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  • 04. Solid Earth::04.08. Volcanology::04.08.01. Gases  (13)
  • Palaeoclimate
  • Springer Berlin Heidelberg  (8)
  • Cabildo Insular de Tenerife Fundación Canaria ITER  (4)
  • Nature Publishing Group  (3)
  • 1
    Publication Date: 2017-04-04
    Description: We report the results of 16 months of continuous measurements of soil CO2 flux at a fumarole field in the summit area of Mt. Etna. The patterns of soil CO2 emissions suggest two contrasting degassing regimes. During the period of observation, volcanic activity at the summit craters displayed striking extremes, ranging from passive to explosive degassing, which culminated in lava fountains. These changes in activity coincided with fluctuation between the two degassing patterns. Building on the findings of previous studies, we propose an interpretative framework that explains the observed correlation in terms of a modification of the dynamics of magma supply. We argue that periods of higher CO2 flux are associated with deep open system degassing conditions, whereas low-level CO2 flux signals closed system degassing and less efficient discharge of deeply exsolved gas. An important implication of our study is that, in relation to the two degassing regimes, two types of activity are expected at the summit craters. Thus, our measurements represent a valuable tool for the evaluation of the evolution of volcanic activity
    Description: Published
    Description: 846
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: JCR Journal
    Description: restricted
    Keywords: Magma supply dynamics ; Soil CO2 emissions ; Lava fountain ; Mt. Etna ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: Near-infrared room temperature tunable diode lasers(TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross sections of the atmospheric plumes of two major fumarolic fields (Solfatara and Pisciarelli). By using a tomographic post-processing routine, we resolved, for each of the two fields, the contour maps of CO2 mixing ratios in the atmosphere, from the integration of which (and after multiplication by the plumes’ transport speeds) the CO2 fluxes were finally obtained. We evaluate a total CO2 output from the Campi Flegrei fumaroles of ∼490 Mg/day, in line with independent estimates based on in situ (Multi-GAS) observations. We conclude that TDL technique may enable CO2 flux quantification at other volcanoes worldwide.
    Description: 1- Progetto V2 “Precursori” DPC-INGV research agreement 2012-2013; 2- Miur (PRIN 2009; PI M.V.), and 3-European Research Council under the European Union’s Seventh Framework Programme (FP7/2007/2013)/ERC grant agreement n1305377 (PI, A.A).
    Description: Published
    Description: 812
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Tunable diode lasers ; Atmospheric CO2 monitoring ; gas sensing ; spectroscopy ; Volcanic CO2 fluxes ; Campi Flegrei ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
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  • 3
    Publication Date: 2017-04-04
    Description: Between 1994 and 2010, we completed 16 thermal surveys of Vulcano’s Fossa fumarole field (Aeolian Islands, Italy). In each survey, between 400 and 1,200 vent temperatures were collected using a thermal infrared thermometer from distances of ∼1 m. The results show a general decrease in average vent temperature during 1994–2003, with the average for the entire field falling from ∼220°C in 1994 to ∼150°C by 2003. However, between 2004 and 2010, we witnessed heating, with the average increasing to ∼190°C by 2010. Alongside these annual-scale field-wide trends, we record a spatial re-organisation of the fumarole field, characterised by shut down of vent zones towards the crater floor, matched by rejuvenation of zones located towards the crater rim. Heating may be expected to be associated with deflation because increased amounts of vaporisation will remove volume from the hydrothermal system Gambino and Guglielmino (J Geophys Res 113: B07402, 2008). However, over the 2004–2010 heating period, no ground deformation was observed. Instead, the number of seismic events increased from a typical rate of 37 events per month during 1994–2000 to 195 events per month during 2004–2010. As part of this increase, we noticed a much greater number of high-frequency events associated with rock fracturing. We thus suggest that the heating event of 2004–2010 was the result of changed permeability conditions, rather than change in the heat supply from the deeper magmatic source. Within this scenario, cooling causes shut down of lower sectors and re-establishment of pathways located towards the crater rim, causing fracturing, increased seismicity and heat flow in these regions. This is consistent with the zone of rejuvenation (which lies towards and at the rim) being the most favourable location for fracturing given the stress field of the Fossa cone Schöpa et al. (J Volcanol Geotherm Res 203:133–145, 2011); it is also the most established zone, having been active at least since the early twentieth century. Our data show the value of deploying multi-disciplinary geophysical campaigns at degassing (fumarolic) hydrothermal systems. This allows more complete and constrained understanding of the true heat loss dynamics of the system. In the case study presented here, it allows us to distinguish true heating from apparent heating phases. While the former are triggered from the bottom-up, i.e. they are driven by increases in heat supply from the magmatic source, the latter are triggered from the top-down, i.e. by changing permeability conditions in the uppermost portion of the system to allow more efficient heat flow over zones predisposed to fracturing.
