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  • American Geophysical Union  (321)
  • Nature Publishing Group
  • Springer Nature
  • 2020-2023  (362)
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  • 1
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125(6), (2020): e2019JB019239, doi:10.1029/2019JB019239.
    Description: P‐to‐S‐converted waves observed in controlled‐source multicomponent ocean bottom seismometer (OBS) records were used to derive the Vp/Vs structure of Cascadia Basin sediments. We used P‐to‐S waves converted at the basement to derive an empirical function describing the average Vp/Vs of Cascadia sediments as a function of sediment thickness. We derived one‐dimensional interval Vp/Vs functions from semblance velocity analysis of S‐converted intrasediment and basement reflections, which we used to define an empirical Vp/Vs versus burial depth compaction trend. We find that seaward from the Cascadia deformation front, Vp/Vs structure offshore northern Oregon and Washington shows little variability along strike, while the structure of incoming sediments offshore central Oregon is more heterogeneous and includes intermediate‐to‐deep sediment layers of anomalously elevated Vp/Vs. These zones with elevated Vp/Vs are likely due to elevated pore fluid pressures, although layers of high sand content intercalated within a more clayey sedimentary sequence, and/or a higher content of coarser‐grained clay minerals relative to finer‐grained smectite could be contributing factors. We find that the proto‐décollement offshore central Oregon develops within the incoming sediments at a low‐permeability boundary that traps fluids in a stratigraphic level where fluid overpressure exceeds 50% of the differential pressure between the hydrostatic pressure and the lithostatic pressure. Incoming sediments with the highest estimated fluid overpressures occur offshore central Oregon where deformation of the accretionary prism is seaward vergent. Conversely, landward vergence offshore northern Oregon and Washington correlates with more moderate pore pressures and laterally homogeneous Vp/Vs functions of Cascadia Basin sediments.
    Description: This research was funded by National Science Foundation (NSF) Grant OCE‐1657237 to J. P. C, OCE‐1657839 to A. F. A. and S. H., and OCE‐1657737 to S. M. C. Data used in this study were acquired with funding from NSF Grants OCE‐1029305 and OCE‐1249353. Data used in this research were provided by instruments from the Ocean Bottom Seismic Instrument Center (http://obsic.whoi.edu, formerly OBSIP), which is funded by the NSF. OBSIC/OBSIP data are archived at the IRIS Data Management Center (http://www.iris.edu) under network code X6 (https://doi.org/10.7914/SN/X6_2012). Data processing was conducted with Emerson‐Paradigm Software package Echos licensed to Woods Hole Oceanographic Institution under Paradigm Academic Software Program and MATLAB package SeismicLab of the University of Alberta, Canada (http://seismic-lab.physics.ualberta.ca), under GNU General Public License (MATLAB® is a registered trademark of MathWorks).
    Description: 2020-11-28
    Keywords: Vp/Vs ; sediments ; ocean bottom seismometer ; Juan de Fuca plate ; Cascadia
    Repository Name: Woods Hole Open Access Server
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  • 2
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016068, doi:10.1029/2020JC016068.
    Description: Labrador Sea Water (LSW) is a major component of the deep limb of the Atlantic Meridional Overturning Circulation, yet LSW transport pathways and their variability lack a complete description. A portion of the LSW exported from the subpolar gyre is advected eastward along the North Atlantic Current and must contend with the Mid‐Atlantic Ridge before reaching the eastern basins of the North Atlantic. Here, we analyze observations from a mooring array and satellite altimetry, together with outputs from a hindcast ocean model simulation, to estimate the mean transport of LSW across the Charlie‐Gibbs Fracture Zone (CGFZ), a primary gateway for the eastward transport of the water mass. The LSW transport estimated from the 25‐year altimetry record is 5.3 ± 2.9 Sv, where the error represents the combination of observational variability and the uncertainty in the projection of the surface velocities to the LSW layer. Current velocities modulate the interannual to higher‐frequency variability of the LSW transport at the CGFZ, while the LSW thickness becomes important on longer time scales. The modeled mean LSW transport for 1993–2012 is higher than the estimate from altimetry, at 8.2 ± 4.1 Sv. The modeled LSW thickness decreases substantially at the CGFZ between 1996 and 2009, consistent with an observed decline in LSW volume in the Labrador Sea after 1994. We suggest that satellite altimetry and continuous hydrographic measurements in the central Labrador Sea, supplemented by profiles from Argo floats, could be sufficient to quantify the LSW transport at the CGFZ.
    Description: A. G. N. appreciates conversations with Kathy Donohue, Tom Rossby and Lisa Beal, which helped to interpret the results. J. B. P. acknowledges support from NSF through Grant OCE‐1947829. The authors thank all colleagues and ship crew involved in the R/V Meteor cruise M‐82/2 and Maria S. Merian cruise MSM‐21/2. The mooring data presented in this paper were funded by NSF through Grant OCE‐0926656.
    Description: 2021-01-03
    Repository Name: Woods Hole Open Access Server
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  • 3
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(3), (2020): e2019GL086703, doi:10.1029/2019GL086703.
    Description: Salt marsh assessments focus on vertical metrics such as accretion or lateral metrics such as open‐water conversion, without exploration of how the dimensions are related. We exploited a novel geospatial data set to explore how elevation is related to the unvegetated‐vegetated marsh ratio (UVVR), a lateral metric, across individual marsh “units” within four estuarine‐marsh systems. We find that elevation scales consistently with the UVVR across systems, with lower elevation units demonstrating more open‐water conversion and higher UVVRs. A normalized elevation‐UVVR relationship converges across systems near the system‐mean elevation and a UVVR of 0.1, a critical threshold identified by prior studies. This indicates that open‐water conversion becomes a dominant lateral instability process at a relatively conservative elevation threshold. We then integrate the UVVR and elevation to yield lifespan estimates, which demonstrate that higher elevation marshes are more resilient to internal deterioration, with an order‐of‐magnitude longer lifespan than predicted for lower elevation marshes.
    Description: This study was supported by the USGS through the Coastal Marine Hazards/Resources Program, the National Park Service through the Natural Resource Preservation Program, and the U.S. Fish and Wildlife Service through the Science Support Partnership. Erika Lentz, Elizabeth Pendleton, Meagan Gonneea, Joel Carr, and two anonymous reviewers provided constructive advice on the study. S.F. was partly supported by US National Science Foundation award 1637630 (PIE LTER), 1832221 (VCR LTER). The geospatial data used in this study are published in the Coastal Wetlands Synthesis Products catalog on ScienceBase (https://www.sciencebase.gov/catalog/item/5b73325ee4b0f5d5787c5ff3).
    Repository Name: Woods Hole Open Access Server
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  • 4
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research- Biogeosciences 125(4), (2020): e2019JG005158, doi:10.1029/2019JG005158.
    Description: Long‐term soil warming can decrease soil organic matter (SOM), resulting in self‐reinforcing feedback to the global climate system. We investigated additional consequences of SOM reduction for soil water holding capacity (WHC) and soil thermal and hydrological buffering. At a long‐term soil warming experiment in a temperate forest in the northeastern United States, we suspended the warming treatment for 104 days during the summer of 2017. The formerly heated plot remained warmer (+0.39 °C) and drier (−0.024 cm3 H2O cm−3 soil) than the control plot throughout the suspension. We measured decreased SOM content (−0.184 g SOM g−1 for O horizon soil, −0.010 g SOM g−1 for A horizon soil) and WHC (−0.82 g H2O g−1 for O horizon soil, −0.18 g H2O g−1 for A horizon soil) in the formerly heated plot relative to the control plot. Reduced SOM content accounted for 62% of the WHC reduction in the O horizon and 22% in the A horizon. We investigated differences in SOM composition as a possible explanation for the remaining reductions with Fourier transform infrared (FTIR) spectra. We found FTIR spectra that correlated more strongly with WHC than SOM, but those particular spectra did not differ between the heated and control plots, suggesting that SOM composition affects WHC but does not explain treatment differences in this study. We conclude that SOM reductions due to soil warming can reduce WHC and hydrological and thermal buffering, further warming soil and decreasing SOM. This feedback may operate in parallel, and perhaps synergistically, with carbon cycle feedbacks to climate change.
    Description: We would like to acknowledge Jeffery Blanchard, Priya Chowdhury, Kristen DeAngelis, Luiz Dominguez‐Horta, Kevin Geyer, Rachelle Lacroix, Xaiojun Liu, William Rodriguez, and Alexander Truchonand and for assistance with field sampling. We would like to acknowledge Michael Bernard for assistance with field sampling and lab work. We would like to acknowledge Aaron Ellison for statistical consultation. This research was financially supported by the U.S. National Science Foundation's Long Term Ecological Research Program (NSF‐DEB‐0620443 and NSF‐DEB‐1237491), the Long Term Research in Environmental Biology Program (NSF DEB‐1456528) , and the U.S. Department of Energy (DOE‐DE‐SC0005421 and DOE‐DE‐SC0010740). Data used in this study are available from the Harvard Forest Data Archive (Datasets HF018‐03, HF018‐04, and HF018‐13), accessible at https://harvardforest.fas.harvard.edu/harvard‐forest‐data‐archive.
    Description: 2020-10-04
    Repository Name: Woods Hole Open Access Server
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  • 5
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016445, doi:10.1029/2020JC016445.
    Description: The Mid‐Atlantic Bight (MAB) Cold Pool is a bottom‐trapped, cold (temperature below 10°C) and fresh (practical salinity below 34) water mass that is isolated from the surface by the seasonal thermocline and is located over the midshelf and outer shelf of the MAB. The interannual variability of the Cold Pool with regard to its persistence time, volume, temperature, and seasonal along‐shelf propagation is investigated based on a long‐term (1958–2007) high‐resolution regional model of the northwest Atlantic Ocean. A Cold Pool Index is defined and computed in order to quantify the strength of the Cold Pool on the interannual timescale. Anomalous strong, weak, and normal years are categorized and compared based on the Cold Pool Index. A detailed quantitative study of the volume‐averaged heat budget of the Cold Pool region (CPR) has been examined on the interannual timescale. Results suggest that the initial temperature and abnormal warming/cooling due to advection are the primary drivers in the interannual variability of the near‐bottom CPR temperature anomaly during stratified seasons. The long persistence of temperature anomalies from winter to summer in the CPR also suggests a potential for seasonal predictability.
    Description: This work was funded by the National Oceanic and Atmospheric Administration through Awards NOAA‐NA‐15OAR4310133 and NOAA‐NA‐13OAR4830233 and the National Science Foundation Awards OCE‐1049088, OCE‐1419584, and OCE‐0961545.
    Description: 2021-02-03
    Keywords: Mid‐Atlantic Bight ; Cold Pool ; continental shelf ; temperature balance ; interannual variability ; near‐bottom temperature
    Repository Name: Woods Hole Open Access Server
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  • 6
    Publication Date: 2022-05-25
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ferrer-González, F. X., Widner, B., Holderman, N. R., Glushka, J., Edison, A. S., Kujawinski, E. B., & Moran, M. A. Resource partitioning of phytoplankton metabolites that support bacterial heterotrophy. ISME Journal, (2020), doi:10.1038/s41396-020-00811-y.
    Description: The communities of bacteria that assemble around marine microphytoplankton are predictably dominated by Rhodobacterales, Flavobacteriales, and families within the Gammaproteobacteria. Yet whether this consistent ecological pattern reflects the result of resource-based niche partitioning or resource competition requires better knowledge of the metabolites linking microbial autotrophs and heterotrophs in the surface ocean. We characterized molecules targeted for uptake by three heterotrophic bacteria individually co-cultured with a marine diatom using two strategies that vetted the exometabolite pool for biological relevance by means of bacterial activity assays: expression of diagnostic genes and net drawdown of exometabolites, the latter detected with mass spectrometry and nuclear magnetic resonance using novel sample preparation approaches. Of the more than 36 organic molecules with evidence of bacterial uptake, 53% contained nitrogen (including nucleosides and amino acids), 11% were organic sulfur compounds (including dihydroxypropanesulfonate and dimethysulfoniopropionate), and 28% were components of polysaccharides (including chrysolaminarin, chitin, and alginate). Overlap in phytoplankton-derived metabolite use by bacteria in the absence of competition was low, and only guanosine, proline, and N-acetyl-d-glucosamine were predicted to be used by all three. Exometabolite uptake pattern points to a key role for ecological resource partitioning in the assembly marine bacterial communities transforming recent photosynthate.
    Description: This work was supported by grants from the Gordon and Betty Moore Foundation (5503) and the National Science Foundation (IOS-1656311) to MAM, ASE, and EBK, and by the Simons Foundation grant 542391 to MAM within the Principles of Microbial Ecosystems (PriME) Collaborative.
    Repository Name: Woods Hole Open Access Server
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  • 7
    Publication Date: 2022-05-25
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016197, doi:10.1029/2020JC016197.
    Description: Synoptic shipboard measurements, together with historical hydrographic data and satellite data, are used to elucidate the detailed structure of the Atlantic Water (AW) boundary current system in the southern Canada Basin and its connection to the upstream source of AW in the Chukchi Borderland. Nine high‐resolution occupations of a transect extending from the Beaufort shelf to the deep basin near 152°W, taken between 2003 and 2018, reveal that there are two branches of the AW boundary current that flow beneath and counter to the Beaufort Gyre. Each branch corresponds to a warm temperature core and transports comparable amounts of Fram Strait Branch Water between roughly 200–700 m depth, although they are characterized by a different temperature/salinity (T/S) structure. The mean volume flux of the combined branches is 0.87 ± 0.13 Sv. Using the historical hydrographic data, the two branches are tracked upstream by their temperature cores and T/S signatures. This sheds new light on how the AW negotiates the Chukchi Borderland and why two branches emerge from this region. Lastly, the propagation of warm temperature anomalies through the region is quantified and shown to be consistent with the deduced circulation scheme.
    Description: This work was funded by the following sources: National Science Foundation Grants PLR‐1504333, OPP‐1733564, and OPP‐1504394; National Oceanic and Atmospheric Administration Grant NA14OAR4320158; and National Aeronautics and Space Administration Grant NNX10AF42G.
    Description: 2021-01-27
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  • 8
    Publication Date: 2022-03-16
    Description: Of all the socio-economic changes caused by the Covid-19 pandemic, the disruption to workforce organizations will probably leave the largest indelible mark. The way work will be organized in the future will be closely linked to the experience of work-ing under the same institution’s response to the pandemic. This paper aims to fill the gap in knowledge about smart working (SW) in public organizations, with a focus on the experience of the employees of two Italian research organizations, CNR and INGV. Analysing primary data, it explored and assessed how SW had been experi-enced following the implementation of governmental measures aimed at limiting the spread of COVID-19
    Description: Published
    Description: 815–833
    Description: 2TM. Divulgazione Scientifica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 9
    Publication Date: 2022-03-16
    Description: Data visualization, and to a lesser extent data sonification, are classic tools to the scientific community. However, these two approaches are very rarely combined, although they are highly complementary: our visual system is good at recognizing spatial patterns, whereas our auditory system is better tuned for temporal patterns. In this article, data representation methods are proposed that combine visualization, sonification, and spatial audio techniques, in order to optimize the user’s perception of spatial and temporal patterns in a single display, to increase the feeling of immersion, and to take advantage of multimodal integration mechanisms. Three seismic data sets are used to illustrate the methods, covering different physical phenomena, time scales, spatial distributions, and spatio-temporal dynamics. The methods are adapted to the specificities of each data set, and to the amount of information that the designer wants to display. This leads to further developments, namely the use of audification with two time scales, the switch from pure audification to time-modulated noise, and the switch from pure audification to sonic icons. First user feedback from live demonstrations indicates that the methods presented in this article seem to enhance the perception of spatio-temporal patterns, which is a key parameter to the understanding of seismically active systems, and a step towards apprehending the processes that drive this activity.
    Description: Published
    Description: 125–142
    Description: 7T. Variazioni delle caratteristiche crostali e "precursori"
    Description: JCR Journal
    Keywords: 04.06. Seismology
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  • 10
    Publication Date: 2022-02-21
    Description: The stability of the West Antarctic Ice Sheet is threatened by the incursion of warm Circumpolar Deepwater which flows southwards via cross-shelf troughs towards the coast there melting ice shelves. However, the onset of this oceanic forcing on the development and evolution of the West Antarctic Ice Sheet remains poorly understood. Here, we use single- and multichannel seismic reflection profiles to investigate the architecture of a sediment body on the shelf of the Amundsen Sea Embayment. We estimate the formation age of this sediment body to be around the Eocene-Oligocene Transition and find that it possesses the geometry and depositional pattern of a plastered sediment drift. We suggest this indicates a southward inflow of deep water which probably supplied heat and, thus, prevented West Antarctic Ice Sheet advance beyond the coast at this time. We conclude that the West Antarctic Ice Sheet has likely experienced a strong oceanic influence on its dynamics since its initial formation.
    Repository Name: EPIC Alfred Wegener Institut
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  • 11
    Publication Date: 2022-01-07
    Description: Vegetation biomass is a globally important climate-relevant terrestrial carbon pool. Landsat, Sentinel-2 and Sentinel-1 satellite missions provide a landscape-level opportunity to upscale tundra vegetation communities and biomass in high latitude terrestrial environments. We assessed the applicability of landscape-level remote sensing for the low Arctic Lena Delta region in Northern Yakutia, Siberia, Russia. The Lena Delta is the largest delta in the Arctic and is located North of the treeline and the 10 °C July isotherm at 72° Northern Latitude in the Laptev Sea region. During the LENA2018 expedition, we set up plots for plant projective cover and Above Ground Biomass (AGB) and sampled shrubs for shrub-ring analyses. AGB is providing the magnitude of the carbon flux, whereas stand age is irreplaceable to provide the cycle rate. AGB data and shrub age data clearly show a separation between i) low disturbance landscape types with dominant AGB moss contribution, but always low vascular plant AGB (〈0.5 kg m-2) characterised by old shrubs of several decades of stand age versus ii) a much higher vascular plant AGB contribution (〉 0.5 kg m-2) with only young shrubs in high disturbance regimes. The low disturbance regimes are represented on the Holocene and Pleistocene delta terraces in form of azonal polygonal tundra complexes and softly dissected valleys with zonal tussock tundra. In contrast, the high disturbance regimes are sites of thermo-erosion such as along thermo-erosional valleys and on floodplains. We upscaled AGB and above ground carbon pool ages using a Sentinel-2 satellite acquisition from early August 2018. We classified via classification training using Elementary Sampling Units that are the 30 m x 30 m vegetation field plots. We then used the land cover classes and grouped them according to their settings either in high disturbance or low disturbance regimes with each associated AGB value ranges and shrub age regimes. We also evaluated circum-Arctic harmonized ESA GlobPermafrost land cover and vegetation height remote sensing products covering subarctic to Arctic land cover types for the central Lena Delta. The products are freely available and published in the PANGAEA data repository under https://doi.org/10.1594/PANGAEA.897916 and https://doi.org/10.1594/PANGAEA.897045. ESA GlobPermafrost land cover and vegetation height remote sensing products and our Sentinel-2 derived AGB product for the central Lena Delta shows realistic spatial patterns of landcover classes and biomass distribution at landscape level. However, in all products, the high biomass patches of high shrubs in the tundra landscape could not spatially be resolved as they are confined to patchy and linear distribution, not representing large enough areas suitable for upscaling. We found that high disturbance regimes with linked high and rapid AGB fluxes are distributed mainly on the floodplains and as patches along thermoerosioal features, e.g. valleys. Whereas the low disturbance landscapes on Yedoma upland tundra and Holocene terraces occur with larger area coverage representing decades slower and in magnitude smaller AGB fluxes.
