/Ra (corrected for air contamination), showing in the easternmost sites a small but significant mantle input. Isotopic composition of CH4-C indicates a thermogenic origin for the CH4-rich samples and hydrothermal origin for the remaining samples. Positive 15N values indicate a contribution of crustal derived nitrogen for the N2-rich samples. The 13C values of most the CO2-enriched samples show a mixed origin (mantle and marine carbonates). Also the chemical composition of the waters shows differences along the graben and two main groups can be separated. The first, represented by dilute waters (E.C. 〈 600 S/cm), is found in the westernmost sites characterised by the presence of CH4-rich and mixed N2-CH4 gases. The remaining waters display higher salinities (E.C. from 12 to 56 mS/cm) due to the mixing with a modified marine component. Only the water composition of easternmost sites in the Giggenbach’s cation triangular graph plots in the field of the partially equilibrated waters giving estimated temperatures at depth of 150-160 C.
    Description: Published
    Description: Vienna, Austria
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: hydrothermal systems ; gas chemistry ; water chemistry ; stable isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 84
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    Geophysical and geochemical methods applied to investigate fissure-related hydrothermal systems on the summit area of Mt. Etna volcano (Italy) (2015)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: A multidisciplinary approach integrating self-potential, soil temperature, heat flux, CO2 efflux and gravity gradiometry signals was used to investigate a relatively small fissure-related hydrothermal systemnear the summit of Mt. Etna volcano (Italy). Measurements were performed through two different surveys carried out at the beginning and at the end of July 2009, right after the end of the long-lived 2008–2009 flank eruption and in coincidencewith an increase in diffuse flank degassing related to a reactivation of the volcano, leading to the opening of a new summit vent (NSEC). The main goal was to use a multidisciplinary approach to the detection of hidden fractures in an area of evident near-surface hydrothermal activity. Despite the different methodologies used and the different geometry of the sampling grid between the surveys, all parameters concurred in confirming that the study area is crossed by faults related with the main fracture systems of the south flank of the volcano,where a continuous hydrothermal circulation is established. Results also highlighted that hydrothermal activity in this area changed both in space and in time. These changes were a clear response to variations in themagmatic system, notably tomigration of magma at various depth within the main feeder systemof the volcano. The results suggest that this specific area, initially chosen as the optimal test-site for the proposed approach, can be useful in order to get information on the potential reactivation of the summit craters of Mt. Etna.
    Description: Istituto Nazionale di Geofisica e Vulcanologia — Sezione di Catania — Osservatorio Etneo
    Description: Published
    Description: 111-125
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: restricted
    Keywords: Etna volcano ; Hydrothermal system ; Fractures systems ; Multidisciplinary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 85
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    Quantitative models of hydrothermal fluid–mineral reaction: The Ischia case (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: The intricate pathways of fluid–mineral reactions occurring underneath active hydrothermal systems are explored in this study by applying reaction path modelling to the Ischia case study. Ischia Island, in Southern Italy, hosts a well-developed and structurally complex hydrothermal system which, because of its heterogeneity in chemical and physical properties, is an ideal test sites for evaluating potentialities/limitations of quantitative geochemical models of hydrothermal reactions. We used the EQ3/6 software package, version 7.2b, to model reaction of infiltrating waters (mixtures of meteoric water and seawater in variable proportions) with Ischia’s reservoir rocks (the Mount Epomeo Green Tuff units; MEGT). The mineral assemblage and composition of such MEGT units were initially characterised by ad hoc designed optical microscopy and electron microprobe analysis, showing that phenocrysts (dominantly alkali–feldspars and plagioclase) are set in a pervasively altered (with abundant clay minerals and zeolites) groundmass. Reaction of infiltrating waters with MEGT minerals was simulated over a range of realistic (for Ischia) temperatures (95–260 C) and CO2 fugacities (10 0.2 to 100.5) bar. During the model runs, a set of secondary minerals (selected based on independent information from alteration minerals’ studies) was allowed to precipitate from model solutions, when saturation was achieved. The compositional evolution of model solutions obtained in the 95– 260 C runs were finally compared with compositions of Ischia’s thermal groundwaters, demonstrating an overall agreement. Our simulations, in particular, well reproduce the Mg-depleting maturation path of hydrothermal solutions, and have end-ofrun model solutions whose Na–K–Mg compositions well reflect attainment of full-equilibrium conditions at run temperature. High-temperature (180–260 C) model runs are those best matching the Na–K–Mg compositions of Ischia’s most chemically mature water samples, supporting quenching of deep-reservoir conditions for these surface manifestations; whilst Fe, SiO2 and, to a lesser extent, SO4 contents of natural samples are better reproduced in low-temperature (95 C) runs, suggesting that these species reflect conditions of water–rock interaction in the shallow hydrothermal environment. The ability of model runs to reproduce the compositional features of Ischia’s thermal manifestations, demonstrated here, adds supplementary confidence on reaction path modelling as a realistic and insightful representation of mineral–fluid hydrothermal reactions. Our results, in particular, demonstrate the significant impact of host rock minerals’ assemblage in governing the paths and trends of hydrothermal fluids’ maturation.
    Description: Published
    Description: 108-129
    Description: JCR Journal
    Description: restricted
    Keywords: Ischia ; Hydrothermal systems ; EQ3-6 ; Geochemical modelling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
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  • 86
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    Space–time evolution of crustal deformation related to the Mw 6.3, 2009 L'Aquila earthquake (central Italy) from principal component analysis inversion of GPS position time-series (2020)
    Details
    Publication Date: 2020-03-03
    Description: This article has been accepted for publication in Geophysical Journal International ©: 2014, Published by Oxford University Press on behalf of the Royal Astronomical Society. All rights reserved.
