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  • 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases  (17)
  • Elsevier  (15)
  • Blackwell Publishing Ltd  (2)
  • Nature Publishing Group
  • 2005-2009  (17)
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  • 1
    Publication Date: 2021-06-25
    Description: We report in this paper a systematic investigation of the chemical and isotopic composition of groundwaters flowing in the volcanic aquifer of Mt. Vesuvius during its current phase of dormancy, including the first data on dissolved helium isotope composition and tritium content. The relevant results on dissolved He and C presented in this paper reveal that an extensive interaction between rising magmatic volatiles and groundwaters currently takes place at Vesuvius. Vesuvius groundwaters are dilute (mean TDS 2800 mg/L) hypothermal fluids (mean T 17.7°C) with a prevalent alkaline-bicarbonate composition. Calcium-bicarbonate groundwaters normally occur on the surrounding Campanian Plain, likely recharged from the Apennines. D and 18O data evidence an essentially meteoric origin of Vesuvius groundwaters, the contribution from either Tyrrhenian seawater or 18O-enriched thermal water appearing to be small or negligible. However, the dissolution of CO2-rich gases at depth promotes acid alteration and isochemical leaching of the permeable volcanic rocks, which explains the generally low pH and high total carbon content of waters. Attainment of chemical equilibrium between the rock and the weathering solutions is prevented by commonly low temperature (10 to 28°C) and acid-reducing conditions. The chemical and isotope (C and He) composition of dissolved gases highlights the magmatic origin of the gas phase feeding the aquifer. We show that although the pristine magmatic composition may vary upon gas ascent because of either dilution by a soil-atmospheric component or fractionation processes during interaction with the aquifer, both 13C/12C and 3He/4He measurements indicate the contribution of a magmatic component with a 13C 0‰ and R/Ra of 2.7, which is consistent with data from Vesuvius fumaroles and phenocryst melt inclusions in olivine phenocrysts. A main control of tectonics on gas ascent is revealed by data presented in this paper. For example, two areas of high CO2 release and enhanced rock leaching are recognized on the western (Torre del Greco) and southwestern (Torre Annunziata–Pompeii) flanks of Vesuvius, where important NE-SW and NW-SE tectonic structures are recognized. In contrast, waters flowing through the northern sector of the volcano are generally colder, less saline, and CO2 depleted, despite in some cases containing significant concentrations of magmaderived helium. The remarkable differences among the various sectors of the volcano are reconciled in a geochemical interpretative model, which is consistent with recent structural and geophysical evidences on the structure of Somma-Vesuvius volcanic complex.
    Description: -European Union, -Ministero dell’Universita’ e della Ricerca Scientifica e Tecnologica; -CNR–Gruppo Nazionale per la Vulcanologia.
    Description: Published
    Description: 963–981
    Description: partially_open
    Keywords: isotopes ; water chemistry ; dissolved gases ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 03. Hydrosphere::03.04. Chemical and biological::03.04.07. Radioactivity and isotopes ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 2
    Publication Date: 2017-04-04
    Description: This work presents the results of hydrogeochemical studies carried out at Vesuvius during the period May 1998 - December 2001, mostly focusing on compositional time variations observed during this time. Based on their chemistry, groundwater samples are distinguished into two groups, 1 and 2, representative of water circulation in the southern and northern sectors of the volcano, respectively. Waters from group 1 are typically more acidic, warmer,and more saline than those of group 2. They also have higher CO2 and CH4 contents, attributed to enhanced input of deep-rising volatiles and prolonged water-rock interactions. Time-series highlight the fairly constant chemical composition of the entire aquifer. Groundwater temperature, pH, bicarbonate content and dissolved CO2 display quite stable values in the study period, particularly in deep wells (piezometric level more than 100 m deep). Shallower water bodies present more evident temporal variations, related to seasonal and anthropogenic effects. This paper also describes some important variations in water chemistry which had occurred by the time of the seismic event in early October 1999, particularly in the Olivella spring located on the northern flank of the volcano. At this site, a great decrease in water pH and redox potential, and increased dissolved CO2 contents and 3He/4He ratios were observed. These changes in chemical and isotope composition support the hypothesis of an input of magma-derived helium and carbon dioxide into the aquifer feeding the Olivella spring by the time of the earthquake.
