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  • 1
    Publication Date: 2024-06-04
    Description: Yedoma is a permafrost deposit widely distributed across the Arctic and found exclusively within the unglaciated regions in northern Siberia, Alaska, and the Yukon, which are the core regions of Beringia. Yedoma deposits accumulated during the late Pleistocene Stage and are characterized by their predominantly fine-grained texture and association with syngenetic perma-frost formation. The very high ground ice content is most commonly present as pore ice and wedge ice that formed contemporaneously with sediment deposition. In the last decade, research has transitioned from debates about the origin of the Yedoma deposits towards increasing attention on the large carbon and nitrogen pools in Yedoma, their vulnerability to thaw, and increasing mobilization as the climate has warmed across the Arctic. In addition to classical cryolithological and sedimentological research, new methods such as stable isotope paleoclimate reconstruction and ancient sedimentary DNA studies have been more widely applied to better understand the characteristics of Yedoma deposits and helped emphasize their value as archives of Quaternary climate and paleoecological conditions during Ice Age Beringia.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 2
    Publication Date: 2024-06-02
    Description: Manganese (Mn) is an essential micro-nutrient that can limit or, along with iron (Fe), co-limit phytoplankton growth in the ocean. Glacier meltwater is thought to be a key source of trace metals to high latitude coastal systems, but little is known about the nature of Mn delivered to glacially-influenced fjords and adjacent coastal waters. In this work, we combine in-situ dissolved Mn (dMn) measurements of surface waters with Mn K-edge X-ray absorption spectroscopy (XAS) data of suspended particles in four fjords of West Greenland. Data were collected from transects of up to 100 km in fjords with different underlying bedrock geology from 64 to 70°N. We found that dMn concentrations generally decreased conservatively with increasing salinity (from 80-120 nM at salinity 〈8 to 〈40 nM at salinities 〉25). Dissolved Fe (dFe) trends in these fjords similarly declined with increasing distance from glacier outflows (declining from 〉20 nM to 〈8 nM). However, the dMn/dFe ratio increased rapidly likely due to the greater stability of dMn at intermediate salinities (i.e. 10 – 20) compared to rapid precipitation of dFe across the salinity gradient. The XAS data indicated a widespread presence of Mn(II)-rich suspended particles near fjord surfaces, with structures akin to Mn(II)-bearing phyllosilicates. However, a distinct increase in Mn oxidation state with depth and the predominance of birnessite-like Mn(IV) oxides was observed for suspended particles in a fjord with tertiary basalt geology. The similar dMn behaviour in fjords with different suspended particle Mn speciation (i.e., Mn(II)-bearing phyllosilicates and Mn(IV)-rich birnessite) is consistent with the decoupling of dissolved and particulate Mn and suggests that dMn concentrations on the scale of these fjords are controlled primarily by dilution of a freshwater dMn source rather than exchange between dissolved and particle phases. This work provides new insights into the Mn cycle in high latitude coastal waters, where small changes in the relative availabilities of dMn, dFe and macronutrients may affect the identity of the nutrient(s) proximally limiting primary production.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2024-05-31
    Description: The mesopelagic or ocean twilight zone (OTZ) in the ocean contains huge numbers of fish in a relatively pristine environment and may therefore attract interest as a commercial fishery. In this study we evaluate in economic terms, the likely trade-offs between the different services provided by the mesopelagic layer in the Bay of Biscay and the societal benefits of its commercial exploitation. Benefits arise mainly from the likely use of this group of species as raw material for producing fishmeal and fish oil. Costs are derived from the loss in climate regulating and cultural, services, but also from the loss in the provisioning service of other commercial species. To do so we compare the current non-exploited status with a situation in where mesopelagic fishes are harvested at levels capable of producing the Maximum Sustainable Yield. Results suggest that if mesopelagic fishes are harvested, a mean value of 1.2 million Euro loss in a year will be created in the Bay of Biscay, although in a range between 42 million Euro loss and 48 Euro million benefits. This uncertainty comes, mainly, from the limited existing knowledge of the mesopelagic fishes’ biomass but also from the uncertainty on the biomass of the rest of the species of the studied ecosystem. The large range indicates that a better understanding of the mesopelagic ecosystem is needed, however, results also show that ecosystem services under no exploitation provided by the OTZ could be more valuable than the fishmeal and fish oil that potentially could be obtained from the fishes harvested in this sea layer.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 4
    Publication Date: 2024-05-29
    Description: Fault creep along the lower eastern flank of Mt. Etna volcano has been documented since the end of the 19th century and significantly contributes to the surface faulting hazard in the area. On 29 October 2002, during a seismic swarm related to dyke intrusions, two earthquakes caused extensive damage and surface faulting in an area between the Santa Venerina and Santa Tecla villages. On the same day after the two earthquakes, an episodic aseismic creep occurred along the Scalo Pennisi Fault close to the Santa Tecla coastline. On 8 February 2022, during another aseismic creep event along the Scalo Pennisi Fault, we observed the reopening of the pre existing 2002 ground ruptures mostly as pure dilational fractures. We mapped the 2002 and 2022 surface ruptures, and collected data on displacement, length, and pattern of ground breaks. Ground ruptures affected structures located along the activated fault segments, including roads, walls and buildings. The 2002 surface faulting propagation can be ascribed to a sliding of the Mt. Etna eastern flank toward the SE, as also suggested by the related shallow seismicity, and InSAR and geodetic data between 2002 and 2005. For the 2022 event, dif ferential InSAR data, acquired in both descending and ascending views, allowed us to decompose Line of Sight (LOS) displacement into horizontal and vertical components. We detect a ~ 700 m long and ~ 500 m wide deformation zone with a downward and eastward motion (max displacement ~1,5 cm) consistent with a normal fault. We inverted the InSAR–detected surface deformation using a uniform-slip fault model and obtained a shallow detachment for the causative fault, located at ~300 m depth, within the volcanic pile. This is the first in depth study along the Scalo Pennisi Fault to suggest a shallow faulting that accommodates Mt. Etna E flank gravitational sliding.
    Description: Published
    Description: 229829
    Description: JCR Journal
    Keywords: Etna ; Aseismic creep ; Earthquake ; Surface faulting ; Volcano-tectonic deformation ; InSAR
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2024-05-28
    Description: Nominally anhydrous minerals (NAMs) may contain significant amounts of water and constitute an important reservoir for mantle hydrogen. The colloquial term ‘water’ in NAMs is related to the presence of hydroxyl-bearing (OH􀀀 ) point defects in their crystal structure, where hydrogen is bonded to lattice oxygen and is charge-balanced by cation vacancies. This hydrous component may therefore have substantial effects on the thermoelastic parameters of NAMs, comparable to other major crystal-chemical substitutions (e.g., Fe, Al). Assessment of water concentrations in natural minerals from mantle xenoliths indicates that olivine commonly stores ~0–200 ppm of water. However, the lack of samples originating from depths exceeding ~250 km coupled with the rapid diffusion of hydrogen in olivine at magmatic temperatures makes the determination of the olivine water content in the upper mantle challenging. On the other hand, numerous experimental data show that, at pressures and temperatures corresponding to deep upper mantle conditions, the water storage capacity of olivine increases to 0.2–0.5 wt%. Therefore, determining the elastic properties of olivine samples with more realistic water contents for deep upper mantle conditions may help in interpreting both seismic velocity anomalies in potentially hydrous regions of Earth’s mantle as well as the observed seismic velocity and density contrasts across the 410-km discontinuity. Here, we report simultaneous single-crystal X-ray diffraction and Brillouin scattering experiments at room temperature up to 11.96(2) GPa on hydrous [0.20(3) wt% H2O] Fo90 olivine to assess its full elastic tensor, and complement these results with a careful re-analysis of all the available single-crystal elasticity data from the literature for anhydrous Fo90 olivine. While the bulk (K) and shear (G) moduli of hydrous Fo90 olivine are virtually identical to those of the corresponding anhydrous phase, their pressure derivatives K′ and G′ are slightly larger, although consistent within mutual uncertainties. We then defined linear relations between the water concentration in Fo90 olivine, the elastic moduli and their pressure derivatives, which were then used to compute the sound velocities of Fo90 olivine with higher degrees of hydration. Even for water concentrations as high as 0.5 wt%, the sound wave velocities of hydrous and anhydrous olivines were found to be identical within uncertainties at pressures corresponding to the base of the upper mantle. Contrary to previous claims, our data suggest that water in olivine is not seismically detectable, at least for contents consistent with deep upper mantle conditions. In addition to that, our data reveal that the hydration of olivine is unlikely to be a key factor in reconciling seismic velocity and density contrasts across the 410-km discontinuity with a pyrolitic mantle.
    Description: Published
    Description: 107011
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2024-05-28
    Description: The rapid decline in both quality and availability of freshwater resources on our planet necessitates their thorough assessment to ensure sustainable usage. The growing demand for water in industrial, agricultural, and domestic sectors poses significant challenges to managing both surface and groundwater resources. This study tests and proposes a hybrid evaluation approach to determine Groundwater Quality Indices (GQIs) for irrigation (IRRI), seawater intrusion (SWI), and potability (POT), finalized to the spatial distribution of groundwater suitability involving water quality indicator along with hydrogeological and socio-economic factors. Mean Decrease Accuracy (MDA) and Information Gain Ratio (IGR) were used to state the importance of chosen factors such as level of groundwater above the sea, thickness of the aquifer, land cover, distance from coastline, silt soil content, recharge, distance from river and lagoons, depth to water table from ground, distance from agricultural wells, hydraulic conductivity, and lithology for each quality index, separately. The results of both methods showed that recharge is the most important parameter for GQIIRRI and GQIPOT, while the distance from the coastline and the rivers, are the most important for GQISWI. The spatial modelling of GQIIRRI and GQIPOT in the study area has been achieved applying three machine learning (ML) algorithms: the Boosted Regression Tree (BRT), the Random Forest (RF), and the Support Vector Machine (SVM). Validation results showed that RF has the highest prediction for GQIIRRI, while the SVM model has the highest prediction for the GQIPOT index. It is worth to mention that the future utilization and testing of new algorithms could produce even better results. Finally, GQIIRRI and GQIPOT were combined and compared using two combine and overlay methods to prepare a hybrid map of multi-GQIs. The results showed that 69% of the study area is suitable for irrigation and potable use, due to both geogenic and anthropogenic activities which contribute to make some water resources unsuitable for either use. Specifically, the northern, western, and eastern portions of the study area are in the "very high and high quality" classes while the southern portion shows "very low and low quality" classes. In conclusion, the developed map and approach can serve as a practical guide for enhancing groundwater management, identifying suitable areas for various uses and pinpointing regions requiring improved management practices.
    Description: Published
    Description: 119041
    Description: JCR Journal
    Keywords: Artificial intelligence ; Groundwater suitability ; Quality index ; Vulnerability map
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 7
    Publication Date: 2024-05-28
    Description: The spatial pattern of Antarctic surface air temperature variability on multi–decadal to multi–centennial time scales is poorly known because of the short instrumental records, the relatively small number of high–resolution paleoclimate observations, and biases in climate models. Here, changes in surface air temperature over Antarctica are reconstructed over the past two millennia using data assimilation constrained by different ice core water isotope records in order to identify robust signals. The comparison between previous statistically based temperature reconstructions and simulations covering the full Common Era driven by natural and anthropogenic forcings shows major discrepancies occurring in the period 1–1000 CE over East Antarctica, with the reconstructions displaying a warming over 1–500 CE that is not reproduced by the simulations. This suggests that the trends in the first millennium deduced from the statistically based reconstructions are unlikely to be entirely forced by external forcings. Our reconstructions show the high sensitivity of the 500-year temperature trend in Antarctica and its spatial distribution to selection of the records for the reconstructions, especially during 1–500 CE. A robust cooling over Antarctica during 501–1000 CE has been obtained in three data assimilation–based reconstructions with a larger magnitude in the WAIS than elsewhere over Antarctica, in agreement with previous estimates with the larger changes than simulated in climate models. The reconstructions for atmospheric circulation indicate that the pattern of temperature changes over 501–1000 CE is related to the positive trend of Southern Annular Mode and a deepening of Amundsen Sea Low. This confirms the role of internal variability in the temperature trends on multi–centennial scales.
    Type: Article , PeerReviewed
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  • 8
    Publication Date: 2024-05-27
    Description: In this paper we employ a combination of gravity and hydrologic data to constrain a hydraulic model of the Škocjan Caves, an allogenic dominated karstic system in Slovenia. The gravity time-series recorded by a spring-based gravimeter, are carefully analyzed to remove tidal and non-tidal effects and unveil the local hydrologic contribution, which is influenced by the temporary accumulation of water in the cave system during the flood events of the Reka river. We make use of a combined analysis of three large flood events with peak river discharge of about 200, 230 and 300 m3/s, that caused significant water level and gravity variations sensed by the pressure transducer and by the gravimeter. By the integration of hydraulic modelling we study the different coupled gravimetric-hydrologic responses to these flood events: we show that, depending on the peak discharge and duration of the event, different flow conditions are present in the cave system. In addition to the information provided by the pressure transducer, the gravimeter is sensitive to the flow dynamics in a different sector of the cave due to the choice of its location; this configuration helps to better constrain the hydraulic model. Moreover, we find that the autogenic recharge by percolating water can significantly affect the gravity time-series and must be considered in related models. By inclusion of both the hydraulic model outcomes and of the modelling of the autogenic recharge, we are able to better explain the gravity transients during the two smaller magnitude events. In particular, during such events the autogenic contribution produces a transient gravity signal, which is about 4 times larger than the allogenic one, while during the largest flood the allogenic contribution drastically overcomes the autogenic effect by a factor 20. By discussing this case, we prove the potential of terrestrial gravity observation to depict the hydro-dynamics of these complex karstic systems as well as the potential of gravimetry to remotely monitor these storage units.
    Description: Published
    Description: 130453
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2024-05-27
    Description: The 28th September 2018 Sulawesi Supershear earthquake (MW 7.5) was one of the deadliest earthquakes in the recent history of Indonesia causing ∼4000 causalities. The earthquake caused a ∼ 177 km long surface rupture along the Palu-Karo fault. Apart from surface rupture, the earthquake caused extensive earthquake environmental effects (EEEs) around the Palu-Donggala area of Central Sulawesi, Indonesia, which includes tsunami, coastal landslide, liquefaction, ground cracks and more than 7300 landslides in hilly areas. Initial post-event analysis and reports assigned a Modified Mercalli Intensity (MMI) of VII to VIII in Palu City and the surrounding area. Building damage and ground effects caused by the earthquake suggested that seismic intensity was understated. Here we applied the EEEs information from field survey data, published reports, and remote sensing tools to determine macroseismic intensity using the Environmental Seismic Intensity (ESI-07) Scale. The ESI-07 intensity derived from the ground effects suggests the maximum intensity of X-XI, which is 3–4° higher than the traditional intensity estimated by the United States Geological Survey (USGS) and the Indonesian Agency for Meteorology, Climatology, and Geophysics (BMKG). ShakeMaps were generated considering the ESI-07 values. The ShakeMap was compared with the instrumentally derived ShakeMap for the Palu earthquake, which proves that the ShakeMap prepared from the instrumental data or structural damage data is underrated. We argue that proper documentation of the EEEs is necessary for such damaging earthquakes for future earthquake hazard mapping and planning in the study area and other earthquakes in Indonesia. In addition, this will help in defining the on-fault and off-fault damage zone towards reducing the seismic risk of the Palu Donggala area.
    Description: Published
    Description: 107054
    Description: JCR Journal
    Keywords: Sulawesi Earthquake ; Indonesia ; EEEs ; ESI-07 ; ShakeMap ; Seismic Hazard
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2024-05-27
    Description: Extreme rainfall generated by storms and atmospheric instability causes innumerable damage to coastal areas and their marine ecosystems. This chapter describes some of the processes that generate critical precipitation events in coastal areas. Among these, the typical synoptic conditions combine with the increase in sea surface temperature and air temperature, coastal geomorphology, and sea breeze. Coastal and regional rainfall events should be studied to understand the meteorological, oceanographic, and geomorphological conditions that cause the extreme events, to later relate them with the consequences on coasts. The effects of the interaction of storms with tides originating storm surges and the effect of sea-level rise are described as well as the main consequences of extreme rainfall events such as beach erosion, decrease in water quality, changes in plankton and fish species that inhabit coastal waters, among others.
    Type: Book chapter , PeerReviewed
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  • 11
    Publication Date: 2024-05-24
    Description: Highlights • Investigation into the potential of Porites microatolls for SST reconstruction. • Comparison between recent and more conventional coral paleoclimatology methods. • Application of Srsingle bondU and Li/Mg paleothermometer. • Accuracy and reproducibility of Sr/Ca proved to be the most suitable proxy for SST reconstruction. Abstract Massive dome-shaped coral Porites are the predominant choice for paleoclimate studies due to their consistent and reliable growth. When growing close to sea level, they become limited in their vertical growth and form so-called ‘microatolls’. Microatolls have not yet been extensively explored for paleoclimate reconstruction. Here, we investigate how reliable modern Porites microatolls are against empirical sea-surface temperature using Sr/Ca, δ18O, Li/Mg and Srsingle bondU paleothermometry methods on samples from the Society Islands, French Polynesia. Our results show Sr/Ca ratios have the lowest Standard Error of the Inverse Prediction (SEIP) at 0.415 °C (N = 41) with a calibration of Sr/Ca (mmol mol−1) = −0.082 ± 0.006 SST (°C) + 11.256 ± 0.170 and with high reproducibility across multiple corals. The reproducibility of δ18O was less good, with SEIP increasing to 0.829 °C (N = 41). Considering methods directly from the literature, Li/Mg ratio empirically corrected for Sr/Ca had the best balance between bias and precision where no local calibration could be available. This study independently evaluates and confirms the suitability of Porites microatolls from well-flushed environments for paleoclimate studies. Fossil dome-shaped Porites grow anywhere between near-surface and roughly 20 m depths which inherently incorporates uncertainty into any sea surface temperature reconstruction. This uncertainty is significantly reduced for microatolls due to their well-constrained bathymetry. The study represents a fundamental step in paleoclimate research targeting consistently near the water-air interface bringing reliability and, especially when combined with their ability to reconstruct past sea-level changes, microatolls have the potential to be central for future paleoenvironmental studies.