    Repository Name: EPIC Alfred Wegener Institut
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  • 12
    Publication Date: 2021-11-03
    Description: Short-term earthquake clustering properties in the Eastern Aegean Sea (Greece) area investigated through the application of an epidemic type stochastic model (Epidemic Type Earthquake Sequence; ETES). The computations are performed in an earthquake catalog covering the period 2008 to 2020 and including 2332 events with a completeness threshold of Mc = 3.1 and separated into two subcatalogs. The first subcatalog is employed for the learning period, which is between 2008/01/01 and 2016/12/31 (N = 1197 earthquakes), and used for the model’s parameters estimation. The second subcatalog from 2017/01/01 to 2020/11/10 (1135 earthquakes), in which the sequences of 2017 Mw = 6.4 Lesvos, 2017 Mw = 6.6 Kos and 2020 Mw = 7.0 Samos main shocks are included, and used for a retrospective forecast testing based on the constructed model. The estimated model parameters imply a swarm like behavior, indicating the ability of earthquakes of small to moderate magnitude above Mc to produce their own offsprings, along with the stronger earthquakes. The retrospective evaluation of the model is examined in the three aftershock sequences, where lack of foreshocks resulted in low predictability of the mainshocks, with estimated daily probabilities around 10– 5. Immediately after the mainshocks occurrence the model adjusts with notable resemblance between the expected and observed aftershock rates, particularly for earthquakes with M ≥ 3.5.
    Description: Published
    Description: 1085–1099
    Description: 6T. Studi di pericolosità sismica e da maremoto
    Description: JCR Journal
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  • 13
    Publication Date: 2021-11-29
    Description: This work presents an up-to-date model for the simulation of non-stationary ground motions, including several novelties compared to the original study of Sabetta and Pugliese (Bull Seism Soc Am 86:337–352, 1996). The selection of the input motion in the framework of earthquake engineering has become progressively more important with the growing use of nonlinear dynamic analyses. Regardless of the increasing availability of large strong motion databases, ground motion records are not always available for a given earthquake scenario and site condition, requiring the adoption of simulated time series. Among the different techniques for the generation of ground motion records, we focused on the methods based on stochastic simulations, considering the time- frequency decomposition of the seismic ground motion. We updated the non-stationary stochastic model initially developed in Sabetta and Pugliese (Bull Seism Soc Am 86:337–352, 1996) and later modified by Pousse et al. (Bull Seism Soc Am 96:2103–2117, 2006) and Laurendeau et al. (Nonstationary stochastic simulation of strong ground-motion time histories: application to the Japanese database. 15 WCEE Lisbon, 2012). The model is based on the S-transform that implicitly considers both the amplitude and frequency modulation. The four model parameters required for the simulation are: Arias intensity, significant duration, central frequency, and frequency bandwidth. They were obtained from an empirical ground motion model calibrated using the accelerometric records included in the updated Italian strong-motion database ITACA. The simulated accelerograms show a good match with the ground motion model prediction of several amplitude and frequency measures, such as Arias intensity, peak acceleration, peak velocity, Fourier spectra, and response spectra.
    Description: Published
    Description: 3287–3315
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
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  • 14
    Publication Date: 2021-12-01
    Description: Probabilistic earthquake locations provide confidence intervals for the hypocentre solutions such as errors encountered in the position, the origin time, and in magnitude. If the relationship of the parameters relative to the local arrangement of the seismic network is considered, such as the node distance, the number of stations, the seismic gap, and the quality of phase readings), the uncertainties can then provide insights on the location capability of the network. In this paper, we collect the earthquake data recorded from the Italian Seismic Network for a time span of 5 years. The data pertain to three different catalogues according to the progressive refinement phases of the location procedure: automatic location, revised location, and published location. By means of spatial analysis,we assess the distribution of the location-related and network-related estimators across the study area. These estimators are subsequently combined to assess the existence of spatial correlations at a local scale. The results indicate that the Italian network is generally able to provide robust locations at the national scale and for smaller earthquakes, and the elongated shape of Italy (and of its network) does not cause systematic bias in the locations. However, we highlight the existence of subregions in which the performance of the network is weaker. At present, a unique 2D, 3-layer velocity model is used for the earthquake location procedure, and this could represent the main limitation for the improvement of the locations. Therefore, the assessment of locally optimized velocity models is the priority for the homogenization and the improvement of the Italian Seismic Network performance.
    Description: Published
    Description: 1061–1076
    Description: 1IT. Reti di monitoraggio e sorveglianza
    Description: JCR Journal
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  • 15
    Publication Date: 2021-12-06
    Description: This paper provides a new contribution to the construction of the complex and fragmentary mosaic of the Late Holocene earthquakes history of the İznik segment of the central strand of the North Anatolian Fault (CNAF) in Turkey. The CNAF clearly displays lower dextral slip rates with respect to the northern strand however, surface rupturing and large damaging earthquakes (M 〉 7) occurred in the past, leaving clear signatures in the built and natural environments. The association of these historical events to specific earthquake sources (e.g., Gemlik, İznik, or Geyve fault segments) is still a matter of debate. We excavated two trenches across the İznik fault trace near Mustafali, a village about 10 km WSW of İznik where the morphological fault scarp was visible although modified by agricultural activities. Radiocarbon and TL dating on samples collected from the trenches show that the displaced deposits are very recent and span the past 2 millennia at most. Evidence for four surface faulting events was found in the Mustafali trenches. The integration of these results with historical data and previous paleoseismological data yields an updated Late Holocene history of surface-rupturing earthquakes along the İznik Fault in 1855, 740 (715), 362, and 121 CE. Evidence for the large M7 + historical earthquake dated 1419 CE generally attributed to this fault, was not found at any trench site along the İznik fault nor in the subaqueous record. This unfit between paleoseismological, stratigraphic, and historical data highlights one more time the urge for extensive paleoseismological trenching and offshore campaigns because of the high potential to solve the uncertainties on the seismogenic history (age, earthquake location, extent of the rupture and size) of this portion of NAFZ and especially on the attribution of historical earthquakes to the causative fault.
    Description: Published
    Description: 115–128
    Description: 2T. Deformazione crostale attiva
    Description: N/A or not JCR
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  • 16
    Publication Date: 2022-02-10
    Description: Muography represents a recent and innovative tool for investigating the interior of active volcanoes. However, when dealing with frequently erupting open-vent volcanoes such as Stromboli, any result should take into con- sideration the structural and morphology changes caused by the eruptive activity. This may cause either summit collapses by magma withdrawal, or morphology growth by the accumulations of a fallout from the explosive activity, or more often a combination of both. In this chapter, we present an integration of various techniques, comprising muography and digital elevation model reconstruction, together with GBInSAR ground deformation and volcano seismicity, to reconstruct the geometry of the shallow magma supply system of the volcano and its changes in time. We show how muography can display the interior of the volcano as well as its outer growth, being sensitive to all volume changes that occurred between the framed surface and the detector. This was discovered in Stromboli by comparing digital topography in the interval between 2010 and 2012, when the rapid growth of the volcano summit by the accumulation of ballistic products in the area between the crater zone and the muon detec- tor occurred. This deposit, together with the filling in of the graben-like depression, formed during the 2007 eruption, by fallout during the persistent explosive activity, contributed to generating a remarkable anomaly in the summit area of the volcano visualized by muography. In addition, the shallow feeding system of the volcano was surveyed by GBInSAR and seismicity, which allowed us to reconstruct its path up to a depth of a few hundred meters.
    Description: Published
    Description: 75-91
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Keywords: Stromboli volcano ; Shallow supply system ; Muography of active volcanoes
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book chapter
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  • 17
    Publication Date: 2021-11-29
    Description: In this paper the site categorization criteria and the corresponding site amplification factors proposed in the 2021 draft of Part 1 of Eurocode 8 (2021-draft, CEN/TC250/SC8 Working Draft N1017) are first introduced and compared with the current version of Eurocode 8, as well as with site amplification factors from recent empirical ground motion prediction equations. Afterwards, these values are checked by two approaches. First, a wide dataset of strong motion records is built, where recording stations are classified according to 2021-draft, and the spectral amplifications are empirically estimated computing the site-to-site residuals from regional and global ground motion models for reference rock conditions. Second, a comprehensive parametric numerical study of one-dimensional (1D) site amplification is carried out, based on randomly generated shear-wave velocity profiles, classified according to the new criteria. A reasonably good agreement is found by both approaches. The most relevant discrepancies occur for the shallow soft soil conditions (soil category E) that, owing to the complex interaction of shear wave velocity, soil deposit thickness and frequency range of the excitation, show the largest scatter both in terms of records and of 1D numerical simulations. Furthermore, 1D numerical simulations for soft soil conditions tend to provide lower site amplification factors than 2021-draft, as well as lower than the corresponding site-to-site residuals from records, because of higher impact of non-linear (NL) site effects in the simulations. A site-specific study on NL effects at three KiK-net stations with a significantly large amount of high-intensity recorded ground motions gives support to the 2021-draft NL reduction factors, although the very limited number of recording stations allowing such analysis prevents deriving more general implications. In the presence of such controversial arguments, it is reasonable that a standard should adopt a prudent solution, with a limited reduction of the site amplification factors to account for NL soil response, while leaving the possibility to carry out site-specific estimations of such factors when sufficient information is available to model the ground strain dependency of local soil properties.
    Description: Published
    Description: 4199–4234
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: article
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  • 18
    Publication Date: 2021-11-29
    Description: ShakeMap is the tool to evaluate the ground motion effect of earthquakes in vast areas. It is useful to delimit the zones where the shaking is expected to have been most significant, for civil defense rapid response. From the earthquake engineering point of view, it can be used to infer the seismic actions on the built environment to calibrate vulnerability models or to define the reconstruction policies based on observed damage vs shaking. In the case of long-lasting seismic sequences, it can be useful to develop ShakeMap envelopes, that is, maps of the largest ground intensity among those from the ShakeMap of (selected) events of a seismic sequence, to delimit areas where the effects of the whole sequence have been of structural engineering relevance. This study introduces ShakeMap envelopes and discusses them for the central Italy 2016–2017 seismic sequence. The specific goals of the study are: (i) to compare the envelopes and the ShakeMap of the main events of the sequence to make the case for sequence-based maps; (ii) to quantify the exceedance of design seismic actions based on the envelopes; (iii) to make envelopes available for further studies and the reconstruction planning; (iv) to gather insights on the (repeated) exceedance of design seismic actions at some sites. Results, which include considerations of uncertainty in ShakeMap, show that the sequence caused exceedance of design hazard in thousands of square kilometers. The most relevant effects of the sequence are, as expected, due to the mainshock, yet seismic actions larger than those enforced by the code for structural design are found also around the epicenters of the smaller magnitude events. At some locations, the succession of ground-shaking that has excited structures, provides insights on structural damage accumulation that has likely taken place; something that is not accounted for explicitly in modern seismic design. The envelopes developed are available as supplemental material.
    Description: Published
    Description: 5391–5414
    Description: 5T. Sismologia, geofisica e geologia per l'ingegneria sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 19
    Publication Date: 2021-12-13
    Description: Analyzing seismic data to get information about earthquakes has always been a major task for seismologists and, more in general, for geophysicists. Recently, thanks to the technological development of observation systems, more and more data are available to perform such tasks. However, this data “grow up” makes “human possibility” of data processing more complex in terms of required efforts and time demanding. That is why new technological approaches such as artificial intelligence are becoming very popular and more and more exploited. In this paper, we explore the possibility of interpreting seismic waveform segments by means of pre-trained deep learning. More specifically, we apply convolutional networks to seismological waveforms recorded at local or regional distances without any pre-elaboration or filtering. We show that such an approach can be very successful in determining if an earthquake is “included” in the seismic wave image and in estimating the distance between the earthquake epicenter and the recording station.
    Description: Published
    Description: 1347–1359
    Description: 1T. Struttura della Terra
    Description: 3T. Fisica dei terremoti e Sorgente Sismica
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 20
    Publication Date: 2021-10-25
    Description: Themain climatological features of the ionospheric equivalent slab thickness (τ ) for the Northern hemispheremidlatitudes are analyzed. F2-layer peak electron density values recorded at three midlatitude ionospheric stations (Chilton 51.5° N, 0.6° W, U.K.; Roquetes 40.8° N, 0.5° E, Spain;Wallops Island 37.9° N, 75.5°W, USA) and vertical total electron content values from colocated ground-based Global Navigation Satellite System receivers are used to calculate a dataset of τ values for the last two solar cycles, considering only magnetically quiet periods. Results are presented both as grids of binned medians and as boxplots as a function of local time and month of the year, for different solar activity levels. Corresponding trends are first compared to those output by the midlatitude empirical model developed by Fox et al. (Radio Sci 26:429–438, 1991) and then discussed in the light of what is known so far. From this investigation, the strong need to implement an improved empirical model of τ has emerged. Both Space Weather and Space Geodesy applications might benefit from such model. Therefore, both the dataset and the methodology described in the paper represent a first fundamental step aimed at implementing an empirical climatological model of the ionospheric equivalent slab thickness. The study highlighted also that at midlatitudes τ shows the following main patterns: daytime values considerably smaller than nighttime ones (except in summer); well-defined maxima at solar terminator hours; a greater dispersion during nighttime and solar terminator hours; no clear and evident solar activity dependence.
    Description: Published
    Description: 124
    Description: 2A. Fisica dell'alta atmosfera
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 21
    Publication Date: 2021-11-26
    Description: The eruption of basaltic magmas dominates explosive volcanism on Earth and other planets within the Solar System. The mechanism through which continuous magma fragments into volcanic particles is central in governing eruption dynamics and the ensuing hazards. However, the mechanism of fragmentation of basaltic magmas is still disputed, with both viscous and brittle mechanisms having been proposed. Here we carry out textural analysis of the products of ten eruptions from seven volcanoes by scanning electron microscopy. We find broken crystals surrounded by intact glass that testify to the brittle fragmentation of basaltic magmas during explosive activity worldwide. We then replicated the natural textures of broken crystals in laboratory experiments where variably crystallized basaltic melt was fragmented by rapid deformation. The experiments reveal that crystals are broken by the propagation of a network of fractures through magma, and that afterwards the fractures heal by viscous flow of the melt. Fracturing and healing affect gas mobility, stress distribution, and bubble and crystal size distributions in magma. Our results challenge the idea that the grain size distribution of basaltic eruption products reflects the density of fractures that initially fragmented the magma and ultimately indicate that brittle fracturing and viscous healing of magma may underlie basaltic explosive eruptions globally.
    Description: Published
    Description: 248–254
    Description: 4V. Processi pre-eruttivi
    Description: 5V. Processi eruttivi e post-eruttivi
    Description: JCR Journal
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 22
    Publication Date: 2022-02-11
    Description: Magmatism accompanies rifting along divergent plate boundaries, although its role before continental breakup remains poorly understood. For example, the magma-assisted Northern Main Ethiopian Rift (NMER) lacks current volcanism and clear tectono-magmatic relationships with its contiguous rift portions. Here we define its magmatic behaviour, identifying the most recent eruptive fissures (EF) whose aphyric basalts have a higher Ti content than those of older monogenetic scoria cones (MSC), which are porphyritic and plagioclase-dominated. Despite these differences, calculations highlight a similar parental melt for EF and MSC products, suggesting only a different evolutionary history after melt generation. While MSC magmas underwent a further step of storage at intermediate crustal levels, EF magmas rose directly from the base of the crust without contamination, even below older polygenetic volcanoes, suggesting rapid propagation of transcrustal dikes across solidified magma chambers. Whether this recent condition in the NMER is stable or transient, it indicates a transition from central polygenetic to linear fissure volcanism, indicative of increased tensile conditions and volcanism directly fed from the base of the crust, suggesting transition towards mature rifting.
    Description: Published
    Description: 21821
    Description: 2V. Struttura e sistema di alimentazione dei vulcani
    Description: JCR Journal
    Keywords: 04.08. Volcanology
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
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  • 23
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    Springer Nature
    Publication Date: 2021-12-24
    Description: This book serves as a guide to discovering the most interesting volcano sites in Italy. Accompanied by some extraordinary contemporary images of active Neapolitan volcanoes, it explains the main volcanic processes that have been shaping the landscape of the Campania region and influencing human settlements in this area since Greek and Roman times and that have prompted leading international scientists to visit and study this natural volcanology laboratory. While volcanology is the central topic, the book also addresses other aspects related to the area’s volcanism and is divided into three sections: 1) Neapolitan volcanic activity and processes (with a general introduction to volcanology and its development around Naples together with descriptions of the landscape and the main sites worth visiting); 2) Volcanoes and their interactions with local human settlements since the Bronze Age, recent population growth and the transformation of the territory; 3) The risks posed by Neapolitan Volcanoes, their recent activity and the problem of forecasting any future eruption.