    Description: Published
    Description: 81-104
    Description: partially_open
    Keywords: Vesuvius ; volcanic surveillance ; groundwater ; hydro-geochemistry ; oxygen-18 ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 3
    Publication Date: 2017-04-04
    Description: The Albano Lake is the deepest volcanic lake in Italy (−167 m) and fills the youngest maar of the quiescent Colli Albani volcano. The lake has undergone significant level changes and lahar generating overflows occurred about 5800 yrs B.P. and likely in 398 b.C., when Romans excavated a tunnel drain through the maar wall. Hazardous lake rollovers and CO2 release are still possible because the Albano volcano shows active ground deformation, gas emission and periodic seismic swarms. On November 2005, the first high resolution bathymetric survey of the Albano Lake was performed. Here we present the results provided by a Digital Elevation Model and 2-D and 3-D images of the crater lake floor, which is made by coalescent and partly overlapping craters and wide flat surfaces separated by some evident scarps. Submerged shorelines are identified at depths between −20 m and −41 m and indicate the occurrence of significant lake level changes, likely between 7.1 and 4.1 ka. The current lake volume is ~447.5×106 m3 and the total quantity of dissolved CO2 is 6850 t estimated by chemical analyses of samples collected on May 2006. A decrease of nearly one order of magnitude of the CO2 dissolved in the lake water below −120 m, observed from December 1997 to May 2006 (from 4190 to 465 t respectively), has been attributed to lake water overturn. The observed oscillations of the dissolved CO2 concentrations justify the efforts of monitoring the chemical and physical characteristics of the lake. At present the quantity of dissolved CO2 is very far from saturation and Nyostype events cannot presently occur.
    Description: DPC-INGV Project V3_1
    Description: Published
    Description: 258–268
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: 1.3. TTC - Sorveglianza geodetica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Albano maar ; lake bathymetry ; geochemistry ; crater lake hazard ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.06. Seismology::04.06.04. Ground motion ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 4
    Publication Date: 2017-04-04
    Description: The “methane-led hypotheses” assume that gas hydrates and marine seeps are the sole geologic factors controlling Quaternary atmospheric and climate changes. Nevertheless, a wider class of geologic sources of methane exist which could have played a role in past climate changes. Beyond offshore seepage, relevant geologic emissions of methane (GEM) are from onshore seepage, including mud volcanism, microseepage and geothermal flux; altogether GEM are the second most important natural source of atmospheric methane at present. The amount of methane entering the atmosphere from onshore GEM seems to prevail on that from offshore seepage. Onshore sources inject a predominantly isotopically heavy (13C-enriched) methane into the atmosphere. They are controlled mainly by endogenic (geodynamic) processes, which induce large-scale gas flow variations over geologic and millennial time scales, and only partially by exogenic (surface) conditions, so that they are not affected by negative feedbacks. The eventual influence on atmospheric methane concentration does not necessarily require catastrophic or abrupt releases, as proposed for the “clathrate gun hypothesis”. Enhanced degassing from these sources could have contributed to the methane trends observed in the ice core records, and could explain the late Quaternary peaks of increased methane concentrations accompanied by the enrichment of isotopically heavy methane, as recently observed. This hypothesis shall be tested by means of robust multidisciplinary studies, mainly based on a series of atmospheric, biologic and geologic proxies.