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  • 12
    Publication Date: 2024-05-23
    Description: Geofluids from natural springs connect with the crust and/or mantle in many cases, and their geochemical anomalies could be significant for the study on faults activity and even earthquakes. Several natural springs are distributed along the Lenglongling fault zone (LLLFZ) in the northeastern margin of the Tibetan Plateau, where the Ms 6.9 Menyuan earthquake occurred on January 8th, 2022. Based on chemical and isotopic compositions (δD, δ18O, δ13C, and 3He/4He) of water and gas samples, the origin of geofluids and their potential correlation with fault activity even including earthquakes are preliminarily assessed in this paper. The δ13CCO2 values and 3He/4He ratios showed that the gas originating from the crust was associated with the metamorphism of carbonate rocks, whereas the δ18O and δD values of water samples indicated that the natural springs were predominantly infiltrated with precipitations from local mountains ranging 3.7 - 5.5 km in height. Obvious changes of Ca2+ and HCO3􀀀 concentrations in SZK spring waters in the surface rupture zones were observed in a short period (about three months) after the main shock, in contrast to those of the GSK springs far from the surface rupture zones. Such variations might be correlated with the stress increase prior to the 2022 Menyuan Ms 6.9 earthquake. The mechanical fracturing of surrounding limestone rocks during the slipping movement of LLLF could facilitate the water-rock interactions. Compared to three-month observations after the main shock, relatively higher concentrations of HCO3􀀀 and heavier δ18OH2O values of the LHG springs were also observed in the short-term period. The shallow stored formation water might be squeezed along the cracks and rose to the surface during earthquake tremors, causing a sandblasting water phenomenon.
    Description: Published
    Description: 105767
    Description: JCR Journal
    Keywords: Menyuan earthquake ; Natural spring ; Fluid geochemistry ; Lenglongling fault ; Tibetan plateau
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 13
    Publication Date: 2024-05-23
    Description: The influence of the hydrothermal circulation on seismicity and uplift observed at the Campi Flegrei caldera (Italy) is a topic of great interest to the scientific community. Recently, Thermo-Poro-Elastic (TPE) inclusions were proposed as likely deformation sources. They are suitable to explain the mechanical effects induced by hot and pressurized hydrothermal fluids, possibly exsolved from underlying magma, and pervading an overlying brittle layer. Recent works show that a TPE inclusion located at approximately 2 km depth below the Campi Flegrei caldera significantly contributed to the large and rapid soil uplift observed during the ‘82-’84 unrest phase. In the present work we demonstrate that such a source of deformation is likely playing a role even in the current unrest phase, which is characterized by a much lower uplift-rate with respect to the one occurred in the previous unrest phase. We will show that the time-series of soil uplift observed in the last 18 years can be reproduced by assuming the reactivation of the same deformation source responsible of the ‘82-’84 unrest located within a shallow brittle layer at about 2 km depth. The presence of a brittle layer has been evidenced in the past by tomographic studies and is confirmed by a sharp variation of the b-value at the corresponding depth.We believe that our results provide very important insights and evidences, supporting the existence and the importance of an active thermo-poro-elastic deformation source, which can be useful for understanding the unrest of the Campi Flegrei caldera, from both a scientific and geohazard perspective.
    Description: Published
    Description: 107930
    Description: JCR Journal
    Keywords: Campi Flegrei ; Hydrothermal fluids ; Caldera ; Uplift ; Induced seismicity ; Deformation source
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 14
    Publication Date: 2024-05-23
    Description: Plastic removal technologies can temporarily mitigate plastic accumulation at local scales, but evidence-based criteria are needed in policies to ensure that they are feasible and that ecological benefits outweigh the costs. To reduce plastic pollution efficiently and economically, policy should prioritize regulating and reducing upstream production rather than downstream pollution cleanup.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , notRev
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  • 15
    Publication Date: 2024-05-23
    Description: Since net-zero greenhouse gas emissions targets have become a keystone of European and German climate policy, a debate about the need to actively remove carbon dioxide from the atmosphere in addition to drastically reducing emissions has emerged. Although still relatively scarce, empirical studies on the emergence of carbon dioxide removal (CDR) on the political agenda have shown that variations in the constellations and positions of policy-relevant actors play a key role in shaping patterns of CDR policymaking. The German and wider European Union (EU) CDR policy space is emergent, and political actors are just beginning to position themselves. Building on our previous work which established a typology of CDR policy integration patterns and developed a discourse analytical framework for mapping CDR-policy-relevant speaker positions, we present the first fine-grained empirical reconstruction of CDR-policy-relevant actors and their positions in the German context. Our analytical approach aims to improve understanding of patterns in CDR policymaking by showing that on the EU, national, and subnational levels, a multitude of institutional actors may adopt differing positions as the CDR policy space evolves. In addition to identifying fine-grained ‘ideal types’ of positions that policy actors may adopt in the formative phase of German CDR policy, our analysis provides an empirical ‘map’ of CDR policy-relevant actors and explores hypotheses about emerging discourse coalitions and potential conflict cleavages.
    Type: Article , PeerReviewed
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  • 16
    Publication Date: 2024-05-23
    Description: Highlights • Climate engineering presents a novel challenge for global environmental governance • Institutional and discursive structures co-shape global environmental governance • A lack of joint analyses of both structures impedes understanding of governance emergence • A joint neo-institutionalist and post-structuralist analysis addresses this gap • Varying structures shape differing climate engineering governance decisions in several forums Abstract The Anthropocene is giving rise to novel challenges for global environmental governance. The barriers and opportunities shaping the ways in which some of these complex environmental challenges become governable on the global level are of increasing academic and practical relevance. In this article, we bring neo-institutionalist and post-structuralist perspectives together in an innovative framework to analyse how both institutional and discursive structures together bound and shape the global governance opportunities which become thinkable and practicable in the face of new global environmental challenges. We apply this framework to explore how governance of climate engineering – large scale, deliberate invention into the global climate system – is being shaped by discursive and institutional structures in three international forums: The London Convention and its Protocol, the Convention on Biological Diversity, and the United Nations Environment Assembly. We illustrate that the ‘degree of fit’ between discursive and institutional structures made climate engineering (un)governable in each of these forums. Furthermore, we find that the ‘type of fit’ set the discursive and institutional conditions of possibility for what type of governance emerged in each of these cases. Based on our findings, we critically discuss the implications for the future governance of climate engineering at the global level.
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  • 17
    Publication Date: 2024-05-22
    Description: The Arctic is greatly impacted by climate change. The increase in air temperature drives the thawing of permafrost and an increase in coastal erosion and river discharge. This leads to a greater input of sediment and organic matter into coastal waters, which substantially impacts the ecosystems by reducing light transmission through the water column and altering the biogeochemistry, but also the subsistence economy of local people, and changes in climate because of the transformation of organic matter into greenhouse gases. Yet, the quantification of suspended sediment in Arctic coastal and nearshore waters remains unsatisfactory due to the absence of dedicated algorithms to resolve the high loads occurring in the close vicinity of the shoreline. In this study we present the Arctic Nearshore Turbidity Algorithm (ANTA), the first reflectance-turbidity relationship specifically targeted towards Arctic nearshore waters that is tuned with in-situ measurements from the nearshore waters of Herschel Island Qikiqtaruk in the western Canadian Arctic. A semi-empirical model was calibrated for several relevant sensors in ocean color remote sensing, including MODIS, Sentinel 3 (OLCI), Landsat 8 (OLI), and Sentinel 2 (MSI), as well as the older Landsat sensors TM and ETM+. The ANTA performed better with Landsat 8 than with Sentinel 2 and Sentinel 3. The application of the ANTA to Sentinel 2 imagery that matches in-situ turbidity samples taken in Adventfjorden, Svalbard, shows transferability to nearshore areas beyond Herschel Island Qikiqtaruk.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , peerRev , info:eu-repo/semantics/article
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  • 18
    Publication Date: 2024-05-22
    Description: Delineating hydrothermal alteration and supergene caps is fundamental for mineral exploration of sulfide ores. The aim of this study is to apply a multi-scale workflow based on hyperspectral remote and proximal sensing data in order to delineate hydrothermal dolomitization and supergene alteration associated with the Mississippi Valley-Type Zn-Pb(-Ag) deposit of Jabali (Western Yemen). The area was investigated through hyperspectral images derived from the new launched Italian Space Agency’s PRISMA satellite, which has a higher spectral resolution compared to multispectral sensors and covers the mineral-diagnostic wavelength regions (such as the 2100 nm to 2300 nm range) with a Signal to Noise Ratio (SNR) ≥ 100. Spectral mineral maps were produced through the band ratios method using specific feature extraction indices applied to the hyperspectral satellite data. The results were validated by using Visible Near InfraRed (VNIR) to Short Wave InfraRed (SWIR) reflectance spectra, mineralogical (XRPD) and geochemical (ICP-ES/MS) analyses on rock samples collected in the Jabali area. The dolomites footprint was mapped using a PRISMA Level 2C image, by enhancing the spectral differences between limestones and dolomites in the SWIR-2 region (major features centered at 2340 nm and 2320 nm, respectively). Gossans were detected due to the Fe3+ absorption band in the VNIR region at 900 nm. The Zn-Pb mineralized area, extended for approximately 25 km2, was thus identified by recognizing gossan occurrences in dolomites. The study demonstrates that the PRISMA satellite is effective in identifying Zn-Pb mineralized outcrops in sedimentary basins.
    Description: Published
    Description: 105244
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2024-05-21
    Description: The increase in summer monsoon precipitation over western Africa during the last interglacial (LIG) relative to the pre-industrial (PI) is well documented, but it is uncertain whether this increase is due to larger rainfall rate alone, an extension of the summer monsoon season or a combination of the two. Due to different orbital config- uration, the boreal summer of the LIG was warmer but shorter than the PI, potentially influencing the summer monsoon duration. In this study, we employ a newly developed isotope-enabled climate model, AWI-ESM-wiso to investigate the intensity and length of the West African Summer Monsoon (WASM) for both LIG and PI time periods. Our model results indicate that, despite an intensification in summer insolation and an enhanced hydro-logical cycle, WASM season in the LIG is 9 days shorter compared to the PI. During the LIG, increased insolation in late spring and early summer strengthens the Saharan heat low (SHL) and its associated sub-systems, facilitating a faster accumulation of potential instability and an earlier WASM onset. However, a substantial earlier withdrawal of the WASM is also detected, driven by an earlier southward shift of insolation maximum. More- over, our findings are further supported by models participating in the 4th phase of the Paleoclimate Modelling Intercomparison Project (PMIP4).
    Repository Name: EPIC Alfred Wegener Institut
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  • 20
    Publication Date: 2024-05-21
    Description: Highlights • δ13C and δ18O profiles increase from exterior to interior until reaching a plateau. • Primary Layer δ13C reflects the δ13C of the Dissolved Inorganic Carbon. • In high pCO2 experiments, δ13C and δ18O closer to equilibrium fields. • Brachiopods grow according to an incremental growth model. Abstract Brachiopod shells are ubiquitous since the Early Cambrian up to now. As they secrete a shell made of low-magnesium calcite, more resistant to diagenesis than biocarbonates richer in Mg, their geochemical signatures are generally considered a powerful tool for paleo-environmental and paleo-climatic reconstructions. However, gaps in knowledge still remain on the underlying controls of the shell chemistry, in particular at a high spatial resolution. In this study, in situ oxygen and carbon isotope measurements by SIMS (Secondary Ion Mass Spectrometry) were performed in brachiopod shells of the cold-temperate water species Magellania venosa, constituted of a primary and a secondary layer. The individual specimens studied here grew under controlled conditions mimicking the natural environment and in experiments under low-pH (high pCO2) and high-temperature conditions. Transversal carbon and oxygen profiles showed a “brachiopod pattern” typical of extant two-layered brachiopods, with the primary layer depleted in 18O and 13C relative to equilibrium and the secondary layer showing a gradual increasing trend until reaching a near-equilibrium plateau. Overall, shells cultured at low pH were found to have δ18O and δ13C values closer to equilibrium when compared to shells from the control experiment. These near-equilibrium values may reflect a decrease in shell precipitation rate, leading to less kinetic effects, and/or a more rapid kinetics for the equilibration between DIC species and water. By close pairing of seawater δ18O and δ13C to that of shell microstructure, our study enables us to derive layer-specific C and O enrichment factors, which show the extent of pH and temperature effects superimposed on the seawater δ18O and DIC δ13C signal inherited. Finally, we show that during brachiopod shell growth, newly precipitated calcite is added to the calcite already existing, thus empirically validating the conceptual accretionary growth model proposed by Ackerly (1989).
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 21
    Publication Date: 2024-05-21
    Description: Highlights: • Huidobria chilensis is an endemic shrub distributed in the south of the Atacama Desert with a disjunct population at the northern coast. • Population and genetic structure correlate with geographic distance and geological factors. • Rain fall and fog, as well as ground water, must be regarded as important factors for populations at the coast and the Andean valleys, respectively. • A combination of different software tool to analyze GBS data allowed a good understanding of the population structure and genetic diversity. Abstract: Survival in hyperarid deserts is a major challenge for life in general and for plants in particular. The Atacama Desert presents harsh conditions such as limited rainfall, crusted soils, high soil salinity, high altitude, and intense solar radiation. These conditions, together with paleoclimatic variations over the last 10 million years, have influenced the genetic structure and connectivity of plant populations, resulting in a diverse flora with high endemism. However, the diversification of most lineages appears to be relatively recent, in contrast to the reported age of the Atacama Desert and the onset and expansion of hyperarid conditions since the late Oligocene and early Miocene. A prominent exception is Huidobria chilensis (Loasaceae), which is thought to be endemic to the Atacama since the Eocene. However, it is still not understood why this plant has been successful in adapting to the harshening environmental conditions. To investigate its genetic structure in relation to the history of the Atacama Desert, we studied 186 individuals from 11 populations using genotyping-by-sequencing (GBS). A total of nearly 56 k genome-wide single nucleotide polymorphisms (SNPs) were analyzed for population structure and genetic diversity. We identified four genetic clusters corresponding to geographic regions: the coastal region south of Tocopilla, the Cordillera de la Costa around Chañaral, and the Copiapó catchment 1 and 2. Genetic diversity within and between these clusters was analyzed along with rainfall, altitude, and landscape data. Although the genetic data support `isolation by distance’ as a major factor for genetic divergence between populations, the study also reveals the influence of topography on the distribution of H. chilensis and highlights the role of hydrologically connected watersheds and rivers in plant migration and colonization. This shapes the species' evolutionary trajectory and genetic diversity. Understanding these patterns in H chilensis lets one draw general conclusions about adaptation and survival strategies of plants in extreme desert environments such as the Atacama.
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  • 22
    Publication Date: 2024-05-20
    Description: Meta menardi (Latreille, 1804) and M. bourneti Simon, 1922 (Araneae: Tetragnathidae) are ubiquitous inhabitants of the twilight zone of most hypogean sites across Europe. The two species are broadly distributed in Italy, including Sicily, where they show a remarkable segregation along the altitudinal gradient of Mount Etna. Thanks to our recent sampling activities in this area, we create a georeferenced dataset allowing the application of Species Distribution Modelling aiming at evaluating the current and the future habitat in light of the impacts caused by climate change on the local populations. We predicted a relatively wide suitable area for M bourneti, ranging from the sea level up to 1100 m a.sl., whereas for M. menardi the suitable area encompasses a narrow mid altitude strip, extending halfway between the areas suitable for M. bourneti, and the highly unsuitable volcanic uplands, heavily disturbed by the volcanic activity. The averaged future predictions for 2070 under RCP 8.5 scenario, show that M. bourneti will expand its range upwards, in areas that are now suitable for M. menardi. In turn, predictions for M. menardi indicate an extreme reduction of the current strip of suitable habitat, likely determining its local extinction. Our findings are further corroborated by the analysis of the bioclimatic niche of the two species assessed via multidimensional Hutchinsonian hypervolume, being much smaller in M. menardi compared to of M. bourneti. In light of our results, it seems likely that having wider climatic preference, M. bourneti will substitute M. menardi in most of its current range in Sicily. Future interventions aiming at the conservation of M. menardi on Mount Etna are strongly advised.
    Description: Published
    Description: e02699
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Cave-dwelling spiders ; Mount Etna ; Lava caves ; Climate change ; Niche segregation ; Species distribution modelling
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
    Publication Date: 2024-05-20
    Description: Observations of the tidal response of celestial bodies quantified by the Love numbers are highly relevant in planetary geophysical investigations because they provide unique insight into the interior structures. For example, the high sensitivity of tidal deformations to the properties of the oceans detected beneath the icy surfaces of some moons is of paramount importance for investigations of their habitability. We present here PyALMA3, a software framework developed in Python devoted to the computation of planetary Love numbers. PyALMA3 is based on ALMA3, a previous version developed in Fortran. Conversion to Python significantly improves the accessibility and portability of the software. We tested PyALMA3 by applying it to the exploration of the tidal responses of Europa and the other Galilean moons. We show that accurate modeling of effects such as the viscoelastic deformations of ice and the water density gradient in the ocean (variations of 2–3% on the real part of k2) will be important in the context of geophysical investigations that will be conducted by future missions targeting icy moons, such as Europa Clipper and JUICE.
    Description: Published
    Description: 116120
    Description: JCR Journal
    Keywords: Galilean satellites ; Tides ; Planetary interior ; Ocean planets
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 24
    Publication Date: 2024-05-20
    Description: When approximating elliptic problems by using specialized approximation techniques, we obtain large structured matrices whose analysis provides information on the stability of the method. Here we provide spectral and norm estimates for matrix-sequences arising from the approximation of the Laplacian via ad hoc finite differences. The analysis involves several tools from matrix theory and in particular from the setting of Toeplitz operators and Generalized Locally Toeplitz matrix-sequences. Several numerical experiments are conducted, which confirm the correctness of the theoretical findings.
    Description: Published
    Description: 10-43
    Description: JCR Journal
    Keywords: Toeplitz matrix ; Generating function and spectral symbol ; Approximation of differential operators
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 25
    Publication Date: 2024-05-20
    Description: To ensure the long-term sustainable use of African Great Lakes (AGL), and to better understand the functioning of these ecosystems, authorities, managers and scientists need regularly collected scientific data and information of key environmental indicators over multi-years to make informed decisions. Monitoring is regularly conducted at some sites across AGL; while at others sites, it is rare or conducted irregularly in response to sporadic funding or short-term projects/studies. Managers and scientists working on the AGL thus often lack critical long-term data to evaluate and gauge ongoing changes. Hence, we propose a multi-lake approach to harmonize data collection modalities for better understanding of regional and global environmental impacts on AGL. Climate variability has had strong impacts on all AGL in the recent past. Although these lakes have specific characteristics, their limnological cycles show many similarities. Because different anthropogenic pressures take place at the different AGL, harmonized multilake monitoring will provide comparable data to address the main drivers of concern (climate versus regional anthropogenic impact). To realize harmonized long-term multi-lake monitoring, the approach will need: (1) support of a wide community of researchers and managers; (2) political goodwill towards a common goal for such monitoring; and (3) sufficient capacity (e.g., institutional, financial, human and logistic resources) for its implementation. This paper presents an assessment of the state of monitoring the AGL and possible approaches to realize a long-term, multi-lake harmonized monitoring strategy. Key parameters are proposed. The support of national and regional authorities is necessary as each AGL crosses international boundaries.