    Description: In this work, we present a study of the coseismic and post-seismic crustal deformation associ- ated to the Mw 6.3, 2009 April 6 L’Aquila earthquake from the analysis of GPS displacement time-series. We use a principal component decomposition-based inversion method to study the space- and time-dependent evolution of slip on faults without any a priori assumption on the model used to characterize the temporal evolution of crustal deformation. The method adopted allows us to account for the initial post-seismic deformation in estimating the coseismic dis- placements, in a consistent manner for the whole GPS network. We use elastic dislocation theory and a least-squares procedure to invert for the slip distribution on the mainshock fault (Paganica fault) and a second fault (Campotosto fault), where a Mw 5.2 aftershock occurred on April 9. The geometries for these faults are obtained from a singular value decomposition of precisely relocated aftershocks. We find that the use of complex fault geometries is not justified by the GPS observations available. An inversion that accounts for post-seismic slip to occur on both the Paganica and Campotosto faults provides a better fit to the GPS time-series observations, than using only the Paganica fault segment, at a 95 per cent confidence level. Within our resolution, afterslip regions do not migrate over time and are localized on fault patches that are approximately complementary to those of coseismic slip. We find that the position of some relevant afterslip patches is different if the inversion is performed assuming a fixed rake or not. We estimate the parameter a – b of rate- and state-dependent friction on those fault regions accommodating afterslip that are robustly characterized in our inversions. We find values of the order of 10−3, which is near the transition from potentially unstable to nominally stable friction. These results are in agreement with laboratory measurements performed on typical rocks of the L’Aquila region.
    Description: Published
    Description: 174–191
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: 3T. Sorgente sismica
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.03. Geodesy ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 87
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    Tectonics and seismicity in the Northern Apennines driven by slab retreat and lithospheric delamination (2020)
    Elsevier
    Details
    Publication Date: 2020-06-10
    Description: Understanding how long-term subduction dynamics relates to the short-term seismicity and crustal tec tonics is a challenging but crucial topic in seismotectonics. We attempt to address this issue by linking long-term geodynamic evolution with short-term seismogenic deformation in the Northern Apennines. This retreating subduction orogen displays tectonic and seismogenic behaviors on various spatiotemporal scales that also characterize other subduction zones in the Mediterranean area. We use visco-elasto-plastic seismo-thermo-mechanical (STM) modeling with a realistic 2D setup based on available geological and geophysical data. The subduction dynamics and seismicity are coupled in the numerical modeling, and driven only by buoyancy forces, i.e., slab pull. Our results suggest that lower crustal rheology and lithospheric mantle temperature modulate the crustal tectonics of the Northern Apennines, as inferred by previous studies. The observed spatial distribution of upper crustal tectonic regimes and surface displacements requires buoyant, highly ductile material in the subduction channel beneath the internal part of the orogen. This allows protrusion of the asthenosphere in the lower crust and lithospheric delamination associated with slab retreat. The resulting surface velocities and principal stress axes generally agree with present-day observations, suggesting that slab delamination and retreat can explain the dynamics of the orogen. Our simulations successfully reproduce the type and overall distribution of seismicity with thrust faulting events in the external part of the orogen and normal faulting in its internal part. Slab temperatures and lithospheric mantle stiffness affect the cumulative seismic moment release and spatial distribution of upper crustal earthquakes. The properties of deep, sub-crustal material are thus shown to influence upper crustal seismicity in an orogen driven by slab retreat, even though the upper crust is largely decoupled from the lithospheric mantle. Our simulations therefore highlight the effect of deep lower crustal rheologies, self-driven subduction dynamics and mantle properties in controlling shallow deformation and seismicity.
    Description: Published
    Description: 228481
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: Numerical modeling ; Geodynamics ; Seismotectonics orogen ; Delamination ; Northern Apennines ; 04.06. Seismology ; 04.03. Geodesy ; 05.01. Computational geophysics ; 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 88
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    Theory of second order stationary random processes applied to GPS coordinate time-series (2019)
    Springer Berlin Heidelberg
    Details
    Publication Date: 2019-12-05
    Description: The analysis of Global Positioning System (GPS) coordinates time series is a valuable tool in quantifying crustal deformations. The longer continuous GPS time series allow estimation of nonlinear signatures. As a matter of fact, besides the linear and periodic behaviors, other relevant signals are present in such time series as the so-called transient deformations. They can be related to, e.g., slow slip events, which play a crucial role in studying fault mechanisms. To give reliable estimates of these signals, an appropriate and rigorous approach for defining the deterministic and the stochastic models of the data is needed. We prove that the theory of the second order stationary random process (SOSRP) can be used to describe the stochastic behavior of the daily GPS time series. In particular, the second order stationarity condition has to be verified for the daily GPS coordinate time series to be described as a SOSRP. This method has been already used for modeling the gravity field of the earth and in predicting/filtering problems, and this work shows that it can also be useful for characterizing the colored noise in the GPS time series.