    Description: Published
    Description: On line First
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; climate change ; seepage ; Quaternary ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 5
    Publication Date: 2017-04-03
    Description: Central to any study of climate change is the development of an inventory that identifies and quantifies natural and anthropogenic sources and sinks of greenhouse gases (GHG). Recent studies have demonstrated that geologic emissions of methane (GEM), although not considered in the inventories of the IntergovernmentalPanel on Climate Change (IPCC), are an important GHG source. Etiope and Klusman (2002, Chemosphere 49, 777–789) documented that significant amounts of methane, produced within the Earth crust, are released naturally into the atmosphere through faults and fractured rocks. Major GEMs are related to hydrocarbon production in sedimentary basins (biogenic and thermogenic methane), through continuous exhalation and eruptions from more than 1200 onshore and offshore mud volcanoes (MVs), through diffuse soil microseepage, and shallow marine seeps; secondarily, methane is released from geothermal and volcano-magmatic systems. Minor geologic sources are those related to natural exhalation from coal-bearing rocks (influenced by mining activities), degassing from crystalline basement and mantle. While marine seeps have been studied for decades, methane flux from MVs has been the object of detailed measurements only since 2001, when hundreds of gas flux measurements were performed from vents and soilin the main terrestrial MVs of Europe, in Romania and Italy (Etiope et al.,2003, Geophysical Research Letters 30, 1094, doi:10.1029/2002GL016287; and references therein). In 2003 gas flux was measured in Azerbaijan, which hosts the world’s biggest MVs and densest MV population (Etiope et al., 2004, Geology, in press). In all areas investigated around 102–103 tons of methane per km2 are annually injected into the atmosphere. The global estimates of GEM from MVs range from 5 to 13Tg yr-1 (Etiope and Milkov, 2004, Environmental Geology, in press).
    Description: Published
    Description: 3099-3100
    Description: 4.5. Degassamento naturale
    Description: JCR Journal
    Description: reserved
    Keywords: Methane ; atmospheric gas budget ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 6
    Publication Date: 2017-04-04
    Description: This survey proposes a new approach to identify buried caldera boundaries of a volcanic cone, combining (1) a systematic elliptic Fourier functions (EFF) analysis on the contour lines based on the external shape of the edifice with (2) self-potential (SP) measurements on volcano flanks. The methodology of this approach is to investigate the relationships between (1) vertical morphological changes inferred from EFF analysis and (2) lateral lithological transition inside the edifice inferred from SP/elevation gradients. The application of these methods on Misti volcano in southern Peru displays a very good correlation. The three main boundaries evidenced by hierarchical cluster analysis on the contour lines coincide with the two main boundaries characterised by SP signal and with a secondary SP signature related with a summit caldera. In order to explain these results showing a very good correlation between morphologic and lithologic changes as function of elevation, caldera boundaries have been suggested. The latter would be located at an average elevation of (1) 4350–4400 m, (2) 4950–5000 m, and (3) 5500– 5550 m. For the lowest boundary in elevation, the coincidence with the lateral extension of the hydrothermal system inferred from SP measurements suggests that caldera walls act as a barrier for lateral extension of hydrothermal systems. In the summit area, the highest boundary has been related with the summit caldera, inferred by a secondary SP minimum and geological evidence.
    Description: - Institut de Recherche pour le Développement (IRD) - Instituto Geofisico del Peru´ (IGP).
    Description: Published
    Description: 283– 297
    Description: partially_open
    Keywords: caldera ; elliptic Fourier functions ; geomorphology ; self-potential ; Misti volcano ; Peru ; 03. Hydrosphere::03.02. Hydrology::03.02.02. Hydrological processes: interaction, transport, dynamics ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.02. Hydrology::03.02.04. Measurements and monitoring ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.02. Exploration geophysics::04.02.04. Magnetic and electrical methods ; 04. Solid Earth::04.04. Geology::04.04.03. Geomorphology ; 04. Solid Earth::04.04. Geology::04.04.09. Structural geology ; 04. Solid Earth::04.04. Geology::04.04.11. Instruments and techniques ; 04. Solid Earth::04.08. Volcanology::04.08.05. Volcanic rocks ; 05. General::05.02. Data dissemination::05.02.04. Hydrogeological data ; 05. General::05.05. Mathematical geophysics::05.05.99. General or miscellaneous ; 05. General::05.08. Risk::05.08.99. General or miscellaneous ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