    Description: Published
    Description: 101988
    Description: JCR Journal
    Keywords: Fisheries ; Limnology ; Pollution ; Biodiversity ; Climate change ; Erosion
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 26
    Publication Date: 2024-05-17
    Description: Volcanic ashes can threaten the human respiratory system through inhalation. In this study we investigated the physical and chemical characteristics of volcanic ashes from the Pomici di Avellino (PdA) eruption, an Early Bronze Age (ca. 3.9 ka) Plinian event from Somma-Vesuvius volcano, southern Italy, whose wide dispersal affected most of the Italian peninsula. In particular, we analysed particle size, shape, composition, and surface reactivity of samples from both proximal and distal locations. Our results indicate that some tephra layers north of Rome have a phonolitic composition and match that of PdA eruption; they reach grain-sizes 〈2 μm (~13.5%), thus having the potential to enter the deep respiratory system. Furthermore, the reactivity in free radical generation makes these products potentially able to cause oxidative stress within cells. While commonly no volcanic hazard assessment is made in areas far from active volcanoes, this study highlights that fine ashes from future similar large eruptions, producing high amount of highly fragmented material, can pose a health hazard even in remote, non-volcanic areas, hundreds of km away from the vent, suggesting that further studies on ash toxicity (e.g., in vitro toxicity studies) are required.
    Description: Published
    Description: 107826
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 27
    Publication Date: 2024-05-17
    Description: Several high spatial resolution thermal infrared (TIR) missions are planned for the coming decade and their data will be crucial to constrain volcanic activity patterns throughout pre- and post-eruption phases. Foundational to these patterns is the subtle (1−2 K) thermal behavior, which is easily overlooked using lower spatial resolution data. In preparation for these new data, we conducted the first study using the entire twenty-two-year archive of higher spatial, lower temporal resolution TIR data from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor. This archive presents a unique opportunity to quantify low-magnitude temperature anomalies and small plumes over long time periods. We developed a new statistical algorithm to automatically detect the full range of thermal activity and applied it to 〉5000 ASTER scenes of five volcanoes with well-documented eruptions. Unique to this algorithm is its ability to use both day and night data, account for clouds, quantify accurate background temperatures, and dynamically scale depending on the anomaly size. Results improve upon those from the more commonly used lower spatial resolution data, despite the less frequent temporal coverage of ASTER, and show that high spatial resolution TIR data are equally as effective. Significantly, the smaller, subtle thermal detections served as precursory signals in ∼81% of eruptions, and the algorithm's results create a framework for classifying future eruptive styles.
    Description: Published
    Description: 113704
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 28
    Publication Date: 2024-05-17
    Description: This paper presents the results from a geographic information systems (GIS) workflow, which was used to analyze the spatial distribution and temporal evolution of volcanoes in the Mio-Pleistocene monogenetic Bakony- Balaton Highland Volcanic Field (BBHVF), located in the Pannonian Basin, Hungary. Volcanism occurred during the tectonic inversion in a back-arc setting and a compressive/transpressive tectonic regime on the hottest and thinnest lithosphere of continental Europe. The main goal of this study is to clarify the effect of the pre-existing structure of the upper lithosphere in the distribution of the volcanic centers across the volcanic field using an innovative GIS methodology. Orientation of the volcanic field was compared to the orientation of the faults in the BBHVF, and in its larger vicinity, which resulted in correspondence, suggesting the dominance of the SW-NE direction. The directions of the volcanic lineaments fit well to the two main fault directions. The fault-volcano proximity analysis suggests that the fault plane of a thrust fault was an important structural feature during the lifespan of the volcanism. All results suggest that the fault plane of a regionally significant Cretaceous thrust fault (Lit ́er Fault) might have served as a temporary pathway for the ascending magma, whereby (similarly to other, smaller faults) redirecting the magmas causing clustering of the volcanoes. This highlights the importance of major upper crustal structural heterogeneities for magma transport in a compressive tectonic system, espe- cially in the case of active, monogenetic volcanic fields from a volcanic hazard perspective. The present GIS workflow can be effective in analyzing the spatial patterns of the volcanism and its connection with crustal structures at monogenetic volcanic fields worldwide.
    Description: Published
    Description: 107940
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 29
    Publication Date: 2024-05-17
    Description: We present the first investigation of Equatorial Plasma Bubble (EPB) intensities across longitudinal sectors of the globe using observations from global navigation satellite system (GNSS) receivers. GNSS data from a total of 93 receiver stations located within ±20 degrees of the geomagnetic equator across the globe were used. The data covered periods of years 2014 and 2019 which are respectively years of high and low solar activity in solar cycle 24. We define a parameter known as the Standard deviation of Residual TEC (SRT) to characterize the EPB intensities. The EPB occurrence was defined by day-night differences of the rate of change of TEC index (ROTI). We observed a high correlation (r ∼ 0.80) between the magnitudes of the SRT and ROTI during the EPB occurrence, but the correlation is low (r ∼ 0.37) during non occurrence of EPB. The EPB intensities are greater during seasons with high occurrence rates. The EPB intensities and occurrence rates are also greater during the high solar activity. We found that the post-sunset intensities are greatest in the Atlantic region, followed by the African region, then the American, Australian, Asian, and Pacific regions in that order. The post-midnight intensities are greatest in the African region, followed by the Atlantic, American, Australian, Asian, and Pacific regions in that order.
    Description: Published
    Description: 106097
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Keywords: 01.02. Ionosphere
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 30
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    Elsevier
    In:  Ecohydrological Complexity from Catchment to Coast
    Publication Date: 2024-05-17
    Description: The Mekong River Basin: Ecohydrological Complexity from Catchment to Coast, Volume Three presents real facts, data and predictions for quantifying human-induced changes throughout the Mekong watershed, including its estuaries and coasts, and proposes solutions to decrease or mitigate the negative effect and enable sustainable development. This is the first work to link socio–ecological interaction study over the whole Mekong River basin through the lens of ecohydrology. Each chapter is written by a leading expert, with coverage on climate change, groundwater, land use, flooding drought, biodiversity and anthropological issues. Human activities are enormous in the whole watershed and are still increasing throughout the catchment, with severe negative impacts on natural resources are emerging. Among these activities, hydropower dams, especially a series of 11 dams in China, are the most critical as they generate massive changes throughout the system, including in the delta and to the livelihoods of millions of people and they threaten sustainability.
    Type: info:eu-repo/semantics/book
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  • 31
    Publication Date: 2024-05-17
    Description: Recent demands by developing countries, like India, that developed countries need to reach net-negative emissions, must be negotiated seriously under the UNFCCC. Failure to acknowledge that limiting global average temperature rise to 1.5°C leaves very little carbon budget for equitable redistribution risks further ambiguity on how to achieve the Paris Agreement’s goals.
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  • 32
    Publication Date: 2024-05-17
    Description: Highlights • Developed an innovative weighted outlier detection function that adaptively selects the best outlier detection technique, markedly improving precision and robustness in multibeam echosounder data analysis. • Demonstrated superior performance of the weighted function over traditional methods, achieving higher precision, recall, and F1 scores, pivotal for accurate seafloor mapping. • Enhanced data quality for geoscientific applications by effectively identifying and removing outliers without introducing data voids, preserving the integrity of multibeam sonar data. • The function’s significance extends to supporting sustainable environmental and resource management practices through improved accuracy in seabed mapping. • Discussed the adaptability of the method to various outlier patterns and its limitations, highlighting the need for further research and validation across different marine environments and data types. Abstract Multibeam sonar data are a valuable tool for seafloor mapping and geological studies. However, the presence of outliers in multibeam data can distort the results of analyses and reduce the accuracy of seafloor maps. In this paper, we define a weighting function based on the performance of various outlier detection techniques (OTDs) for detecting outliers in multibeam data, which calculates an outlier probability score for each sounding. Our results show that each OTD has its own strengths and weaknesses, and that a combination of outlier detection techniques is promising to improve reproducibility, explainability and the accuracy of the detection process. To address the challenge of detecting outliers in multibeam data, we propose a weighted outlier detection function that outperforms individual outlier detection techniques in terms of precision, recall and F1 scores by considering their strengths and combining them in a way that accounts for variations in the data. The function detects various types of outliers with high precision and recall values, resulting in valuable improvements in outlier detection performance for multibeam data. Overall, our proposed workflow has the potential to significantly improve the way multibeam data cleaning is performed, with the weighted outlier detection function being applied first, detecting most of the outlier automatically, followed by a domain-expert review of a small group of soundings whose automatic outlier labelling is not unequivocal.
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  • 33
    Publication Date: 2024-05-17
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 34
    Publication Date: 2024-05-16
    Description: The China Seismo-Electromagnetic Satellite (CSES) was launched successfully in February 2018. It is China's first satellite to measure geophysical fields with scientific goals in both space and solid earth physics. In this work, we used CSES scalar magnetic data to derive a global lithospheric magnetic field model between ±65° geographic latitudes. The nightside data from March 2018 to November 2022 under quiet space weather conditions were selected. Then, the core and external fields were removed with the CHAOS-7 model. After further data quality control, the data were used to build a lithospheric magnetic field model using a spherical harmonic analysis. The obtained CSES model was compared with the CHAOS-7, CM6, and MF7 models in terms of power spectra and anomaly details, which confirmed that the CSES scalar data had good quality and could provide a reliable lithospheric magnetic field model up to degree 42.
    Description: Published
    Description: 107036
    Description: OSA1: Variazioni del campo magnetico terrestre, imaging crostale e sicurezza del territorio
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 35
    Publication Date: 2024-05-16
    Description: The Caviahue-Copahue Volcanic Complex is one of the most studied active volcanic systems in the South American Andean range, and yet little research has focused on trace and rare-earth elements of waters, especially during an eruptive cycle. In this study, we sampled and investigated natural waters from 23 sites (involving the crater lake, hot springs, streams, rivers, and bubbling pools) in two campaigns in 2017 and 2018, using physi cochemical parameters, major, trace and rare-earth elements concentrations. With this novel dataset, it was possible to identify, characterize and compare three groups of waters with distinctive hydrofacies. Indeed, the normalization of water compositions against host rock concentrations showed a particular trace element pattern for each group of waters. Although the absolute concentrations of the elements in each sampling site changed from 2017 to 2018, the normalized patterns did not. Boron, As, Cd, Tl, Se, and Te, commonly recognized as volatile, are the main trace elements that magmatic gases supply to the system headwaters, whereas elements such as Ca, K, and Ba are affected by precipitation of secondary minerals (gypsum, anhydrite, barite, jarosite, and alunite). Furthermore, the main river draining the summit volcano shows a steep decrease in As, Cr, and V concentrations correlated to the precipitation of Fe and Al hydroxysulfates (schwertmannite and basaluminite, respectively). Moreover, it is the first time that a comparison between the different water groups is made using the patterns of the rare-earth elements, allowing us to identify and separate depletion patterns due to dilution processes from those due to precipitation processes.
    Description: Published
    Description: 121602
    Description: JCR Journal
    Keywords: Copahue volcano ; Hydrological system ; Geothermal ; Trace elements ; Rare earth elements
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 36
    Publication Date: 2024-05-16
    Description: In this work, we present new biostratigraphic and paleoecological data from the Mignone River valley, located in the central sector of the Tyrrhenian Sea margin and part of the wider Tarquinia basin, and cores in the area of Rome. By combining the new paleontological information with a review of the extant literature, we re-examine the stratigraphic architecture of the Pliocene succession in the central sector of the northwestern Tyrrhenian Sea margin, spanning the Zanclean (MPl1; 5.33–5.08 Ma) through the early Piacenzian (MPl4b; 3.57–3.31 Ma), and of the following Pleistocene transgressive-regressive sequence, comprising the Gelasian (MPl6; 2.59–1.81 Ma) through the Santernian (MPl1; 1.81–1.5 Ma). We propose a revision of the paleogeographic evolution of the central Tyrrhenian Sea basins throughout the Pliocene-Lower Pleistocene interval, by coherently framing it within the chronology of the volcanic phases that occurred in this region. In particular, our reconstruction points toward the presence of a single Transgressive- Regressive (T-R) sequence starting with the Zanclean reflooding of the Mediterranean after the Messinian Salinity Crisis and ending in the Piacenzian, as opposed to the previously proposed occurrence of two depositional T-R sequences separated by an erosional phase affecting part of the Globorotalia puncticulata biozone.
    Description: Published
    Description: 1-20
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: OSA4: Ambiente marino, fascia costiera ed Oceanografia operativa
    Description: JCR Journal
    Keywords: Pliocene ; Pleistocene ; Biostratigraphy ; Tyrrhenian sea margin ; Paleoenvironments ; Depositional T-R sequence
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  • 37
    Publication Date: 2024-05-16
    Description: The Latin American Giant Observatory (LAGO) is a ground-based observatory studying solar or high-energy astrophysics transient events. LAGO takes advantage of its distributed network of Water Cherenkov Detectors (WCDs) in Latin America as a tool to measure the secondary particle flux reaching the ground. These secondary particles are produced during the interaction between the modulated cosmic rays flux and the atmosphere. The LAGO WCDs are sensitive to secondary charged particles, high energy photons through pair creation and Compton scattering, and even neutrons thanks to, e.g., the deuteration of protons in the water volume. The pulse shape generated by these particles depends on several factors, such as the detector geometry, the water purity, the sensor response, or the reflectivity and diffusivity of the inner coating. Due to the decentralized nature of LAGO, these properties are different for each node. Additionally, the pulse shape depends on the convolution between the response of the central photomultiplier (PMT) to individual photons and the time distribution of the Cherenkov photons reaching the PMT. Typically, a WCD gives pulses with a sharp rise time ( 10 ns) and a longer decay time ( 70 ns). In this work, the WCD data used is acquired using the original LAGO data-acquisition system that digitizes pulses at a sampling rate of 40 MHz and 10 bits resolution on time windows of 400 ns. Here, we apply unsupervised machine learning techniques to find patterns in the WCDs data and subsequently create groups, through clustering, that can be used to provide particle separation. We use data acquired from an individual WCD, showing that density-based clustering algorithms are suitable for automatic particle separation producing good candidate groups. Improved separation would help LAGO to reconstruct in situ the properties of primary cosmic rays flux. These results open the possibility to deploy machine learning-based models in our distributed detection network for onboard data analysis as an operative prototype, allowing detectors to be installed at very remote sites.
    Description: Published
    Description: 168557
    Description: JCR Journal
    Keywords: 05.07. Space and Planetary sciences
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  • 38
  • 39
    Publication Date: 2024-05-13
    Description: We explore a parameterization for mesoscale turbulence, closely related to that of Gent and McWilliams, in which forcing terms proportional to the isopycnal flux of potential vorticity appear in the averaged momentum equations. We show that in the presence of variable bottom topography, the parameterization predicts alongslope mean flow and a corresponding upslope bolus (eddy) flux of tracer that is associated with an alongslope-directed bottom eddy stress. The upslope bolus flux is in qualitative agreement with observations of a cold dome over seamounts. The predicted alongslope flow corresponds to flow fields found in geostrophic turbulence experiments and has some similarity (although conceptually very different, as discussed in the text) to Holloway's prediction based on statistical mechanics. By considering continuous stratification as a limiting case of a multilayer model, we show how to treat the surface and bottom boundaries. Practical application of the parameterization is illustrated using a three-dimensional -coordinate ocean circulation model that is very similar to the Bryan–Cox–Semtner model. The model-computed flow is consistent with observations of anticyclonic flow around a seamount. We show that the bottom eddy stress associated with the parameterization can be large, even compared to the annual mean surface wind stress, and hence could have important implications for the biology and water mass distribution of the coastal ocean as well as for the large-scale ocean circulation. From the climate modelling perspective, the approach adopted here provides a single formalism that combines the advantages of the Gent and McWilliams parameterization with alongslope mean flow similar to that suggested by Holloway.
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  • 40
    Publication Date: 2024-05-13
    Description: Highlights • Mercury methylation in sediment rapidly transported into water and diatoms. • CH3Hg flux was highest for sediments with higher sulfide and organic content. • Mineral and compressed sediment released minor Hg and CH3Hg. • Higher sediment Hg species flux does not correlate with high sediment content. • Stable isotope incubations provide substantial insight to environmental Hg cycling. Abstract Mercury (Hg) is a conspicuous and persistent global pollutant. Ionic Hg can be methylated into noxious methylmercury (CH3Hg), which biomagnifies in marine tropic webs and poses a health risk to humans and organisms. Sediment Hg methylation rates are variable, and the output flux of created CH3Hg are dependent on sediment characteristics and environmental factors. Thus, uncertainties remain about the formation and flux of CH3Hg from sediment, and how this could contribute to the bioaccumulative burden for coastal organisms in shallow ecosystems. Cores were collected from 3 estuarine locations along the Eastern USA to examine how sediments characteristics influence the introduction of Hg and CH3Hg into the base of the food chain. Stable isotopes of inorganic 200Hg and CH3199Hg were injected into sediments of individual cores, with cultured diatoms constrained to overlying waters. Five different treatments were done on duplicate cores, spiked with: (1) no Hg isotopes (control); (2) inorganic 200Hg; (3) CH3199Hg; (4) both 200Hg and CH3199Hg isotopes, (5) both 200Hg and CH3199Hg into overlying waters (not sediment). Experimental cores were incubated for 3 days under temperature and light controlled conditions. These results demonstrate that upper sediments characteristics lead to high variability in Hg cycling. Notably, sediments which contained abundant and peaty organic material (∼28 %LOI), had the highest pore water DOC (3206 μM) and displayed bands of sulfur reducing bacteria yielded the greatest methylation rate (1.97 % day−1) and subsequent diatom uptake of CH3200Hg (cell quota 0.18 amol/cell) in the overlying water.