    Description: Published
    Description: 2TM. Divulgazione Scientifica
    Repository Name: Istituto Nazionale di Geofisica e Vulcanologia (INGV)
    Type: book
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  • 24
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    American Geophysical Union
    In:  EPIC3Paleoceanography and Paleoclimatology, American Geophysical Union, 37(2), pp. e2020PA003953, ISSN: 2572-4517
    Publication Date: 2022-02-15
    Description: Cenozoic climate changes have been linked to tectonic activity and variations in atmospheric CO2 concentrations. Here we present Miocene and Pliocene sensitivity experiments performed with the climate model COSMOS. The experiments contain changes with respect to paleogeography, ocean gateway configuration, and atmospheric CO2 concentrations, as well as a range of vertical mixing coefficients in the ocean. For the Mid-Miocene, we show that the impact of ocean mixing on surface temperature is comparable to the effect of the possible range in reconstructed CO2 concentrations. In combination with stronger vertical mixing, relatively moderate CO2-concentrations of 450 ppmv enable global mean surface, deep-water and meridional temperature characteristics representative of Mid-Miocene Climatic Optimum (MMCO) reconstructions. The Miocene climate shows a reduced meridional temperature gradient and reduced seasonality. In the case of enhanced mixing, surface and deep ocean temperatures show significant warming of up to 5-10°C and an Arctic temperature anomaly of more than 12°C. In the Pliocene simulations, the impact of vertical mixing and CO2 is less important for the deep ocean, which we interpret as a different sensitivity dependence on the background state and mixed layer dynamics. We find a significant reduction in surface albedo and effective emissivity for either a high level of atmospheric CO2 or increased vertical mixing. Our mixing sensitivity experiments provide a warm deep ocean via ocean heat uptake. We propose that the mixing hypothesis can be tested by reconstructions of the thermocline and seasonal paleoclimate data indicating a lower seasonality relative to today.
    Repository Name: EPIC Alfred Wegener Institut
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  • 25
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    American Geophysical Union
    In:  EPIC3American Geophysical Union Conference 2021, Hybrid Online and in New Orleans, 2021-12-13-2021-12-17AGU 2021, American Geophysical Union
    Publication Date: 2022-02-15
    Description: As air temperatures rise and sea ice cover declines in the Arctic, permafrost coastal cliffs thaw more rapidly and wave energy rises. Thus, as the open water season continues to lengthen, climate change triggers a large part of the Arctic shoreline to become increasingly vulnerable to erosion. Arctic erosion supplies nutrient-laden and carbon-rich sediment into nearshore ecosystems. A retreating coastline also has consequences for residential, cultural, and industrial infrastructure. Despite its importance, erosion is currently neglected in global climate models, and existing physics-based numerical models of Arctic shoreline erosion are too complex and regionally-focused to be applied on a pan-Arctic scale. Here, we apply our simplified numerical erosion model, ArcticBeach v1.0, to the entire Arctic coastline. ArcticBeach v1.0 has previously been shown to simulate retreat rates at two sites that differ substantially in their main mechanisms of retreat (sub-aerial erosion/thaw slumping versus notch/block erosion). The model uses heat and sediment volume balances in order to predict horizontal cliff retreat and vertical erosion of a fronting beach. It contains an erosion module that uses empirical equations to estimate cross-shore sediment transport, coupled to a storm surge module forced by wind. We present Arctic maps of regional variation in trends in 2-meter air temperature, sea ice concentration, and wind speed.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Conference , notRev
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  • 26
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    Springer Nature
    In:  EPIC3npj Climate and Atmospheric Science, Springer Nature, 4(1), ISSN: 2397-3722
    Publication Date: 2022-02-15
    Repository Name: EPIC Alfred Wegener Institut
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  • 27
    Publication Date: 2022-06-20
    Description: Between 2003-2016, the Greenland ice sheet (GrIS) was one of the largest contributors to sea level rise, as it lost about 255 Gt of ice per year. This mass loss slowed in 2017 and 2018 to about 100 Gt yr−1. Here we examine further changes in rate of GrIS mass loss, by analyzing data from the GRACE-FO (Gravity Recovery and Climate Experiment – Follow On) satellite mission, launched in May 2018. Using simulations with regional climate models we show that the mass losses observed in 2017 and 2018 by the GRACE and GRACE-FO missions are lower than in any other two year period between 2003 and 2019, the combined period of the two missions. We find that this reduced ice loss results from two anomalous cold summers in western Greenland, compounded by snow-rich autumn and winter conditions in the east. For 2019, GRACE-FO reveals a return to high melt rates leading to a mass loss of 223 ± 12 Gt month−1 during the month of July alone, and a record annual mass loss of 532 ± 58 Gt yr−1.
    Repository Name: EPIC Alfred Wegener Institut
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  • 28
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    Nature Publishing Group
    In:  EPIC3Nature Climate Change, Nature Publishing Group, 12(3), pp. 249-255
    Publication Date: 2022-06-20
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 29
    Publication Date: 2022-07-13
    Description: The stratified Chilean Comau Fjord sustains a dense population of the cold-water coral (CWC) Desmophyllum dianthus in aragonite supersaturated shallow and aragonite under- saturated deep water. This provides a rare opportunity to evaluate CWC fitness trade-offs in response to physico-chemical drivers and their variability. Here, we combined year-long reciprocal transplantation experiments along natural oceanographic gradients with an in situ assessment of CWC fitness. Following transplantation, corals acclimated fast to the novel environment with no discernible difference between native and novel (i.e. cross-transplanted) corals, demonstrating high phenotypic plasticity. Surprisingly, corals exposed to lowest ara- gonite saturation (Ωarag 〈 1) and temperature (T 〈 12.0 °C), but stable environmental condi- tions, at the deep station grew fastest and expressed the fittest phenotype. We found an inverse relationship between CWC fitness and environmental variability and propose to consider the high frequency fluctuations of abiotic and biotic factors to better predict the future of CWCs in a changing ocean.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
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  • 30
    Publication Date: 2022-08-16
    Description: The El Niño/Southern Oscillation (ENSO), the dominant driver of year-to-year climate variability in the equatorial Pacific Ocean, impacts climate pattern across the globe. However, the response of the ENSO system to past and potential future temperature increases is not fully understood. Here we investigate ENSO variability in the warmer climate of the mid-Pliocene (~3.0–3.3 Ma), when surface temperatures were ~2–3 °C above modern values, in a large ensemble of climate models—the Pliocene Model Intercomparison Project. We show that the ensemble consistently suggests a weakening of ENSO variability, with a mean reduction of 25% (±16%). We further show that shifts in the equatorial Pacific mean state cannot fully explain these changes. Instead, ENSO was suppressed by a series of off-equatorial processes triggered by a northward displacement of the Pacific intertropical convergence zone: weakened convective feedback and intensified Southern Hemisphere circulation, which inhibit various processes that initiate ENSO. The connection between the climatological intertropical convergence zone position and ENSO we find in the past is expected to operate in our warming world with important ramifications for ENSO variability.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , NonPeerReviewed
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  • 31
    Publication Date: 2022-10-27
    Description: This paper is not subject to U.S. copyright. The definitive version was published in ten Brink, U. S., Vanacore, E. A., Fielding, E. J., Chaytor, J. D., Lopez-Venegas, A. M., Baldwin, W. E., Foster, D. S., & Andrews, B. D. Mature diffuse tectonic block boundary revealed by the 2020 southwestern Puerto Rico seismic sequence. Tectonics, 41(3), (2022): e2021TC006896, https://doi.org/10.1029/2021TC006896.
    Description: Distributed faulting typically tends to coalesce into one or a few faults with repeated deformation. The progression of clustered medium-sized (≥Mw4.5) earthquakes during the 2020 seismic sequence in southwestern Puerto Rico (SWPR), modeling shoreline subsidence from InSAR, and sub-seafloor mapping by high-resolution seismic reflection profiles, suggest that the 2020 SWPR seismic sequence was distributed across several short intersecting strike-slip and normal faults beneath the insular shelf and upper slope of Guayanilla submarine canyon. Multibeam bathymetry map of the seafloor shows significant erosion and retreat of the shelf edge in the area of seismic activity as well as slope-parallel lineaments and submarine canyon meanders that typically develop over geological time. The T-axis of the moderate earthquakes further matches the extension direction previously measured on post early Pliocene (∼〉3 Ma) faults. We conclude that although similar deformation has likely taken place in this area during recent geologic time, it does not appear to have coalesced during this time. The deformation may represent the southernmost part of a diffuse boundary, the Western Puerto Rico Deformation Boundary, which accommodates differential movement between the Puerto Rico and Hispaniola arc blocks. This differential movement is possibly driven by the differential seismic coupling along the Puerto Rico—Hispaniola subduction zone. We propose that the compositional heterogeneity across the island arc retards the process of focusing the deformation into a single fault. Given the evidence presented here, we should not expect a single large event in this area but similar diffuse sequences in the future.
    Description: 2022-08-08
    Keywords: Rupture of multiple faults ; Intra-arc deformation ; Earthquake-generated submarine canyon ; Anisotropic arc composition ; Caribbean seismic hazard
    Repository Name: Woods Hole Open Access Server
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  • 32
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Donatelli, C., Kalra, T. S., Fagherazzi, S., Zhang, X., & Leonardi, N. Dynamics of marsh-derived sediments in lagoon-type estuaries. Journal of Geophysical Research: Earth Surface, 125(12), (2020): e2020JF005751, doi:10.1029/2020JF005751.
    Description: Salt marshes are valuable ecosystems that must trap sediments and accrete in order to counteract the deleterious effect of sea level rise. Previous studies have shown that the capacity of marshes to build up vertically depends on both autogenous and exogenous processes including ecogeomorphic feedbacks and sediment supply from in‐land and coastal ocean. There have been numerous efforts to quantify the role played by the sediments coming from marsh edge erosion on the resistance of salt marshes to sea level rise. However, the majority of existing studies investigating the interplay between lateral and vertical dynamics use simplified modeling approaches, and they do not consider that marsh retreat can affect the regional‐scale hydrodynamics and sediment retention in back‐barrier basins. In this study, we evaluated the fate of the sediments originating from marsh lateral loss by using high‐resolution numerical model simulations of Jamaica Bay, a small lagoonal estuary located in New York City. Our findings show that up to 42% of the sediment released during marsh edge erosion deposits on the shallow areas of the basin and over the vegetated marsh platforms, contributing positively to the sediment budget of the remaining salt marshes. Furthermore, we demonstrate that with the present‐day sediment supply from the ocean, the system cannot keep pace with sea level rise even accounting for the sediment liberated in the bay through marsh degradation. Our study highlights the relevance of multiple sediment sources for the maintenance of the marsh complex.
    Description: This study was supported by the Department of the Interior Hurricane Sandy Recovery program (ID G16AC00455, subaward to University of Liverpool). S. F. was partly supported by NSF awards 1637630 (PIE LTER) and 1832221 (VCR LTER). We thank Robert Chant from Rutgers University for sharing the hydrodynamic measurements in Jamaica Bay.
    Keywords: Marsh erosion ; Sediment recycling ; Sea level rise ; Jamaica Bay
    Repository Name: Woods Hole Open Access Server
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  • 33
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ruppel, C. D., & Waite, W. F. Timescales and processes of methane hydrate formation and breakdown, with application to geologic systems. Journal of Geophysical Research: Solid Earth, 125(8), (2020): e2018JB016459, doi:10.1029/2018JB016459.
    Description: Gas hydrate is an ice‐like form of water and low molecular weight gas stable at temperatures of roughly −10°C to 25°C and pressures of ~3 to 30 MPa in geologic systems. Natural gas hydrates sequester an estimated one sixth of Earth's methane and are found primarily in deepwater marine sediments on continental margins, but also in permafrost areas and under continental ice sheets. When gas hydrate is removed from its stability field, its breakdown has implications for the global carbon cycle, ocean chemistry, marine geohazards, and interactions between the geosphere and the ocean‐atmosphere system. Gas hydrate breakdown can also be artificially driven as a component of studies assessing the resource potential of these deposits. Furthermore, geologic processes and perturbations to the ocean‐atmosphere system (e.g., warming temperatures) can cause not only dissociation, but also more widespread dissolution of hydrate or even formation of new hydrate in reservoirs. Linkages between gas hydrate and disparate aspects of Earth's near‐surface physical, chemical, and biological systems render an assessment of the rates and processes affecting the persistence of gas hydrate an appropriate Centennial Grand Challenge. This paper reviews the thermodynamic controls on methane hydrate stability and then describes the relative importance of kinetic, mass transfer, and heat transfer processes in the formation and breakdown (dissociation and dissolution) of gas hydrate. Results from numerical modeling, laboratory, and some field studies are used to summarize the rates of hydrate formation and breakdown, followed by an extensive treatment of hydrate dynamics in marine and cryospheric gas hydrate systems.
    Description: Both authors have received nearly two decades of support from the U.S. Geological Survey's (USGS's) Energy Resources Program and the Coastal/Marine Hazards and Resources Program and from numerous DOE‐USGS Interagency Agreements, most recently DE‐FE0023495. C. R. acknowledges support from NOAA's Office of Ocean Exploration and Research (OER) under NOAA‐USGS Interagency Agreement 16‐01118.
    Keywords: Gas hydrate ; Hydrate breakdown ; Hydrate formation ; Permafrost hydrate ; Geologic systems ; Marine hydrate
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  • 34
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 126(5), (2021): e2020JG006217, https://doi.org/10.1029/2020JG006217.
    Description: It is assumed that to treat excess NO3− high soil organic matter content (%OM) is required to maintain high denitrification rates in natural or restored wetlands. However, this excess also represents a risk by increasing soil decomposition rates triggering peat collapse and wetland fragmentation. Here, we evaluated the role of %OM and temperature interactions controlling denitrification rates in eroding (Barataria Bay-BLC) and emerging (Wax Lake Delta-WLD) deltaic regions in coastal Louisiana using the isotope pairing (IPT) and N2:Ar techniques. We also assessed differences between total (direct denitrification + coupled nitrification-denitrification) and net (total denitrification minus nitrogen fixation) denitrification rates in benthic and wetland habitats with contrasting %OM and bulk density (BD). Sediment (benthic) and soil (wetland) cores were collected during summer, spring, and winter (2015–2016) and incubated at close to in-situ temperatures (30°C, 20°C, and 10°C, respectively). Denitrification rates were linearly correlated with temperature; maximum mean rates ranged from 40.1–124.1 μmol m−2 h−1 in the summer with lower rates (〈26.2 ± 5.3 μmol m−2 h−1) in the winter seasons. Direct denitrification was higher than coupled denitrification in all seasons. Denitrification rates were higher in WLD despite lower %OM, lower total N concentration, and higher BD in wetland soils. Therefore, in environments with low carbon availability, high denitrification rates can be sustained as long as NO3− concentrations are high (〉30 μM) and water temperature is 〉10°C. In coastal Louisiana, substrates under these regimes are represented by emergent supra-tidal flats or land created by sediment diversions under oligohaline conditions (〈1 ppt).
    Description: This study was supported by the NOAA-Sea Grant Program-Louisiana (Grant 2013R/E-24) to Victor H. Rivera-Monroy and Kanchan Maiti. Victor H. Rivera-Monroy was also supported by the Department of the Interior South-Central Climate Adaptation Science Center (Cooperative Agreement #G12AC00002).
    Keywords: Coastal Louisiana ; Deltaic system ; Denitrification ; Nitrate loading ; Organic matter ; Seasonal change ; Sediment and freshwater diversions
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  • 35
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2022. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 49(6), (2022): e2021GL095559, https://doi.org/10.1029/2021GL095559.
    Description: The valuable ecosystem services of salt marshes are spurring marsh restoration projects around the world. However, it is difficult to determine the final vegetated area based on physical drivers. Herein, we use a 3D fully coupled vegetation-hydrodynamic-morphological modeling system to simulate the final vegetation cover and the timescale to reach it under various forcing conditions. Marsh development in our simulations can be divided in three distinctive phases: A preparation phase characterized by sediment accumulation in the absence of vegetation, an encroachment phase in which the vegetated area grows, and an adjustment phase in which the vegetated area remains relatively constant while marsh accretes vertically to compensate for sea level rise. Sediment concentration, settling velocity, sea level rise, and tidal range each comparably affect equilibrium coverage and timescale in different ways. Our simulations show that the Unvegetated-Vegetated Ratio also relates to sediment budget in marsh development under most conditions.
    Description: This study was supported by the Department of the Interior Hurricane Sandy Recovery program (ID G16AC00455), NSF awards 1637630 (PIE LTER) and 1832221 (VCR LTER), and China Scholarship Council.
    Description: 2022-09-16
    Keywords: Marsh restoration ; Land reclamation ; COAWST ; Vegetation dynamics ; Phases of marsh development ; Expectance of marsh coverage
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  • 36
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zakem, E. J., Mahadevan, A., Lauderdale, J. M., & Follows, M. J. Stable aerobic and anaerobic coexistence in anoxic marine zones. ISME Journal, 14, (2019): 288–301, doi: 10.1038/s41396-019-0523-8.
    Description: Mechanistic description of the transition from aerobic to anaerobic metabolism is necessary for diagnostic and predictive modeling of fixed nitrogen loss in anoxic marine zones (AMZs). In a metabolic model where diverse oxygen- and nitrogen-cycling microbial metabolisms are described by underlying redox chemical reactions, we predict a transition from strictly aerobic to predominantly anaerobic regimes as the outcome of ecological interactions along an oxygen gradient, obviating the need for prescribed critical oxygen concentrations. Competing aerobic and anaerobic metabolisms can coexist in anoxic conditions whether these metabolisms represent obligate or facultative populations. In the coexistence regime, relative rates of aerobic and anaerobic activity are determined by the ratio of oxygen to electron donor supply. The model simulates key characteristics of AMZs, such as the accumulation of nitrite and the sustainability of anammox at higher oxygen concentrations than denitrification, and articulates how microbial biomass concentrations relate to associated water column transformation rates as a function of redox stoichiometry and energetics. Incorporating the metabolic model into an idealized two-dimensional ocean circulation results in a simulated AMZ, in which a secondary chlorophyll maximum emerges from oxygen-limited grazing, and where vertical mixing and dispersal in the oxycline also contribute to metabolic co-occurrence. The modeling approach is mechanistic yet computationally economical and suitable for global change applications.