    Description: Published
    Description: id 86
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: GPS ; time series ; Stationary stochastic process ; Auto-covariance function ; Power law spectrum ; 04.03. Geodesy
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 89
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    Blind source separation problem in GPS time series (2020)
    Springer
    Details
    Publication Date: 2020-03-03
    Description: A critical point in the analysis of ground dis- placement time series, as those recorded by space geodetic techniques, is the development of data-driven methods that allow the different sources of deformation to be discerned and characterized in the space and time domains. Multivariate statistic includes several approaches that can be considered as a part of data-driven methods. A widely used technique is the principal component analysis (PCA), which allows us to reduce the dimensionality of the data space while maintain- ing most of the variance of the dataset explained. However, PCA does not perform well in finding the solution to the so-called blind source separation (BSS) problem, i.e., in recovering and separating the original sources that gener- ate the observed data. This is mainly due to the fact that PCA minimizes the misfit calculated using an L 2 norm (χ 2 ), look- ing for a new Euclidean space where the projected data are uncorrelated. The independent component analysis (ICA) is a popular technique adopted to approach the BSS problem. However, the independence condition is not easy to impose, and it is often necessary to introduce some approximations. To work around this problem, we test the use of a modi- fied variational Bayesian ICA (vbICA) method to recover the multiple sources of ground deformation even in the presence of missing data. The vbICA method models the probability density function (pdf) of each source signal using a mix of Gaussian distributions, allowing for more flexibility in the description of the pdf of the sources with respect to standard ICA, and giving a more reliable estimate of them. Here we present its application to synthetic global positioning system (GPS) position time series, generated by simulating deforma- tion near an active fault, including inter-seismic, co-seismic, and post-seismic signals, plus seasonal signals and noise, and an additional time-dependent volcanic source. We evaluate the ability of the PCA and ICA decomposition techniques in explaining the data and in recovering the original (known) sources. Using the same number of components, we find that the vbICA method fits the data almost as well as a PCA method, since the χ 2 increase is less than 10 % the value cal- culated using a PCA decomposition. Unlike PCA, the vbICA algorithm is found to correctly separate the sources if the correlation of the dataset is low (〈0.67) and the geodetic network is sufficiently dense (ten continuous GPS stations within a box of side equal to two times the locking depth of a fault where an earthquake of Mw 〉 6 occurred). We also provide a cookbook for the use of the vbICA algorithm in analyses of position time series for tectonic and non-tectonic applications.
    Description: Published
    Description: 323–341
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.03. Geodesy
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  • 90
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    Isostasy, dynamic topography, and the elevation of the Apennines of Italy (2020)
    Elsevier
    Details
    Publication Date: 2020-03-03
    Description: The elevation of an orogenic belt is commonly related to crustal/lithosphere thickening. Here, we discuss the Apennines as an example to show that topography at a plate margin may be controlled not only by isostatic adjustment but also by dynamic, mantle-driven processes. Using recent structural constraints for the crust and mantle we find that the expected crustal isostatic component explains only a fraction of the topography of the belt, indicating positive residual topography in the central Apennines and negative residual topography in the northern Apennines and Calabria. The trend of the residual topography matches the mantle flow induced dynamic topography estimated from regional tomography models. We infer that a large fraction of the Apennines topography is related to mantle dynamics, producing relative upwellings in the central Apennines and downwellings in the northern Apennines and Calabria where subduction is still ongoing. Comparison between geodetic and geological data on vertical motions indicates that this dynamic process started in the early Pleistocene and the resulting uplift appears related to the formation and enlargement of a slab window below the central Apennines. The case of the Apennines shows that at convergent margins the elevation of a mountain belt may be significantly different from that predicted solely by crustal isostasy and that a large fraction of the elevation and its rate of change are dynamically controlled by mantle convection.
    Description: Published
    Description: 163-174
    Description: 1T. Struttura della Terra
    Description: 2T. Deformazione crostale attiva
    Description: JCR Journal
    Keywords: 04. Solid Earth ; 04.03. Geodesy
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  • 91
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    Modeling of unrest signals in heterogeneous hydrothermal systems (2010)
    American Geophysical Union
    Details
    Publication Date: 2019-10-10
    Description: An edited version of this paper was published by AGU. Copyright (2010) American Geophysical Union.
    Description: Monitoring of quiescent volcanoes, such as Campi Flegrei (Italy), involves the measurement of geochemical and geophysical parameters that are expected to change as eruptive conditions approach. Some of these changes are associated with the hydrothermal activity that is driven by the release of heat and magmatic fluids. This work focuses on the properties of the porous medium and on their effects on the signals generated by the circulating fluids. The TOUGH2 porous media flow model is applied to simulate a shallow hydrothermal system fed by a source of magmatic fluids. The simulated activity of the source, with periods of increased fluid discharge, generates changes in gas composition, gravity, and ground deformation. The same boundary conditions and source activity were applied to simulate the evolution of homogeneous and heterogeneous systems, characterized by different rock properties. Phase distribution, fluid composition, and the related signals depend on the nature and properties of the rock sequence through which the fluids propagate. Results show that the distribution of porosity and permeability affects all the observable parameters, controlling the timing and the amplitude of their changes through space and time. Preferential pathways for fluid ascent favor a faster evolution, with larger changes near permeable channels. Slower changes over wider areas characterize less permeable systems. These results imply that monitoring signals do not simply reflect the evolution of the magmatic system: intervening rocks leave a marked signature that should be taken into account when monitoring data are used to infer system conditions at depth.
