ALBERT

Description: A preliminary comparison of the GEOS-1 (Goddard Earth Observing System) data assimilation system convective cloud mass fluxes with fluxes from a cloud-resolving model (the Goddard Cumulus Ensemble Model, GCE) is reported. A squall line case study (10-11 June 1985 Oklahoma PRESTORM episode) is the basis of the comparison. Regional (central U. S.) monthly total convective mass flux for June 1985 from GEOS-1 compares favorably with estimates from a statistical/dynamical approach using GCE simulations and satellite-derived cloud observations. The GEOS-1 convective mass fluxes produce reasonable estimates of monthly-averaged regional convective venting of CO from the boundary layer at least in an urban-influenced continental region, suggesting that they can be used in tracer transport simulations.

Description: The U.S. upper Midwest was subjected to severe flooding during the summer of 1993. Heavy rainfall in the Mississippi River basin from April through July caused flooding on many Midwest rivers, including the Mississippi, Illinois, Missouri, and Kansas Rivers. The flood crest of 15.1 m at St. Louis, Missouri, on 1 August 1993 was the highest ever measured, surpassing the previous record of 13.2 m set on 28 April 1973. Damage estimates include at least 47 flood-related deaths and a total damage cost of $12 billion. Remotely sensed imagery of severe flooding in the U.S. Midwest was obtained under cloud-free skies on 29 July 1993 by the MODIS (Moderate Resolution Imaging Spectroradiometer) Airborne Simulator (MAS). The MAS is a newly developed scanning spectrometer with 50 spectral bands in the wavelength range 0.55-14.3 micrometers. Estimation of the total flooded area in the MAS scene acquired near St. Louis was accomplished by comparing the MAS scene to a Landsat-5 thematic mapper (TM) scene of the same area acquired on 14 April 1984 in nonflood conditions. For comparison, the MAS band centered at 0.94 micrometers and the TM band centered at 1.65 micrometers were selected because of the high contrast seen in these bands between land and water-covered surfaces. An estimate of the area covered by water in the MAS and TM scenes was obtained by developing land/water brightness thresholds from histograms of the MAS and TM digital image data. Afetr applying the thresholds, the difference between the area covered by water in the MAS and TM scenes, and hence the flooded area in the MAS scene, was found to be about 396 sq km, or about 153 square miles.

Description: Shortwave radiative fluxes that reach the earth's surface are key factors that influence atmospheric and oceanic circulations as well as surface climate. Yet, information on these fluxes is meager. Surface site data are generally available from only a limited number of observing stations over land. Much less is known about the large-scale variability of the shortwave radiative fluxes over the oceans, which cover most of the globe. Recognizing the need to produce global-scale fields of such fluxes for use in climate research, the World Climate Research Program has initiated activities that led to the establishment of the Surface Radiation Budget Climatology Project with the ultimate goal to determine various components of the surface radiation budget from satellite data. In this paper, the first global products that resulted from this activity are described. Monthly and daily data on a 280-km grid scale are available. Samples of climate parameters obtainable from the dataset are presented. Emphasis is given to validation and limitations of the results. For most of the globe, satellite estimates have bias values between +/- 20 W/sq m and root mean square (rms) values are around 25 W/sq m. There are specific regions with much larger uncertainties however.

Description: The deployment of a space-based Doppler lidar would provide information that is fundamental to advancing the understanding and prediction of weather and climate. This paper reviews the concepts of wind measurement by Doppler lidar, highlights the results of some observing system simulation experiments with lidar winds, and discusses the important advances in earth system science anticipated with lidar winds. Observing system simulation experiments, conducted using two different general circulation models, have shown (1) that there is a significant improvement in the forecast accuracy over the Southern Hemisphere and tropical oceans resulting from the assimilation of simulated satellite wind data, and (2) that wind data are significantly more effective than temperature or moisture data in controlling analysis error. Because accurate wind observations are currently almost entirely unavailable for the vast majority of tropical cyclones worldwide, lidar winds have the potential to substan- tially improve tropical cyclone forecasts. Similarly, to improve water vapor flux divergence calculations, a direct measure of the ageostrophic wind is needed since the present level of uncer- tainty cannot be reduced with better temperature and moisture soundings alone.

Description: The 'satellite-gauge model' (SGM) technique is described for combining precipitation estimates from microwave satellite data, infrared satellite data, rain gauge analyses, and numerical weather prediction models into improved estimates of global precipitation. Throughout, monthly estimates on a 2.5 degrees x 2.5 degrees lat-long grid are employed. First, a multisatellite product is developed using a combination of low-orbit microwave and geosynchronous-orbit infrared data in the latitude range 40 degrees N - 40 degrees S (the adjusted geosynchronous precipitation index) and low-orbit microwave data alone at higher latitudes. Then the rain gauge analysis is brougth in, weighting each field by its inverse relative error variance to produce a nearly global, observationally based precipitation estimate. To produce a complete global estimate, the numerical model results are used to fill data voids in the combined satellite-gauge estimate. Our sequential approach to combining estimates allows a user to select the multisatellite estimate, the satellite-gauge estimate, or the full SGM estimate (observationally based estimates plus the model information). The primary limitation in the method is imperfections in the estimation of relative error for the individual fields. The SGM results for one year of data (July 1987 to June 1988) show important differences from the individual estimates, including model estimates as well as climatological estimates. In general, the SGM results are drier in the subtropics than the model and climatological results, reflecting the relatively dry microwave estimates that dominate the SGM in oceanic regions.