    Description: We are grateful for the thorough and thoughtful comments of two anonymous reviewers. We also thank Andrew Babbin for helpful comments. EJZ was supported by the Simons Foundation (Postdoctoral Fellowship in Marine Microbial Ecology). AM was supported by the Office of Naval Research (ONR #N000-14-15-1-2555). JML was supported by U.S. National Science Foundation (NSF #OCE-1259388). MJF was supported by the Gordon and Betty Moore Foundation (GBMF #3778) and the Simons Foundation: the Simons Collaboration on Ocean Processes and Ecology (SCOPE #329108) and the Simons Collaboration on Computational Biogeochemical Modeling of Marine Ecosystems (CBIOMES #549931).
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  • 37
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ponnudurai, R., Heiden, S. E., Sayavedra, L., Hinzke, T., Kleiner, M., Hentschker, C., Felbeck, H., Sievert, S. M., Schlüter, R., Becher, D., Schweder, T., & Markert, S. Comparative proteomics of related symbiotic mussel species reveals high variability of host-symbiont interactions. ISME Journal, 14, (2019): 649–656, doi: 10.1038/s41396-019-0517-6.
    Description: Deep-sea Bathymodiolus mussels and their chemoautotrophic symbionts are well-studied representatives of mutualistic host–microbe associations. However, how host–symbiont interactions vary on the molecular level between related host and symbiont species remains unclear. Therefore, we compared the host and symbiont metaproteomes of Pacific B. thermophilus, hosting a thiotrophic symbiont, and Atlantic B. azoricus, containing two symbionts, a thiotroph and a methanotroph. We identified common strategies of metabolic support between hosts and symbionts, such as the oxidation of sulfide by the host, which provides a thiosulfate reservoir for the thiotrophic symbionts, and a cycling mechanism that could supply the host with symbiont-derived amino acids. However, expression levels of these processes differed substantially between both symbioses. Backed up by genomic comparisons, our results furthermore revealed an exceptionally large repertoire of attachment-related proteins in the B. thermophilus symbiont. These findings imply that host–microbe interactions can be quite variable, even between closely related systems.
    Description: Thanks to captain, crew, and pilots of the research vessels Atlantis (ROV Jason cruise AT26–10 in 2014) and Meteor (cruise M82–3 in 2010). We thank Jana Matulla, Sebastian Grund, and Annette Meuche for excellent technical assistance during sample preparation, MS measurements in the Orbitrap Classic, and TEM imaging preparation, respectively. We appreciate Nikolaus Leisch’s help with TEM image interpretation, Inna Sokolova’s advice on bivalve physiology, and Marie Zühlke’s support during manuscript revision. RP was supported by the EU-funded Marie Curie Initial Training Network ‘Symbiomics’ (project no. 264774) and by a fellowship of the Institute of Marine Biotechnology e.V. TH was supported by the German Research Foundation DFG (grant MA 6346/2–1 to SM). The Atlantis cruise was funded by a grant of the US National Science Foundation’s Dimensions of Biodiversity program to SMS (OCE-1136727).
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  • 38
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Miller, C. A., Holm, H. C., Horstmann, L., George, J. C., Fredricks, H. F., Van Mooy, B. A. S., & Apprill, A. Coordinated transformation of the gut microbiome and lipidome of bowhead whales provides novel insights into digestion. ISME Journal, 14, (2019): 688-701, doi: 10.1038/s41396-019-0549-y.
    Description: Whale digestion plays an integral role in many ocean ecosystems. By digesting enormous quantities of lipid-rich prey, whales support their energy intensive lifestyle, but also excrete nutrients important to ocean biogeochemical cycles. Nevertheless, whale digestion is poorly understood. Gastrointestinal microorganisms play a significant role in vertebrate digestion, but few studies have examined them in whales. To investigate digestion of lipids, and the potential contribution of microbes to lipid digestion in whales, we characterized lipid composition (lipidomes) and bacterial communities (microbiotas) in 126 digesta samples collected throughout the gastrointestinal tracts of 38 bowhead whales (Balaena mysticetus) harvested by Alaskan Eskimos. Lipidomes and microbiotas were strongly correlated throughout the gastrointestinal tract. Lipidomes and microbiotas were most variable in the small intestine and most similar in the large intestine, where microbiota richness was greatest. Our results suggest digestion of wax esters, the primary lipids in B. mysticetus prey representing more than 80% of total dietary lipids, occurred in the mid- to distal small intestine and was correlated with specific microorganisms. Because wax esters are difficult to digest by other marine vertebrates and constitute a large reservoir of carbon in the ocean, our results further elucidate the essential roles that whales and their gastrointestinal microbiotas play in the biogeochemical cycling of carbon and nutrients in high-latitude seas.
    Description: Devonshire Foundation (to CAM), Marine Mammal Center, Woods Hole Oceanographic Institution (WHOI; to CAM), WHOI Ocean Life Institute (to AA and CAM), Dalio Foundation’s Dalio Ocean Initiative (now ‘OceanX’) (to AA), National Science Foundation (OCE-1756254 and OPP-1543328 to BASVM). Samples were collected under Department of Commerce National Oceanic and Atmospheric Administration National Marine Fisheries Service permit numbers 17350-00, 17350-01, and 17350-02 to North Slope Borough Department of Wildlife Management.
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  • 39
    Publication Date: 2022-05-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Rheuban, J. E., Doney, S. C., McCorkle, D. C., & Jakuba, R. W. Quantifying the effects of nutrient enrichment and freshwater mixing on coastal ocean acidification. Journal of Geophysical Research-Oceans, 124, (2019): 9085-9100, doi: 10.1029/2019JC015556.
    Description: The U.S. Northeast is vulnerable to ocean and coastal acidification because of low alkalinity freshwater discharge that naturally acidifies the region, and high anthropogenic nutrient loads that lead to eutrophication in many estuaries. This study describes a combined nutrient and carbonate chemistry monitoring program in five embayments of Buzzards Bay, Massachusetts to quantify the effects of nutrient loading and freshwater discharge on aragonite saturation state (Ω). Monitoring occurred monthly from June 2015 to September 2017 with higher frequency at two embayments (Quissett and West Falmouth Harbors) and across nitrogen loading and freshwater discharge gradients. The more eutrophic stations experienced seasonal aragonite undersaturation, and at one site, nearly every measurement collected was undersaturated. We present an analytical framework to decompose variability in aragonite Ω into components driven by temperature, salinity, freshwater endmember mixing, and biogeochemical processes. We observed strong correlations between apparent oxygen utilization and the portion of aragonite Ω variation that we attribute to biogeochemistry. The regression slopes were consistent with Redfield ratios of dissolved inorganic carbon and total alkalinity to dissolved oxygen. Total nitrogen and the contribution of biogeochemical processes to aragonite Ω were highly correlated, and this relationship was used to estimate the likely effects of nitrogen loading improvements on aragonite Ω. Under nitrogen loading reduction scenarios, aragonite Ω in the most eutrophic estuaries could be raised by nearly 0.6 units, potentially increasing several stations above the critical threshold of 1. This analysis provides a quantitative framework for incorporating ocean and coastal acidification impacts into regulatory and management discussions.
    Description: We thank Kelly Luis, Michaela Fendrock, Will Oesterich, Sheron Luk, Marti Jeglinksi, and Tony Williams for their help with field sample collection and logistical support and Chris Neill, Lindsay Scott, Rich McHorney, and Paul Henderson for laboratory sample analysis. We also thank the Waquoit Bay National Estuarine Research Reserve for loaning their handheld water quality meters and two anonymous reviewers for their feedback on this manuscript. Financial support for this work was provided by the John D. and Catherine T. MacArthur Foundation (grant no. 14‐106159‐000‐CFP), MIT Sea Grant (subaward 5710004045) and the West Wind Foundation. The data used in this analysis can be found in the NOAA NCEI repository for carbonate chemistry measurements, the Ocean Carbon Data System at the following link: https://www.nodc.noaa.gov/ocads/data/0206206.xml.
    Keywords: Coastal Acidification ; Eutrophication
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  • 40
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology, 34, (2019): 2141-2157, doi: 10.1029/2019PA003731.
    Description: Dissolution of calcite in deep ocean sediments, which is required to balance global marine CaCO3 production and burial fluxes, is still a poorly understood process. In order to assess the mechanisms of dissolution in sediments, we analyzed four multicore tops taken along a depth transect on the Ontong‐Java Plateau. These cores were taken directly on the equator, and span water column calcite saturation states from ∼0.93 to ∼0.74, allowing us to assess the effect of dissolution on carbonate sediment composition. The top 2 cm of each multicore was sectioned and sieved to separate coccolith from foraminiferal calcite, and the %CaCO3, δ13C, Δ14C, and Mg/Ca were evaluated. The mass ratio of coccoliths to foraminifera increases by a factor of 3 as a function of water depth, reflecting the preferential dissolution of foraminifera. Carbon isotope (δ13C and Δ14C) data suggest that most dissolution takes place at the sediment‐water interface and primarily affects foraminifera. Mg/Ca analyses indicate that the Mg content of the entire foraminiferal assemblage decreases as a function of dissolution. In contrast, coccolith dissolution takes place within the sediments, rather than at the interface. Together these two processes cause coccoliths to be up to 1,000 radiocarbon years younger than foraminifera from the same depth horizon. Despite this within‐sediment coccolith dissolution flux, sediments below the calcite saturation horizon remain enriched in coccolith calcite. Combined with global seafloor hypsometry and calcium carbonate content, this enrichment suggests that globally, coccoliths may outweigh foraminifera in deep ocean sediments by a factor of 1.8.
    Description: A. V. S. thanks the NOSAMS facility and the WHOI/NOSAMS postdoc scholar program, James Funds, and the Bessette family for funding and support. A. Q. acknowledges Williams College research and travel funds. We thank the Stanley W. Watson Director's Discretionary Fund for the Picarro‐Automate analyzer. We thank Ellen Roosen at the WHOI core repository for help with sample identification and sectioning. Thanks to Gretchen Swarr and the WHOI plasma mass spectrometry facility. Finally, we thank Bill Martin and Wally Broecker for enlightening discussions on dissolution and radiocarbon dating of deep ocean sediments. All data are included as supporting information files and are archived with NOAA's World Data Service for Paleoceanography (WDS Paleo; https://www.ncdc.noaa.gov/paleo/study/28150).
    Description: 2020-05-15
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  • 41
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(1), (2020): e2019GL085378, doi:10.1029/2019GL085378.
    Description: Retrospectively comparing future model projections to observations provides a robust and independent test of model skill. Here we analyze the performance of climate models published between 1970 and 2007 in projecting future global mean surface temperature (GMST) changes. Models are compared to observations based on both the change in GMST over time and the change in GMST over the change in external forcing. The latter approach accounts for mismatches in model forcings, a potential source of error in model projections independent of the accuracy of model physics. We find that climate models published over the past five decades were skillful in predicting subsequent GMST changes, with most models examined showing warming consistent with observations, particularly when mismatches between model‐projected and observationally estimated forcings were taken into account.
    Description: Z. H. conceived the project, Z. H. and H. F. D. created the figures, and Z. H., H. F. D., T. A., and G. S. helped gather data and wrote the article text. A public GitHub repository with code used to analyze the data and generate figures and csv files containing the data shown in the figures is available online (https://github.com/hausfath/OldModels). Additional information on the code and data used in the analysis can be found in the supporting information. We would like to thank Piers Forster for providing the ensemble of observationally‐informed radiative forcing estimates. No dedicated funding from any of the authors supported this project.
    Description: 2020-06-04
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  • 42
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Liang, Y., Kwon, Y., Frankignoul, C., Danabasoglu, G., Yeager, S., Cherchi, A., Gao, Y., Gastineau, G., Ghosh, R., Matei, D., Mecking, J., V., Peano, D., Suo, L., & Tian, T. Quantification of the arctic sea ice-driven atmospheric circulation variability in coordinated large ensemble simulations. Geophysical Research Letters, 47(1), (2020): e2019GL085397, doi:10.1029/2019GL085397.
    Description: A coordinated set of large ensemble atmosphere‐only simulations is used to investigate the impacts of observed Arctic sea ice‐driven variability (SIDV) on the atmospheric circulation during 1979–2014. The experimental protocol permits separating Arctic SIDV from internal variability and variability driven by other forcings including sea surface temperature and greenhouse gases. The geographic pattern of SIDV is consistent across seven participating models, but its magnitude strongly depends on ensemble size. Based on 130 members, winter SIDV is ~0.18 hPa2 for Arctic‐averaged sea level pressure (~1.5% of the total variance), and ~0.35 K2 for surface air temperature (~21%) at interannual and longer timescales. The results suggest that more than 100 (40) members are needed to separate Arctic SIDV from other components for dynamical (thermodynamical) variables, and insufficient ensemble size always leads to overestimation of SIDV. Nevertheless, SIDV is 0.75–1.5 times as large as the variability driven by other forcings over northern Eurasia and Arctic.
    Description: The authors thank Editor Christina Patricola and two anonymous reviewers for their comprehensive and insightful comments, which have led to improved presentation of this manuscript. We acknowledge support by the Blue‐Action Project (European Union's Horizon 2020 research and innovation program, 727852, http://www.blue‐action.eu/index.php?id = 3498). The WHOI‐NCAR group is also supported by the US National Science Foundation (NSF) Office of Polar Programs Grants 1736738 and 1737377, and their computing and data storage resources, including the Cheyenne supercomputer (doi:10.5065/D6RX99HX), were provided by the Computational and Information Systems Laboratory at NCAR. NCAR is a major facility sponsored by the U.S. NSF under Cooperative Agreement 1852977. The LOCEAN‐IPSL group was granted access to the HPC resources of TGCC under the Allocation A5‐017403 made by GENCI. The SST and SIC data were downloaded from the U.K. Met Office Hadley Centre Observations Datasets (http://www.metoffice.gov.uk/hadobs/hadisst).
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  • 43
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(2), (2020): e2019GC008414, doi:10.1029/2019GC008414.
    Description: X‐ray fluorescence (XRF) core scanning of marine and lake sediments has been extensively used to study changes in past environmental and climatic processes over a range of timescales. The interpretation of XRF‐derived element ratios in paleoclimatic and paleoceanographic studies primarily considers differences in the relative abundances of particular elements. Here we present new XRF core scanning data from two long sediment cores in the Andaman Sea in the northern Indian Ocean and show that sea level related processes influence terrigenous inputs based proxies such as Ti/Ca, Fe/Ca, and elemental concentrations of the transition metals (e.g., Mn). Zr/Rb ratios are mainly a function of changes in median grain size of lithogenic particles and often covary with changes in Ca concentrations that reflect changes in biogenic calcium carbonate production. This suggests that a common process (i.e., sea level) influences both records. The interpretation of lighter element data (e.g., Si and Al) based on low XRF counts is complicated as variations in mean grain size and water content result in systematic artifacts and signal intensities not related to the Al or Si content of the sediments. This highlights the need for calibration of XRF core scanning data based on discrete sample analyses and careful examination of sediment properties such as porosity/water content for reliably disentangling environmental signals from other physical properties. In the case of the Andaman Sea, reliable extraction of a monsoon signal requires accounting for the sea level influence on the XRF data.
    Description: The staff at the Bremen Core Repository is thanked for their help with core handling and Sam Müller at the University of Kiel provided technical assistance with the XRF scanner. We thank two anonymous reviewers for their insightful comments that improved the manuscript significantly. This work was partially funded through DFG Grant HA 5751/3. P. A. and K. N.‐K. acknowledge support from UK‐IODP and Natural and Environment Research Council, UK. The authors express their thanks to all those who contributed to the success of the National Gas Hydrate Program Expedition 01 (NGHP01) and Expedition 353. The data set supporting the conclusions of this article is available in the PANGEA repository (doi: https://doi.pangaea.de/10.1594/PANGAEA.910533).
    Description: 2020-07-10
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  • 44
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 125(4), (2020): e2019JC015470, doi:10.1029/2019JC015470.
    Description: This study is to quantify the effects of mesoscale eddies on air‐sea heat fluxes and related air‐sea variables in the South China Sea. Using satellite observations of sea surface temperature (SST) and sea surface height anomaly and a high‐resolution air‐sea heat flux product for the 16‐year period from 2000 to 2015, we conducted the composite patterns of air‐sea fluxes and variables associated with anticyclonic eddies (AEs) and cyclonic eddies (CEs). It is found that the SST‐sea surface height correlations over eddies are not always positive. Only 56% of AEs are corresponded with positive SST anomalies (SSTA), that is, SST+ AEs, and 58% of CEs with negative SSTA, that is, SST− CEs. The percentage of these eddies increases with eddy amplitude and shows slight seasonal variations, higher in winter and lower in summer. Composites of SSTA, air‐sea variables, and fluxes are constructed over all eddies, including both SST+ eddies and SST− eddies. All composites show asymmetric patterns, showing that the centers (where the extrema are located) of the fluxes and variables shift westward and poleward (equatorward) relative to the AEs (CEs) cores. Besides, composites of latent heat flux (LHF), sensible heat flux (SHF), and air temperature show monopole patterns, while composites of wind speed and specific humidity show dipole patterns. For SST+ AEs, the coupling strength is 39.6 ± 6.5 W/m2 (7.2 ± 1.7 W/m2) per degree increase of SSTA for LHF (SHF). For SST− CEs, the coupling strength is 39.0 ± 2.0 W/m2 (9.0 ± 0.96 W/m2) per degree decrease of SSTA for LHF (SHF).
    Description: This research was conducted while Y. Liu was a visiting graduate student at Woods Hole Oceanographic Institution (WHOI). She sincerely thanks the WHOI Academic Programs Office for hosting her visit and is grateful to the support from China Scholarship Council (CSC). This study was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant XDA19060101), the Key R & D project of Shandong Province (Grant 2019JZZY010102), the Key deployment project of Center for Ocean Mega‐Science, CAS (Grant COMS2019R02), the CAS Program (Grant Y9KY04101L), and the National Natural Science Foundation of China (Grant 41776183 and 41906157). Dr. Xiangze Jin is acknowledged for providing the OAFluxHR analysis and for his programming support and guidance to this study. Heat flux data used in this paper can be downloaded (from https://figshare.com/articles/Eddy‐induced_heat_flux_in_the_South_China_Sea/11949735). AVISO SSH data are downloaded from the website (http://www.aviso.altimetry.fr), OISST from the ftp://eclipse.ncdc.noaa.gov/ site, and OAFluxHR analysis will be available from the project website (http://oaflux.whoi.edu).