    Description: Published
    Description: 1293-1311
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: 1.4. TTC - Sorveglianza sismologica delle aree vulcaniche attive
    Description: 1.5. TTC - Sorveglianza dell'attività eruttiva dei vulcani
    Description: 3.6. Fisica del vulcanismo
    Description: JCR Journal
    Description: restricted
    Keywords: Fumaroles ; Vulcano ; Vent temperature ; Seismicity ; Ground Deformation ; Permeability ; 04. Solid Earth::04.03. Geodesy::04.03.01. Crustal deformations ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.06. Surveys, measurements, and monitoring ; 04. Solid Earth::04.06. Seismology::04.06.08. Volcano seismology ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: Editor’s Note: The following comment and reply arise from an article published in Geophysical Research Letters by Voigt et al. (2014). The article addresses a volcanology topic, and the commenters take issue with some conclusions and offer an analysis of their own. Voigt and co-authors have responded. Why is this comment-and-reply being published in the Bulletin? It is because Geophysical Research Letters is one of a number of journals that do not offer any published forum for discussion of the papers they publish. This is a matter of editorial policy, and a decision for each journal. The Bulletin of Volcanology does provide a forum for discussion of articles published. When contacted by Marcello Liotta with the request that the Bulletin consider hosting a discussion of the Voigt et al. volcanology article in GRL, I agreed to do so if the GRL authors were willing to engage with the comment. Voigt and co-authors were willing to do so, and have been allowed a small amount of additional space to summarize for Bulletin readers the key points of the GRL paper under discussion before responding directly to the comment from Liotta and Rizzo. I hope that Bulletin readers find the discussion and reply of interest. James D.L. White Executive Editor, Bulletin of Volcanology
    Description: Published
    Description: 864
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Evolution . Mt. Etna . Volcanic plumes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-04
    Description: Editor’s Note: The following comment and reply arise from an article published in Geophysical Research Letters by Voigt et al. (2014). The article addresses a volcanology topic, and the commenters take issue with some conclusions and offer an analysis of their own. Voigt and co-authors have responded. Why is this comment-and-reply being published in the Bulletin? It is because Geophysical Research Letters is one of a number of journals that do not offer any published forum for discussion of the papers they publish. This is a matter of editorial policy and a decision for each journal. The Bulletin of Volcanology does provide a forum for discussion of articles published. When contacted by Marcello Liotta with the request that the Bulletin consider hosting a discussion of the Voigt et al. volcanology article in GRL, I agreed to do so if the GRL authors were willing to engage with the comment. Voigt and co-authors were willing to do so and have been allowed a small amount of additional space to summarize for Bulletin readers the key points of the GRL paper under discussion before responding directly to the comment from Liotta and Rizzo. I hope that Bulletin readers find the discussion and reply of interest.
    Description: Published
    Description: 865
    Description: 4V. Vulcani e ambiente
    Description: JCR Journal
    Description: open
    Keywords: Volcanic degassing ; Volcanic plume ; Etna ; Chemical evolution of trace gases ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: In open conduit volcanoes, volatile-rich magma continuously enters into the feeding system nevertheless the eruptive activity occurs intermittently. From a practical perspective, the continuous steady input of magma in the feeding system is not able to produce eruptive events alone, but rather surplus of magma inputs are required to trigger the eruptive activity. The greater the amount of surplus of magma within the feeding system, the higher is the eruptive probability.Despite this observation, eruptive potential evaluations are commonly based on the regular magma supply, and in eruptive probability evaluations, generally any magma input has the same weight. Conversely, herein we present a novel approach based on the quantification of surplus of magma progressively intruded in the feeding system. To quantify the surplus of magma, we suggest to process temporal series of measurable parameters linked to the magma supply. We successfully performed a practical application on Mt Etna using the soil CO2 flux recorded over ten years.