Description: The lower stratospheric variability of equatorial water vapor, measured by the Microwave Limb Sounder (MLS), follows an annual cycle modulated by the quasi-biennial oscillation. At levels higher in the stratosphere, water vapor measurements exhibit a semi-annual oscillatory signal with the largest amplitudes at 2.2 and 1hPa. Zonal-mean cross sections of MLS water vapor are consistent with previous satellite measurements from the limb infrared monitor of the stratosphere (LIMS) and the stratospheric Aerosol and Gas Experiment 2 (SAGE 2) instruments in that they show water vapor increasing upwards and the polewards from a well defined minimum in the tropics. The minimum values vary in height between the retrieved 46 and 22hPa pressure levels.

Description: The absolute rate constant for the reaction O((3)P) + HOBr has been measured between T = 233K and 423K using the discharge-flow kinetic technique coupled to mass spectrometric detection. The value of the rate coefficient at room temperature is (2.5 +/- 0.6) x 10(exp -11)cu cm/molecule/s and the derived Arrhenius expression is (1.4 +/- 0.5) x 10(exp -10) exp((-430 +/- 260)/T)cu cm/molecule/s. From these rate data the atmospheric lifetime of HOBr with respect to reaction with O((3)P) is about 0.6h at z = 25 km which is comparable to the photolysis lifetime based on recent measurements of the UV cross section for HOBr. Implications for HOBr loss in the stratosphere have been tested using a 1D photochemical box model. With the inclusion of the rate parameters and products for the O + HOBr reaction, calculated concentration profiles of BrO increase by up to 33% around z = 35 km. This result indicates that the inclusion of the O + HOBr reaction in global atmospheric chemistry models may have an impact on bromine partitioning in the middle atmosphere.

Description: A diagnostic analysis of the VVP (volume velocity processing) retrieval method is presented, with emphasis on understanding the technique as a linear, multivariate regression. Similarities and differences to the velocity-azimuth display and extended velocity-azimuth display retrieval techniques are discussed, using this framework. Conventional regression diagnostics are then employed to quantitatively determine situations in which the VVP technique is likely to fail. An algorithm for preparation and analysis of a robust VVP retrieval is developed and applied to synthetic and actual datasets with high temporal and spatial resolution. A fundamental (but quantifiable) limitation to some forms of VVP analysis is inadequate sampling dispersion in the n space of the multivariate regression, manifest as a collinearity between the basis functions of some fitted parameters. Such collinearity may be present either in the definition of these basis functions or in their realization in a given sampling configuration. This nonorthogonality may cause numerical instability, variance inflation (decrease in robustness), and increased sensitivity to bias from neglected wind components. It is shown that these effects prevent the application of VVP to small azimuthal sectors of data. The behavior of the VVP regression is further diagnosed over a wide range of sampling constraints, and reasonable sector limits are established.

Description: Analysis of the version 16 Halogen Occultation Experiment (HALOE) CH4 data shows that this long-lived trace gas is well correlated with potential vorticity (PV) computed from National Meteorological Center balanced winds. Analyzing late September and October 1992 data, we show that very low CH4 values are confined to the interior of a vortex edge defined by the maximum gradient in PV. The CH4 and HF time tendency is used to estimate the descent rate in the Antarctic vortex. After removing a component of the trend correlated with the HALOE sampling pattern, we compute the lower stratosphere vertical descent rates and net heaing rates in the spring Antarctic vortex. Our computations of the spring Antarctic vortex heating rates give -0.5 to -0.1 K/day. Over the winter season, the overall lower stratospheric descent rate averages about 1.8-1.5 km/month. These computations are in line with radiative transfer estimates of the heating and descent rate. The HALOE data thus appear to be consistent with the picture of an isolated lower stratospheric Antarctic vortex.

Description: Using delta C-13 measurements in atmospheric CO2 from a cooperative global air sampling network, we determined the partitioning of the net uptake of CO2 between ocean and land as a function of latitude and time. The majority of delta C-13 measurements were made at the Institute of Arctic and Alpine Research (INSTAAR) of the University of Colorado. We perform an inverse deconvolution of both CO2 and delta C-13 observations, using a two-dimensional model of atmospheric transport. Also, the discrimination against C-13 by plant photosynthesis, as a function of latitude and time, is calculated from global runs of the simple biosphere (SiB) model. Uncertainty due to the longitudinal structure of the data, which is not represented by the model, is studied through a bootstrap analysis by adding and omitting measurement sites. The resulting error estimates for our inferred sources and sinks are of the order of 1 GTC (1 GTC = 10(exp 15) gC). Such error bars do not reflect potential systematic errors arising from our estimates of the isotopic disequilibria between the atmosphere and the oceans and biosphere, which are estimated in a separate sensitivity analysis. With respect to global totals for 1992 we found that 3.2 GTC of carbon dissolved into the ocean and that 1.5 GTC were sequestered by land ecosystems. Northern hemisphere ocean gyres north of 15 deg N absorbed 2.7 GTC. The equatorial oceans between 10 deg S and 10 deg N were a net source to the atmosphere of 0.9 GTC. We obtained a sink of 1.6 GTC in southern ocean gyres south of 20 deg S, although the deconvolution is poorly constrained by sparse data coverage at high southern latitudes. The seasonal uptake of CO2 in the northern gyres appears to be correlated with a bloom of phytoplankton in surface waters. On land, northern temperate and boreal ecosystems between 35 deg N and 65 deg N were found to be a major sink of CO2 in 1992, as large as 3.5 GTC. Northern tropical ecosystems (equator-30 deg N) appear to be a net source to the source to the atmosphere of 2 GTC which could reflect biomass burning. A small sink, 0.3 GTC, was inferred for southern tropical ecosystems (30 deg S-equator).