    Description: 2020-09-16
    Keywords: mesoscale eddies ; air‐sea coupling ; South China Sea
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  • 45
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015348, doi:10.1029/2019JC015348.
    Description: Here we present an assessment of eddy activity in a 3,500 × 2,000 km region of the North Pacific. Eddies were identified and tracked within a numerical simulation that used the Massachusetts Institute of Technology general circulation model and an eddy characterization algorithm. Spatially, eddy births were more frequent: (1) nearshore (cyclones) and offshore (anticyclones) on the windward side of the main Hawai‘ian Islands; (2) in patches of cyclones and anticyclones that resembled the dipole structure of wind stress curl along the islands’ leeward side; and (3) in zonal patches of eddies of both polarities west and north of the islands. Temporally, high eddy activities occurred in spring. There was a meridional distribution of eddy lifespans, which increased northward. Cyclones were more abundant, longer‐lived, smaller, and more nonlinear. Reef fish spawning locations in Hawai‘i coincide with the regions of high eddy activity, with nonlinear eddies responsible for high larval retention.
    Description: This work was supported by the National Ocean and Atmospheric Administration (NOAA) Fisheries And The Environment (FATE) Award WE133F17SE1020. This work used the Extreme Science and Engineering Discovery Environment (XSEDE), which is supported by the National Science Foundation Grant NSF‐OCE170005.
    Description: 2020-10-29
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  • 46
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Gazitua, M. C., Vik, D. R., Roux, S., Gregory, A. C., Bolduc, B., Widner, B., Mulholland, M. R., Hallam, S. J., Ulloa, O., & Sullivan, M. B. Potential virus-mediated nitrogen cycling in oxygen-depleted oceanic waters. Isme Journal, (2020), doi:10.1038/s41396-020-00825-6.
    Description: Viruses play an important role in the ecology and biogeochemistry of marine ecosystems. Beyond mortality and gene transfer, viruses can reprogram microbial metabolism during infection by expressing auxiliary metabolic genes (AMGs) involved in photosynthesis, central carbon metabolism, and nutrient cycling. While previous studies have focused on AMG diversity in the sunlit and dark ocean, less is known about the role of viruses in shaping metabolic networks along redox gradients associated with marine oxygen minimum zones (OMZs). Here, we analyzed relatively quantitative viral metagenomic datasets that profiled the oxygen gradient across Eastern Tropical South Pacific (ETSP) OMZ waters, assessing whether OMZ viruses might impact nitrogen (N) cycling via AMGs. Identified viral genomes encoded six N-cycle AMGs associated with denitrification, nitrification, assimilatory nitrate reduction, and nitrite transport. The majority of these AMGs (80%) were identified in T4-like Myoviridae phages, predicted to infect Cyanobacteria and Proteobacteria, or in unclassified archaeal viruses predicted to infect Thaumarchaeota. Four AMGs were exclusive to anoxic waters and had distributions that paralleled homologous microbial genes. Together, these findings suggest viruses modulate N-cycling processes within the ETSP OMZ and may contribute to nitrogen loss throughout the global oceans thus providing a baseline for their inclusion in the ecosystem and geochemical models.
    Description: We thank Sullivan Lab members and Heather Maughan for comments on the paper, Bess Ward for her contribution in the N-cycle context of our story, Kurt Hanselmann for his assistance in the calculations of the Gibbs-free energies, and the scientific party and crew of the R/V Atlantis (grant OCE-1356056 to MRM) for the sampling opportunity and support at sea. This work was funded in part by awards from the Agouron Institute to OU and MBS, a Gordon and Betty Moore Foundation Investigator Award (#3790) and NSF Biological Oceanography Awards (#1536989 and #1829831) to MBS, and the Millennium Science Initiative (grant ICN12_019-IMO) to OU. The work conducted by the U.S. Department of Energy Joint Genome Institute is supported by the Office of Science of the U.S. Department of Energy under contract no. DE-AC02-05CH11231.
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  • 47
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(15), (2020): e2020GL089135, doi:10.1029/2020GL089135.
    Description: Convection penetrates to the ocean bottom in the North Atlantic but not in the North Pacific. This study examines the role of basin width in shutting down high‐latitude ocean convection. Deep convection is triggered by polar cooling, but it is opposed by precipitation. A two‐layer analytical model illustrates that the overturning circulation acts to mitigate the effect of precipitation by advecting salty, dense water from subtropical latitudes to polar latitudes. The nonlinear dependence of the overturning strength on basin width makes it more efficient in a narrow basin, resulting in a convection shutdown at a stronger freshwater forcing. These predictions are confirmed by simulations with a general circulation model configured with a single closed basin to the north and a reentrant channel to the south. This suggests that basin width may play a role in suppressing convection in the North Pacific but not in the North Atlantic.
    Description: M. K. Y. and R. F. acknowledge support through National Science Foundation (NSF) Awards OCE‐1536515 and AGS‐1835576. M. K. Y. acknowledges funding from the National Defense Science and Engineering Graduate Fellowship and the American Meteorological Society Graduate Student Fellowship. G. R. F. was supported by NSF OCE‐1459702.
    Description: 2020-01-2021
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  • 48
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Babbin, A. R., Tamasi, T., Dumit, D., Weber, L., Rodríguez, M. V. I., Schwartz, S. L., Armenteros, M., Wankel, S. D., & Apprill, A. Discovery and quantification of anaerobic nitrogen metabolisms among oxygenated tropical Cuban stony corals. ISME Journal, (2020), doi:10.1038/s41396-020-00845-2.
    Description: Coral reef health depends on an intricate relationship among the coral animal, photosynthetic algae, and a complex microbial community. The holobiont can impact the nutrient balance of their hosts amid an otherwise oligotrophic environment, including by cycling physiologically important nitrogen compounds. Here we use 15N-tracer experiments to produce the first simultaneous measurements of ammonium oxidation, nitrate reduction, and nitrous oxide (N2O) production among five iconic species of reef-building corals (Acropora palmata, Diploria labyrinthiformis, Orbicella faveolata, Porites astreoides, and Porites porites) in the highly protected Jardines de la Reina reefs of Cuba. Nitrate reduction is present in most species, but ammonium oxidation is low potentially due to photoinhibition and assimilatory competition. Coral-associated rates of N2O production indicate a widespread potential for denitrification, especially among D. labyrinthiformis, at rates of ~1 nmol cm−2 d−1. In contrast, A. palmata displays minimal active nitrogen metabolism. Enhanced rates of nitrate reduction and N2O production are observed coincident with dark net respiration periods. Genomes of bacterial cultures isolated from multiple coral species confirm that microorganisms with the ability to respire nitrate anaerobically to either dinitrogen gas or ammonium exist within the holobiont. This confirmation of anaerobic nitrogen metabolisms by coral-associated microorganisms sheds new light on coral and reef productivity.
    Description: Research was conducted in the Gardens of the Queen, Cuba in accordance with the requirements of the Republic of Cuba, conducted under permit NV2370 and NV2568 issued by the Ministerio de Relaciones Exteriores. We gratefully acknowledge funding for this research by MIT Sea Grant award #2018-DOH-49-LEV, Simons Foundation award #622065, and MIT ESI seed funding to ARB, the MIT Montrym, Ferry, and mTerra Seed Grant Funds, and the generous contributions by Dr Bruce L. Heflinger.
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  • 49
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Seyler, L. M., Trembath-Reichert, E., Tully, B. J., & Huber, J. A. Time-series transcriptomics from cold, oxic subseafloor crustal fluids reveals a motile, mixotrophic microbial community. Isme Journal, (2020), doi:10.1038/s41396-020-00843-4.
    Description: The oceanic crustal aquifer is one of the largest habitable volumes on Earth, and it harbors a reservoir of microbial life that influences global-scale biogeochemical cycles. Here, we use time series metagenomic and metatranscriptomic data from a low-temperature, ridge flank environment representative of the majority of global hydrothermal fluid circulation in the ocean to reconstruct microbial metabolic potential, transcript abundance, and community dynamics. We also present metagenome-assembled genomes from recently collected fluids that are furthest removed from drilling disturbances. Our results suggest that the microbial community in the North Pond aquifer plays an important role in the oxidation of organic carbon within the crust. This community is motile and metabolically flexible, with the ability to use both autotrophic and organotrophic pathways, as well as function under low oxygen conditions by using alternative electron acceptors such as nitrate and thiosulfate. Anaerobic processes are most abundant in subseafloor horizons deepest in the aquifer, furthest from connectivity with the deep ocean, and there was little overlap in the active microbial populations between sampling horizons. This work highlights the heterogeneity of microbial life in the subseafloor aquifer and provides new insights into biogeochemical cycling in ocean crust.
    Description: The Gordon and Betty Moore Foundation sponsored most of the observatory components at North Pond through grant GBMF1609. This work was supported by NSF OCE-1062006, OCE-1745589 and OCE-1635208 to J.A.H. E.T.R. was supported by a NASA Postdoctoral Fellowship with the NASA Astrobiology Institute and a L’Oréal USA For Women in Science Fellowship. The Center for Dark Energy Biosphere Investigations (C-DEBI OCE-0939564) also supported the participation of J.A.H. and B.T. This is C-DEBI contribution number 548.
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  • 50
    Publication Date: 2022-05-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Schultz, C., Doney, S. C., Zhang, W. G., Regan, H., Holland, P., Meredith, M. P., & Stammerjohn, S. Modeling of the influence of sea ice cycle and Langmuir circulation on the upper ocean mixed layer depth and freshwater distribution at the West Antarctic Peninsula. Journal of Geophysical Research: Oceans, 125(8), (2020): e2020JC016109, doi:10.1029/2020JC016109.
    Description: The Southern Ocean is chronically undersampled due to its remoteness, harsh environment, and sea ice cover. Ocean circulation models yield significant insight into key processes and to some extent obviate the dearth of data; however, they often underestimate surface mixed layer depth (MLD), with consequences for surface water‐column temperature, salinity, and nutrient concentration. In this study, a coupled circulation and sea ice model was implemented for the region adjacent to the West Antarctic Peninsula, a climatically sensitive region which has exhibited decadal trends towards higher ocean temperature, shorter sea ice season, and increasing glacial freshwater input, overlain by strong interannual variability. Hindcast simulations were conducted with different air‐ice drag coefficients and Langmuir circulation parameterizations to determine the impact of these factors on MLD. Including Langmuir circulation deepened the surface mixed layer, with the deepening being more pronounced in the shelf and slope regions. Optimal selection of an air‐ice drag coefficient also increased modeled MLD by similar amounts and had a larger impact in improving the reliability of the simulated MLD interannual variability. This study highlights the importance of sea ice volume and redistribution to correctly reproduce the physics of the underlying ocean, and the potential of appropriately parameterizing Langmuir circulation to help correct for biases towards shallow MLD in the Southern Ocean. The model also reproduces observed freshwater patterns in the West Antarctic Peninsula during late summer and suggests that areas of intense summertime sea ice melt can still show net annual freezing due to high sea ice formation during the winter.
    Description: C. Schultz and S. Doney acknowledge support by the U.S. National Science Foundation (grant PLR‐1440435 to the Palmer Long Term Ecological Research program) and support from the University of Virginia. W. G. Zhang acknowledge support by the U.S. National Science Foundation (grant OPP‐1643901). The MITgcm model is an open source model (mitgcm.org). The version used in this study, with added parameterizations and specific configurations, is on C. Schultz’s github (https://github.com/crisoceano/WAP_MITgcm). A copy of the files with specific configurations for this study, the forcing files needed for the simulations, and a copy of the files used for the KPP package are in three separate records on zenodo.org, under DOIs 10.5281/zenodo.3627365, 10.5281/zenodo.3627564, and 10.5281/zenodo.3627742.
    Keywords: West Antarctic Peninsula ; sea ice ; Langmuir circulation ; mixed layer depth ; glacial runoff
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  • 51
    Publication Date: 2022-05-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(12),(2020): e2020JC016271, https://doi.org/10.1029/2020JC016271.
    Description: Asian summer monsoon has a planetary‐scale, westward propagating “quasi‐biweekly” mode of variability with a 10–25 day period. Six years of moored observations at 18°N, 89.5°E in the north Bay of Bengal (BoB) reveal distinct quasi‐biweekly variability in sea surface salinity (SSS) during summer and autumn, with peak‐to‐peak amplitude of 3–8 psu. This large‐amplitude SSS variability is not due to variations of surface freshwater flux or river runoff. We show from the moored data, satellite SSS, and reanalyses that surface winds associated with the quasi‐biweekly monsoon mode and embedded weather‐scale systems, drive SSS and coastal sea level variability in 2015 summer monsoon. When winds are calm, geostrophic currents associated with mesoscale ocean eddies transport Ganga‐Brahmaputra‐Meghna river water southward to the mooring, salinity falls, and the ocean mixed layer shallows to 1–10 m. During active (cloudy, windy) spells of quasi‐biweekly monsoon mode, directly wind‐forced surface currents carry river water away to the east and north, leading to increased salinity at the moorings, and rise of sea level by 0.1–0.5 m along the eastern and northern boundary of the bay. During July–August 2015, a shallow pool of low‐salinity river water lies in the northeastern bay. The amplitude of a 20‐day oscillation of sea surface temperature (SST) is two times larger within the fresh pool than in the saltier ocean to the west, although surface heat flux is nearly identical in the two regions. This is direct evidence that spatial‐temporal variations of BoB salinity influences sub‐seasonal SST variations, and possibly SST‐mediated monsoon air‐sea interaction.
    Description: The authors thank the Ministry of Earth Sciences (MoES) institutes NIOT and INCOIS, and the Upper Ocean Processes (UOP) group at WHOI for design, integration, and deployment of moorings in the BoB. The WHOI mooring was deployed from the ORV Sagar Nidhi and recovered from the ORV Sagar Kanya—we thank the officers, crew and science teams on the cruises for their support. Sengupta, Ravichandran and Sukhatme acknowledge MoES and the National Monsoon Mission, Indian Institute of Tropical Meteorology (IITM), Pune, for support; Lucas and Farrar acknowledge the US Office of Naval Research for support of ASIRI through grants N00014‐13‐1‐0489, N0001413‐100453, N0001417‐12880. We thank S. Shivaprasad, Dipanjan Chaudhuri and Jared Buckley for discussion on ocean currents and Ekman flow, and Fabien Durand for discussion on sea level. JSL would like to thank the Divecha Center for Climate Change, IISc., for support. DS acknowledges support from the Department of Science and Technology (DST), New Delhi, under the Indo‐Spanish Programme.
    Description: 2021-05-16
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  • 52
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124(8), (2019): 7525-7537, doi: 10.1029/2019JB018186.
    Description: The proliferation of drilling expeditions focused on characterizing natural gas hydrate as a potential energy resource has spawned widespread interest in gas hydrate reservoir properties and associated porous media phenomena. Between 2017 and 2019, a Special Section of this journal compiled contributed papers elucidating interactions between gas hydrate and sediment based on laboratory, numerical modeling, and field studies. Motivated mostly by field observations in the northern Gulf of Mexico and offshore Japan, several papers focus on the mechanisms for gas hydrate formation and accumulation, particularly with vapor phase gas, not dissolved gas, as the precursor to hydrate. These studies rely on numerical modeling or laboratory experiments using sediment packs or benchtop micromodels. A second focus of the Special Section is the role of fines in inhibiting production of gas from methane hydrate, controlling the distribution of hydrate at a pore scale, and influencing the bulk behavior of seafloor sediments. Other papers fill knowledge gaps related to the physical properties of hydrate‐bearing sediments and advance new approaches in coupled thermal‐mechanical modeling of these sediments during hydrate dissociation. Finally, one study addresses the long‐standing question about the fate of methane hydrate at the molecular level when CO2 is injected into natural reservoirs under hydrate‐forming conditions.
    Description: C. R. was supported by the U.S. Geological Survey's Energy Resources Program and the Coastal/Marine Hazards and Resources Program, as well as by DOE Interagency Agreement DE‐FE0023495. C. R. thanks W. Waite and J. Jang for discussions and suggestions that improved this paper and L. Stern for a helpful review. J. Y. Lee was supported by the Ministry of Trade, Industry, and Energy (MOTIE) through the Project “Gas Hydrate Exploration and Production Study (19‐1143)” under the management of the Gas Hydrate Research and Development Organization (GHDO) of Korea and the Korea Institute of Geoscience and Mineral Resources (KIGAM). Any use of trade, firm, or product name is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Keywords: Gas hydrate ; Methane ; Reservoir properties ; Multiphase flow
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  • 53
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015989, doi:10.1029/2019JC015989.
    Description: Relatively minor amounts of methane, a potent greenhouse gas, are currently emitted from the oceans to the atmosphere, but such methane emissions have been hypothesized to increase as oceans warm. Here, we investigate the source, distribution, and fate of methane released from the upper continental slope of the U.S. Mid‐Atlantic Bight, where hundreds of gas seeps have been discovered between the shelf break and ~1,600 m water depth. Using physical, chemical, and isotopic analyses, we identify two main sources of methane in the water column: seafloor gas seeps and in situ aerobic methanogenesis which primarily occurs at 100–200 m depth in the water column. Stable isotopic analyses reveal that water samples collected at all depths were significantly impacted by aerobic methane oxidation, the dominant methane sink in this region, with the average fraction of methane oxidized being 50%. Due to methane oxidation in the deeper water column, below 200 m depth, surface concentrations of methane are influenced more by methane sources found near the surface (0–10 m depth) and in the subsurface (10–200 m depth), rather than seafloor emissions at greater depths.
    Description: This research was supported by DOE Grant (DE‐FE0028980) to J. K. and by DOE‐USGS Interagency Agreement DE‐FE0026195.
    Description: 2020-10-04
    Keywords: Methane ; Ocean ; Isotopes ; Gas seeps ; Mid Atlantic bight ; Oxidation
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  • 54
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 125(1), (2020): e2019JG005222, doi:10.1029/2019JG005222.