    Description: Published
    Description: 30471
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: eruptive potential ; eruptive probability ; open conduit volcanoes ; Etna ; Soil CO2 flux ; 04. Solid Earth::04.08. Volcanology::04.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.08. Risk::05.08.01. Environmental risk
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  • 7
    Publication Date: 2022-05-25
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 6 (2016): 21728, doi:10.1038/srep21728
    Description: Most Atlantic hurricanes form in the Main Development Region between 9°N to 20°N along the northern edge of the Intertropical Convergence Zone (ITCZ). Previous research has suggested that meridional shifts in the ITCZ position on geologic timescales can modulate hurricane activity, but continuous and long-term storm records are needed from multiple sites to assess this hypothesis. Here we present a 3000 year record of intense hurricane strikes in the northern Bahamas (Abaco Island) based on overwash deposits in a coastal sinkhole, which indicates that the ITCZ has likely helped modulate intense hurricane strikes on the western North Atlantic margin on millennial to centennial-scales. The new reconstruction closely matches a previous reconstruction from Puerto Rico, and documents a period of elevated intense hurricane activity on the western North Atlantic margin from 2500 to 1000 years ago when paleo precipitation proxies suggest that the ITCZ occupied a more northern position. Considering that anthropogenic warming is predicted to be focused in the northern hemisphere in the coming century, these results provide a prehistoric analog that an attendant northern ITCZ shift in the future may again return the western North Atlantic margin to an active hurricane interval.
    Description: This research was supported by NSF Awards: OCE-1519578, OCE-1356708, BCS-1118340.
    Keywords: Climate-change impacts ; Forest ecology ; Ocean sciences ; Palaeoclimate
    Repository Name: Woods Hole Open Access Server
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  • 8
    Publication Date: 2017-04-04
    Description: In 2009, Mt. Etna (Italy) activity was characterised by the end of a long-lasting flank eruption started on 13 May 2008 and by the opening of a new summit degassing vent on the E flank of the South-East crater on 6 November. This was preceded by a sequence of significant anomalies in volcanic degassing, detected by periodic measurements of soil CO2 efflux on the east flank of the volcano, continuous measurements of SO2 flux from five fixed monitoring stations, and periodic FTIR measurements of the SO2/HCl and SO2/HF molar ratios in the volcanic plume. Since April 2009, soil and crater emissions showed a progressive increase marked at least by two major steps, in April-May and September-October. Increases were not observed simultaneously; in fact, they were detected first in soil CO2 emissions and then, a few days/weeks later, in crater SO2 flux. Only minor increases of HCl and HF crater fluxes were observed between November and December. The highest SO2 and halogens fluxes were recorded in coincidence with the opening of the November 6 vent. The degassing behaviour of the volcano in 2009 is consistent with the differential release of magmatic gas species, according to their different solubilities, from a magma body rising from ~5 km depth to the surface. Our results suggest the start of a new phase in Etna’s activity, in which the new vent might reflect improved efficiency in the release of magmatic gas through the main feeding system, supplied by a magma body stored at depths between 4 and 2 km. If degassing at the new vent will remain steadystate, thus forming a stable feeding system, then its opening might represent the eastward migration of the South-East crater activity with the likely formation of a new stable summit cone.