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  • 7
    Publication Date: 2017-04-04
    Description: Volcanism at Mount Etna (Italy) has been observed for millennia and inspired ancient mythologies as well as scientific thought through countless generations.Yetmuch of our understanding of the way this volcano works stems fromstudies of the past 20 years, and in particular from strengthened monitoring since the late 1980s. In addition, the eruptive activity of Etna has undergone significant changes during the past 13 years, and these have led to an improved understanding of the relationship between the plumbing system of the volcano and instability of its eastern to southern f lanks. Following the end of the 1991–1993 eruption, a new eruptive cycle began, which so far has produced about 0.23 km3 of lavas and pyroclastics (dense-rock equivalent). The cycle evolved frominitial recharging of the plumbing system and inf lation, followed by powerful summit eruptions and slow spreading of the eastern to southern f lanks, to a sequence of f lank eruptions accompanied by accelerated f lank displacement. Structurally, the volcanic system has become increasingly unstable during this period. Volcanological, geophysical and geochemical data allow the cause–effect and feedback relationships between magma accumulation below the volcano, f lank instability, and the shift from continuous summit activity to episodic f lank eruptions to be investigated. In this scenario, the growth of magma storage areas at a depth of 3–5 km below sea level exerts pressure against those f lank sectors prone to displacement, causing them to detach from the stable portions of the volcanic edifice. Geochemical data indicate that magma remains stored belowthe volcano, even during phases of intense eruptive activity, thus causing a net volumetric increase that is accommodated by f lank displacement. Instability can be enhanced by the forceful uprise ofmagma through the f lanks, as in 2001, when the f irst f lank eruption of the current eruptive cycle took place. Subsequent f lank eruptions in 2002–2003 and 2004– 2004, on the other hand, were, at least in part, facilitated by the opening of fractures at the head of moving f lank sector, although the eruptions were significantly dissimilar from one another. Renewed inflation of the volcano after the 2004–2005 eruption, continued displacement of the unstable f lank sector, and gradual resumption of summit activity in late-2005, demonstrate that the same feedback mechanisms continue to be active, and the Etna system remains highly unstable. The evolution of earlier eruptive cycles shows that a return to a state of relative stability is only possible once a voluminous f lank eruption effectively drains the magmatic plumbing system.
    Description: Published
    Description: 85–114
    Description: reserved
    Keywords: Mount Etna ; eruptive cycle ; volcano monitoring ; seismicity ; deformation ; geochemistry ; structural geology ; magma storage ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 04. Solid Earth::04.01. Earth Interior::04.01.02. Geological and geophysical evidences of deep processes ; 04. Solid Earth::04.03. Geodesy::04.03.06. Measurements and monitoring
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 8
    Publication Date: 2017-04-04
    Description: The paper describes a case of a natural emission of methane from soil in an urban development area, generating a significant risk for the local population and buildings, due to gas explosiveness and asphyxiation potential. The site is located on the south-western margin of the East-European Platform in eastern Romania, in a hydrocarbon-prone area crossed by the Pericarpathian lineament and regional faults. Molecular composition of gas and stable isotopic analyses of methane (CH4〉90%, δ to the power of 13 C1: -49.4‰, δD1: -173.4‰) indicate a dominant thermogenic origin, with significant amounts of C2-C5 alkanes (~5%), likely migrating through faults from a deep reservoir. Possible candidates are the Saucesti and Secuieni gas fields, located in the same petroleum system. Two surface geochemical surveys, based on closed-chamber flux measurements, were performed to assess the degassing intensity and the extent of the affected area. Methane fluxes from soil reach orders of 10 to the power of 4 mg m to the power of -2 day to the power of -1. Gas seepage mainly occurs in one zone 30 000 m2 wide, and it is likely controlled by channeling along a fault and gas accumulation in permeable sediments and shallow subsoil. The estimated total CH4 emission is about 40 t year to the power of -1 CH4, of which 8–9 t year to the power of -1 are naturally released from soil and 30–35 t year to the power of -1 are emitted from shallow boreholes. These wells have likely channeled the gas accumulated in shallow alluvial sediment but gas flux from soil is still high and mitigation measures are needed to reduce the risk for humans and buildings.