    Description: Wetlands play an important role in reducing global warming potential in response to global climate change. Unfortunately, due to the effects of human disturbance and natural erosion, wetlands are facing global extinction. It is essential to implement engineering measures to restore damaged wetlands. However, the carbon sink capacity of restored wetlands is unclear. We examined the seasonal change of greenhouse gas emissions in both restored wetland and natural wetland and then evaluated the carbon sequestration capacity of the restored wetland. We found that (1) the carbon sink capacity of the restored wetland showed clear daily and seasonal change, which was affected by light intensity, air temperature, and vegetation growth, and (2) the annual daytime (8–18 hr) sustained‐flux global warming potential was −11.23 ± 4.34 kg CO2 m−2 y−1, representing a much larger carbon sink than natural wetland (−5.04 ± 3.73 kg CO2 m−2 y−1) from April to December. In addition, the results showed that appropriate tidal flow management may help to reduce CH4 emission in wetland restoration. Thus, we proposed that the restored coastal wetland, via effective engineering measures, reliably acted as a large net carbon sink and has the potential to help mitigate climate change.
    Description: We would like to thank Yangtze Delta Estuarine Wetland Ecosystem Ministry of Education & Shanghai Observation and Research Station for providing sites during our research. This research was supported by the National Key Research and Development Program of China (Grant 2017YFC0506002), the National Natural Science Foundation of China Overseas and Hong Kong‐Macao Scholars Collaborative Research Fund (Grant 31728003), the China Postdoctoral Science Foundation (Grant 2018M640362), the Shanghai University Distinguished Professor (Oriental Scholars) Program (Grant JZ2016006), the Open Fund of Shanghai Key Lab for Urban Ecological Processes and Eco‐Restoration (Grant SHUES2018B06), and the Scientific Projects of Shanghai Municipal Oceanic Bureau (Grant 2018‐03). The complete data set is available at https://data.4tu.nl/repository/uuid:536b2614‐c4ca‐43d2‐84dd‐6180fd859544.
    Keywords: Blue carbon ; Restored wetland ; Sustained‐flux global warming potential (SGWP) ; Greenhouse gas (GHG) ; Carbon sequestration capacity
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  • 55
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 125(8),(2020): e2020JF005558, doi:10.1029/2020JF005558.
    Description: Sediment supply is a primary factor in determining marsh response to sea level rise and is typically approximated through high‐resolution measurements of suspended sediment concentrations (SSCs) from adjacent tidal channels. However, understanding sediment transport across the marsh itself remains limited by discontinuous measurements of SSC over individual tidal cycles. Here, we use an array of optical turbidity sensors to build a long‐term, continuous record of SSC across a marsh platform and adjacent tidal channel. We find that channel and marsh concentrations are correlated (i.e., coupled) within tidal cycles but are largely decoupled over longer time scales. We also find that net sediment fluxes decline to near zero within 10 m of the marsh edge. Together, these results suggest that large sections of the marsh platform receive minimal sediment independent of flooding frequency or channel sediment supply. Marsh‐centric, as opposed to channel‐centric, measures of sediment supply may better characterize marsh platform vulnerability.
    Description: This work was funded by NSF Awards 1529245, 1654374, 1426981, 1637630, and 1832221, the NSF Graduate Research Fellowship Program, and the USGS Climate and Land Use Research and Development program. We thank D. Walters, J. Himmelstein, D. Nicks, R. Walker, T. Messerschmidt, and the Plum Island Ecosystems LTER, especially S. Kelsey for laboratory and field assistance. Additionally, we thank C. Friedrichs, G. Guntenspergen, and O. Duran Vinent for contributing ideas that helped develop the work, and the reviewers who helped improve the manuscript. This work is Contribution Number 3928 of the Virginia Institute of Marine Science. In memoriam of David Nicks.
    Description: 2021-01-27
    Keywords: Salt marsh ; Sediment transport ; Turbidity ; Flux convergence ; Decoupling
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  • 56
    Publication Date: 2022-10-27
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Riedel, M., Rohr, K. M. M., Spence, G. D., Kelley, D., Delaney, J., Lapham, L., Pohlman, J. W., Hyndman, R. D., & Willoughby, E. C. Focused fluid flow along the Nootka fault zone and continental slope, explorer-Juan de Fuca Plate Boundary. Geochemistry Geophysics Geosystems, 21(8), (2020): e2020GC009095, doi:10.1029/2020GC009095.
    Description: Geophysical and geochemical data indicate there is abundant fluid expulsion in the Nootka fault zone (NFZ) between the Juan de Fuca and Explorer plates and the Nootka continental slope. Here we combine observations from 〉20 years of investigations to demonstrate the nature of fluid‐flow along the NFZ, which is the seismically most active region off Vancouver Island. Seismicity reaching down to the upper mantle is linked to near‐seafloor manifestation of fluid flow through a network of faults. Along the two main fault traces, seismic reflection data imaged bright spots 100–300 m below seafloor that lie above changes in basement topography. The bright spots are conformable to sediment layering, show opposite‐to‐seafloor reflection polarity, and are associated with frequency reduction and velocity push‐down indicating the presence of gas in the sediments. Two seafloor mounds ~15 km seaward of the Nootka slope are underlain by deep, nonconformable high‐amplitude reflective zones. Measurements in the water column above one mound revealed a plume of warm water, and bottom‐video observations imaged hydrothermal vent system biota. Pore fluids from a core at this mound contain predominately microbial methane (C1) with a high proportion of ethane (C2) yielding C1/C2 ratios 〈500 indicating a possible slight contribution from a deep source. We infer the reflective zones beneath the two mounds are basaltic intrusions that create hydrothermal circulation within the overlying sediments. Across the Nootka continental slope, gas hydrate‐related bottom‐simulating reflectors are widespread and occur at depths indicating heat flow values of 80–90 mW/m2.
    Description: This study represents data from numerous cruises acquired over more than two decades. We would like to thank all the scientific personnel and technical staff involved in data acquisition, processing of samples, and making observations during the ROV dives, as well as the crews and captains of the various research vessels involved. This is contribution #5877 from the University of Maryland Center for Environmental Science. This is NRCan contribution number / Numéro de contribution de RNCan: 20200324.
    Keywords: Fluid flow ; Nootka transform fault ; Gas hydrate ; Intrusion ; Heat flow
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  • 57
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Biogeosciences 126(1), (2021): e2019JG005621, https://doi.org/10.1029/2019JG005621.
    Description: Ongoing ocean warming can release methane (CH4) currently stored in ocean sediments as free gas and gas hydrates. Once dissolved in ocean waters, this CH4 can be oxidized to carbon dioxide (CO2). While it has been hypothesized that the CO2 produced from aerobic CH4 oxidation could enhance ocean acidification, a previous study conducted in Hudson Canyon shows that CH4 oxidation has a small short‐term influence on ocean pH and dissolved inorganic radiocarbon. Here we expand upon that investigation to assess the impact of widespread CH4 seepage on CO2 chemistry and possible accumulation of this carbon injection along 234 km of the U.S. Mid‐Atlantic Bight. Consistent with the estimates from Hudson Canyon, we demonstrate that a small fraction of ancient CH4‐derived carbon is being assimilated into the dissolved inorganic radiocarbon (mean fraction of 0.5 ± 0.4%). The areas with the highest fractions of ancient carbon coincide with elevated CH4 concentration and active gas seepage. This suggests that aerobic CH4 oxidation has a greater influence on the dissolved inorganic pool in areas where CH4 concentrations are locally elevated, instead of displaying a cumulative effect downcurrent from widespread groupings of CH4 seeps. A first‐order approximation of the input rate of ancient‐derived dissolved inorganic carbon (DIC) into the waters overlying the northern U.S. Mid‐Atlantic Bight further suggests that oxidation of ancient CH4‐derived carbon is not negligible on the global scale and could contribute to deepwater acidification over longer time scales.
    Description: This study was sponsored by U.S. Department of Energy (DE‐FE0028980, awarded to J. D. K; DE‐FE0026195 interagency agreement with C. D. R.). We thank the crew of the R/V Hugh R. Sharp for their support, G. Hatcher, J. Borden, and M. Martini of the USGS for assistance with the LADCP, and Zach Bunnell, Lillian Henderson, and Allison Laubach for additional support at sea.
    Description: 2021-06-23
    Keywords: Radiocarbon ; Methane ; DIC ; Ocean acidification ; Climate change ; U.S Mid-Atlantic Bight
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  • 58
    Publication Date: 2022-10-27
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 126(10),(2021): e2021JB022050, https://doi.org/10.1029/2021JB022050.
    Description: On-fault earthquake magnitude distributions are calculated for northern Caribbean faults using estimates of fault slip and regional seismicity parameters. Integer programming, a combinatorial optimization method, is used to determine the optimal spatial arrangement of earthquakes sampled from a truncated Gutenberg-Richter distribution that minimizes the global misfit in slip rates on a complex fault system. Slip rates and their uncertainty on major faults are derived from a previously published GPS block model for the region, with fault traces determined from offshore geophysical mapping and previously published onshore studies. The optimal spatial arrangement of the sampled earthquakes is compared with the 500-year history of earthquake observations. Rupture segmentation of the subduction interface along the Hispaniola-Puerto Rico Trench (PRT) fault and seismic coupling on the PRT fault appear to exert the primary control over this spatial arrangement. Introducing a rupture barrier for the Hispaniola-PRT fault northwest of Mona Passage, based on geophysical and seismicity observations, and assigning a low slip rate of 2 mm/yr on the PRT fault are most consistent with historical earthquakes in the region. The addition of low slip-rate secondary faults as well as segmentation of the Hispaniola and Septentrional strike-slip fault improves the consistency with historical seismicity. An important observation from the modeling is that varying the slip rate on the PRT fault and different segmentation scenarios result in significant changes to the optimal magnitude distribution on faults farther away. In general, optimal on-fault magnitude distributions are more complex and inter-dependent than is typically assumed in probabilistic seismic hazard analysis and probabilistic tsunami hazard analysis.
    Description: Funding for this study is from the U.S. Geological Survey Coastal and Marine Hazards and Resources Program.
    Description: 2022-04-11
    Keywords: Northern Caribbean ; Rupture forecast ; Combinatorial optimization ; Integer programming
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  • 59
    Publication Date: 2022-10-27
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Fu, X., Waite, W. F., & Ruppel, C. D. Hydrate formation on marine seep bubbles and the implications for water column methane dissolution. Journal of Geophysical Research: Oceans, 126(9), (2021): e2021JC017363, https://doi.org/10.1029/2021JC017363.
    Description: Methane released from seafloor seeps contributes to a number of benthic, water column, and atmospheric processes. At seafloor seeps within the methane hydrate stability zone, crystalline gas hydrate shells can form on methane bubbles while the bubbles are still in contact with the seafloor or as the bubbles begin ascending through the water column. These shells reduce methane dissolution rates, allowing hydrate-coated bubbles to deliver methane to shallower depths in the water column than hydrate-free bubbles. Here, we analyze seafloor videos from six deepwater seep sites associated with a diverse range of bubble-release processes involving hydrate formation. Bubbles that grow rapidly are often hydrate-free when released from the seafloor. As bubble growth slows and seafloor residence time increases, a hydrate coating can form on the bubble's gas-water interface, fully coating most bubbles within ∼10 s of the onset of hydrate formation at the seafloor. This finding agrees with water-column observations that most bubbles become hydrate-coated after their initial ∼150 cm of rise, which takes about 10 s. Whether a bubble is coated or not at the seafloor affects how much methane a bubble contains and how quickly that methane dissolves during the bubble's rise through the water column. A simplified model shows that, after rising 150 cm above the seafloor, a bubble that grew a hydrate shell before releasing from the seafloor will have ∼5% more methane than a bubble of initial equal volume that did not grow a hydrate shell after it traveled to the same height.
    Description: X. Fu acknowledges support from the Miller Fellowship during her time at U.C. Berkeley. W. Waite and C. Ruppel are supported by the United States Geological Survey (USGS) Coastal/Marine Hazards and Resources Program and the Energy Resources Program, with research conducted under USGS-Department of Energy interagency agreements DE-FE0023495 and 89243320SFE000013.
    Keywords: Gas and hydrate systems ; Oceanography: biological and chemical ; Carbon cycling ; Biogeochemical cycles, processes, and modeling
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  • 60
    Publication Date: 2022-10-27
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Loescher, H., Vargas, R., Mirtl, M., Morris, B., Pauw, J., Yu, X., Kutsch, W., Mabee, P., Tang, J., Ruddell, B., Pulsifer, P., Bäck, J., Zacharias, S., Grant, M., Feig, G., Zheng, L., Waldmann, C., & Genazzio, M. Building a global ecosystem research infrastructure to address global grand challenges for macrosystem ecology. Earth’s Future, 10(5), (2022): e2020EF001696, https://doi.org/10.1029/2020ef001696.
    Description: The development of several large-, “continental”-scale ecosystem research infrastructures over recent decades has provided a unique opportunity in the history of ecological science. The Global Ecosystem Research Infrastructure (GERI) is an integrated network of analogous, but independent, site-based ecosystem research infrastructures (ERI) dedicated to better understand the function and change of indicator ecosystems across global biomes. Bringing together these ERIs, harmonizing their respective data and reducing uncertainties enables broader cross-continental ecological research. It will also enhance the research community capabilities to address current and anticipate future global scale ecological challenges. Moreover, increasing the international capabilities of these ERIs goes beyond their original design intent, and is an unexpected added value of these large national investments. Here, we identify specific global grand challenge areas and research trends to advance the ecological frontiers across continents that can be addressed through the federation of these cross-continental-scale ERIs.
    Description: This manuscript is in part the product of several workshops and ongoing GERI development. The first workshop was the Terrestrial Ecosystem Research Network (TERN) sponsored and entitled: “Towards a Global Ecosystem Observatory”, 5–7 March 2017, University of Queensland, Brisbane Australia. Another workshop was sponsored by Chinese Academy of Sciences (CAS) and entitled: “Global Integrated Research Infrastructure component in Next Generation ILTER”, 17–20 April, 2018, South China Botanical Garden, Zhaoqing, Guangdong Province, China. The National Science Foundation (NSF) supported two workshops. The first was entitled: ‘Building a Global Ecological Understanding’ held at the University of Delaware, Newark Delaware, 3–6 June, 2016 (NSF 1347883) and the second entitled: “Global Environmental Research Infrastructure (GERI) Planning Workshop”, held at NEON HQ, Boulder Colorado, 25–27 June 2019 (NSF 1917180). The authors wish to thank the workshop attendees for their thoughtful contributions. NEON is a project sponsored by the NSF and managed under cooperative support agreement (DBI-1029808) to Battelle.
    Keywords: Environmental research infrastructure ; Macrosystem science ; Interoperability ; Societal benefit ; New capabilities ; Federating infrastructure
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  • 61
    Publication Date: 2022-10-27
    Description: This paper is not subject to U.S. copyright. The definitive version was published in Hegermiller, C. A., Warner, J. C., Olabarrieta, M., Sherwood, C. R., & Kalra, T. S. Modeling of barrier breaching during hurricanes Sandy and Matthew. Journal of Geophysical Research: Earth Surface, 127(3), (2022): e2021JF006307, https://doi.org/10.1029/2021JF006307.
    Description: Physical processes driving barrier island change during storms are important to understand to mitigate coastal hazards and to evaluate conceptual models for barrier evolution. Spatial variations in barrier island topography, landcover characteristics, and nearshore and back-barrier hydrodynamics can yield complex morphological change that requires models of increasing resolution and physical complexity to predict. Using the Coupled Ocean-Atmosphere-Wave-Sediment Transport (COAWST) modeling system, we investigated two barrier island breaches that occurred on Fire Island, NY during Hurricane Sandy (2012) and at Matanzas, FL during Hurricane Matthew (2016). The model employed a recently implemented infragravity (IG) wave driver to represent the important effects of IG waves on nearshore water levels and sediment transport. The model simulated breaching and other changes with good skill at both locations, resolving differences in the processes and evolution. The breach simulated at Fire Island was 250 m west of the observed breach, whereas the breach simulated at Matanzas was within 100 m of the observed breach. Implementation of the vegetation module of COAWST to allow three-dimensional drag over dune vegetation at Fire Island improved model skill by decreasing flows across the back-barrier, as opposed to varying bottom roughness that did not positively alter model response. Analysis of breach processes at Matanzas indicated that both far-field and local hydrodynamics influenced breach creation and evolution, including remotely generated waves and surge, but also surge propagation through back-barrier waterways. This work underscores the importance of resolving the complexity of nearshore and back-barrier systems when predicting barrier island change during extreme events.
    Description: C. A. Hegermiller is grateful to the U.S. Geological Survey (USGS) Mendenhall Research Fellowship Program for support. This project was supported by the USGS Coastal and Marine Geology Program and the Office of Naval Research, Increasing the Fidelity of Morphological Storm Impact Predictions Project. M. Olabarrieta acknowledges support from the NSF project OCE-1554892.
    Description: 2022-07-26
    Keywords: Breach ; Barrier island ; Hurricane
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  • 62
    Publication Date: 2022-10-27
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Zeigler, S. L., Gutierrez, B. T., Lentz, E. E., Plant, N. G., Sturdivant, E. J., & Doran, K. S. Predicted sea-level rise-driven biogeomorphological changes on Fire Island, New York: implications for people and plovers. Earth’s Future, 10(4), (2022): e2021EF002436, https://doi.org/10.1029/2021EF002436.
    Description: Forecasting biogeomorphological conditions for barrier islands is critical for informing sea-level rise (SLR) planning, including management of coastal development and ecosystems. We combined five probabilistic models to predict SLR-driven changes and their implications on Fire Island, New York, by 2050. We predicted barrier island biogeomorphological conditions, dynamic landcover response, piping plover (Charadrius melodus) habitat availability, and probability of storm overwash under three scenarios of shoreline change (SLC) and compared results to observed 2014/2015 conditions. Scenarios assumed increasing rates of mean SLC from 0 to 4.71 m erosion per year. We observed uncertainty in several morphological predictions (e.g., beach width, dune height), suggesting decreasing confidence that Fire Island will evolve in response to SLR as it has in the past. Where most likely conditions could be determined, models predicted that Fire Island would become flatter, narrower, and more overwash-prone with increasing rates of SLC. Beach ecosystems were predicted to respond dynamically to SLR and migrate with the shoreline, while marshes lost the most area of any landcover type compared to 2014/2015 conditions. Such morphological changes may lead to increased flooding or breaching with coastal storms. However—although modest declines in piping plover habitat were observed with SLC—the dynamic response of beaches, flatter topography, and increased likelihood of overwash suggest storms could promote suitable conditions for nesting piping plovers above what our geomorphology models predict. Therefore, Fire Island may offer a conservation opportunity for coastal species that rely on early successional beach environments if natural overwash processes are encouraged.