    Description: Published
    Description: Puerto de la Cruz, Tenerife, Canary Islands, Spain
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; crater degassing ; soil gases ; volcanic activity ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 9
    Publication Date: 2017-04-04
    Description: Mount Etna in Sicily (973 km2), the most active European volcano, is known as one of the largest contributors of magmatic CO2 released to the atmosphere. A significant part of this gas is released in diffuse form through the volcano’s flanks, along faults and fractured zones, particularly around its summit (about 3350 m). Etna is also characterized by significant and often dramatic slope failure of its eastern flank, which is thought to trigger summit collapses and some lateral eruptions. In order to map the faulted areas near Etna’s summit and to study possible weak zones, a diffuse CO2 efflux survey was carried out at Mt. Etna in October, 2008. A total of 1442 sites were surveyed for soil CO2 efflux and soil temperature over an area of about 9 km2 that included most of the summit part of Mt. Etna above 2600 m a.s.l. The results show the presence of several degassing faults in all of the surveyed area except its west part, which seems to be structurally stable. Most of the degassing faults start from the summit craters and run parallel to the borders of the eastward collapsing sector of the volcano. Many of them are related to the development of the South-East Crater, but others seem to be related to a large buried crater rim, probably a remnant of the 1669 collapse crater formed during the largest eruption in the last 2000 years. Some degassing faults are not accompanied by thermal anomalies, thus suggesting that the gas source is too deep and/or the ground permeability is too low to allow high-enthalpy fluids to reach the surface before their condensation. These “cold” faults bound the anomalous degassing areas to the west, therefore they would be relatively new and shallow, suggesting a progressive westward shift of slope failure.
    Description: Published
    Description: Puerto de la Cruz, Tenerife, Canary Islands, Spain
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; soil CO2 effluxes ; hidden faults ; soil temperature ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: Oral presentation
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  • 10
    Publication Date: 2017-04-04
    Description: Active volcanoes can influence surrounding vegetation both through passive degassing during quiescent periods and through eruptive degassing, by introducing into the atmosphere several metals as gases and particles. The chemical composition of tree-rings has been generally used to investigate the effects of anthropogenic gas emissions and dendrochemical methods have successfully recorded variations in the pollution levels. The use of tree-rings analysis in active volcanic areas has shown that vascular plants could be used as archives of volcanogenic metals deposition. Tree cores of Pinus Nigra and Populus tremula were collected in sites located both on the downwind (Citelli and Mt. Fontane sites) and on the upwind (Mt. Intraleo site) sectors of Mt. Etna in June 2008. Individual and composited tree-rings were analyzed by inductively-coupled-plasma mass-spectrometry for the determination of several trace elements (As, Cd, Li, Mn, Mo, Ni, Se, Sr, Pb, V). Tree cores were dated dendrochronologically before analysis, and their ages date back to 1915. The preliminary results show that some elements have significant differences in concentration between the two tree species analyzed, and in general metals are more concentrated in the samples from the downwind sites, hence more exposed to crater gas emissions. Furthermore, the temporal patterns of metal contents show some evident peaks likely related to some of the major flank eruptions of the volcano, particularly those occurred after 1945. This method can be used in many active volcanoes to reconstruct their past degassing rate and recognize possible eruptive cycles, thus helping forecast their future behaviour.
    Description: Published
    Description: Puerto de la Cruz, Tenerife, Canary Islands, Spain
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; tree rings ; trace metals ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 11
    Publication Date: 2017-04-04