    Type: Article , PeerReviewed
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  • 41
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Current Opinion in Neurobiology, Elsevier, 60, pp. 55-66, ISSN: 0959-4388
    Publication Date: 2024-05-10
    Description: Animal life is rhythmic. Here we provide an overview of various rhythmic behaviors, connected environmental factors and endogenous mechanisms. We not only cover terrestrial species, but also highlight aquatic environments with typically complex interconnected rhythms. We further address diel, seasonal and potential lunar rhythms of humans. While we cannot be complete, we aim to emphasize three aspects: First, to raise awareness for the all-encompassing presence of behavioral rhythms and their importance in ecology and evolution. Second, to raise awareness how limited our mechanistic understanding is, besides analyses in a small set of model species. Finally, we discuss how anthropogenic effects can affect behavioral rhythmicity and how this might affect ecosystems in the future, as ‘For the times they are a-changin'’.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 42
    Publication Date: 2024-05-10
    Description: The Changbaishan Tianchi intraplate volcano is one of the most active and hazardous volcanoes of NE Asia, characterized by a summit caldera formed after the 946 CE ‘Millennium’ Plinian eruption. From December 2020 to June 2021, the frequency and magnitude of earthquakes at Tianchi were significantly higher than during background periods, with hundreds of earthquakes (46 events per month in average) and reaching a local magnitude of ML 3.1. This study reports a comprehensive deformation analysis and geophysical inversion scheme aimed to unveil the dynamics of this period. Multi-temporal InSAR analysis results of 32 ALOS-2 images from 2018 to 2022 show that the surface deformation is a combination of seasonal fluctuations (± 25 mm in average, with a maximum ± 45 mm) and a long-term positive component. The least squares linear regression of the deformation time series and temperature data, isolates the seasonal fluctuations, revealing a clear upliftsubsidence process from June 2020 to July 2021 in the caldera area. To constrain the Tianchi plumbing system dynamics, a combined inversion scheme consisting of three deformation sources is designed. The inversion results and the seismic records indicate that Tianchi volcano has experienced a low-level unrest episode from December 2020 to June 2021. The shallower plumbing system, located at about 5–9 km depth and modelled by pressurized spheroids, underwent a cumulative volume increase of 26 × 106 m3 from November 2018 to April 2021, followed by a volume decrease of 9 × 106 m3 from April to July 2021. This suggests magma uprising from the 14 km deep storage zone to the shallower plumbing system, followed by depressurization of the plumbing system due to the escape of fluids. This research provides a comprehensive understanding of the magma and fluid migration dynamics within the Tianchi multi-level plumbing system for the first time.
    Description: Published
    Description: 103775
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 43
    Publication Date: 2024-05-10
    Description: Seaweeds and their bioactive compounds, particularly polysaccharides and phenolics can be regarded as great dietary supplements with gut health benefits and prebiotics. These components are resistant to digestion by enzymes present in the human gastrointestinal tract, also selectively stimulate the growth of beneficial gut bacteria and the production of fermentation products such as short chain fatty acids. Commonly, the health benefits of seaweed components are assessed by including them in an in vitro anaerobic fermentation system containing human fecal inocula that mimics the environment of the human large bowel. Regarding to the complex interactions between dietary components, gastrointestinal physiological processes, and gut microbiota are difficult to model in vitro. Consequently it is important to follow up the promising in vitro results with in vivo animal or human testing. The aim of this chapter is to have a comprehensive review on the application of seaweeds and seaweed-derived metabolites as prebiotics, and understand the trends, gaps and future directions of both scientific and industrial developments. This work contributes to develop and expand new platform of seaweed utilization for higher-value products, particularly to functional food and nutraceutical industries in order to serve the social demand for health awareness and support economic development.
    Type: Book chapter , PeerReviewed
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  • 44
    Publication Date: 2024-05-09
    Description: A geochemical survey of thermal waters collected from submarine vents at Panarea Island (Aeolian Islands, southern Italy) was carried out from December 2002 to March 2007, in order to investigate i) the geochemical processes controlling the chemical composition of the hydrothermal fluids and ii) the possible relations between the chemical features of the hydrothermal reservoir and the activity of the magmatic system. Compositional data of the thermal water samples were integrated in a hydrological conceptual model, which describes the formation of the vent fluid by mixing of seawater, seawater concentrated by boiling, and a deep, highly-saline end-member, whose composition is regulated by water-rock interactions at relatively high temperature and shows clear clues of magmatic-related inputs. The chemical composition of concentrated seawater was assumed to be represented by that of the water sample having the highest Mg content. The composition of the deep end-member was instead calculated by extrapolation assuming a zero-Mg end-member. The Na–K–Ca geothermometer, when applied to the thermal end-member composition, indicated an equilibrium temperature of approximately 300 °C, a temperature in agreement with the results obtained by gas-geothermometry.
    Description: Published
    Description: 246-254
    Description: 3V. Proprietà chimico-fisiche dei magmi e dei prodotti vulcanici
    Description: JCR Journal
    Description: reserved
    Keywords: low-pH waters; shallow submarine hydrothermal springs; Panarea Island ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 45
    Publication Date: 2024-05-09
    Description: A geochemical survey of 197 fluid discharges (cold and thermal waters and bubbling pools) and 15 gas emissions from the western sector of the Sabatini Volcanic District and the Tolfa Mountains (Latium, Central Italy) was carried out in 2007–2008. The chemical and isotopic compositions of the fluid discharges indicate the occurrence of two main sources: 1) relatively shallow aquifers with Ca(Na,K)–HCO3 and Ca(Mg)–HCO3 compositions when trapped in volcanic and sedimentary formations, respectively; and 2) a deep reservoir, which is hosted in the Mesozoic carbonate sequence, rich in CO2 and having a Ca–SO4(HCO3) composition. Dissolution of a CO2-rich gas phase into the shallow aquifers produces high-TDS and high-pCO2 cold waters, while oxidation of deep-derived H2S to SO4 2− generates low-pH (b4) sulfate waters. The δ13C–CO2 values for gas emissions (from−2.8 to+2.7‰vs. VPDB) suggest that the origin of CO2 associated with the deep fluids ismainly related to thermo-metamorphic reactions within the carbonate reservoir, although significant mantle contribution may also occur. However, R/Ra values (0.37–0.62) indicate that He is mainly produced by a crustal source, with a minor component from a crust-contaminated mantle. On the basis of the δ13C–CH4 and δD–CH4 values (from −25.7 to −19.5‰ vs. VPDB and from −152 to −93.4‰ vs. VSMOW, respectively) CH4 production is associated with thermogenic processes, possibly related to abiogenic CO2 reduction within the carbonate reservoir. The δ34S–H2S values (from+9.3 to +10.4‰ vs. VCDT) are consistent with the hypothesis of a sedimentary source of sulfur from thermogenic reduction of Triassic sulfates. Geothermometric evaluations based on chemical equilibria CO2–CH4 and, separately, H2S suggest that the reservoir equilibriumtemperature is up to ~300 °C. The δDand δ18O data indicate thatwater recharging both the shallow and deep aquifers has a meteoric origin. Fluid geochemistry, coupled with gravimetric data and tectonic lineaments, supports the idea that significant contributions from a deep-seated geothermal brine are present in the Stigliano thermal fluid discharges. Exploration surveys investigated this area during 70's–90's for geothermal purposes. Nevertheless, presently the area is still under-exploited. The presence of thermal waters and anomalous heat flow together with the demographic growth of the last years,makes this site a suitable location for direct applications of the geothermal resource.
    Description: Published
    Description: 160-181
    Description: 2.4. TTC - Laboratori di geochimica dei fluidi
    Description: JCR Journal
    Description: reserved
    Keywords: Geochemistry Water Gas Stable isotope Geothermometry Central Italy ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 46
    Publication Date: 2024-05-09
    Description: The carbon isotopic composition of dissolved C-bearing species is a powerful tool to discriminate the origin of carbon in thermal waters from volcanic and hydrothermal systems. However, the δ13C values of dissolved CO2 and TDIC (Total Dissolved Inorganic Carbon) are often different with respect to the isotopic signature that characterizes the potential carbon primary sources, i.e. deep hydrothermal reservoirs, magmatic gases and organic activity. The most commonly invoked explanation for such isotopic values is related to mixing processes between deep and shallow end-members. Nevertheless, experimental and empirical investigations demonstrated that isotopic fractionation due to secondary processes acting on the uprising fluids from the hydrothermal reservoirs is able to reproduce the measured isotopic values. In this paper,we investigated the chemistry of thermalwaters, collected at Campi Flegrei and Vulcano Island (southern Italy),whose origin is related to interaction processesamongmagmatic gases, meteoric water, seawater and hosting rocks. A special focus was dedicated to the δ13C values of dissolved CO2 (δ13CCO2(aq)) and total dissolved inorganic carbon (δ13CTDIC). The δ13CCO2(aq) and δ13CTDIC values in the water samples fromboth these systems ranged from(i) those measured in fumarolic gases, likely directly related to the deep hydrothermal-magmatic reservoir, and (ii) those typically characterizing biogenic CO2, i.e. produced by microbially-driven degradation of organic matter. A simple mixingmodel of the two end-members, apparently explaining these intermediate carbon isotopic values, contrastswith the chemical composition of the dissolved gases. On the contrary, isotopic fractionation due to secondary processes, such as calcite precipitation, affecting hydrothermal fluids during their underground circulation, seems to exhaustively justify both the chemical and isotopic data. If not recognized, these processes, which frequently occur in volcanic and hydrothermal systems, may lead to an erroneous interpretation of the carbon source, causing an underestimation of the contribution of the hydrothermal/magmatic fluids to the dissolved carbon species. These results pose extreme caution in the interpretation of intermediate δ13CCO2(aq) and δ13CTDIC values for the assessment of the carbon budget of hydrothermal- volcanic systems.
    Description: Published
    Description: 46–57
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: 4V. Dinamica dei processi pre-eruttivi
    Description: JCR Journal
    Keywords: Thermal waters ; Carbon isotopes ; Dissolved CO2 ; TDIC ; Volcanic-hydrothermal systems ; Secondary fractionation processes ; 04.08. Volcanology ; 03.02. Hydrology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 47
    Publication Date: 2024-05-09
    Description: This study aims to understand the relationship between the palaeoenvironmental evolution of the southern margin of the Salpi lagoon (Tavoliere coastal plain, Apulia, Italy) and the development of settlements on its shores during the last part of the Holocene (Late Northgrippian to Late Meghalayan) to complement recent archaeological investigations at the site of pre-Roman Salpia Vetus, Roman Salapia and Medieval Salpi. Micropalaeontological, palynological, and sedimentological analyses were conducted on a total of ten drilled cores, revealing local and regional events. Facies and micropalaeontological analyses show that the lagoon was partially connected to the sea between 6.2 ka BP and 3.1 ka BP. Between 3.1 ka BP and 2.4 ka BP, the area was characterised by marshes and swamps with restricted brackish lagoon conditions and permanent freshwater input. After 2.4 ka BP, the continuous freshwater influx from the major rivers of the coastal plain determined the progradation of the floodplain and the closure of the lagoon, with the formation of the two coastal lakes of Lago Salso (north) and Lago Salpi (south). Pollen data show the expansion of halophytic herbs under local brackish conditions during the Early Meghalayan and the continuous spread of dryland herbs consistent with the closure of the basin. The alluvial plain progradation during the Late Meghalayan allowed the intensive exploitation of the area and the development of a highly anthropogenic landscape. The development of the settlements of pre-Roman Salpia Vetus, Roman Salapia, and Medieval Salpi was mainly determined by the insalubrious condition of the surrounding marshes, due to the reduction in water depth and oscillations in salinity.
    Description: Published
    Description: 37-54
    Description: 5A. Ricerche polari e paleoclima
    Description: JCR Journal
    Keywords: Holocene ; Palaeoenvironmental reconstruction ; 04.04. Geology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 48
    Publication Date: 2024-05-09
    Description: The integrated interpretation of high-resolution multibeam bathymetry, seismic profiles and backscatter data in the S. Eufemia Gulf (SEG; Calabro-Tyrrhenian continental margin, south-eastern Tyrrhenian Sea) documents the relationship between postglacial fault activity and morpho-sedimentary processes. Three systems of active normal faults that affect the seafloor or the shallow subsurface, have been identified: 1) the S. Eufemia fault system located on the continental shelf with fault planes mainly oriented N26E-N40E; 2) the offshore fault system that lies on the continental slope off Capo Suvero with fault planes mainly oriented N28E-N60E; 3) the Angitola Canyon fault system located on the seafloor adjacent to the canyon having fault planes oriented N60E- N85E. The faults produce a belt of linear escarpments with vertical displacement varying from a few decimeters to about 12 m. One of the most prominent active structures is the fault F1 with the highest fault length (about 9.5 km). Two main segments of this fault are identified: a segment characterised by seafloor deformation with metric slip affecting Holocene deposits; a segment characterised by folding of the seafloor. A combined tectono- stratigraphic model of an extensional fault propagation fold is proposed here to explain such different deformation. In addition to the seabed escarpments produced by fault deformation, in the SEG, a strong control of fault activity on recent sedimentary processes is clearly observed. For example, canyons and channels frequently change their course in response to their interaction with main tectonic structures. Moreover, the upper branch of the Angitola Canyon shows straight flanks determined by fault scarps. Tectonics also determined different sediment accumulation rates and types of sedimentation (e.g., the accumulation of hanging wall turbidite deposits and the development of contourite deposits around the Maida Ridge). Furthermore, the distribution of landslides is often connected to main fault scarps and fluids are locally confined in the hanging wall side of faults and can escape at the seabed, generating pockmarks aligned along their footwall.
    Description: Published
    Description: 108775
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: High-resolution mapping ; Active faults ; Submarine landslides ; Tectonic geomorphology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 49
    Publication Date: 2024-05-09
    Description: Tectono-stratigraphic analysis coupled with digital 3D surface modelling derived from high-resolution seismic profiles is performed along a narrow turbidite basin offshore E-Sicily in order to increase understanding on the processes that contributed to the shaping of the Western Ionian Basin. Seismic-reflector patterns of the identified Pliocene-Quaternary sequence point to syn-depositional deformation during the Pliocene associated with the simultaneous activity of regional faults and underlying ductile units. Long-wavelength sediment fanning results from the extensional activity of the Malta Escarpment faults. Conversely, internal reflector architecture and lateral terminations indicate localized subsidence associated with the growth of uprising structures in the easternmost part of the basin. Lateral shifting of basin depocenters is in line with withdrawal effects observed in basins floored by ductile units (salt or shale). 3D modelling of time-reference surfaces highlights sub-circular depressions associated with nearby structural culminations. This pattern is similar to salt-withdrawal mini- basins commonly reported in evaporite-floored basins. Accordingly, salt migration/flow triggered by sediment loading, locally enhanced by fault activity, is proposed as the process controlling basin evolution during the Pliocene in the Western Ionian Domain. Nevertheless, the possibility of shale/mud tectonics as the ductile source of deformation cannot be discounted
    Description: Published
    Description: 104932
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Syn-depositional deformation ; Ductile flow ; Turbidite basin ; Western Ionian Basin
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 50
    Publication Date: 2024-05-09
    Description: The chemical composition of volatile organic compounds (VOCs) in interstitial soil gases from hydrothermal areas is commonly shaped by both deep hydrothermal conditions (e.g., temperature, redox, sulfur fugacity) and shallow secondary processes occurring near the soil-atmosphere interface. Caldara di Manziana and Solfatara di Nepi, i.e., two hydrothermal systems characterized by diverse physicochemical conditions located in the Sabatini Volcanic District and Vicano-Cimino Volcanic District, respectively (Central Italy), were investigated to evaluate the capability of VOCs in soil gases to preserve information from the respective feeding deep fluid reservoirs. Hierarchical cluster analyses and robust principal component analyses allowed recognition of distinct groups of chemical parameters of soil gases collected from the two study areas. The compositional dissimilarities from the free-gas discharges were indeed reflected by the chemical features of soil gases collected from each site, despite the occurrence of shallow processes, e.g., air mixing and microbial degradation processes, affecting VOCs. Four distinct groups of VOCs were recognized suggesting similar sources and/or geochemical behaviors, as follows: (i) S-bearing compounds, whose abundance (in particular that of thiophenes) was strictly dependent on the sulfur fugacity in the feeding system; (ii) C4,5,7+ alkanes, n-hexane, cyclics and alkylated aromatics, related to relatively low-temperature conditions at the gas source; (iii) C2,3 alkanes, benzene, benzaldehyde and phenol, i.e., stable compounds and thermal degradation products; and (iv) aliphatic O-bearing compounds, largely influenced by shallow processes within the soil. However, they maintain a chemical speciation that preserves a signature derived from the supplying deep-fluids, with aldehydes and ketones becoming more enriched after intense interaction of the hypogenic fluids with shallow aquifers. Accordingly, the empirical results of this study suggest that the chemical composition of VOCs in soil gases from hydrothermal areas provides insights into both deep source conditions and fluid circulation dynamics, identifying VOCs as promising geochemical tracers for geothermal exploration.
    Description: Published
    Description: 169047
    Description: JCR Journal
    Keywords: Central Italy; Geochemical tracers; Hydrothermal reservoirs; Soil gases; VOCs
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 51
    Publication Date: 2024-05-08
    Description: In the last few years, several works have analyzed rainfall regime changes with the increase of temperature as a result of global warming. These changes, documented mainly in northern Europe, still need to be clarified in the Mediterranean area. Many studies have identified sometimes contradictory trends according to the type of data used, the methodology, and the daily or subdaily types of events. Therefore, an in-depth investigation of the Mediterranean area is required for the definition of more certain future scenarios. In this study, we examined a very large database including 〉1000 raingauges and thermometers in northern and central Italy to analyze the relationship between temperature and rainfall using the relation Clausius-Clapeyron. Furthermore, we analyzed the relationship between temperature and extreme precipitation events (EPEs, defined as the events higher than the 95th percentile) calculating the temperature anomalies occurred during these events. This large database covers a low rainfall accumulation period (RAP) that allowed us to study the relationship between temperature and rainfall and to distinguish rapid from long events related to rainfall intensity. The results show different relationships between rainfall and temperature in relation to seasons, RAPs, rainfall intensity, and geographical factors. The high spatial density of the database made it possible to identify spatial clusters with homogenous characteristics mainly influenced by geographical factors. With an increase in temperature, the wet season is characterized by a general increase in rainfall with a higher surge for intense and fast events. Instead, the dry season shows a general rainfall decrease for less intense and longer events, but an increase in rapid and more intensive rainfall events. This outcome has further implications involving a future decrease in water availability and an increase of the EPEs, causing an extremization of the climate during the dry season for northern and central Italy.