    Description: Funding for this work was provided by the U.S. Geological Survey's Coastal and Marine Hazards and Resources Program, with supplemental funding through the Disaster Relief Act.
    Keywords: Sea level rise ; Erosion ; Coastal habitats ; Barrier island ; Shorebirds
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  • 63
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Johnson, H. L., Cessi, P., Marshall, D. P., Schloesser, F., & Spall, M. A. Recent contributions of theory to our understanding of the Atlantic Meridional Overturning Circulation. Journal of Geophysical Research-Oceans, 124(8), (2019): 5376-5399, doi: 10.1029/2019JC015330.
    Description: Revolutionary observational arrays, together with a new generation of ocean and climate models, have provided new and intriguing insights into the Atlantic Meridional Overturning Circulation (AMOC) over the last two decades. Theoretical models have also changed our view of the AMOC, providing a dynamical framework for understanding the new observations and the results of complex models. In this paper we review recent advances in conceptual understanding of the processes maintaining the AMOC. We discuss recent theoretical models that address issues such as the interplay between surface buoyancy and wind forcing, the extent to which the AMOC is adiabatic, the importance of mesoscale eddies, the interaction between the middepth North Atlantic Deep Water cell and the abyssal Antarctic Bottom Water cell, the role of basin geometry and bathymetry, and the importance of a three‐dimensional multiple‐basin perspective. We review new paradigms for deep water formation in the high‐latitude North Atlantic and the impact of diapycnal mixing on vertical motion in the ocean interior. And we discuss advances in our understanding of the AMOC's stability and its scaling with large‐scale meridional density gradients. Along with reviewing theories for the mean AMOC, we consider models of AMOC variability and discuss what we have learned from theory about the detection and meridional propagation of AMOC anomalies. Simple theoretical models remain a vital and powerful tool for articulating our understanding of the AMOC and identifying the processes that are most critical to represent accurately in the next generation of numerical ocean and climate models.
    Description: H. L. J. and D. P. M. are grateful for funding from the U.K. Natural Environment Research Council under the UK‐OSNAP project (NE/K010948/1). P. C. gratefully acknowledges support by the National Science Foundation through OCE‐1634128. M. A. S. was supported by the National Science Foundation Grants OCE‐1558742 and OCE‐1634468. We are also grateful to Eli Tziperman and an anonymous reviewer whose comments helped us to improve the manuscript. The Estimating the Circulation and Climate of the Ocean state estimate (ECCO version 4 release 3) used to produce Figure 2 is available online (https://ecco.jpl.nasa.gov). Please refer to the original papers reviewed here for access to any other data discussed.
    Keywords: Atlantic ; Overturning circulation
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  • 64
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124(8), (2019): 5999-6014, doi: 10.1029/2019JC015034.
    Description: Oceanic fronts are dynamically active regions of the global ocean that support upwelling and downwelling with significant implications for phytoplankton production and export. However (on time scales urn:x-wiley:jgrc:media:jgrc23568:jgrc23568-math-0001 the inertial time scale), the vertical velocity is 103–104 times weaker than the horizontal velocity and is difficult to observe directly. Using intensive field observations in conjunction with a process study ocean model, we examine vertical motion and its effect on phytoplankton fluxes at multiple spatial horizontal scales in an oligotrophic region in the Western Mediterranean Sea. The mesoscale ageostrophic vertical velocity (∼10 m/day) inferred from our observations shapes the large‐scale phytoplankton distribution but does not explain the narrow (1–10 km wide) features of high chlorophyll content extending 40–60 m downward from the deep chlorophyll maximum. Using modeling, we show that downwelling submesoscale features concentrate 80% of the downward vertical flux of phytoplankton within just 15% of the horizontal area. These submesoscale spatial structures serve as conduits between the surface mixed layer and pycnocline and can contribute to exporting carbon from the sunlit surface layers to the ocean interior.
    Description: The AlborEx experiment was conducted in the framework of PERSEUS EU‐funded project (Grant 287600) and was led by the Spanish National Research Council (CSIC) and involved other national and international partners: Balearic Islands Coastal Observing and Forecasting System (SOCIB, Spain); Consiglio Nazionale delle Ricerche (CNR, Italy); Istituto Nazionale di Oceanografia e di Geofisica Sperimentale (OGS, Italy); and Woods Hole Oceanographic Institution (WHOI, ONR Grant N00014‐16‐1‐3130). Glider operations were partially funded by JERICO FP7 project. Part of this work has been carried out as part of the Copernicus Marine Environment Monitoring Service (CMEMS) MedSUB project. CMEMS is implemented by Mercator Ocean in the framework of a delegation agreement with the European Union. S. R. and A. P. acknowledge support from WHOI Subcontract A101339. Data available from authors: Ship CTDs, glider and VM‐ADCP data files are available in the SOCIB data catalog (https://doi.org/10.25704/z5y2-qpye); model data are available at IMEDEA data catalog https://ide.imedea.uib-csic.es/thredds/catalog/data/projects/alborex/catalog.html. We thank all the crew and participants on board R/V SOCIB for their collaboration and Marc Torner and the SOCIB glider Facility for their efficient cooperation. We also thank B. Mourre for numerical data from the Western Mediterranean Operational Model to initialize the Process Study Ocean Model. Figures were created using the cmocean colormaps package (Thyng et al., 2016).
    Keywords: Vertical motion ; Ocean front ; Mesoscale ; Submesoscale ; Transport ; Phytoplankton
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  • 65
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Little, C. M., Hu, A., Hughes, C. W., McCarthy, G. D., Piecuch, C. G., Ponte, R. M., & Thomas, M. D. The relationship between U.S. East Coast sea level and the Atlantic Meridional Overturning Circulation: a review. Journal of Geophysical Research-Oceans, 124(9), (2019): 6435-6458, doi:10.1029/2019JC015152.
    Description: Scientific and societal interest in the relationship between the Atlantic Meridional Overturning Circulation (AMOC) and U.S. East Coast sea level has intensified over the past decade, largely due to (1) projected, and potentially ongoing, enhancement of sea level rise associated with AMOC weakening and (2) the potential for observations of U.S. East Coast sea level to inform reconstructions of North Atlantic circulation and climate. These implications have inspired a wealth of model‐ and observation‐based analyses. Here, we review this research, finding consistent support in numerical models for an antiphase relationship between AMOC strength and dynamic sea level. However, simulations exhibit substantial along‐coast and intermodel differences in the amplitude of AMOC‐associated dynamic sea level variability. Observational analyses focusing on shorter (generally less than decadal) timescales show robust relationships between some components of the North Atlantic large‐scale circulation and coastal sea level variability, but the causal relationships between different observational metrics, AMOC, and sea level are often unclear. We highlight the importance of existing and future research seeking to understand relationships between AMOC and its component currents, the role of ageostrophic processes near the coast, and the interplay of local and remote forcing. Such research will help reconcile the results of different numerical simulations with each other and with observations, inform the physical origins of covariability, and reveal the sensitivity of scaling relationships to forcing, timescale, and model representation. This information will, in turn, provide a more complete characterization of uncertainty in relevant relationships, leading to more robust reconstructions and projections.
    Description: The authors acknowledge funding support from NSF Grant OCE‐1805029 (C. M. L.) and NASA Contract NNH16CT01C (C. M. L. and R. M. P.), the Regional and Global Model Analysis (RGMA) component of the Earth and Environmental System Modeling Program of the U.S. Department of Energy's Office of Biological & Environmental Research Cooperative Agreement DE‐FC02‐97ER62402 (A. H.), Natural Environment Research Council NE/K012789/1 (C. W. H.), Irish Marine Institute Project A4 PBA/CC/18/01 (G. D. M.), and NSF Awards OCE‐1558966 and OCE‐1834739 (C. G. P.). The National Center for Atmospheric Research is sponsored by National Science Foundation. The authors thank the two reviewers for their comments, and CLIVAR and the U.S. AMOC Science Team for inspiration and patience. All CMIP5 data used in Figures 4-6 are available at http://pcmdi9.llnl.gov/ website; the AMOC strength fields were digitized from Chen et al. (2018, supporting information Figure S3).
    Keywords: Sea level ; AMOC ; United States ; Coastal ; Climate model ; Review
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  • 66
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Solid Earth 124 (2019): 10023–10055, doi: 10.1029/2019JB017648.
    Description: We studied long‐term evolution of nontransform discontinuities (NTDs) on the Mid‐Atlantic Ridge from 0‐ to ~20‐ to 25‐Ma crust using plate reconstructions of multibeam bathymetry, long‐range HMR1 sidescan sonar, residual mantle Bouguer gravity anomaly (RMBA), and gravity‐derived crustal thickness. NTDs have propagated north and south with respect to flowlines of relative plate motion and both rapidly and slowly compared to the half spreading rate; at times they have been quasi‐stable. Fast, short‐term (〈2 Myr) propagation is driven by reduced magma supply (increased tectonic extension) in the propagating ridge tip when NTD ridge‐axis offsets are small (≲5 km). Propagation at larger offsets generally is slower and longer term. These NTDs can show classic structures of rift propagation including inner and outer pseudofaults and crustal blocks transferred between ridge flanks by discontinuous jumps of the propagating ridge tip. In all cases crustal transfer occurs within the NTD valley. Aside from ridge‐axis offset, the evolution of NTDs appears to be controlled by three factors: (1) gross volume and distribution of magma supplied to ridge segments as controlled by 3‐D heterogeneities in mantle fertility and/or dynamic upwelling; this controls fundamental ridge segmentation. (2) The lithospheric plumbing system through which magma is delivered to the crust. (3) The consequent focusing of tectonic extension in magma‐poor parts of spreading segments, typically at segment ends, which can drive propagation. We also observe long‐wavelength (5‐10 Myr) RMBA asymmetry between the conjugate ridge flanks, and we attribute this to asymmetric distribution of density anomalies in the upper mantle.
    Description: We thank Tingting Wang for providing plate‐reconstruction codes, Ross Parnell‐Turner for technical support, and Anouk Beniest and an anonymous reviewer for comments that helped to improve the manuscript. We benefited greatly from discussion with the Deep Sea Geodynamics Group of the South China Sea Institute of Oceanology. Figures were drawn using the GMT software of Wessel and Smith (1998). This study was supported by National Natural Science Foundation of China (91628301, 41890813, and U1606401), Chinese Academy of Sciences (Y4SL021001, QYZDY‐SSW‐DQC005, and 133244KYSB20180029), Chinese National 985 Project (1350141509), International Exchange Program for Graduate Students of Tongji University (2016020006), China Scholarship Council (201706260034), and Woods Hole Oceanographic Institution. We thank the crews and science parties of the ARSRP, MAREAST, MODE94, and MODE98 expeditions for their contributions to data acquisition. ARSRP and MAREAST data acquisition was funded by Office of Naval Research grant N00014‐90‐J‐6121 and by U.S. National Science Foundation grant OCE‐9503561, respectively. Access to the original data used in this study is available at https://doi.org/10.26025/z2z7‐kd89.
    Description: 2020-03-11
    Keywords: Mid‐Atlantic Ridge ; Nontransform discontinuity ; Plate reconstruction ; Propagating rift
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  • 67
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124 (2019): 7201-7225, doi: 10.1029/2019JC015520.
    Description: The oceanographic response and atmospheric forcing associated with downwelling along the Alaskan Beaufort Sea shelf/slope is described using mooring data collected from August 2002 to September 2004, along with meteorological time series, satellite data, and reanalysis fields. In total, 55 downwelling events are identified with peak occurrence in July and August. Downwelling is initiated by cyclonic low‐pressure systems displacing the Beaufort High and driving westerly winds over the region. The shelfbreak jet responds by accelerating to the east, followed by a depression of isopycnals along the outer shelf and slope. The storms last 3.25 ± 1.80 days, at which point conditions relax toward their mean state. To determine the effect of sea ice on the oceanographic response, the storms are classified into four ice seasons: open water, partial ice, full ice, and fast ice (immobile). For a given wind strength, the largest response occurs during partial ice cover, while the most subdued response occurs in the fast ice season. Over the two‐year study period, the winds were strongest during the open water season; thus, the shelfbreak jet intensified the most during this period and the cross‐stream Ekman flow was largest. During downwelling, the cold water fluxed off the shelf ventilates the upper halocline of the Canada Basin. The storms approach the Beaufort Sea along three distinct pathways: a northerly route from the high Arctic, a westerly route from northern Siberia, and a southerly route from south of Bering Strait. Differences in the vertical structure of the storms are presented as well.
    Description: The authors thank Paula Fratantoni and Dan Torres for processing the moored profiler and ADCP data, respectively. Data from the SBI mooring array can be found at https://archive.eol.ucar.edu/projects/sbi/all_data.shtml. Funding for the analysis was provided by the following grants: National Science Foundation Grants OCE‐1259618 (N. F. and R. P.), OCE‐1756361 (N. F.), and PLR‐1504333 (N. F. and R. P.); National Oceanic and Atmospheric Administration Grant NA14‐OAR4320158 (R. P. and P. L.); and the Natural Sciences and Engineering Research Council of Canada (K. M.).
    Description: 2020-04-16
    Keywords: Downwelling ; Beaufort Sea ; Shelfbreak ; North Slope ; Arctic cyclone
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  • 68
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(3), (2020): e2019GC008847, doi:10.1029/2019GC008847.
    Description: To learn more about magnetic properties of the lower ocean crust and its contributions to marine magnetic anomalies, gabbro samples were collected from International Ocean Discovery Program Hole U1473A at Atlantis Bank on the Southwest Indian Ridge. Detailed magnetic property work links certain magnetic behaviors and domain states to specific magnetic mineral populations. Measurements on whole rocks and mineral separates included magnetic hysteresis, first‐order reversal curves, low‐temperature remanence measurements, thermomagnetic analysis, and magnetic force microscopy. Characteristics of the thermomagnetic data indicate that the upper ~500 m of the hole has undergone hydrothermal alteration. The thermomagnetic and natural remanent magnetization data are consistent with earlier observations from Hole 735B that show remanence arises from low‐Ti magnetite and that natural remanent magnetizations are up to 25 A m−1 in evolved Fe‐Ti oxide gabbros, but are mostly 〈1 A m−1. Magnetite is present in at least three forms. Primary magnetite is associated with coarse‐grained oxides that are more frequent in the upper part of the hole. This magnetic population is linked to dominantly “pseudo‐single‐domain” behavior that arises from fine‐scale lamellar intergrowths within the large oxides. Deeper in the hole the magnetic signal is more commonly dominated by an interacting single‐domain assemblage most likely found along crystal discontinuities in olivine and/or pyroxene. A third contribution is from noninteracting single‐domain inclusions within plagioclase. Because the concentration of the highly magnetic, oxide‐rich gabbros is greatest toward the surface, the signal from coarse oxides will likely dominate the near‐bottom magnetic anomaly signal at Atlantis Bank.
    Description: This work used samples and data provided by the International Ocean Discovery Program. Funding was provided by the U.S. Science Support Program (J.B.). I.L. has benefited from a Smithsonian Edward and Helen Hintz Secretarial Scholarship. We thank the members of the IODP Expedition 360 Science Party, and the captain and crew of the JOIDES Resolution. Part of this work was done as a Visiting Fellow at the Institute for Rock Magnetism (IRM) at the University of Minnesota. The IRM is made possible through the Instrumentation and Facilities program of the National Science Foundation, Earth Sciences Division, and by funding from the University of Minnesota. We would like to thank IRM staff M. Jackson, P. Solheid, and D. Bilardello for their generous assistance. Many thanks to A. Butula, K. Vernon, and J. Marquardt for their assistance with rock magnetic measurements at UWM and to L. McHenry for assistance with XRD. We also thank two anonymous reviewers for their thoughtful comments that improved the manuscript. Magnetic data associated with this manuscript are available in the Magnetics Information Consortium (MagIC) database at https://www.earthref.org/MagIC/doi/10.1029/2019GC008847. XRD data are available at https://zenodo.org/record/3611642.
    Description: 2020-08-28
    Keywords: Marine magnetic anomalies ; Ocean crust magnetization ; Magnetic mineralogy ; IODP ; Expedition 360 ; JOIDES Resolution
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  • 69
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 125(4), (2020): e2020JC016046, doi:10.1029/2020JC016046.
    Description: Momentum input from westerly winds blowing over the Southern Ocean can be modulated by mesoscale surface currents and result in changes in large‐scale ocean circulation. Here, using an eddy‐resolving 1/20 degree ocean model configured near Drake Passage, we evaluate the impact of current‐wind interaction on vertical processes. We find a reduction in momentum input from the wind, reduced eddy kinetic energy, and a modification of Ekman pumping rates. Wind stress curl resulting from current‐wind interaction leads to net upward motion, while the nonlinear Ekman pumping term associated with horizontal gradients of relative vorticity induces net downward motion. The spatially averaged mixed layer depth estimated using a density criteria is shoaled slightly by current‐wind interaction. Current‐wind interaction, on the other hand, enhances the stratification in the thermocline below the mixed layer. Such changes have the potential to alter biogeochemical processes including nutrient supply, biological productivity, and air‐sea carbon dioxide exchange.
    Description: The MITgcm can be obtained online (http://mitgcm.org). The geostrophic current product derived from the sea level anomaly can be downloaded in the Copernicus Marine and Environment Monitoring Service of Ssalto/Duacs gridded “allsat” series and along‐track Sea Level Anomalies, Absolute Dynamic Topographies and Geostrophic velocities over the Global Ocean, Mediterranean Sea, Black Sea, European Seas and Acrtic Ocean areas, in Delayed‐Time and in Near‐Real‐Time. Resources supporting this work were provided by the NASA High‐End Computing (HEC) Program through the NASA Advanced Supercomputing (NAS) Division at Ames Research Center with the award number SMD‐15‐5752. H. S., J. M., and D. J. M. were supported by the NSF MOBY project (OCE‐1048926 and OCE‐1048897). H. S. acknowledges the support by National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIT) (NRF‐2019R1C1C1003663) and Yonsei University Research Fund of 2018‐22‐0053. D. J. M. also gratefully acknowledges NSF and NASA support, along with the Holger W. Jannasch and Columbus O'Donnell Iselin shared chairs for Excellence in Oceanography. H. Seo acknowledges the support from the ONR (N00014‐17‐1‐2398), NOAA (NA10OAR4310376), and the Andrew W. Mellon Foundation Endowed Fund for Innovative Research at WHOI. We also thank two anonymous referees whose comments significantly improved the presentation of results.