    Description: This work reports the first estimation of total CO2 emission to the atmosphere (visible and non-visible) from Etna volcano, Sicily, by means of direct methods. Until present, only direct measurements of the CO2 emitted by the volcanic plume of Etna had been performed, and not data of direct soil CO2 efflux from surface environment of this volcano were available. To estimate the total CO2 emission, 4075 soil CO2 efflux measurements were performed by means of the accumulation chamber method in October-November 2008. Most of the study area showed background levels of soil CO2 efflux (0.53 g·m-2·d-1), while peak values (〉1725 g·m-2·d-1) were mainly identified inside the summit craters and at Torre del Filosofo area. Other zones with relatively high CO2 efflux values were identified at Paternó, Zafferana Etnea and Trecastagni-Viagrande. The total output of CO2 diffuse emission from the study area (973 km2) was computed in 20320 t·d-1, where 1671 t·d-1, about 8.3% of CO2 diffuse emission, was emitted by an area of 87 km2 which includes the summit craters and Torre del Filosofo. To evaluate the visible/diffuse CO2 emission ratio, plume CO2 emission rate was estimated by multiplying SO2 emission rate times observed CO2/SO2 plume ratio following the methodology described by Shinohara (2005). Total CO2 visible emission was estimated about 31.5 kt·d-1, value is in the range reported for Etna volcano (0.9-67.5 kt·d-1; Aiuppa et al., 2006). The total output of CO2 diffuse emission represents 39% of the total CO2 emission from Etna volcano to the atmosphere. These results agree with the observations of Allard et al. (1991), who reported that diffuse and visible CO2 emissions were in the same order of magnitude. This study demonstrates the importance of measuring diffuse CO2 emissions from active volcanoes like Mt. Etna in order to have a better approach on the global estimate of CO2 emission to the atmosphere from subaerial volcanoes
    Description: Published
    Description: Puerto de la Cruz, Tenerife, Canary Islands, Spain
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: open
    Keywords: Mt. Etna ; soil CO2 effluxes ; CO2 budget ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 12
    Publication Date: 2022-05-25
    Description: The continuous measurement of molecular hydrogen (H2) emissions from passively degassing volcanoes has recently been made possible using a new generation of low-cost electrochemical sensors. We have used such sensors to measure H2, along with SO2, H2O and CO2, in the gas and aerosol plume emitted from the phonolite lava lake at Erebus volcano, Antarctica. The measurements were made at the crater rim between December 2010 and January 2011. Combined with measurements of the long-term SO2 emission rate for Erebus, they indicate a characteristic H2 flux of 0. 03 kg s-1 (2. 8 Mg day-1). The observed H2 content in the plume is consistent with previous estimates of redox conditions in the lava lake inferred from mineral compositions and the observed CO2/CO ratio in the gas plume (~0. 9 log units below the quartz-fayalite-magnetite buffer). These measurements suggest that H2 does not combust at the surface of the lake, and that H2 is kinetically inert in the gas/aerosol plume, retaining the signature of the high-temperature chemical equilibrium reached in the lava lake. We also observe a cyclical variation in the H2/SO2 ratio with a period of ~10 min. These cycles correspond to oscillatory patterns of surface motion of the lava lake that have been interpreted as signs of a pulsatory magma supply at the top of the magmatic conduit.
    Description: Published
    Description: 2109 – 2120
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Erebus volcano; Hydrogen; Lava lake; Magma redox conditions; Volcanic degassing ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases
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  • 13
    Publication Date: 2022-05-26
    Description: © The Author(s), 2016. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Scientific Reports 6 (2016): 29587, doi:10.1038/srep29587.
    Description: Interactions between climate, fire and CO2 are believed to play a crucial role in controlling the distributions of tropical woodlands and savannas, but our understanding of these processes is limited by the paucity of data from undisturbed tropical ecosystems. Here we use a 28,000-year integrated record of vegetation, climate and fire from West Africa to examine the role of these interactions on tropical ecosystem stability. We find that increased aridity between 28–15 kyr B.P. led to the widespread expansion of tropical grasslands, but that frequent fires and low CO2 played a crucial role in stabilizing these ecosystems, even as humidity changed. This resulted in an unstable ecosystem state, which transitioned abruptly from grassland to woodlands as gradual changes in CO2 and fire shifted the balance in favor of woody plants. Since then, high atmospheric CO2 has stabilized tropical forests by promoting woody plant growth, despite increased aridity. Our results indicate that the interactions between climate, CO2 and fire can make tropical ecosystems more resilient to change, but that these systems are dynamically unstable and potentially susceptible to abrupt shifts between woodland and grassland dominated states in the future.
    Description: This work was supported by NSF grants EAR0601998, EAR0602355, AGS0402010, ATM0401908, ATM0214525, ATM0096232 and AGS1243125 and a Chevron Centennial Fellowship at the University of Texas at Austin awarded to T.M.S.