    Description: This work was carried out within the research project V1-UNREST, founded by the Italian Civil Protection Department
    Description: Published
    Description: B09213
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: open
    Keywords: hydrothermal circulation ; observable ; volcanic unrest ; permeability ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
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  • 92
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    Questo caldo, caldo, caldo mondo (2011)
    Details
    Publication Date: 2017-04-04
    Description: La mostra consente fin dal suo inizio di “entrare” nel mondo degli spettacolari fenomeni geotermici. Immagini di geyser, pozze di fango ribollente, fumarole, acque termali dai colori più improbabili, incrostazioni multicolori e affascinanti cristalli, provenienti da varie parti del mondo accompagneranno i visitatori alla scoperta delle caratteristiche naturalistiche del fenomeno. Ad arricchire l'esposizione iniziale curata da Vulcano Esplorazioni, un video con immagini raccolte in varie parti del pianeta, eccezionali campioni di minerali di origine idrotermale provenienti dal Museo di Storia Naturale di Milano e diorami esplicativi, in scala e ridotti. Ricostruzioni, schemi ed exhibit facilitano la comprensione del meccanismo fisico che scatena questi fenomeni. La parte scientifica, curata in particolare dall’INGV, ripercorre anche le esperienze pionieristiche di Larderello, ricostruendo il primo esperimento del 1904 di produzione di energia elettrica da vapore geotermico. Il percorso museale illustra anche il grande potenziale energetico presente soprattutto in Italia, il paese più caldo d'Europa, offerto dal calore della Terra, un’energia rinnovabile e pulita. L'esibizione termina con uno spettacolare filmato in 3D.
    Description: Festival della Scienza, CLIVET,
    Description: Unpublished
    Description: Palazzo Ducale, Loggia degli Abati P.zza Matteotti, 9 - Genova
    Description: 4.4. Scenari e mitigazione del rischio ambientale
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: 5.9. Formazione e informazione
    Description: open
    Keywords: Geotermia, potenziale geotermico Italia ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Conference paper
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  • 93
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    The geothermal exploration of Campanian volcanoes: Historical review and future development (2011)
    ELSEVIER
    Details
    Publication Date: 2017-04-04
    Description: Since Roman time, the heat produced by Neapolitan volcanoes was an appeal for people living in and outside the area, for the fruition of the famous thermal baths. This very large area, which spans from Campi Flegrei and Ischia calderas to Somma-Vesuvius volcano, is characterized by high temperature at shallow depth and intense heat flow, and is yet utilized for the bathing and spa treatment industry, while only in the middle of the 20th century a tentative of geothermal exploitation for energy production was performed. Pioneering researches of geothermal resource were carried out in Campanian region since 1930, until 1985, during which a large amount of geological data were collected. In this paper, we make for the first time a review of the history of geothermal explorations in the active Campanian volcanic area. By the analysis of a great amount of literature data and technical reports we reconstruct the chronology and the main information of the drillings performed since 1930 by the SAFEN Company and successively in the framework of the ENEL-AGIP Joint Venture for geothermal exploration. The available data are utilized to correlate the temperatures measured within the deeper wells with the possible sources of geothermal heat in the shallow crust, down to about 8–10 km of depth. Finally, we assess the geothermal potential of the hottest areas, Ischia Island and Campi Flegrei, which have shown the best data and favorable physical conditions for a reliable, and cost-effective, exploitation for thermal and electric purposes.
    Description: EU-VIIFP GEISER Project (ENERGY:2009.2.4.1)
    Description: Published
    Description: 1004-1030
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: reserved
    Keywords: Campi Flegrei ; Geothermal potential ; Geotherm ; Campanian Volcanoes ; Ischia ; Vesuvius ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 94
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    The Geothermal Potential Of Campania Volcanoes (2011)
    Details
    Publication Date: 2017-04-04
    Description: x
    Description: Published
    Description: Torino
    Description: 3.6. Fisica del vulcanismo
    Description: open
    Keywords: Campania volcanoes ; Campi Flegrei ; Ischia ; Vesuvio ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Poster session
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  • 95
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    Carbon Dioxide Diffuse Soil Degassing: A Precious Tool For Identifying Productive Geothermal Reservoirs (2011)
    Details
    Publication Date: 2017-04-04
    Description: that deep wells find high temperatures but are not productive because they don’t cross any permeable fractured reservoir. Because of the high cost of deep drillings, this aspect represents one of the main economic risk of geothermal exploration. The aim of this paper is to show that a detailed survey of diffuse CO2 soil flux allows to identify from the surface the permeable portions of a deep-seated actively degassing geothermal reservoir, drastically reducing that risk. The first application of the method has been made in the Quaternary Latera caldera, North of Rome. We will show that productive wells were all located on high CO2 flux zones, whereas the not-productive wells were sited on low flux areas. In addition the survey allows to identify some as yet unexplored portions of the geothermal reservoir where future wells should be conveniently located. The same technique has been applied in the geothermal exploration of Platanares and Azacualpa, Honduras and of Las Pailas, Costa Rica. Obviously, CO2 flux cannot provide any estimate of temperature at depth, which has to be assessed with other geochemical or geophysical exploration techniques.