    Description: Published
    Description: 163368
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Current global warming; Extreme precipitation events; Italy; Mediterranean; Temperature increase
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 52
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Elsevier, ISBN: 9780128220146
    Publication Date: 2024-05-07
    Description: Marine Neurotoxins, Volume Five provides comprehensive information on marine toxins present in the human food chain and the affecting targets relevant for the functioning of the brain and our nervous system, covering all the information ...
    Repository Name: EPIC Alfred Wegener Institut
    Type: Inbook , peerRev
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  • 53
    Publication Date: 2024-05-07
    Description: Active volcanoes often discharge hot (T ≫ 100 °C) magmatic gases whose original composition has been modified through partial interaction with an externally fed hydrothermal system. The study of methane (CH4) in these volcanic discharges may provide useful information on the interplay between deep magmatic gases and shallow circulation of hydrothermal fluids. However, the origin of CH4 in high-temperature volcanic gases and the factors exerting control on its abundance and stable isotope composition are still largely unknown. Here, we present the abundances and stable isotopic composition of CH4 in hot (99–387 °C) volcanic gases from the La Fossa volcanic crater of Vulcano Island (Southern Italy). Our investigation revealed low (〈1.5 μmol/mol) CH4 concentrations and an extraordinarily large variability in CH4 stable isotopic composition, with δ13C and δ2H values being positively correlated and varying from −35 to −9.2 ‰ and −670 to −102 ‰, respectively. Notably, CH4 isotopes measured at Vulcano almost encompasses the global-scale variability observed in natural fluids, with δ2H values ≤ −500 ‰ being the first ever reported in nature. Gases showing extremely negative δ13C-CH4 and δ2H-CH4 values systematically display higher CH4 abundances. We propose two possible scenarios in order to explain the observed huge variation in δ13C and δ2H: (1) mixing of 13C- and 2H-depleted CH4 with 13C- and 2H-enriched CH4 of thermogenic origin formed under hydrothermal conditions; (2) post-genetic removal and isotopic alteration of 13C- and 2H-depleted CH4 occurring during the ascent of volcanic gases. Comparing our dataset with available isotopic data from naturally occurring and artificially produced CH4, a thermogenic origin for the isotopically light CH4 seems unlikely. We postulate that the 13C- and 2H-depleted CH4 may have formed via kinetically-controlled abiotic synthesis through CO (or CO2) hydrogenation reactions in the hot ascending gas phase, possibly at temperatures intermediate between those typical of magmatic and hydrothermal conditions. Further investigations of methane in high-temperature volcanic gases are necessary to test this hypothesis.
    Description: Published
    Description: 148-165
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 54
    Publication Date: 2024-05-07
    Description: Subduction zone volcanoes may show irregular bursts of high-frequency or high-magnitude activity. The andesitic Mt. Tongariro (New Zealand) experienced an unusual 〈200 year-long magmatic flare-up at ~11 ka that produced seven eruption episodes of a higher magnitude (M = 4–5) than seen before or since. This brief sequence produced a total of 4.5 km3 of dominantly tephra fall (Mangamate Formation) sourced by multiple vents aligned along the NNE trending axis of the tectonic Tongariro Graben. The magmatic system responsible for sporadic M = 1–2 eruptions underwent extensive change to feed the flare-up. Petrography and phase equilibria suggest that a coalesced network of magma mush zones formed along the N-S graben axis extending down to ~11 km during the episode. Recharge, mingling and mixing of formerly isolated heterogenous magmas within the plumbing system well before these eruptions is indicated by crystal zonation patterns. Mafic end members are evidenced by Fo86–89 olivine, clinopyroxene with Mg# 〉 85 and calcic plagioclase (An73–89), while evolved magma end members contained Mg# 〈 75 clinopyroxene and An56–63 plagioclase. Rim-zoning of these phases reflect timespans for equilibration of evolved and mafic crystals to a hybrid melt. The whole-rock compositions of lapilli reflect the hybrid basaltic andesite to andesite, but show diverse glass compositions (56–72 wt% SiO2) implying that magma homogenisation was incomplete before eruption. Crystal-melt equilibria of olivine and clinopyroxene rims reveal polybaric crystallisation, showing mean depths of ~8.5 km (230 ± 70 MPa) at temperatures between 1000 and 1150 °C. At the northern margins of the system, volatile-rich amphibole-bearing magmas were erupted for the first and last eruption of the series, creating stable Plinian eruption styles. This flare-up was previously interpreted as tectonically controlled, however, there were low tectonic extension rates at that time. Hence, we propose instead that magma pressure build-up and recharge beneath Mt. Tongariro drove the inflation and homogenisation of the magma system, fueling the ~200 year-long flare-up. Subsequently, the magma supply system returned to pre-Mangamate activity levels, so that vigorous recharge would be required for a return to 〉M 4 eruptions.
    Type: Article , PeerReviewed
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  • 55
    Publication Date: 2024-05-06
    Description: Here, we characterize the temporal evolution of volatiles during the Tajogaite eruption by analyzing the elemental (He-Ar-CO2-N2) and isotopic (He-Ar-Ne) composition of fluid inclusions (FI) in phenocrysts (olivine+ pyroxene) identified in erupted lavas. Our 2021 lava samples identify substantial temporal variations in volatile composition. We show that, during the 2021 Tajogaite eruption, the He-CO2-N2 concentrations in FI increased since October 15th; this increase was accompanied by increasing 40Ar/36Ar ratios (from ~300 to 〉500), and paralleled a major shift in bulk lava chemistry, with increasing Mg contents (Mg#, from 47 to 52 to 55–59), CaO/Al2O3 (from 0.65 to 0.74 to 0.75–0.90), Ni and Cr, and decreasing TiO2, P2O5 and incompatible elements. The olivine core composition also became more forsteritic (from Mg# = 80–81 to Mg# = 84–86). Mineral thermobarometry and FI barometry results indicate that the eruption was sustained by magmas previously stored in at least two magma accumulation zones, at respectively ~6–12 km and 15–30 km, corroborating previous seismic and FI evidence. We therefore propose that the compositional changes seen throughout the eruption can be explained by an increased contribution - since early/mid-October - of more primitive, less degassed magma from the deeper (mantle) reservoir. Conversely, Rc/Ra values (3He/4He ratios corrected for atmospheric contamination) remained constant throughout the whole eruption at MORB-like values (7.38 ± 0.22 Ra, 1σ), suggesting an isotopically homogeneous magma feeding source. The Tajogaite He isotope signature is within the range of values observed for the 1677 San Antonio lavas (7.37 ± 0.17Ra, 1σ), but is more radiogenic than the 3He/4He values (〉9 Rc/Ra) observed in the Caldera de Taburiente to the north. The 3He/4He ratios (6.75 ± 0.20 Ra, 1σ) measured in mantle xenoliths from the San Antonio volcano indicate a relatively radiogenic nature of the mantle beneath the Cumbre Vieja ridge. Based on these results and mixing modeling calculations, we propose that the homogeneous He isotopic signatures observed in volatiles from the Tajogaite/San Antonio lavas reflect three component mixing between a MORB-like source, a radiogenic component and small additions (6–15%) of a high 3He/4He reservoir-derived (〉9Ra) fluid components. The simultaneous occurrence of high 3He/4He (〉9Ra)- and MORB-like He signatures in northern and southern La Palma is interpreted to reflect small-scale heterogeneities in the local mantle, arising from spatially variable proportions of MORB, radiogenic, and high 3He/4He components.
    Description: Published
    Description: 107928
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: La Palma ; 2021 Tajogaite eruption ; Fluid inclusions ; Noble gas ; Magma feeding system ; Mantle source heterogeneity ; 04.08. Volcanology ; 04.01. Earth Interior
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 56
    Publication Date: 2024-05-06
    Description: Mantle volatiles are transported to Earth’s crust and surface by basaltic volcanism. During subaerial eruptions, vast amounts of carbon, sulfur and halogens can be released to the atmosphere during a short time-interval, with impacts ranging in scale from the local environment to the global climate. By contrast, passive volatile release at the surface originating from magmatic intrusions is characterized by much lower flux, yet may outsize eruptive volatile quantities over long timescales. Volcanic hydrothermal systems (VHSs) act as conduits for such volatile release from degassing intrusions and can be used to gauge the contribution of intrusive magmatism to global volatile cycles. Here, we present new compositional and isotopic (δD and δ18O-H2O, 3He/4He, δ13C-CO2, Δ33S- δ34S-H2S and SO4) data for thermal waters and fumarole gases from the Askja and Kverkfj¨oll volcanoes in central Iceland. We use the data together with magma degassing modelling and mass balance calculations to constrain the sources of volatiles in VHSs and to assess the role of intrusive magmatism to the volcanic volatile emission budgets in Iceland. The CO2/ΣS (10􀀀 30), 3He/4He (8.3–10.5 RA; 3He/4He relative to air), δ13C-CO2 (􀀀 4.1 to 􀀀 0.2 ‰) and Δ33S- δ34S-H2S (􀀀 0.031 to 0.003 ‰ and 􀀀 1.5 to +3.6‰) values in high-gas flux fumaroles (CO2 〉 10 mmol/mol) are consistent with an intrusive magmatic origin for CO2 and S at Askja and Kverkfj¨oll. We demonstrate that deep (0.5–5 kbar, equivalent to ~2–18 km crustal depth) decompression degassing of basaltic intrusions in Iceland results in CO2 and S fluxes of 330–5060 and 6–210 kt/yr, respectively, which is sufficient to account for the estimated CO2 flux of Icelandic VHSs (3365–6730 kt/yr), but not the VHS S flux (220–440 kt/yr). Secondary, crystallization-driven degassing from maturing intrusions and leaching of crustal rocks are suggested as additional sources of S. Only a minor proportion of the mantle flux of Cl is channeled via VHSs whereas the H2O flux remains poorly constrained, because magmatic signals in Icelandic VHSs are masked by a dominant shallow groundwater component of meteoric water origin. These results suggest that the bulk of the mantle CO2 and S flux to the atmosphere in Iceland is supplied by intrusive, not eruptive magmatism, and is largely vented via hydrothermal fields.
    Description: Published
    Description: 107776
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 57
    Publication Date: 2024-05-03
    Description: Although many studies have demonstrated that arc magmas are more oxidized than mid-ocean ridge (MORB) and oceanic island basalts (OIB), the oxidation state of their mantle source is still debated. This ongoing debate is mainly due to contradictory fO2 values obtained from different proxies (e.g., Fe3+/ΣFe of olivine-hosted melt inclusions and glasses; Zn/ΣFe, V/Sc, V/Ga of lavas). On the one hand, some studies using V/Sc, V/Ga and Zn/ ΣFe of lavas tend to show that the oxidation state of the mantle beneath arcs cannot be distinguished from that of the MORB mantle. On the other, Fe3+/ΣFe of glasses and olivine-hosted melt inclusions suggest that the sub-arc mantle is more oxidized than the mantle beneath ridges. Here, we estimate the oxygen fugacity of high-Mg olivine-hosted melt inclusions from various mid-ocean ridges and arcs, from one hot spot (Reunion Island) and Mount Etna using two fO2 proxies: the Fe3+/ΣFe of melts and the partition coefficient of V between olivine and melt (Dv Ol/Melt). After assessing the role of secondary processes such as volatile degassing and fractional crystallization on the fO2 of melts and reconstructing primary melt compositions, we show that (1) fO2 values derived from Fe3+/ΣFe and Dv Ol/Melt are comparable and (2) arc and Mount Etna primary melts are more oxidized than mid-ocean ridge and Reunion Island primary melts. We then demonstrate, from Zr/Nb, that the observed variability in primary melt fO2 is not due to chemical variability of the mantle source. Finally, the correlations between incompatible trace element ratios such as Th/La, Ba/La, Ba/Th and La/Yb and the fO2 of primary melts reveal a link between the oxidized nature of arc and Mount Etna primary magmas to slab fluid and/or sediment melt influence. Our arc dataset displays a variety of subduction influences, from fluid-dominated (Aoba and Mount Meager) to sediment melt-dominated (La Sommata) influences. The origin of the oxidation of Mount Etna magmas is more complicated to identify and the nature of the oxidized metasomatic fluids that likely percolated through the mantle source before magma generation is yet to be determined. 1.
    Description: Published
    Description: 121701
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 58
    Publication Date: 2024-05-03
    Description: Radon is a radioactive gas and a major source of ionizing radiation exposure for humans. Consequently, it can pose serious health threats when it accumulates in confined environments. In Europe, recent legislation has been adopted to address radon exposure in dwellings; this law establishes national reference levels and guidelines for defining Radon Priority Areas (RPAs). This study focuses on mapping the Geogenic Radon Potential (GRP) as a foundation for identifying RPAs and, consequently, assessing radon risk in indoor environments. Here, GRP is proposed as a hazard indicator, indicating the potential for radon to enter buildings from geological sources. Various approaches, including multivariate geospatial analysis and the application of artificial intelligence algorithms, have been utilised to generate continuous spatial maps of GRP based on point measurements. In this study, we employed a robust multivariate machine learning algorithm (Random Forest) to create the GRP map of the central sector of the Pusteria Valley, incorporating other variables from census tracts such as land use as a vulnerability factor, and population as an exposure factor to create the risk map. The Pusteria Valley in northern Italy was chosen as the pilot site due to its well-known geological, structural, and geochemical features. The results indicate that high Rn risk areas are associated with high GRP values, as well as residential areas and high population density. Starting with the GRP map (e.g., Rn hazard), a new geological-based definition of the RPAs is proposed as fundamental tool for mapping Collective Radon Risk Areas in line with the main objective of European regulations, which is to differentiate them from Individual Risk Areas.
    Description: Published
    Description: 169569
    Description: OSA5: Energia e georisorse
    Description: JCR Journal
    Keywords: Collective Radon Risk Areas; Geogenic Radon Potential; Machine learning; Pusteria Valley; Radon risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 59
    Publication Date: 2024-05-03
    Description: Uncertainty concerning the processes responsible for slip-rate fluctuations associated with temporal clustering of surface faulting earthquakes is a fundamental, unresolved issue in tectonics, because strain-rates accommodated by fault/shear-zone structures are the key to understanding the viscosity structure of the crust and seismic hazard. We constrain the timing and amplitude of slip-rate fluctuations that occurred on three active normal faults in central Italy over a time period of 20–30 kyrs, using in situ 36Cl cosmogenic dating of fault planes. We identify five periods of rapid slip on individual faults lasting a few millennia, separated time periods of up to 10 millennia with low or zero slip-rate. The rapid slip pulses migrated across the strike between the faults in two waves from SW to NE. We replicate this migration with a model where rapid slip induces changes in differential stress that drive changes in strain-rate on viscous shear zones that drive slip-rate variability on overlying brittle faults. Earthquakes increase the differential stress and strain-rate on underlying shear zones, which in turn accumulate strain, re-loading stress onto the overlying brittle fault. This positive feedback produces high strain-rate episodes containing several large magnitude surface faulting earthquakes (earthquake clusters), but also reduce the differential stress on the viscous portions of neighbouring fault/shear-zones slowing the occurrence of large-magnitude surface faulting earthquakes (earthquake anticlusters). Shear-zones on faults experiencing anticlusters continue to accumulate viscous strain at a lowered rate, and eventually this loads the overlying brittle fault to failure, initiating a period of rapid slip through the positive feedback process described above, and inducing lowered strain-rates onto neighbouring fault/shear-zones. We show that these patterns of differential stress change can replicate the measured earthquake clustering implied by the 36Cl data. The stress changes are related to the fault geometry in terms of distance and azimuth from the slipping structure, implying that (a) strain-rate and viscosity fluctuations for studies of continental rheology, and (b) slip-rates for seismic hazard purposes are to an extent predictable given knowledge of the fault system geometry.
    Description: Published
    Description: 105096
    Description: OST2 Deformazione e Hazard sismico e da maremoto
    Description: JCR Journal
    Keywords: Active Faults ; Central Apennines ; Fault interaction
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 60
    Publication Date: 2024-05-03
    Description: Identifying potential dust sources of Loess-Paleosol-Sequences (LPS) is important to understand past climatic and environmental conditions. For loess deposits of Central Italy different hypothesis on particle sources have been proposed, but none of them has been tested using a comprehensive geochemical approach yet. Here we present geochemical, mineralogical and grain-size data from selected deposits of a LPS situated at Ponte Crispiero (Marche, Central Italy) to obtain first insights on the provenance of particles deposited here. Loess deposits within the Ponte Crispiero succession are rather coarse (mostly coarse silt and fine sand) indicating a dominance of proximal dust sources. Applied geochemical indices suggest the alluvial plains of the Po River (Northern Italy) and its discharging area as major particle sources. According to these findings, the so-called “Great Po Plain” hypothesis, that claims the presence of a vast alluvial landscape related to the sea-level drop of the Adriatic Sea during the Pleniglacial (i.e. Marine Isotope Stage MIS 4–2), may be considered as a realistic scenario. Such a considerable alluvial plain would have the potential as major source for silt and sand particles not only for the Ponte Crispiero LPS, but also for the loess on the Adriatic side of Central Italy. The main geochemical characteristics of Ponte Crispiero loess are the low concentrations of Zr and Hf and the high contents of carbonate and transition elements compared to the Upper Continental Crust and other European loess sections. Overall, this study contributes towards a better understanding of the provenance and origin of Italian loess. However, for further testing the “Great Po Plain” hypothesis, more (geochemical) investigations need to be conducted, especially in the surrounding areas of the Po plain.