    Keywords: Climate-change ecology ; Palaeoclimate
    Repository Name: Woods Hole Open Access Server
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  • 14
    Publication Date: 2023-01-27
    Description: One of the major objectives of volcanology remains relating variations in surface monitoring signals to the magmatic processes at depth that cause these variations. We present a method that enables compositional and temporal information stored in zoning of minerals (olivine in this case) to be linked to observations of real-time degassing data. The integrated record may reveal details of the dynamics of gradual evolution of a plumbing system during eruption. We illustrate our approach using the 2006 summit eruptive episodes of Mt. Etna. We find that the history tracked by olivine crystals, and hence, most likely the magma pathways within the shallow plumbing system of Mt. Etna, differed considerably between the July and October eruptions. The compositional and temporal record preserved in the olivine zoning patterns reveal two mafic recharge events within months of each other (June and September 2006), and each of these magma supplies may have triggered the initiation of different eruptive cycles (July 14–24 and August 31–December 14). Correlation of these observations with gas monitoring data shows that the systematic rise of the CO2/SO2gas values is associated with the gradual (preand syn-eruptive) supply of batches of gas-rich mafic magma into segments of Etna’s shallow plumbing system, where mixing with pre-existing and more evolved magma occurred.
    Description: This work was funded by the German Science Foundation as part of the collaborative research centre (SFB) on Rheology of the Crust—from the upper crust to the subduction zone (SFB 526).
    Description: Published
    Description: 692
    Description: 2V. Dinamiche di unrest e scenari pre-eruttivi
    Description: 3V. Dinamiche e scenari eruttivi
    Description: 5V. Sorveglianza vulcanica ed emergenze
    Description: JCR Journal
    Description: restricted
    Keywords: Crystal zoning ; Plumbing system Mt. Etna ; Magma mixing ; Gas monitoring ; 04. Solid Earth::04.04. Geology::04.04.05. Mineralogy and petrology ; 04. Solid Earth::04.04. Geology::04.04.07. Rock geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.03. Magmas ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions ; 05. General::05.09. Miscellaneous::05.09.99. General or miscellaneous
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 15
    Publication Date: 2024-05-09
    Description: Abstract A geochemical survey of fumarolic and submerged gases from fluid discharges located in the Nea Kameni and Palea Kameni islets (Santorini Island, Greece) was carried out before, during, and after the unrest related to the anomalously high seismic and ground deformation activity that affected this volcanic system since January 2011. Our data show that from May 2011 to February 2012, the Nea Kameni fumaroles showed a significant increase of H2 concentrations. After this period, an abrupt decrease in the H2 contents, accompanied by decreasing seismic events, was recorded. A similar temporal pattern was shown by the F−, Cl−, SO4 2−, and NH4 + concentrations in the fumarolic condensates. During the sharp increase of H2 concentrations, when values up to 158 mmol/ mol were measured, the δ13C–CO2 values, which prior to January 2011 were consistent with a dominant CO2 thermometamorphic source, have shown a significant decrease, suggesting an increase of mantle CO2 contribution. Light hydrocarbons, including CH4, which are controlled by chemical reactions kinetically slower than H2 production from H2O dissociation, displayed a sharp increase in March 2012, under enhanced reducing conditions caused by the high H2 concentrations of May 2011–February 2012. The general increase in light hydrocarbons continued up to July 2012, notwithstanding the contemporaneous H2 decrease. The temporal patterns of CO2 concentrations and N2/Ar ratios increased similarly to that of H2, possibly due to sealing processes in the fumarolic conduits that diminished the contamination related to the entrance of atmospheric gases in the fumarolic conduits. The compositional evolution of the Nea Kameni fumaroles can be explained by a convective heat pulse from depth associated with the seismic activation of the NE–SW-oriented Kameni tectonic lineament, possibly triggered by either injection of new magma below Nea Kameni island, as apparently suggested by the evolution of the seismic and ground deformation activity, or increased permeability of the volcanic plumbing system resulting from the tectonic movements affecting the area. The results of the present study demonstrate that the geophysical and geochemical signals at Santorini are interrelated and may be precursory signals of renewed volcanic activity and encourage the development of interdisciplinary monitoring program to mitigate the volcanic risk in the most tourist-visited island of the Mediterranean Sea.
    Description: Published
    Description: 711
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: 4.5. Studi sul degassamento naturale e sui gas petroliferi
    Description: JCR Journal
    Description: restricted
    Keywords: Santorini Island . ; Fluid geochemistry ; Geochemical monitoring ; Seismic crisis ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.07. Instruments and techniques
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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