    Description: Comission of Cities and Volcanoes (CaV) of the International Association of Volcanology and Chemistry of the Earth's Interior (IAVCEI) Agencia Española de Cooperación Internacional para el Desarrollo (AECID), Gobierno de España Ministerio de Ciencia e Innovación (MICINN), Gobierno de España Unidad Militar de Emergencias (UME), Ministerio de Defensa, Gobierno de España Agencia Canaria de Investigación, Innovación y Sociedad de la Información (ACIISI), Gobierno de Canarias Viceconsejería de Infraestructuras y Planificación, Gobierno de Canarias Consejería de Turismo, Gobierno de Canarias Consejería de Medio Ambiente y Ordenación Territorial, Gobierno de Canarias Viceconsejería de Cultura y Deportes, Gobierno de Canarias Instituto Español de Oceanografía (IEO)Instituto Geológico y Minero de España (IGME)Instituto Geográfico Nacional (IGN)Academia Canaria de Seguridad Federación Canaria de Municipios (FECAM) Universidad de La Laguna (ULL)Instituto de Estudios Hispánicos de Canarias (IEHC) CajaCanarias
    Description: Published
    Description: Puerto de la Cruz, Tenerife, Spain
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: geothermal exploration, CO2 soil flux ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 96
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    Discrimination between effects induced by microbial activity and water-rock interactions under hydrothermal conditions according to REE behaviour (2012)
    Details
    Publication Date: 2017-04-04
    Description: Rare Earths (REE) were investigated in siliceous stromatolites forming in the Specchio di Venere Lake in Pantelleria Island. Chondrite-normalised patterns show significant La enrichments and Eu depletions suggesting that fluids involved in stromatolite growth experienced strong rock-water interactions under hydrothermal conditions. At the same time, enrichments of heavy REE (HREE), with respect to intermediate REE (MREE) suggest that hydrothermal fluids interacted with microbial mats during deposition of stromatolites. The above-mentioned features suggest that rock-water interactions and bacterial activity were simultaneously recorded in REE patterns of stromatolites and can be discriminated in terms of amplitudes of La anomaly and HREE/MREE ratio
    Description: Unpublished
    Description: Avignon, France
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: open
    Keywords: Stromatolites ; REE ; Bacterial activity ; Rock-water interactions ; Hydrothermal system ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 97
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    Origin and evolution of the fluids emitted along the “Sperchios Basin – Evoikos Gulf” Graben (Central Greece) (2013)
    University of Patras, Greece
    Details
    Publication Date: 2017-04-04
    Description: The study area is a 130 km long fast spreading graben in Central Greece bordered by active faults. Its complex geodynamical setting includes the presence at depth of a subduction slab responsible for the recent (Quaternary) volcanic activity in the area which possibly represents the northward continuation of the South Aegean active volcanic arc. To the area belongs also the western termination of the North-Anatolian fault a tectonic lineament of regional importance. The high geothermal gradient of the area is evidenced by the presence of many thermal springs with temperatures from 19 to 82 °C, issuing along the normal faults bordering the graben. In the period 2004-2012 more than 60 gas and water samples have been collected and their chemical and isotopic analysis revealed a wide range of compositions. Going from west to east the gas composition changes (Fig. 1) from CH4- to CO2-dominated passing through mixed N2-CH4 and N2-CO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (0.02 R/Ra) up to 0.87 R/Ra (corrected for air contamination), showing in the easternmost sites a small but significant mantle input (up to ~ 10%). Isotopic composition of CH4-C indicates a thermogenic origin for the CH4-rich samples (δ13C from -50 to -37 ‰) and hydrothermal origin for the remaining samples (〉 -25‰). Positive δ15N values (around +2 ‰) indicate a contribution of crustal derived nitrogen for the N2-rich samples. The most pristine values of δ13C(CO2) refer to the most CO2-rich samples. These values (~ -3 ‰) point to a mixed mantle-marine carbonate source. Lower δ13C values (-10 ÷ -5 ‰) of the other sites can be explained by loss of CO2 due to dissolution processes. Also temperature and salinity of the waters shows differences along the graben increasing from west to east (Fig. 2). Two main groups can be separated on the basis of the total dissolved salts (TDS). The first, represented by dilute waters (TDS 〈 500 mg/l), is found in the westernmost sites characterised by the presence of CH4-rich and mixed N2-CH4 gases. The remaining waters display higher salinities (TDS from 9 to 35 g/l) due to the mixing with high salinity waters. The water composition can be explained by mixing of two end-members, one with low salinity of meteoric origin and the other with high salinity of marine origin. The mixing can be evidenced in Fig. 2. Low salinity waters show low chloride contents and their light water isotope composition overlaps the field of the cold groundwaters of the area confirming their meteoric origin. High salinity waters are aligned along the mixing line between the cold groundwaters and the seawater confirming the contribution of marine component. Most of the water compositions in the triangular graph of Giggenbach fall in the field of the non equilibrated waters being therefore unsuitable for geothermometric estimations. Only the easternmost sites (Gialtra, Ilion and Edipsos) falling the field of the partially equilibrated waters yield estimated temperatures in the range 150-170 °C. Silica geothermometers confirm these estimations. This study revealed that the complex geodynamic setting of the area is clearly reflected in the wide compositional range of the gases collected in the area that evidence contributions from different end-members (atmosphere, crust, mantle and hydrothermal systems). Water chemistry can be explained mainly from the mixing of a meteoric low-salinity end-member with a high-salinity marine end-member partially modified by hydrothermal water-rock interactions. The highest estimated temperatures in the hydrothermal reservoirs are in the range 150-170 °C.
    Description: Published
    Description: Patras, Greece
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: open
    Keywords: gas geochemistry ; hydrothermal systems ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Extended abstract
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  • 98
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    Geochemical survey of Levante Bay, Vulcano Island (Italy), a natural laboratory for the study of ocean acidification (2013)
    Elsevier Science Limited
    Details
    Publication Date: 2017-04-04
    Description: Shallow submarine gas vents in Levante Bay, Vulcano Island (Italy), emit around 3.6t CO2 per day providing a natural laboratory for the study of biogeochemical processes related to seabed CO2 leaks and ocean acidification. The main physico-chemical parameters (T, pH and Eh) were measured at more than 70 stations with 40 seawater samples were collected for chemical analyses. The main gas vent area had high concentrations of dissolved hydrothermal gases, low pH and negative redox values all of which returned to normal seawater values at distances of about 400 m from the main vents. Much of the bay around the vents is corrosive to calcium carbonate; the north shore has a gradient in seawater carbonate chemistry that is well suited to studies of the effects of long-term increases in CO2 levels. This shoreline lacks toxic compounds (such as H2S) and has a gradient in carbonate saturation states.