    Description: Published
    Description: 107064
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 61
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    Elsevier
    In:  EPIC3Journal of Sea Research, Elsevier, 199, pp. 102497-102497, ISSN: 1385-1101
    Publication Date: 2024-05-03
    Description: Biological monitoring of planktonic animals is greatly dependent on the deployment of traps. A variety of specialized traps have been designed for surface plankton and vertebrates. However, certain groups, such as planktonic larvae of benthic marine invertebrates remain underrepresented in sampling efforts. Catching them has proven to be more challenging because of their size, swimming ability, location, and abundance. In the present study a successful light trap for sampling American lobster larvae in New Brunswick, Canada, is evaluated on the island of Helgoland (German Bight, North Sea). Our results showed the traps were successful in catching larvae in laboratory experiments but were unable to catch European lobster larvae in the field. Traps deployed in the field were successful in capturing other benthic and pelagic zooplankton predominantly consisting of crustaceans from the orders: Cumacea, Amphipoda, Mysida and Isopoda. The low density of lobster larvae, the island's topography, and their unique photactic response possibly limited the success rate of the light traps. Future research is needed to construct a specialized trap to sample Helgoland's lobster larvae and provide information on the current larval fitness and population numbers.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 62
    Publication Date: 2024-05-03
    Description: The Wadden Sea is a transition area between land, rivers, and the North Sea. It is of great ecological importance for a wide range of fish species that use it in the course of their life cycle for various purposes. It is a highly dynamic environment and is subject to strong seasonal patterns and annual variations in abiotic conditions. The Sylt-Rømø Bight (SRB) is a semi-enclosed tidal basin in the northern Wadden Sea between the islands of Sylt (Germany) and Rømø (Denmark). Monthly monitoring data of juvenile fish taken in the SRB from 2007 to 2019 were analyzed to determine the changes in species composition in comparison to previous monitoring programs (1989–1995). The long-term trends, common patterns, and potential effects of environmental parameters (sea surface temperature (SST), salinity, chlorophyll a, and the North Atlantic Oscillation (NAO) winter indices) were determined. In total, 55 species were recorded and only 22 of these together accounted for more than 95% of the total abundance for the entire monitoring. Results showed a changed species composition as we did not find two boreal, one Lusitanian, and one circum-temperate species recorded in the previous programs. Instead, one boreal, six Lusitanian, and one Atlantic species were observed for the first time. The fish community was dominated by high seasonal fluctuations of abundance with either dome-shaped, increasing, or decreasing trends. Dynamic Factor Analysis (DFA) partitioned the fish community into three seasonal assemblages based on SST preferences. Redundancy Analysis (RDA) revealed that environmental parameters explained 29 % of the variations in the fish community. These variances were partly a result of the spring immigration of Lusitanian species and the emigration of boreal species and vice versa in autumn. The absence of four previously reported species and the addition of eight new species support the hypothesis that warm-adapted species are increasing in the Wadden Sea. The inclusion of these seasonal variations into conservation and management practices is critical to the sustainable management of marine and coastal ecosystems covering spawning, nursery, and feeding grounds.
    Repository Name: EPIC Alfred Wegener Institut
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  • 63
    Publication Date: 2024-05-03
    Description: Rapid changes of the biosphere observed in recent years are caused by both small and large scale drivers, like shifts in temperature, transformations in land-use, or changes in the energy budget of systems. While the latter processes are easily quantifiable, documentation of the loss of biodiversity and community structure is more difficult. Changes in organismal abundance and diversity are barely documented. Censuses of species are usually fragmentary and inferred by often spatially, temporally and ecologically unsatisfactory simple species lists for individual study sites. Thus, detrimental global processes and their drivers often remain unrevealed. A major impediment to monitoring species diversity is the lack of human taxonomic expertise that is implicitly required for large-scale and fine-grained assessments. Another is the large amount of personnel and associated costs needed to cover large scales, or the inaccessibility of remote but nonetheless affected areas. To overcome these limitations we propose a network of Automated Multisensor stations for Monitoring of species Diversity (AMMODs) to pave the way for a new generation of biodiversity assessment centers. This network combines cutting-edge technologies with biodiversity informatics and expert systems that conserve expert knowledge. Each AMMOD station combines autonomous samplers for insects, pollen and spores, audio recorders for vocalizing animals, sensors for volatile organic compounds emitted by plants (pVOCs) and camera traps for mammals and small invertebrates. AMMODs are largely self-containing and have the ability to pre-process data (e.g. for noise filtering) prior to transmission to receiver stations for storage, integration and analyses. Installation on sites that are difficult to access require a sophisticated and challenging system design with optimum balance between power requirements, bandwidth for data transmission, required service, and operation under all environmental conditions for years. An important prerequisite for automated species identification are databases of DNA barcodes, animal sounds, for pVOCs, and images used as training data for automated species identification. AMMOD stations thus become a key component to advance the field of biodiversity monitoring for research and policy by delivering biodiversity data at an unprecedented spatial and temporal resolution.
    Repository Name: EPIC Alfred Wegener Institut
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  • 64
    Publication Date: 2024-05-03
    Description: Highlights: • Mnemiopsis leidyi is capable of catching and digesting herring yolk-sac larvae. • Predation on herring larvae is decreasing with prey age and increasing with predator size. • Predation of M. leidyi on herring larvae is not affected by the presence of alternative natural prey represented by the copepod Acartia tonsa. • Substantial predation of M. leidyi on yolk-sac herring larvae may occur in the field, when both overlap spatially and temporarily. Western Baltic spring spawning herring (Clupea harengus, L.) is a commercially important fish stock currently suffering a strong decline. Larval survival is essential for stock recruitment and can be substantially decreased by predation. The comb jelly Mnemiopsis leidyi A. Agassiz, 1865, is a lobate ctenophore which is invasive to the Baltic Sea and a known ichthyoplankton predator. However, predation on herring larvae in the Baltic Sea by M. leidyi has not been studied since its initial establishment in 2006. To address this knowledge gap, we conducted feeding experiments to investigate (1) the predation capability of M. leidyi on herring yolk-sac larvae, and (2) the influence of larval age, (3) predator size and (4) the presence of alternative prey on the clearance rate of M. leidyi on herring yolk-sac larvae. Our results showed that M. leidyi exhibited the ability to capture and digest herring larvae. The clearance rates of M. leidyi on herring larvae decreased with larval age and increased with predator size, while the presence of alternative prey had no effect on clearance rates. This finding suggests that M. leidyi can efficiently consume herring yolk-sac larvae under laboratory conditions. However, further investigations using mesocosm or field studies are necessary to evaluate the potential impact of M. leidyi on the mortality and recruitment of herring yolk-sac larvae under Baltic Sea field conditions.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 65
    Publication Date: 2024-05-02
    Description: The recent ability to investigate the features of magnetic field fluctuations at ion/sub-ion scales employing both measurements and simulations has clearly demonstrated how, at these scales, the current has a filamentary structure, i.e., it is not a compact structure. This points toward the idea that the current and the dissipation field may have a fractal structure. An intriguing question immediately arises: is there a relationship between the fractal topology of currents at ion/sub-ion scales and the observed spectral features at the same scales? The goal of this work is to investigate the fractal topology of currents at the Low-end of MHD inertial domain and at ion scales using Hall-MagnetoHydroDynamics and Hybrid Vlasov-Maxwell simulations. The results show a clear relationship between the fractal dimension of the current pattern and the spectral features at ion scales. The relevance of this link is discussed in connection with the dynamics of coherent plasma structures at these scales.
    Description: Published
    Description: 114253
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 66
    Publication Date: 2024-05-02
    Description: Topography plays an important yet uncertain role in modulating the temporal and spatial evolution of the in- ternal structure of pyroclastic density currents (PDCs). Understanding such changes is critical to characterize PDC transport regimes and their hazard. Here we combine paleomagnetic data from PDC deposits of the 18 May 1980 Mt. St. Helens eruption with numerical outcomes to capture spatio-temporal temperature variations induced by topography. We show that emplacement temperatures along the northwest flank of the volcano are ≃ 100◦C colder than those recorded along the northeast flank in response to proximal topographic drops. We further report that such vertical drops lead to an initial transient regime where the PDC internal temperature, velocity, and concentration stratification is altered for periods of time that are proportional to the ratio between the drop height and the square root of the current thickness. The topographic control on PDC dynamics is attenuated moving away from the drops or when a stationary phase is attained. Collectively, our results highlight that topographic regions promoting the flow separation/reattachment process are associated with vigorous entrainment of ambient air in the lower portion of PDCs. Low temperature variability is observed in the absence of such topographic irregularities. Based on our findings, we propose a local sedimentation rate of ≃ 150 ± 100 mm s−1 for PDC deposits in a proximal reattachment region. This investigation demonstrates the importance of transient processes in PDC dynamics, introducing a new methodology to measure sedimentation rates, and highlighting that flow-topography feedbacks should be considered to assess hazards.
    Description: Published
    Description: 118441
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 67
    Publication Date: 2024-05-02
    Description: In this work we describe the implementation of a processing chain for a fully automatic modeling of the seismic source parameters and its slip distribution through the inversion of the InSAR displacements generated from the EPOSAR service. This processing chain consists of a suite of procedures and algorithms handling a sequence of steps: selection of the highest quality InSAR datasets, definition of the area of interest, image sampling, nonlinear and linear inversions to get, respectively, the source geometry and its slip distribution. A set of side procedures and interfaces also allows an interactive refinement and the publication of results, consisting of scientific data and graphical outputs. The whole procedure has been developed, tested and validated by considering 100 events with magnitudes between 5.5 and 8.2, worldwide distributed and covering an exhaustive range of mechanisms and tectonic contexts. Main aim of this work is describing the implementation of the automatic modeling procedures, used to produce solutions in real time, already during the emergency phase. These sources, validated by experts before their publication, can be a reference for operational purposes and initial scientific analyses. The creation of this repository sets also the framework to store, out of the emergency time, more sophisticated solutions, manually revised and/or with peer-review quality.
    Description: Published
    Description: 103445
    Description: OST3 Vicino alla faglia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 68
    Publication Date: 2024-05-02
    Description: The plumbing systems of subduction-zone volcanoes consist of magma reservoirs with different degrees of evolution at multiple depths. The geometries of plumbing system of intraplate monogenetic volcanic fields are generally characterized by basaltic magma ascending from the mantle and/or a shallower reservoir along dikes. However, the shape and vertical extent of these plumbing systems are largely unknown due to the rareness of robust geophysical data. The possible role of faults and mountain chains in controlling the geometry of magma reservoirs is also poorly understood. To address these limitations, we present a three-dimensional resistivity structure beneath the Holocene Jingpohu Monogenetic Volcanic Field (JMVF) in the Zhangguangcai Range (ZGC), northeastern China. The resistivity model was derived from the magnetotelluric data in a dense net-like array. We identified an inverted cone-shaped high-resistivity (~10,000 Ω m) anomaly below the ZGC. This anomaly traverses almost the entire crust. We interpret this high-resistivity anomaly to be the stiff basement of the ZGC. At the base of the resistive volume, we resolved a sill-like, low-resistivity anomaly that occurs at the top of the lithospheric mantle. Sheet-like low-resistivity anomalies surrounding the high-resistivity body depart from the lithospheric mantle. We interpret these sill- and sheet-like anomalies as a trans-crustal saucer-shaped magma plumbing system beneath the JMVF. This system involves multi-level magma reservoirs, including basaltic magma at its base, basaltic dikes/sills swarms in the middle and sill intrusions in the upper crust. We propose that the stiff crustal root and the topographic loading of the ZGC work together to deflect the upward magma propagation towards the edges of the ZGC. The magma ascent to the surface is probably controlled by preexisting, lithospheric faults. Our data show how mountain chains, together with the crustal structure, play a key role in controlling the geometry of multi-level plumbing systems of intraplate monogenetic volcanic fields.
    Description: Published
    Description: 118523
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 69
    Publication Date: 2024-05-02
    Description: Between Permian to Triassic, the Earth experienced climatic and biotic crises, included the greatest mass extinction at the Permian-Triassic boundary. These climatic and biological changes are reflected in both marine and terrestrial depositional systems. Over this time span, the Gondwana supercontinent hosted numerous large basins that may preserve the paleoenvironment response to global changes in the sedimentary record. This study provides a lithostratigraphic reappraisal of the latest Paleozoic-Mesozoic alluvial Beacon Supergroup at Allan Hills (Convoy Range), which is one of the most complete sedimentary sequences in Antarctica. Fieldwork stratigraphic-lithological observation, facies analysis, and petrographic characterization of sedimentary rocks allow the identification of six depositional units. The investigations point out for a conformable relationship between depositional and lithostratigraphic units, characterized by changes in the fluvial style. The reconnaissance of a “transitional interval” showing intermediate features between the Permian Weller Coal Measures and the Triassic Feather Conglomerate strengthen the conformable nature of the sequence across the Permian-Triassic boundary in this region. The lithological features of such interval strongly resemble those observed in the coeval deeply studied Eastern Australia successions crossing the Permian-Triassic boundary as well as the end-Permian extinction. More precisely, the uppermost coal occurrence, just above a glossopterid macroflora-bearing carbonaceous mudstone within the “transitional interval”, marks the disappearance of coal-peat forming Permian vegetation which corresponds with the terrestrial end-Permian extinction, thus representing one of the few end- Permian extinction records in Antarctica.
    Description: Published
    Description: 111741
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Gondwana ; Southern Victoria ; Land Stratigraphy ; Permian-Triassic boundary ; Beacon ; Supergroup ; Allan Hills
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 70
    Publication Date: 2024-05-02
    Description: Thanks to the computational power of modern cluster machines, numerical simulations can provide, with an unprecedented level of details, new insights into fluid mechanics. However, taking full advantage of this hardware remains challenging since data communication remains a significant bottleneck to reaching peak performances. Reducing floating point precision is a simple and effective way to reduce data movement and improve the computational speed of most applications. Nevertheless, special care needs to be taken to ensure the quality and convergence of computed solutions, especially when dealing with complex fluid simulations. In this work, we analyse the impact of reduced (single and mixed compared to double) precision on computational performance and accuracy for computational fluid dynamics. Using the open source library OpenFOAM, we consider incompressible, compressible, and multiphase fluid solvers for testing on relevant benchmarks for flows in the laminar and turbulent regime and in the presence of shock waves. Computational gain and changes in the scalability of applications in reduced precision are also discussed. In particular, an ad hoc theoretical model for the strong scaling allows us to interpret and understand the observed behaviours, as a function of floating point precision and hardware specifics. Finally, we show how reduced precision can significantly speed up a hybrid CPU–GPU implementation, made available to OpenFOAM end-users recently, that simply relies on a GPU linear algebra solver developed by hardware vendors.
    Description: Published
    Description: 1-16
    Description: OSV1: Verso la previsione dei fenomeni vulcanici pericolosi
    Description: JCR Journal
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  • 71
    Publication Date: 2024-05-02
    Description: In the Apennine Mountains of the Italian Peninsula, GPS data display 3–4 mm/yr of divergent motion oriented N50°E between the Adriatic and Tyrrhenian coastlines. However, the mechanisms driving this extension remain debated and along-strike variations of extension within the actively deforming belt remain poorly constrained. Here, we derived the first large-scale extensional and vertical velocity field for the Apennines by multi-temporal InSAR analysis of 7 years of Sentinel-1 data at the scale of the entire range, improving the spatial resolution and vertical accuracy of existing GPS measurements. The results reveal along-strike variations of extensional rates and gradients, with extension concentrated on single fault systems in the north, consistent with the loci of seismicity and recent moderate earthquakes, and distributed throughout the central Apennines, where the range is widening. Vertical surface displacements do not resolve any active long-wavelength uplift of the orogenic belt and, on average, show more subsidence than uplift relative to the Tyrrhenian and Adriatic coasts. This work provides the first InSAR-based geodetic map of differential extension and uplift within the Italian Peninsula. Our results are compatible with a pure shear extensional model of the crust, driven by both boundary and gravitational forces.
    Description: Published
    Description: 230076
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Keywords: 04.07. Tectonophysics
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 72
    Publication Date: 2024-05-02
    Description: We analyze frictional motion for a laboratory fault as it passes through the stability transition from stable sliding to unstable motion. We study frictional stick-slip events, which are the lab equivalent of earthquakes, via dynamical system tools in order to retrieve information on the underlying dynamics and to assess whether there are dynamical changes associated with the transition from stable to unstable motion. We find that the lab seismic cycles characteristics of a low-dimensional system with average dimension similar to that of natural slow earthquakes ($〈$5). We also investigate local properties of the attractor and find maximum instantaneous dimension $\gtrsim$10, indicating that some regions of the phase space require a high number of degrees of freedom (dofs). Our analysis does not preclude deterministic chaos, but the lab seismic cycle is best explained by a random attractor based on rate- and state-dependent friction whose dynamics is stochastically perturbed. We find that minimal variations of 0.05\% of the shear and normal stresses applied to the experimental fault influence the large-scale dynamics and the recurrence time of labquakes. While complicated motion including period doubling is observed near the stability transition, even in the fully unstable regime we do not observe truly periodic behavior. Friction's nonlinear nature amplifies small scale perturbations, reducing the predictability of the otherwise periodic macroscopic dynamics. As applied to tectonic faults, our results imply that even small stress field fluctuations ($\lesssim$150 kPa) can induce coefficient of variations in earthquake repeat time of a few percent. Moreover, these perturbations can drive an otherwise fast-slipping fault, close to the critical stability condition, into a mixed behavior involving slow and fast ruptures.
    Description: Published
    Description: 117995
    Description: OST4 Descrizione in tempo reale del terremoto, del maremoto, loro predicibilità e impatto
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 73
    Publication Date: 2024-05-02
    Description: Highlights • Development of an autonomous DIC analyzer based on Conductometric technique using a cell with 4 hollow brass electrodes. • CO2 extraction from seawater using a gas diffusion cell with a “Tube In A Tube” configuration and a gas permeable membrane. • Formulation of mathematical temperature and salinity correction to determine accurate DIC concentration. • Demonstration of the analyzer performance in the southwest Baltic Sea. Abstract Background The increase in anthropogenic CO2 concentrations in the Earth's atmosphere since the industrial revolution has resulted in an increased uptake of CO2 by the oceans, leading to ocean acidification. Dissolved Inorganic Carbon (DIC) is one of the key variables to characterize the seawater carbonate system. High quality DIC observations at a high spatial-temporal resolution is required to improve our understanding of the marine carbonate system. To meet the requirements, autonomous DIC analyzers are needed which offer a high sampling frequency, are cost-effective and have a low reagent and power consumption. Results We present the development and validation of a novel analyzer for autonomous measurements of DIC in seawater using conductometric detection. The analyzer employs a gas diffusion sequential injection approach in a “Tube In A Tube” configuration that facilitates diffusion of gaseous CO2 from an acidified sample through a gas permeable membrane into a stream of an alkaline solution. The change in conductivity in the alkaline medium is proportional to the DIC concentration of the sample and is measured using a detection cell constructed of 4 hollow brass electrodes. Physical and chemical optimizations of the analyzer yielded a sampling frequency of 4 samples h−1 using sub mL reagent volumes for each measurement. Temperature and salinity effects on DIC measurements were mathematically corrected to increase accuracy. Analytical precision of ±4.9 μmol kg−1 and ±9.7 μmol kg−1 were achieved from measurements of a DIC reference material in the laboratory and during a field deployment in the southwest Baltic Sea, respectively. Significance This study describes a simple, cost-effective, autonomous, on-site benchtop DIC analyzer capable of measuring DIC in seawater at a high temporal resolution as a step towards an underwater DIC sensor. The analyzer is able to measure a wide range of DIC concentrations in both fresh and marine waters. The achieved accuracy and precision offer an excellent opportunity to employ the analyzer for ocean acidification studies and CO2 leakage detection in the context of Carbon Capture and Storage operations.