    Description: Published
    Description: 311-320
    Description: 3.8. Geofisica per l'ambiente
    Description: JCR Journal
    Description: reserved
    Keywords: gas hazard ; methane seepage ; soil degassing ; thermogenic gas ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2017-04-04
    Description: An extensive geochemical survey of the fluids released by the volcanic/geothermal system of Methana was undertaken. Gases were characterized based on the chemical and isotopic [helium (He) and carbon (C)] analysis of 27 samples. Carbon dioxide soil gas concentration and fluxes were measured at 179 sampling sites throughout the peninsula. Forty samples of thermal and cold groundwaters were also sampled and analysed to characterize the geochemistry of the aquifers. Gases of hydrothermal origin gave a preliminary geothermometric estimate of about 210 °C. The He-isotope composition indicated mantle contributions of up to 40%, and the C-isotope composition of CO2 indicated that it predominantly (〉90%) originated from limestone decomposition. The groundwater composition was suggestive of mixing between meteoric and hydrothermally modified sea-water endmembers and water–rock interaction processes limited to simple rock dissolution driven by an increased endogenous CO2 content. All of the thermal manifestations and anomalous degassing areas, although of limited extent, were spatially correlated with the main active tectonic system of the area. The total CO2 output of the volcanic system has been preliminary estimated to be less than 0.05 kg s–1. Although this value is very low compared to those of other volcanic systems, anomalous CO2 degassing at Methana – which is currently restricted to limited areas and at present is the only volcanic risk of the peninsula – is a potential gas hazard that warrants further assessment in future studies.
    Description: Published
    Description: 818-828
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: Methana ; south Aegean volcanic arc ; fluids geochemistry ; soil gases ; groundwaters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.02. Exploration geophysics::04.02.01. Geochemical exploration ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 04. Solid Earth::04.08. Volcanology::04.08.08. Volcanic risk
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 10
    Publication Date: 2017-04-04
    Description: On February 27, 2007 a new eruption started at Stromboli that lasted until April 2 and included a paroxysmal explosion on March 15. Geochemical monitoring carried out over several years revealed some appreciable variations that preceded both the eruption onset and the explosion. The carbon dioxide (CO2) flux from the soil at Pizzo Sopra La Fossa markedly increased a few days before the eruption onset, and continued during lava effusion to reach its maximum value (at 90,000 g m−2 d−1) a few days before the paroxysm. Almost contemporarily, the δ13CCO2 of the SC5 fumarole located in the summit area increased markedly, peaking just before the explosion (δ13CCO2~−1.8‰). Following the paroxysm, helium (He) isotopes measured in the gases dissolved in the basal thermal aquifer sharply increased. Almost contemporarily, the automatic station of CO2 flux recorded an anomalous degassing rate. Also temperatures and the vertical thermal gradient, which had been measured since November 2006 in the soil at Pizzo Sopra La Fossa, showed appreciable variabilities that lasted until the end of the eruption. The geochemical variations indicated the degassing of a new batch of volatile-rich magma that preceded and probably fed the paroxysm. The anomalous 3He/4He ratio suggested that the ascent of a second batch of volatile-rich magma toward the surface was probably responsible of the resumption of the ordinary activity. A comparison with the geochemical variations observed during the 2002–2003 eruption indicated that the 2007 eruption was less energetic.
    Description: Published
    Description: 246-254
    Description: 1.2. TTC - Sorveglianza geochimica delle aree vulcaniche attive
    Description: JCR Journal
    Description: reserved
    Keywords: geochemistry ; eruption ; dissolved gases ; Stromboli ; volcanic activity ; 03. Hydrosphere::03.02. Hydrology::03.02.03. Groundwater processes ; 03. Hydrosphere::03.04. Chemical and biological::03.04.03. Chemistry of waters ; 03. Hydrosphere::03.04. Chemical and biological::03.04.05. Gases ; 03. Hydrosphere::03.04. Chemical and biological::03.04.06. Hydrothermal systems ; 04. Solid Earth::04.04. Geology::04.04.12. Fluid Geochemistry ; 04. Solid Earth::04.08. Volcanology::04.08.01. Gases ; 04. Solid Earth::04.08. Volcanology::04.08.06. Volcano monitoring ; 05. General::05.02. Data dissemination::05.02.01. Geochemical data ; 05. General::05.02. Data dissemination::05.02.03. Volcanic eruptions
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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