    Description: Published
    Description: 485–494
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: ocean acidification ; carbon capture and storage ; marine geochemistry ; carbonate saturation state ; volcanic vents ; carbon dioxide ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 99
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    Monitoraggio sismico del territorio nazionale: stato dell'arte e sviluppo delle reti di monitoraggio sismico (2013)
    Details
    Publication Date: 2017-04-03
    Description: Il sistema CUMAS (Cabled Underwater Module for Acquisition of Seismological data) è un prodotto tecnologico-scientifico complesso nato con il Progetto V4 [Iannaccone et al., 2008] allo scopo di monitorare l’area vulcanica dei Campi Flegrei (fenomeno del bradisismo). Si tratta di un modulo sottomarino cablato e connesso a una boa galleggiante (meda elastica). Il sistema è in grado di acquisire e trasmettere alla sala di monitoraggio dell’OV, in continuo e in tempo reale, sia i segnali sismologici sia quelli di interesse geofisico ed oceanografico (maree, correnti marine, segnali acustici subacquei, parametri funzionali di varia natura). Il sistema è in grado di ricevere comandi da remoto per variare diversi parametri di acquisizione e di monitorare un cospicuo numero di variabili di funzionamento. Il sistema si avvale del supporto di una boa galleggiante attrezzata. La boa è installata a largo del golfo di Pozzuoli (Napoli) a circa 3 km dalla costa. Il modulo sottomarino, collegato via cavo alla parte fuori acqua della boa, è installato sul fondale marino a una profondità di circa 100 metri.
    Description: Submitted
    Description: 82-85
    Description: 1.1. TTC - Monitoraggio sismico del territorio nazionale
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 1.8. Osservazioni di geofisica ambientale
    Description: 2.5. Laboratorio per lo sviluppo di sistemi di rilevamento sottomarini
    Description: 5.2. TTC - Banche dati di sismologia strumentale
    Description: N/A or not JCR
    Description: open
    Keywords: Monitoraggio sismico; sistemi sottomarini; boa; meda elastica ; 01. Atmosphere::01.01. Atmosphere::01.01.99. General or miscellaneous ; 01. Atmosphere::01.01. Atmosphere::01.01.01. Composition and Structure ; 01. Atmosphere::01.01. Atmosphere::01.01.02. Climate ; 01. Atmosphere::01.01. Atmosphere::01.01.03. Pollution ; 01. Atmosphere::01.01. Atmosphere::01.01.04. Processes and Dynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.05. Radiation ; 01. Atmosphere::01.01. Atmosphere::01.01.06. Thermodynamics ; 01. Atmosphere::01.01. Atmosphere::01.01.07. Volcanic effects ; 01. Atmosphere::01.01. Atmosphere::01.01.08. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.99. General or miscellaneous ; 01. Atmosphere::01.02. Ionosphere::01.02.01. Ion chemistry and composition ; 01. Atmosphere::01.02. Ionosphere::01.02.02. Dynamics ; 01. Atmosphere::01.02. Ionosphere::01.02.03. Forecasts ; 01. Atmosphere::01.02. Ionosphere::01.02.04. Plasma Physics ; 01. Atmosphere::01.02. Ionosphere::01.02.05. Wave propagation ; 01. Atmosphere::01.02. Ionosphere::01.02.06. Instruments and techniques ; 01. Atmosphere::01.02. Ionosphere::01.02.07. Scintillations ; 01. Atmosphere::01.03. Magnetosphere::01.03.99. General or miscellaneous ; 01. Atmosphere::01.03. Magnetosphere::01.03.01. Interplanetary physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.02. Magnetic storms ; 01. Atmosphere::01.03. Magnetosphere::01.03.03. Magnetospheric physics ; 01. Atmosphere::01.03. Magnetosphere::01.03.04. Structure and dynamics ; 01. Atmosphere::01.03. Magnetosphere::01.03.05. Solar variability and solar wind ; 01. Atmosphere::01.03. Magnetosphere::01.03.06. Instruments and techniques ; 02. Cryosphere::02.01. Permafrost::02.01.99. General or miscellaneous ; 02. Cryosphere::02.01. Permafrost::02.01.01. Active layer ; 02. Cryosphere::02.01. Permafrost::02.01.02. Cryobiology ; 02. Cryosphere::02.01. Permafrost::02.01.03. Cryosol ; 02. Cryosphere::02.01. Permafrost::02.01.04. Periglacial processes ; 02. Cryosphere::02.01. Permafrost::02.01.05. Seasonally frozen ground ; 02. Cryosphere::02.01. Permafrost::02.01.06. Thermokarst ; 02. Cryosphere::02.01. Permafrost::02.01.07. Tundra ; 02. Cryosphere::02.01. Permafrost::02.01.08. Instruments and techniques ; 02. Cryosphere::02.02. Glaciers::02.02.99. General or miscellaneous ; 02. Cryosphere::02.02. Glaciers::02.02.01. Avalanches ; 02. Cryosphere::02.02. Glaciers::02.02.02. Cryosphere/atmosphere Interaction ; 02. Cryosphere::02.02. Glaciers::02.02.03. Geomorphology ; 02. Cryosphere::02.02. Glaciers::02.02.04. Ice ; 02. Cryosphere::02.02. Glaciers::02.02.05. Ice dynamics ; 02. Cryosphere::02.02. Glaciers::02.02.06. Mass balance ; 02. Cryosphere::02.02. Glaciers::02.02.07. Ocean/ice interaction ; 02. Cryosphere::02.02. Glaciers::02.02.08. Rock glaciers ; 02. Cryosphere::02.02. Glaciers::02.02.09. Snow ; 02. Cryosphere::02.02. Glaciers::02.02.10. Instruments and techniques ; 02. Cryosphere::02.03. Ice cores::02.03.99. General or miscellaneous ; 02. Cryosphere::02.03. Ice cores::02.03.01. Aerosols ; 02. Cryosphere::02.03. Ice cores::02.03.02. Atmospheric