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  • 74
    Publication Date: 2024-04-30
    Description: The Iterative Filtering method is a technique aimed at the decomposition of non-stationary and non-linear signals into simple oscillatory components. This method, proposed a decade ago as an alternative technique to the Empirical Mode Decomposition, has been used extensively in many applied fields of research and studied, from a mathematical point of view, in several papers published in the last few years. However, even if its convergence and stability are now established both in the continuous and discrete setting, it is still an open problem to understand up to what extent this approach can separate two close-by frequencies contained in a signal. In this paper, first we recall previously discovered theoretical results about Iterative Filtering. Afterward, we prove a few new theorems regarding the ability of this method in separating two nearby frequencies both in the case of continuously and discrete sampled signals. Among them, we prove a theorem which allows to construct filters which captures, up to machine precision, a specific frequency. We run numerical tests to confirm our findings and to compare the performance of Iterative Filtering with the one of Empirical Mode Decomposition and Synchrosqueezing methods. All the results presented confirm the ability of the technique under investigation in addressing the fundamental “one or two frequencies” question.
    Description: Published
    Description: 128322
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 75
    Publication Date: 2024-04-30
    Description: The study of the micro-meteoroid environment is relevant to planetary science and space weathering of airless bodies, as the Moon or Mercury. In fact, the meteoroids hit directly the surfaces producing impact debris and vapor, thus contributing to shape the exosphere of the planet. This work is focused on the study and modelling of the Mercury's Ca exosphere formation through the process of Micro-Meteoroids Impact Vaporization (MMIV). The MESSENGER/NASA mission provided measurements of Mercury's Ca exosphere, allowing the study of its configuration and its seasonal variations. The observed Ca exhibited very high energies, with a scale height consistent with a temperature 〉 50,000 K, originated mainly on the dawn-side of the planet. It was suggested that the originating process is due to MMIV, but previous estimations were not able to justify the observed intensity and energy. We investigate the possible pathways to produce the high energy observed in the Ca exosphere and discuss about the generating mechanism. The most likely origin may be a combination of different processes involving the release of atomic and molecular surface particles. We use the exospheric Monte Carlo model by Mura et al. (2007) to simulate the 3-D spatial distribution of the Ca-bearing molecule and atomic Ca exospheres generated through the MMIV process, and we show that their morphology and intensity are consistent with the available MESSENGER observations if we consider a cloud quenching temperature 〈 3750 K. The results presented in this paper can be useful in the exospheric studies and in the interpretation of active surface release processes, as well as in the exosphere observations planning for the ESA-JAXA BepiColombo mission that will start its nominal mission phase in 2026.
    Description: Published
    Description: 115616
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 76
    Publication Date: 2024-04-30
    Description: We investigate the seismic structure of the mantle wedge of the Apennines subduction zone (Central Mediterranean) using teleseismic receiver function (RF). We inverted RF for both isotropic and anisotropic properties of the mantle wedge, from below the overriding Moho to the “plate boundary”, i.e. the interface that separate the slab from the mantle wedge. Given the distribution of the seismic network, we are able to map out the change in the elastic properties at the transition between southern apennines and the Calabrian arc, given by the change in the subduction style (i.e from the subduction of continental materials to oceanic plate). We found that the anisotropy in the mantle wedge is similar between all seismic stations, generally highly anisotropic (〉 10%), with a direction of the symmetry axis that rotates clockwise from North to South, following the Calabrian arc geometry and likely indicating the mantle flow driven by the slab retreat. The elastic properties of the subducted crust are more heterogeneous. To the North, the subducted crust shows a highly anisotropic (〉 10%) behavior, and it occurs at larger depth (around 70 km depth), where to the South anisotropy is less intense (around 7%) and the subducted crust is shallower (around 60 km depth). These results point out a change in the subduction style that can be given by either a change in the metamorphic phase (more evolved blueschist facies stage to the North, initial greenschist facies stage to the South) or a different origin for the subducted materials (continental to the North and oceanic to the South). The differences in the anisotropic behavior of the subducted crust are reflected in the topography of the plate boundary, which becomes shallower from North to South, suggesting the existence of either a step in the slab topography or a more gentle ramp.
    Description: Published
    Description: 102004
    Description: OST1 Alla ricerca dei Motori Geodinamici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 77
    Publication Date: 2024-04-30
    Description: The implications of the COVID-19 outbreak are subjected to an increasing number of studies. So far, air quality trends related to the lockdown due to the pandemic have been analysed in large cities or entire regions. In this work, the region studied is the metropolitan area of Cagliari, which is the main city on the island of Sardinia (Italy) and can be representative of a coastal city that includes industrial settlements. The purpose of the study is to evaluate the effect of restrictions related to the COVID-19 outbreak on air quality levels and the traffic dynamics in this type of urban area. Nitrogen Dioxide (NO₂) levels before, during and after COVID-19 lockdown have been investigated using data acquired from the Sentinel-5P/TROPOMI satellite combined with on-site measurements. Both TROPOMI detected and ground-based data have revealed higher levels of NO₂ before and after the lockdown, compared to those during the period of COVID-related restrictions, in particular in the urban area of Cagliari. On the other hand, NO2 registered in the oil refinery area did not show significant differences associated with lockdown. The correlation of TROPOMI NO₂ tropospheric column with ground data (surface NO2) on a monthly mean basis showed different values based on the background and the highest Pearson's coefficient was of about 0.78 near to the city centre, where traffic can be considered a significant source of emission. In addition, a comparison of the air pollution level with the dynamics of vehicle traffic was investigated. The study highlighted a remarkable correlation between the reduction of the number of vehicles and the corresponding tropospheric NO₂ values that decreased on a weekly mean basis.
    Description: Published
    Description: 165464
    Description: OSA2: Evoluzione climatica: effetti e loro mitigazione
    Description: JCR Journal
    Keywords: Atmospheric pollution; Nitrogen dioxide (NO₂); Pandemic; Sentinel-5P; TROPOspheric monitoring instrument (TROPOMI); Transportation
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  • 78
    Publication Date: 2024-04-30
    Description: Highlights • The Okorusu complex in NE Etendeka have Gough-type isotopic composition. • Messum igneous complex in SW Etendeka show a Doros/Tafelkop-type composition. • Both Gough- and Doros-type components derived from the Tristan-Gough plume. • Doros-type volcanism is surrounded by Gough-type volcanism. • The head-stage of Tristan-Gough plume coincide with the concentric zonation model. Abstract The Etendeka large igneous province in central Namibia is believed to be caused by widespread melting of the Tristan/Gough mantle plume head between ∼137 and 123 Ma ago. To explain the observed compositional variations of the Etendeka flood basalts, a laterally-zoned plume head has been proposed. Here we present new (major and trace element and Sr-Nd-Pb-O-C isotope) geochemical data from the Okorusu and Messum carbonatitic and silica-undersaturated rocks. Okorusu carbonatites, located at the far eastern end of the Etendeka province, have a Gough-type enriched mantle one (EM1) composition, consistent with derivation from a common source with the northern Etendeka flood basalts, Walvis Ridge and Gough (southern) hotspot subtrack of the southern Atlantic Guyot Province including Gough Island. The Messum basanite, erupted directly after the Etendeka event near the central coast of western Namibia, has a different EM1 type flavor (with more radiogenic Nd, less radiogenic Sr and thorogenic Pb isotopes), similar to the Doros, Tafelkop and Horingbaai formations of the Etendeka flood basalts. Combining our new findings with published data from flood basalts, carbonatites and silica-undersaturated rocks from the region, we propose a concentric zonation model for the postulated plume head with the isotopically Gough-type EM1 plume mantle enclosing a blob of Doros-type EM1 plume mantle.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 79
    Publication Date: 2024-04-29
    Description: While the influence of precession on monsoon at low latitudes through insolation forcing is well-known, the role of obliquity is still debated since its influence on the distribution of incoming solar radiation is small in these regions. In southern Africa, long marine and terrestrial sedimentary records attest of a precessional influence on the South African monsoon at orbital time scale. The obliquity signal is occasionally observed in the geological records although modeling results suggest an influence of precession and obliquity on summer monsoon. Here, we present a record of microscopic charcoal from core MD96-2098 located off Namibia covering the past 184,000 years. Our record of fire activity reveals cyclic changes at frequencies of 23, 58 and 12 kyr−1 and lacks the obliquity signal at 41 kyr−1. Changes in fire over southern Africa are interpreted as shifts in large and intense fires spreading in open-grassland savanna as a result of orbitally-driven changes in rainfall intensity associated with the South African monsoon. We show that, despite the absence of a 41 kyr obliquity imprint, the presence of 23, 58 and 12 kyr−1 frequencies likely stems from a nonlinear response of fire to precipitation controlled by a combination of precession and obliquity frequencies, supporting the influence of obliquity on the South African monsoon.
    Repository Name: EPIC Alfred Wegener Institut
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  • 80
    Publication Date: 2024-04-23
    Description: Preface of a special issue.
    Description: Published
    Description: 3365-3366
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 81
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Palaeogeography Palaeoclimatology Palaeoecology, Elsevier, 632, pp. 111863-111863, ISSN: 0031-0182
    Publication Date: 2024-04-22
    Description: Winter climate variations in midlatitude regions have far-reaching effects on both natural and human systems worldwide. However, most climate reconstructions focus on either annual or summer climate conditions. Here we present a stalagmite stable isotope record from Urşilor Cave (Romania) where the δ18O values are controlled by winter temperature. Because of its East-Central Europe (ECE) location, the cave site is well suited to capture variations in precipitation and temperature in response to changes in the North Atlantic region. Present day precipitation and temperature in this region are controlled by two teleconnection patterns, the Arctic Oscillation (AO) and the East Atlantic (EA). By analyzing composite maps for four different scenarios of AO and EA phase, we suggest that between 5.6 and 5.2 ka the positive phases of AO and EA became increasingly dominant. This shift led to generally warmer winters in northern Europe, but drier conditions in southern Europe and the Levant. Considering the compound effect of AO and EA on the hydroclimate of ECE, our study highlights the importance of examining the combined impact of teleconnection patterns on climate proxies influenced by various forcing mechanisms.
    Repository Name: EPIC Alfred Wegener Institut
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  • 82
    facet.materialart.
    Unknown
    Elsevier
    In:  EPIC3Agricultural and Forest Meteorology, Elsevier, 339, pp. 109543-109543, ISSN: 0168-1923
    Publication Date: 2024-04-22
    Description: Tundra is primarily a habitat for shrub growth, not trees, but growth of prostrate forms of trees has been reported occasionally from the subarctic tundra region. In the light of on-going climate change, climate sensitivity studies of these unique trees are essential to predict vegetation dynamics and potential northward expansion of boreal forest tree species into tundra. Here we studied one of the northernmost Larix Mill. trees and Betula nana L. shrubs (72°N) from the Siberian tundra for the common period 1980-2017. We took advantage of the discovery of a single cohort of prostrate Larix trees within a tundra ecosystem, i.e., ca. 60 km northwards from the northern treeline, and compared climate-growth relationships of the two species. Both woody plants were sensitive to the July temperature, however this relationship was stable across the entire study period (1980-2017) only for Betula nana chronology. Additionally, radial growth of Larix trees became negatively correlated to temperatures during the previous summer. In recent period moisture sensitivity between Larix trees and Betula nana shrubs was contrasting, with generally wetter soil conditions favoring Larix trees growth and dryer conditions promoting Betula nana growth. Our study indicates that Larix trees radial growth in recent years is more sensitive to moisture than to summer air temperatures, whereas temperature sensitivity of Betula nana shrub is stable over time. We provide first detailed insight into the annual resolution on Larix tree growth sensitivity to climate in the heart of the tundra. The potentially higher Betula nana shrub resistance to warmer and drier climate versus Larix trees on a tundra revealed in our study needs to be further examined across habitats of various soil, moisture and permafrost status.
    Repository Name: EPIC Alfred Wegener Institut
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  • 83
    Publication Date: 2024-04-22
    Description: Paleoclimate reconstructions are increasingly used to characterize climate variability and change prior to the instrumental record, in order to improve our estimates of climate extremes and to provide a baseline for climate change projections. Most of these reconstructions are focused on temperature, precipitation, and/or drought indices and, to a lesser extent, reconstruct streamflow variability. In this study, the first regional tree-ring width chronology (i.e. Quercus sp.), from the Caraorman forest (Danube Delta, Romania), was used to reconstruct the last ∼250 years of annual (from November previous year to July of the current year) streamflow of the Lower Danube River. The obtained results indicate a stable and significant correlation between the tree-ring width index from the Caraorman forest and the Danube streamflow at the Ceatal Izmail hydrologic station situated in the southeastern part of Europe. Interannual streamflow variation for the analyzed period indicates 14 extremely high flow years, with streamflow greater than 8780 m3/s (1770, 1771, 1799, 1836, 1838, 1839, 1871, 1876, 1877, 1879, 1940, 1941, 1997 and 2010) and 14 extremely low flow years, with streamflow lower than 5300 m3/s (1741, 1745, 1750, 1753, 1773, 1794, 1812, 1832, 1843, 1882, 1899, 1921, 1964 and 1994). Periods characterized by pluvials in the lower Danube Delta are associated with a low-pressure system centered over Europe, positive sea surface temperature (SST) anomalies over the Atlantic Ocean, and negative SST anomalies over the Baltic, North, and Mediterranean Seas. These large-scale conditions favor the advection of moist air from the Mediterranean and the Black Sea towards the southeastern part of Romania, which in turn leads to high precipitation rates over this region. Opposite to this, low streamflow years are associated with a high-pressure system centered over Europe, characterized by a northward shift of the storm tracks and negative SST anomalies over the Atlantic Ocean, and positive SST anomalies over the Baltic, North, and Mediterranean Seas. Based on our results, we argue that the reconstruction of river streamflow data based on the tree-ring width has important scientific and practical implications for a better understanding of the streamflow variation of the past, necessary for water resource management and environmental-hydrological protection.
    Repository Name: EPIC Alfred Wegener Institut
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  • 84
    Publication Date: 2024-04-22
    Description: Amongst other factors, topographic features can influence the genetic variability among populations of marine organisms. This applies to host species but also to their parasites, which are poorly studied regarding this aspect, as well as with regard to their use as bioindicators. In the present work, the ribosomal DNA (28S rDNA) was used to assess genetic diversity of Grillotia (Cestoda, Trypanorhyncha) larvae in one of its paratenic hosts, namely Etmopterus spinax, across five different regions (off Scotland, Celtic, Alboran and Balearic Seas and off Cyprus) belonging to three major geographic areas (Northeast Atlantic, western and eastern Mediterranean). The obtained sequences revealed a total of 18 polymorphic sites and 17 haplotypes, as well as significant values of variance throughout the five different regions. Reconstructed phylogenetic trees highlighted that all Grillotia sp. sequences formed a monophyletic group, but divergent lineages split into different main clades which were in relation to the area of origin, with a consistent cluster of sequences from the Atlantic Ocean, as well as another from the Eastern Mediterranean. In contrast, low genetic differentiation was observed between samples from Balearic and Alboran Seas, and with respect to Grillotia sp. larvae from the Gulf of Naples analysed in a previous study. Geographical differences in parasite infection descriptors (prevalence, abundance, and intensity) were assessed, revealing significant differences among the sampled regions. The present study indicates that geographical distance and submarine barriers affect not only the connectivity of hosts but also their parasite infrapopulations by limiting interpopulation dispersal. It underlines the usefulness of parasites as biological tags for the study of susceptible and data-poor host species such as deep-water sharks and its potential implications for host population management and protection measures.
    Repository Name: EPIC Alfred Wegener Institut
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  • 85
    Publication Date: 2024-04-22
    Description: The enhanced inertia load caused by biofouling on device components, such as the foundations of wind turbines or other structures at sea, modifies the hydrodynamic properties, and increases the stress to structures, predominantly in upper water layers with high impact from wave dynamics. This compromises the stability, functioning, operation as well as the durability of these devices especially in exposed environments. A main challenge is the quantification of the impact of hydrodynamic forces on irregular bodies being overgrown by soft- and hard-bodied biofouling organisms. Therefore, test bodies from the upper 1–5 m water depth and thus exposed to the strongest wave actions close to the surface shall be overgrown by biofouling and used in measurement trials in a wave and current flume. These measurements shall shed light on the varying roughness and its influence on the load bearing capacity of foundation piles. Consequently, the main aims of the present work were the development of two independent test stations as holding devices for artificial test bodies for the collection of biofouling organisms during field studies: a carrying unit floating at the surface in an exposed area (System A) and a sampling device with access from a land-based facility (System B). Both systems are relatively easy to access, exhibit straightforward handling, and are reasonable cost-effective. A Test Body Support Unit (TBSU, System A) was designed and mounted on a spare buoy to carry the test bodies (cylinders), which serve as substrate for the fouling. The system was sufficiently robust to withstand several periods of rough sea conditions over the first two years. This system can only be accessed by vessels. System B (MareLift) provided the robustness and functionality needed for areas exhibiting harsh conditions but can be operated from land. The here used test bodies (steel panels) exhibited a sound basis for the monitoring of succession processes in the biofouling development. System B offered the possibility to analyse two habitats (intertidal and subtidal) and revealed clear differences in the composition and development of their fouling communities. Overall, both systems provide advantages in obtaining standardized biofouling samples compared to previous approaches. Such test stations play an important role in the risk management of marine sectors as they could help characterising biofouling communities over different geographical areas. System A and B provide a sound basis for biofouling research but potentially also for other potential research approaches in exposed areas as they provide space for future developments.