Chemistry ; 02. Cryosphere::02.03. Ice cores::02.03.03. Climate Indicators ; 02. Cryosphere::02.03. Ice cores::02.03.04. Ice Core Air Bubbles ; 02. Cryosphere::02.03. Ice cores::02.03.05. Paleoclimate ; 02. Cryosphere::02.03. Ice cores::02.03.06. Precipitation ; 02. Cryosphere::02.03. Ice cores::02.03.07. Teleconnection ; 02. Cryosphere::02.03. Ice cores::02.03.08. Temperature ; 02. Cryosphere::02.03. Ice cores::02.03.09. Instruments and techniques ; 02. Cryosphere::02.04. Sea ice::02.04.99. General or miscellaneous ; 02. Cryosphere::02.04. Sea ice::02.04.01. Atmosphere/sea ice/ocean interaction ; 02. Cryosphere::02.04. Sea ice::02.04.02. Leads ; 02. Cryosphere::02.04. Sea ice::02.04.03. Polynas ; 02. Cryosphere::02.04. Sea ice::02.04.04. Instruments and techniques ; 03. Hydrosphere::03.01. General::03.01.99. General or miscellaneous ; 03. Hydrosphere::03.01. General::03.01.01. Analytical and numerical modeling ; 03. Hydrosphere::03.01. General::03.01.02. Equatorial and regional oceanography ; 03. Hydrosphere::03.01. General::03.01.03. Global climate models ; 03. Hydrosphere::03.01. General::03.01.04. Ocean data assimilation and reanalysis ; 03. Hydrosphere::03.01. General::03.01.05. Operational oceanography ; 03. Hydrosphere::03.01. General::03.01.06. Paleoceanography and paleoclimatology ; 03. Hydrosphere::03.01. General::03.01.07. Physical and biogeochemical interactions ; 03. Hydrosphere::03.01. General::03.01.08. Instruments and techniques ; 03. Hydrosphere::03.02. Hydrology::03.02.99. General or miscellaneous ; 03. Hydrosphere::03.02. Hydrology::03.02.01. Channel networks ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.02. Hydrology::03.02.05. Models and Forecasts ; 03. Hydrosphere::03.02. Hydrology::03.02.06. Water resources ; 03. Hydrosphere::03.02. Hydrology::03.02.07. Instruments and techniques ; 03. Hydrosphere::03.03. Physical::03.03.99. General or miscellaneous ; 03. Hydrosphere::03.03. Physical::03.03.01. Air/water/earth interactions ; 03. Hydrosphere::03.03. Physical::03.03.02. General circulation ; 03. Hydrosphere::03.03. Physical::03.03.03. Interannual-to-decadal ocean variability ; 03. Hydrosphere::03.03. Physical::03.03.04. Upper ocean and mixed layer processes ; 03. Hydrosphere::03.03. Physical::03.03.05. Instruments and techniques ; 03. Hydrosphere::03.04. Chemical and biological::03.04.99. General or miscellaneous ; 03. Hydrosphere::03.04. Chemical and biological::03.04.01. Biogeochemical cycles ; 03. Hydrosphere::03.04. Chemical and biological::03.04.02. Carbon cycling ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.04. Ecosystems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.08. Instruments and techniques ; 04. Solid Earth::04.01. Earth Interior::04.01.99. General or miscellaneous ; 04. Solid Earth::04.01. Earth Interior::04.01.01. Composition and state ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.01. Earth Interior::04.01.03. Mantle and Core dynamics ; 04. Solid Earth::04.01. Earth Interior::04.01.04. Mineral physics and properties of rocks ; 04. Solid Earth::04.01. Earth Interior::04.01.05. Rheology ; 04. Solid Earth::04.02. Exploration geophysics::04.02.99. General or miscellaneous ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.02. Exploration geophysics::04.02.02. Gravity methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.03. Heat flow ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.05. Downhole, radioactivity, remote sensing, and other methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.06. Seismic methods ; 04. Solid Earth::04.02. Exploration geophysics::04.02.07. Instruments and techniques ; 04. Solid Earth::04.03. Geodesy::04.03.99. General or miscellaneous ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.02. Earth rotation ; 04. Solid Earth::04.03. Geodesy::04.03.03. Gravity and isostasy ; 04. Solid Earth::04.03. Geodesy::04.03.04. Gravity anomalies ; 04. Solid Earth::04.03. Geodesy::04.03.05. Gravity variations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.03. Geodesy::04.03.07. Satellite geodesy ; 04. Solid Earth::04.03. Geodesy::04.03.08. Theory and Models ; 04. Solid Earth::04.03. Geodesy::04.03.09. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.99. General or miscellaneous ; 04. Solid Earth::04.04. Geology::04.04.01. Earthquake geology and paleoseismology ; 04. Solid Earth::04.04. Geology::04.04.02. Geochronology ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.04. Marine geology ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.06. Rheology, friction, and structure of fault zones ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.04. Geology::04.04.08. Sediments: dating, processes, transport ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.10. Stratigraphy ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.05. Geomagnetism::04.05.99. General or miscellaneous ; 04. Solid Earth::04.05. Geomagnetism::04.05.01. Dynamo theory ; 04. Solid Earth::04.05. Geomagnetism::04.05.02. Geomagnetic field variations and reversals ; 04. Solid Earth::04.05. Geomagnetism::04.05.03. Global and regional models ; 04. Solid Earth::04.05. Geomagnetism::04.05.04. Magnetic anomalies ; 04. Solid Earth::04.05. Geomagnetism::04.05.05. Main geomagnetic field ; 04. Solid Earth::04.05. Geomagnetism::04.05.06. Paleomagnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.07. Rock magnetism ; 04. Solid Earth::04.05. Geomagnetism::04.05.08. Instruments and techniques ; 04. Solid Earth::04.05. Geomagnetism::04.05.09. Environmental magnetism ; 04. Solid Earth::04.06. Seismology::04.06.99. General or miscellaneous ; 04. Solid Earth::04.06. Seismology::04.06.01. Earthquake faults: properties and evolution ; 04. Solid Earth::04.06. Seismology::04.06.02. Earthquake interactions and probability ; 04. Solid Earth::04.06. Seismology::04.06.03. Earthquake source and dynamics ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.06. Seismology::04.06.05. Historical seismology ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.07. Tomography and anisotropy ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.06. Seismology::04.06.09. Waves and wave analysis ; 04. Solid Earth::04.06. Seismology::04.06.10. Instruments and techniques ; 04. Solid Earth::04.06. Seismology::04.06.11. Seismic risk ; 04. Solid Earth::04.07. Tectonophysics::04.07.99. General or miscellaneous ; 04. Solid Earth::04.07. Tectonophysics::04.07.01. Continents ; 04. Solid Earth::04.07. Tectonophysics::04.07.02. Geodynamics ; 04. Solid Earth::04.07. Tectonophysics::04.07.03. Heat generation and transport ; 04. Solid Earth::04.07. Tectonophysics::04.07.04. Plate boundaries, motion, and tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.05. Stress ; 04. Solid Earth::04.07. Tectonophysics::04.07.06. Subduction related processes ; 04. Solid Earth::04.07. Tectonophysics::04.07.07. Tectonics ; 04. Solid Earth::04.07. Tectonophysics::04.07.08. Volcanic arcs ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.02. Experimental volcanism ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.04. Thermodynamics ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk ; 05. General::05.01. Computational geophysics::05.01.99. General or miscellaneous ; 05. General::05.01. Computational geophysics::05.01.01. Data processing ; 05. General::05.01. Computational geophysics::05.01.02. Cellular automata, fuzzy logic, genetic alghoritms, neural networks ; 05. General::05.01. Computational geophysics::05.01.03. Inverse methods ; 05. General::05.01. Computational geophysics::05.01.04. Statistical analysis ; 05. General::05.01. Computational geophysics::05.01.05. Algorithms and implementation ; 05. General::05.02. Data dissemination::05.02.99. General or miscellaneous ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.02. Seismological data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.02. Data dissemination::05.02.05. Collections ; 05. General::05.03. Educational, History of Science, Public Issues::05.03.99. General or miscellaneous ; 05. General::05.04. Instrumentation and techniques of general interest::05.04.99. General or miscellaneous ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.06. Methods::05.06.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.99. General or miscellaneous ; 05. General::05.07. Space and Planetary sciences::05.07.01. Solar-terrestrial interaction ; 05. General::05.07. Space and Planetary sciences::05.07.02. Space weather ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.01. Environmental risk ; 05. General::05.08. Risk::05.08.02. Hydrogeological risk ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: manuscript
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  • 100
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    A geochemical traverse along the “Sperchios Basin e Evoikos Gulf” graben (Central Greece): Origin and evolution of the emitted fluids (2014)
    Elsevier Science
    Details
    Publication Date: 2017-04-04
    Description: The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 C, that discharge along the normal faults bordering the graben. In the period 2004e2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal waters can be distinguished on the basis of their chemical composition. The first, represented by dilute waters (E.C. 〈0.6 mS/cm) of the westernmost sites, is characterised by the presence of CH4-rich and mixed N2eCH4 gases. The second displays higher salinities (E.C. from 12 to 56 mS/cm) due to mixing with a modified marine component. Reservoir temperatures of 150e160 C were estimated with cationic geothermometers at the easternmost sites. Along the graben, from west to east, the gas composition changes from CH4- to CO2-dominated through mixed N2eCH4 and N2eCO2 compositions, while at the same time the He isotopic composition goes from typical crustal values (〈0.1 R/RA) up to 0.87 R/RA, showing in the easternmost sites a small (3e11%) but significant mantle input. The d13C values of the CO2-rich samples suggest a mixed origin (mantle and marine carbonates).
    Description: Published
    Description: 295-308
    Description: 2T. Tettonica attiva
    Description: JCR Journal
    Description: restricted
    Keywords: Rift zone ; geothermal activity ; Helium isotopes ; Carbon isotopes ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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