    Repository Name: EPIC Alfred Wegener Institut
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  • 86
    Publication Date: 2024-04-22
    Description: Highlights: • The interactions between vortices in a four-vortex flow field using a rotating water tank. • Driven by the strain field, non-ideal vortices stretch along the centerline, and manifest an asymmetric stretching pattern. • Non-ideal vortices disperse vorticity, accumulate filaments, and exhibit distinctive variations in anti-symmetric vorticity distribution, impacting respective merging efficiency. Abstract: Oceanic vortex merging is an important physical process for the vortex evolution and its impact on marine environment. However, limitation of the in-situ oceanic observational data of vortex merging inhabits its better understanding. This study investigates the interactions between non-ideal vortices in a four-vortex flow field in a rotating tank. We examine the merging stages of anticyclonic vortices, influenced by two other cyclonic vortices and their respective dynamical behaviors and quantify the effects of merging on vortex characteristics. The results indicate a strong shear flow between two counter-rotating vortices, which accelerates the motion of the anticyclonic vortex, while cyclonic ones exhibit greater stability. Subsequently, different stages of non-ideal vortex merging in a co-rotating framework are defined, primarily the encircling stage, rapid approaching stage, and merging vortex stage. In addition, we quantify and compare variations in morphological parameters and anti-symmetric vorticity distribution of non-ideal vortices across these stages. The stretching of vortices primarily occurs along the line connecting their centers due to the strain field exerted by neighboring vortices, resulting in an asymmetric stretching pattern in the interactions among non-ideal vortices. Furthermore, during the merging process, non-ideal vortices disperse vorticity outward and accumulate vortex filaments in the surrounding environment, leading to distinctive variations in anti-symmetric vorticity distribution, affecting their respective merging efficiency.
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  • 87
    Publication Date: 2024-04-22
    Description: In the past three decades, altimeter-based remote sensing has been a widely used system to estimate ocean surface currents. However, it remains a great challenge to effectively resolve scales below ∼100 km at high latitudes and ∼ 300 km at mid-latitudes. In this study, we propose a scheme that utilizes geostrophic equilibrium and surface quasigeostrophy theory (SQG) to improve surface current resolution by incorporating remote sensing sea surface temperature (SST), sea surface height (SSH), and sea surface salinity (SSS) observations. The scheme separately characterizes the larger-scale flows and smaller-scale motions of surface currents. A case study encompassing the Agulhas surface current demonstrates that the smaller-scale motions associated with temperature fronts are well captured by introducing high spatial-temporal resolution SST data. Furthermore, the reconstructed surface current is systemically evaluated by using surface drogued drifters and a Lagrangian synthetic particle tracking tool throughout the South Indian Ocean (SIO) for 2011–2015. Notably, the reconstructed zonal velocity component is closer to the drifter observations than the meridional counterpart and corresponding velocity phase. Regionally, the Antarctic Circumpolar Current (ACC) showcases superior reconstruction performance, with higher skill scores and lower Lagrangian separation distances. However, a relatively large uncertainty is observed around the Agulhas Retroflection (AR) and Greater Agulhas System (GAS), which are linked to complicated regional dynamic regimes. We finally conduct four simulation experiments to explore the effect of different SST products on surface current reconstruction within the subdomain AR. The results indicate the varying potentials of the four evaluated SST products for informing surface current applications. Specifically, the MWIRSST enhances the likelihood of particles reaching the target field, while DMI OI shortens the average deviation distance of the arrived particles.
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  • 88
    Publication Date: 2024-04-22
    Description: Marine imaging studies have unique constraints on the data collected requiring a tool for defining the biological scope to facilitate data discovery, quality evaluation, sharing and reuse. Defining the ‘target population’ is way of scoping biological sampling or observations by setting the pool of organisms to be observed or sampled. It is used in survey design and planning, to determine statistical inference, and is critical for data interpretation and reuse (both images and derived data). We designed a set of attributes for defining and recording the target population in biological studies using marine photography, incorporating ecological and environmental delineation and marine imaging method constraints. We describe how this definition may be altered and recorded at different phases of a project. The set of attributes records the definition of the target population in a structured metadata format to enhance data FAIRness. It is designed as an extension to the image FAIR Digital Objects metadata standard, and we map terms to other biological data standards where possible. This set of attributes serves a need to update ecological metadata to align with new remotely-sensed data, and can be applied to other remotely-sensed ecological image data.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
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  • 89
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    Unknown
    Elsevier
    In:  EPIC3Current Opinion in Environmental Science & Health, Elsevier, 20, pp. 100231-100231, ISSN: 2468-5844
    Publication Date: 2024-04-19
    Description: Declaration of interest was missed out in the published version. The authors have confirmed in the following context: ‘The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.’ The publisher would like to apologise for any inconvenience caused.
    Repository Name: EPIC Alfred Wegener Institut
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  • 90
    Publication Date: 2024-04-19
    Type: Book chapter , PeerReviewed
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  • 91
    Publication Date: 2024-04-18
    Description: The Beagle Channel is a remote subantarctic environment where mussel aquaculture initiatives have existed since the early 1990s. Here we analyze phytoplankton biomass and composition, and the occurrence of harmful microalgae species and their toxins at three sites during the period 2015–2016. The occurrence of potentially harmful algae was observed throughout the study period, including toxigenic dinoflagellates such as Alexandrium catenella (Group I of the A. tamarense complex), A. ostenfeldii, Dinophysis acuminata, Gonyaulax spinifera, Azadinium sp., and the diatoms Pseudo-nitzschia australis and P. fraudulenta. Toxic dinoflagellates were detected in low densities whereas a Pseudo-nitzschia bloom was observed in late February. Isolates of A. catenella and P. delicatissima sensu stricto were phylogenetically characterized. The toxin profile of A. catenella was dominated by GTX4, while P. delicatissima sensu stricto showed no production of the neurotoxin domoic acid in culture conditions. The results provide base-line information for the management of harmful algal blooms in this little explored subantarctic area.
    Repository Name: EPIC Alfred Wegener Institut
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  • 92
    Publication Date: 2024-04-17
    Description: Recent studies have highlighted the prevalence of microplastic (MP) pollution in the global marine environment and these pollutants have been found to contaminate even remote regions, including the Southern Ocean south of the polar front. Previous studies in this region have mostly focused on MPs larger than 300 μm, potentially underestimating the extent of MP pollution. This study is the first to investigate MPs in marine surface waters south of the polar front, with a focus on small MPs 500–11 μm in size. Seventeen surface water samples were collected in the southern Weddell Sea using an in-house-designed sampling system. The analysis of the entire sample using micro-Fourier transform infrared spectroscopy (μFTIR) with focal plane array (FPA) detection revealed the presence of MPs in all samples, with the vast majority of the MPs detected being smaller than 300 μm (98.3 %). The mean concentration reached 43.5 (± 83.8) MPs m−3, with a wide range from 0.5 to 267.2 MPs m−3. The samples with the highest concentrations differed from the other samples in that they were collected north of the continental slope and the Antarctic Slope Current. Sea ice conditions possibly also influenced these varying concentrations. This study reports high concentrations of MPs compared to other studies in the region. It emphasizes the need to analyze small MPs, down to a size of 11 μm or even smaller, in the Antarctic Treaty Area to gain a more comprehensive understanding of MP pollution and its potential ecological impacts.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 93
    Publication Date: 2024-04-17
    Description: Over the past decades, significant efforts have been made to understand the nature, dynamics and evolution of volcanic systems. In parallel, the continuous demographic expansion and extensive urbanization of volcanic areas have increased the exposure of our society to these natural phenomena. This increases the need to improve our capacities to accurately assess projected volcanic hazards and their potential socioeconomic and environmental impact, and Antarctica and the sub-Antarctic islands are no exception. More than a hundred volcanoes have been identified in Antarctica, some of which are entirely buried beneath the ice sheet and others as submarine volcanoes. Of these, at least eight large (basal diameters 〉 c. 20-30 km) volcanoes are known to be active and pose a considerable threat to scientific and ever-increasing tourism activities being carried out in the region. Despite the scientific and socioeconomic interest, many aspects of the past volcanic activity and magmatic processes in Antarctica, and current volcanic hazards and risks, remain unknown. Moreover, many of Antarctica’s volcanoes preserve a remarkable history of the eruptive environment, from which multiple parameters of past configurations of the Antarctic ice sheet (AIS) can be deduced. Given the critical role that the AIS plays in regulating Earth’s climate, Antarctica’s volcanoes therefore can be regarded as the ground truth for current models of past climates derived from modelling and studies of marine sediments. Here, we provide a succinct overview of the evolution of volcanism and magmatism in Antarctica and the sub-Antarctic region over the past 200 million years. Then, we briefly review the current state of knowledge of the most crucial aspects regarding Antarctica’s volcanic and magmatic processes, and the contributions volcanic studies have made to our understanding of ice sheet history and evolution, geothermal heat flow, as well as present-day and future volcanic hazard and risk. A principal objective is to highlight the problems and critical limitations of the current state of knowledge and to provide suggestions for future potential directions of volcanic-driven investigations in Antarctica. Finally, we also discuss and assess the importance and scope of education and outreach activities specifically relating to Antarctic volcanism, and within the context of broader polar sciences.
    Description: Published
    Description: 107941
    Description: OSV2: Complessità dei processi vulcanici: approcci multidisciplinari e multiparametrici
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 94
    Publication Date: 2024-04-17
    Description: We present the results of the tephrochronology study of a 14.49 m long marine sediment core (TR 17–08) collected in the Edisto Inlet, Ross Sea (Antarctica). The core contains four cryptotephra layers at 55–56, 512–513, 517–518, and 524–525 cm of depth, which have been characterised by a detailed description of the texture, mineral assemblage, and single glass shards major and trace element geochemistry. The age model of the investigated sedimentary sequence, based on radiocarbon dating, indicates that the topmost cryptotephra correlates with the widespread 1254 CE tephra erupted by a historical eruption (696 ± 2 cal yrs BP) of Mount Rittmann, in northern Victoria Land. Deeper cryptotephra layers were derived from previously unknown explosive eruptions of Mount Melbourne volcano and were emplaced between 1615 cal yrs BP and 1677 cal yrs BP, e.g. between the 3rd and 4th centuries CE. This discovery demonstrates that the Mount Melbourne volcanic complex has been highly active in historical times allowing significant progress in the current understanding of regional eruptive history. Moreover, from a tephrochronological point of view, the detected cryptotephra provide new regional isochron markers to facilitate high-precision correlations and help stratigraphically constrain changes in environmental and climatic conditions that are identified by multidisciplinary studies.
    Description: Published
    Description: 100079
    Description: OSA3: Climatologia e meteorologia spaziale
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 95
    Publication Date: 2024-04-16
    Description: Phototrophic protists are a fundamental component of the world's oceans by serving as the primary source of energy, oxygen, and organic nutrients for the entire ecosystem. Due to the high thermal seasonality of their habitat, temperate protists could harbour many well-adapted species that tolerate ocean warming. However, these species may not sustain ecosystem functions equally well. To address these uncertainties, we conducted a 30-day mesocosm experiment to investigate how moderate (12C) and substantial (18C) warming compared to ambient conditions (6C) affect the composition (18S rRNA metabarcoding) and ecosystem functions (biomass, gross oxygen productivity, nutritional quality – C:N and C:P ratio) of a North Sea spring bloom community. Our results revealed warming-driven shifts in dominant protist groups, with haptophytes thriving at 12 C and diatoms at 18 C. Species responses primarily depended on the species' thermal traits, with indirect temperature effects on grazing being less relevant and phosphorus acting as a critical modulator. The species Phaeocystis globosa showed highest biomass on low phosphate concentrations and relatively increased in some replicates of both warming treatments. In line with this, the C:P ratio varied more with the presence of P. globosa than with temperature. Examining further ecosystem responses under warming, our study revealed lowered gross oxygen productivity but increased biomass accumulation whereas the C:N ratio remained unaltered. Although North Sea species exhibited resilience to elevated temperatures, a diminished functional similarity and heightened compositional variability indicate potential ecosystem repercussions for higher trophic levels. In conclusion, our research stresses the multifaceted nature of temperature effects on protist communities, emphasising the need for a holistic understanding that encompasses trait-based responses, indirect effects, and functional dynamics in the face of exacerbating temperature changes.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 96
    Publication Date: 2024-04-15
    Description: Fishes occur in a wider range of habitats than any other vertebrate or invertebrate group, from the upper reaches of streams in high mountain ranges to the mouths of temperate and tropical rivers, and from the intertidal zone to the ocean's abyss. Fish grow in size, spawn and die, either from natural causes (predation, diseases, ageing) or from being caught in fishing nets if the population is exploited. These dynamical processes are expressed with mathematical equations and are used in population models to estimate fisheries reference points (stock assessment), which in turn provide the basis for fisheries management. Fish populations subjected to fisheries exploitation are called fish “stocks”. Fishing has been increasingly affecting fish stocks and ecosystems both directly and indirectly, and along with the human-induced climate change they pose major threats to fish biodiversity worldwide. Using the available data stored in local or global databases to assess the status of all stocks, even the data-poor fish stocks, and following an ecosystem approach to fisheries management that incorporates effort reduction through marine protected areas, may contribute to the sustainable exploitation of fisheries resources.
    Type: Book chapter , NonPeerReviewed
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  • 97
    Publication Date: 2024-04-15
    Description: Cadmium (Cd) has a nutrient-like distribution in the ocean, similar to the macronutrient phosphate. Significant isotope fractionation induced by the biological cycling of Cd makes it a potential tracer for nutrients and productivity. However, the Cd flux and Cd isotope composition of marine sediments can also be influenced by local redox conditions and partial remineralization of organically hosted Cd. These confounding factors are under-constrained and render it challenging to use Cd as a reliable paleoproxy. To understand the relative importance of each of these processes, we examined the Cd isotope systematics of 69 modern sediments deposited across a wide range of environments. We complement these data with four profiles of particulate Cd isotope compositions from the Southern Ocean. We report three main results. First, we show that the sedimentary flux of Cd is tightly coupled to that of organic matter. Second, most Cd burial occurs in regions with some bottom-water oxygen, and the flux of CdS to anoxic regions is, globally, minor. Finally, we find that remineralization can substantially modify sedimentary Cd isotope compositions, though it is challenging to relate pelagic and sedimentary processes. For example, we find that the relationship between sedimentary Cd isotope compositions and surface seawater [Cd] is the reverse of that predicted by isotope reactor models. Likewise, sedimentary Cd isotope compositions are anti-correlated with bottom-water oxygen. While this pattern is consistent with preferential remineralization of isotopically heavy Cd, profiles of marine particulate matter reveal the reverse, whereby the Cd isotope composition of large particles, which are most likely to reach the seafloor, becomes increasingly ‘heavy’ with depth. These results highlight how productivity, redox, and remineralization all influence the flux and isotope composition of Cd to marine sediments. While our study suggests that there is no simple way to relate sedimentary Cd isotopes to surface nutrient utilization, our data point toward several potential controls that could form the basis of novel proxies for local redox conditions and remineralization.
    Type: Article , PeerReviewed
    Format: other
    Format: text
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  • 98
    Publication Date: 2024-04-11
    Description: Fluid induced fault reactivation experiments will take place as part of the “Fault Activation and Earthquake Rupture” project (FEAR) at the BedrettoLab, an underground laboratory for geosciences and geo-energy excavated within the Rotondo massif (Swiss Alps). The aim of this publication is to characterize frictional properties and permeability of the main segment of the fault zone selected for limited fluid-induced fault reactivation experiments. Firstly, we characterized fault zone microstructures in the field and in thin sections. Secondly, we assessed fault gouge mineralogy by X-ray powder diffraction analysis, yielding a composition in agreement with similar fault gouges in the same area. Finally, we performed a detailed frictional and permeability characterization in laboratory, using BRAVA (Brittle Rock deformAtion Versatile Apparatus). We performed five frictional experiments, run at the actual in-situ conditions: four experiments for frictional properties characterization; and one further experiment where we stimulated the experimental fault by fluid pressurization applying a similar injection protocol designed for the in-situ hydraulic stimulation experiment. Additionally, we performed microstructural analysis on experimental samples to link frictional and permeability properties with fault fabric evolution. The integration of experimental results with field investigations suggests that the selected fault is potentially seismogenic and can be dynamically reactivated and controlled with hydraulic stimulation. This study highlights the importance of bridging the gap between laboratory and in-situ fault characterization, where experimental results become instrumental for the correct design of injection protocols such as those of FEAR project.
    Description: Published
    Description: 229987
    Description: OST3 Vicino alla faglia
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 99
    Publication Date: 2024-04-10
    Description: Phytoplankton play a central role in the planetary cycling of important elements and compounds. Understanding how phytoplankton are responding to climate change is consequently a major question in Earth Sciences. Monitoring phytoplankton is key to answering this question. Satellite remote sensing of ocean colour is our only means of monitoring phytoplankton in the entire surface ocean at high temporal and large spatial scales, and the continuous ocean-colour data record is now approaching a length suitable for addressing questions around climate change, at least in some regions. Yet, developing ocean-colour algorithms for climate change studies requires addressing issues of ambiguity in the ocean-colour signal. For example, for the same chlorophyll-a concentration (Chl-a) of phytoplankton, the colour of the ocean can be different depending on the type of phytoplankton present. One route to tackle the issue of ambiguity is by enriching the ocean-colour data with information on sea surface temperature (SST), a good proxy of changes in three phytoplankton size classes (PSCs) independent of changes in total Chl-a, a measure of phytoplankton biomass. Using a global surface insitu dataset of HPLC (high performance liquid chromatography) pigments, size-fractionated filtration data, and concurrent satellite SST spanning from 1991 to 2021, we re-tuned, validated and advanced an SST-dependent three-component model that quantifies the relationship between total Chl-a and Chl-a associated with the three PSCs (pico-, nano- and microplankton). Similar to previous studies, striking dependencies between model parameters and SST were captured, which were found to improve model performance significantly. These relationships were applied to 40 years of monthly composites of satellite SST, and significant trends in model parameters were observed globally, in response to climate warming. Changes in these parameters highlight issues in estimating long-term trends in phytoplankton biomass (Chl-a) from ocean colour using standard empirical algorithms, which implicitly assume a fixed relationship between total Chl-a and Chl-a of the three size classes. The proposed ecological model will be at the centre of a new ocean-colour modelling framework, designed for investigating the response of phytoplankton to climate change, described in subsequent parts of this series of papers.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 100
    Publication Date: 2024-04-10
    Description: EnMAP (Environmental Mapping and Analysis Program) is a high-resolution imaging spectroscopy remote sensing mission that was successfully launched on April 1st, 2022. Equipped with a prism-based dualspectrometer, EnMAP performs observations in the spectral range between 418.2 nm and 2445.5 nm with 224 bands and a high radiometric and spectral accuracy and stability. EnMAP products, with a ground instantaneous field-of-view of 30 m×30 m at a swath width of 30 km, allow for the qualitative and quantitative analysis of surface variables from frequently and consistently acquired observations on a global scale. This article presents the EnMAP mission and details the activities and results of the Launch and Early Orbit and Commissioning Phases until November 1st, 2022. The mission capabilities and expected performances for the operational Routine Phase are provided for existing and future EnMAP users.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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