    Description: 2020-09-17
    Keywords: Southern Ocean ; Eddy-wind interaction ; Ekman pumping ; Stratification ; Eddy kinetic energy ; Mixed layer depth
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  • 70
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2019. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research-Oceans 124 (2019): 7575-7590, doi: 10.1029/2019JC015339.
    Description: Satellite altimetry reveals substantial decadal variability in sea level 𝜁 across the tropical Pacific during 1993–2015. An ocean state estimate that faithfully reproduces the observations is used to elucidate the origin of these low-frequency tropical Pacific 𝜁 variations. Analysis of the hydrostatic equation reveals that recent decadal 𝜁 changes in the tropical Pacific are mainly hermosteric in nature, related to changes in upper-ocean heat content. A forcing experiment performed with the numerical model suggests that anomalous wind stress was an important driver of the relevant heat storage and thermosteric variation. Closed budget diagnostics further clarify that the wind-stress-related thermosteric 𝜁 variation resulted from the joint actions of large-scale ocean advection and local surface heat flux, such that advection controlled the budget over shorter, intraseasonal to interannual time scales, and local surface heat flux became increasingly influential at longer decadal periods. In particular, local surface heat flux was important in contributing to a recent reversal of decadal 𝜁 trends in the tropical Pacific. Contributions from local surface heat flux partly reflect damping latent heat flux tied to wind-stress-driven sea-surface-temperature variations.
    Description: This work was supported by NSF Awards OCE‐1558966 and OCE‐1834739. Support of the ECCO project by the NASA Physical Oceanography, Cryospheric Science, and Modeling, Analysis and Prediction programs is also acknowledged. We thank Ou Wang (NASA JPL) for performing the forcing perturbation experiment. Comments from two anonymous reviewers were helpful. Altimetry observations used in Figures 1 and 2 were downloaded from CSIRO (http://www.cmar.csiro.au/sealevel/sl_data_cmar.html). ECCOv4 output is available on the group website (https://ecco.jpl.nasa.gov/).
    Description: 2020-04-30
    Keywords: Sea‐level change ; Sea‐level variability ; Decadal variability ; Tropical Pacific ; State estimation
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  • 71
    Publication Date: 2022-10-26
    Description: © The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ramos, R. D., Goodkin, N. F., Siringan, F. P., & Hughen, K. A. Coral records of temperature and salinity in the tropical western Pacific reveal influence of the Pacific Decadal Oscillation since the late nineteenth century. Paleoceanography and Paleoclimatology, 34(8), (2019): 1344-1358, doi: 10.1029/2019PA003684.
    Description: The Pacific Decadal Oscillation (PDO) is a complex aggregate of different atmospheric and oceanographic forcings spanning the extratropical and tropical Pacific. The PDO has widespread climatic and societal impacts, thus understanding the processes contributing to PDO variability is critical. Distinguishing PDO‐related variability is particularly challenging in the tropical Pacific due to the dominance of the El Niño–Southern Oscillation and influence of anthropogenic warming signals. Century‐long western Pacific records of subannual sea surface temperature (SST) and sea surface salinity (SSS), derived from coral Sr/Ca and δ18O profiles, respectively, allow for evaluating different climatic sensitivities and identifying PDO‐related variability in the region. The summer Sr/Ca‐SST record provides evidence of a significant SST increase, likely tied to greenhouse gas emissions. Anthropogenic warming is masked in the winter Sr/Ca‐SST record by interannual to multidecadal scale changes driven by the East‐Asian Winter Monsoon and the PDO. Decadal climate variability during winter is strongly correlated to the PDO, in agreement with other PDO records in the region. The PDO also exerts influence on the SSS difference between the dry and wet season coral δ18O (δ18Oc)‐SSS records through water advection. The PDO and El Niño–Southern Oscillation constructively combine to enhance/reduce advection of saline Kuroshio waters at our site. Overall, we are able to demonstrate that climate records from a tropical reef environment significantly capture PDO variability and related changes over the period of a century. This implies that the tropical western Pacific is a key site in understanding multifrequency climate variability, including its impact on tropical climate at longer timescales.
    Description: The authors would like to thank J. Ossolinski, J. Aggangan, J. Quevedo, R. Lloren, G. Albano, J. Perez, and A. Bolton for their help in acquiring core samples in the field. The detailed comments and suggestions of two anonymous reviewers significantly improved the original manuscript. This research was funded by the National Research Foundation Singapore under its Singapore NRF Fellowship scheme awarded to N. F. Goodkin (National Research Fellow award NRF‐RF2012‐03), as administered by the Earth Observatory of Singapore and the Singapore Ministry of Education under the Research Centers of Excellence initiative and by the Ministry of Education, Singapore through its Academic Research Fund Tier 2 (Project MOE2016‐T2‐1‐016). The coral Sr/Ca and δ18O data generated in this study are available in the supporting information Data Set S1 and are archived at the NOAA NCDC World Data Center for Paleoclimatology (https://www.ncdc.noaa.gov/paleo/study/27271). Other data and resources used in this study were sourced from the following sites: PDO index (http://research.jisao.washington.edu/pdo/PDO.latest); IPO index (https://www.esrl.noaa.gov/psd/data/timeseries/IPOTPI/ipotpi.hadisst2.data); NP index (https://www.esrl.noaa.gov/psd/data/correlation/np.data); PDO and North Pacific SST reconstructions (https://www.ncdc.noaa.gov/data‐access/paleoclimatology‐data); and MTM coherence and phase analysis MATLAB® code (https://www.mathworks.com/matlabcentral/fileexchange/22551‐multi‐taper‐coherence‐method‐with‐bias‐correction).
    Keywords: Coral proxies ; PDO ; ENSO ; EAWM ; Western Pacific
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  • 72
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Ma, Q., Dick, H. J. B., Urann, B., & Zhou, H. Silica-rich vein formation in an evolving stress field, Atlantis Bank Oceanic Core Complex. Geochemistry Geophysics Geosystems, 21(7), (2020): e2019GC008795, doi:10.1029/2019GC008795.
    Description: Drilling 809‐m Hole U1473A in the gabbro batholith at the Atlantis Bank Oceanic Core Complex (OCC) found two felsic vein generations: late magmatic fractionates, rich in deuteric water, hosted by oxide gabbros, and anatectic veins associated with dike intrusion and introduction of seawater‐derived volatiles. Microtextures show a change from compressional to tensional stress during vein formation. Temperatures and oxidation state were obtained from amphibole‐plagioclase and oxide pairs in the adjacent gabbros. Type I veins generally have reverse shear‐sense, with restricted ΔFMQ, high Mt/Ilm ratios, and low‐amphibole Cl/F indicating deuteric fluids. They formed during percolation and fractionation of Fe‐Ti‐rich melts into the primary olivine gabbro. Type II veins are usually hosted by olivine gabbro, occur at dike contacts and the margins of normal‐sense shear zones. They are undeformed or weakly deformed, with highly variable ΔFMQ, low Mt/Ilm ratios, and high‐amphibole Cl/F, indicating seawater‐derived fluids. The detachment fault on which the gabbro massif was emplaced rooted near the base of the dike‐gabbro transition beneath the rift valley. The ingress of seawater volatiles began at 〉800°C and penetrated at least ~590 m into the lower crust during extensional faulting in the rift valley and adjacent rift mountains. The sequence of the felsic vein formation likely reflects asymmetric diapiric flow, with a reversal of the stress regime, and a transition from juvenile to seawater‐derived volatiles. This, in turn, is consistent with fault capture leading to the large asymmetries in spreading rates during OCC formations and heat flow beneath the rift mountains.
    Description: This study was supported by the Chinese National Key Basic Research Program (Grant 2012CB417300). H. Dick and B. Urann were supported by U.S. National Science Foundation (Grant OCE‐MG&G 8371300). Emmanuel Codillo provided numerous useful comments and moral support. We thank N. Chatterjee for assistance in analyzing major element mineral composition in the MIT Electron Microprobe Laboratory. The great contributions of 360 Scientific Party for their initial shipboard description and interpretations of the Hole U1473A cores made this work possible. Special thanks go to C. J. MacLeod, Expedition cochief scientist, and Peter Blum, staff scientist, Stephen Midgley, IODP operations superintendent, and Siem Offshore James Samuel McLelland, offshore installation manager, ship's master Terry Skinner, and the crew and drillers on the JOIDES Resolution.
    Keywords: Felsic veins ; Magma chambers ; Ocean ridge ; Geothermometry ; Flourine‐chlorine ; Dynamics
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  • 73
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Spooner, P. T., Thornalley, D. J. R., Oppo, D. W., Fox, A. D., Radionovskaya, S., Rose, N. L., Mallett, R., Cooper, E., & Roberts, J. M. Exceptional 20th century ocean circulation in the Northeast Atlantic. Geophysical Research Letters, 47(10), (2020): e2020GL087577, doi:10.1029/2020GL087577.
    Description: The North Atlantic subpolar gyre (SPG) connects tropical and high‐latitude waters, playing a leading role in deep‐water formation, propagation of Atlantic water into the Arctic, and as habitat for many ecosystems. Instrumental records spanning recent decades document significant decadal variability in SPG circulation, with associated hydrographic and ecological changes. Emerging longer‐term records provide circumstantial evidence that the North Atlantic also experienced centennial trends during the 20th century. Here, we use marine sediment records to show that there has been a long‐term change in SPG circulation during the industrial era, largely during the 20th century. Moreover, we show that the shift and late 20th century SPG configuration were unprecedented in the last 10,000 years. Recent SPG dynamics resulted in an expansion of subtropical ecosystems into new habitats and likely also altered the transport of heat to high latitudes.
    Description: We thank Janet Hope and UCL laboratory staff, colleagues who sailed on EN539, Kathryn Pietro‐Rose, Sean O'Keefe and Henry Abrams, Sara Chipperton, Tanya Monica, Laura Thrower and Kitty Green for sediment processing, Miles Irving for artwork assistance, James Rolfe for nitrogen isotope measurement, Maryline Vautravers and Michael Kucera for guidance, Arne Biastoch and Christian Mohn for discussion of VIKING20, and Chris Brierley, Meric Srokosz, and Jon Robson for comments. Funding was provided by National Science Foundation (NSF) grant OCE‐1304291 to D.W.O. and D.J.R.T., the Leverhulme Trust, National Environment Research Council (NERC) grant NE/S009736/1, and the ATLAS project to D.J.R.T. This project has received funding from the European Union's Horizon 2020 research and innovation program under grant agreement 678760 (ATLAS). This paper reflects only the authors views and the European Union cannot be held responsible for any use that may be made of the information contained herein.
    Keywords: Foraminifera ; Subpolar gyre ; North Atlantic ; Ocean circulation ; Industrial era
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  • 74
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(10), (2020): e2020GL087215, doi:10.1029/2020GL087215.
    Description: Cross‐equator transects occupied by an underwater glider and a research vessel in the western Indian Ocean captured the evolution of equatorial circulation during onset of the boreal summer monsoon in 2018. At the end of the winter monsoon in March, surface currents were westward, while the equatorial undercurrent carried salty Arabian Sea High‐Salinity Water eastward. As winds transitioned from westward to eastward during April, an eastward near‐surface Wyrtki Jet developed, while the equatorial undercurrent weakened, vanishing by May. A first‐mode baroclinic Kelvin wave propagated through the survey region after westward winds relaxed. However, the vertical structure of the evolving circulation was inconsistent with the first baroclinic mode, suggesting the influence of higher modes in setting observed vertical structure. The strong equatorial undercurrent at the end of the winter monsoon allowed high‐salinity waters from the western equatorial Indian Ocean to reach the southern Bay of Bengal in summer 2018.
    Description: This work was supported by the Office of Naval Research as part of the NASCar DRI under Grant N000141512632 and as part of the MISO‐BOB DRI under Grant N000141712968.
    Keywords: Monsoon ; Indian Ocean ; Equatorial ; Underwater glider ; Equatorial undercurrent
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  • 75
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016147, doi:10.1029/2020JC016147.
    Description: Net ecosystem calcification (NEC) rates of Palau's largest lagoon and barrier reef system between 1992 and 2015 are estimated from sparse total alkalinity (TA) and salinity measurements and a tidal exchange model in which surface lagoon water transported offshore on the ebb tide is replaced by saltier (denser) ocean water that sinks to the bottom after entering the lagoon on the flood tide. Observed lagoon salinities are accurately reproduced by the model with no adjustable parameters. To accurately reproduce observed lagoon TA, NEC for the lagoon‐barrier reef system was 70 mmols m−2 day−1 from 1992 to 1998, 35 mmols m−2 day−1 from 1999 to 2012, and 25 mmols m−2 day−1 from 2013 to 2015. This indicates that Palau's largest lagoon and barrier reef system has not recovered, as of 2015, from the 50% decline in NEC in 1998 caused by the loss of coral cover following a severe bleaching event. The cause of the further decline in NEC in 2012–2013 is unclear. Lagoon residence times vary from 8 days during spring tides to 14 days during neap tides and drive substantial spring‐neap variations in lagoon TA (~25% of the mean salinity‐normalized ocean‐lagoon TA difference). Sparse measurements that do not resolve these spring‐neap variations can exhibit apparent long‐term variations in alkalinity that are not due to changes in NEC.
    Description: This work was partially supported by NSF award 1220529 to A.L.C., S.J.L., and K.E.F.S and NSF award 1737311 to A.L.C. and the Oceanography Department, Texas A&M University K.E.F.S.
    Description: 2021-01-06
    Keywords: Coral reef ; Calcification ; Bleaching ; Residence time ; Net ecosystem calcification ; Palau
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  • 76
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Dunlea, A. G., Murray, R. W., Tada, R., Alvarez-Zarikian, C. A., Anderson, C. H., Gilli, A., Giosan, L., Gorgas, T., Hennekam, R., Irino, T., Murayama, M., Peterson, L. C., Reichart, G., Seki, A., Zheng, H., & Ziegler, M. Intercomparison of XRF core scanning results from seven labs and approaches to practical calibration. Geochemistry Geophysics Geosystems, 21(9), (2020): e2020GC009248, doi:10.1029/2020GC009248.
    Description: X‐ray fluorescence (XRF) scanning of marine sediment has the potential to yield near‐continuous and high‐resolution records of elemental abundances, which are often interpreted as proxies for paleoceanographic processes over different time scales. However, many other variables also affect scanning XRF measurements and convolute the quantitative calibrations of element abundances and comparisons of data from different labs. Extensive interlab comparisons of XRF scanning results and calibrations are essential to resolve ambiguities and to understand the best way to interpret the data produced. For this study, we sent a set of seven marine sediment sections (1.5 m each) to be scanned by seven XRF facilities around the world to compare the outcomes amidst a myriad of factors influencing the results. Results of raw element counts per second (cps) were different between labs, but element ratios were more comparable. Four of the labs also scanned a set of homogenized sediment pellets with compositions determined by inductively coupled plasma‐optical emission spectrometry (ICP‐OES) and ICP‐mass spectrometry (MS) to convert the raw XRF element cps to concentrations in two ways: a linear calibration and a log‐ratio calibration. Although both calibration curves are well fit, the results show that the log‐ratio calibrated data are significantly more comparable between labs than the linearly calibrated data. Smaller‐scale (higher‐resolution) features are often not reproducible between the different scans and should be interpreted with caution. Along with guidance on practical calibrations, our study recommends best practices to increase the quality of information that can be derived from scanning XRF to benefit the field of paleoceanography.
    Description: Funding for this research was provided by the U.S. National Science Foundation to R. W. M. (Grant 1130531). USSSP postcruise support was provided to Expedition 346 shipboard participants A. G. D., R. W. M., L. G., C. A. Z., and L. P. Portions of this material are based upon work supported while R. W. M. was serving at the National Science Foundation.
    Keywords: XRF scanning ; Quantitative XRF ; Paleoceanography ; Sedimentary geochemistry ; XRF calibration ; XRF intercomparison
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  • 77
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125(9),(2020): e2020JB020393, doi:10.1029/2020JB020393.
    Description: Fast diffusing Li isotopes provide important insights into the “recent” transient events or processes for both modern and ancient times, but questions remain concerning the large Li isotopic variations of mantle peridotites, which greatly hampers their usage as a geochemical tracer. This study investigates in situ Li content and isotopic profiles of the constituent minerals of abyssal peridotites from the Gakkel Ridge and Southwest Indian Ridge. The complicated and large variations of Li isotopic profiles in Clinopyroxene (Cpx) and Orthopyroxene (Opx) indicate Li isotopic disequilibrium at millimeter scale. The negative correlations of a wide range of Li contents (0.5 to 6.5 ppm) and δ7Li values (−10 to +20‰) of olivine, Opx and Cpx grains/relicts, trace element zoning of Cpx, the occurrence of plagioclase, olivine serpentinization along cracks, together with numerical modeling demonstrate the observed Li characteristics to be a manifestation of high‐temperature mineral‐melt Li diffusion during melt impregnation overprinted by low‐temperature mineral‐fluid Li diffusion during dissolution and serpentinization. The preservation of the Li isotopic diffusion profiles requires rapid cooling of 0.3–5°C/year after final‐stage melt impregnation at the Moho boundary, which is consistent with the low temperature at very slow spreadin g ridges caused by conductive cooling. Compared with the well‐studied melt‐rock interaction process, our study indicates that low‐temperature fluid‐rock interaction can induce Li diffusion even in the visibly unaltered mineral relicts of partially altered rocks.
    Description: This study was financially supported by the National Science Foundation of China (grant no. 41872058) and the U.S. National Science Foundation grant.
    Description: 2021-03-07
    Keywords: Li isotope ; Abyssal peridotite ; Isotope diffusion ; Melt‐rock interaction ; Fluid‐rock interaction
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  • 78
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(8), (2020): e2020JC016091, doi:10.1029/2020JC016091.
    Description: The floating ice tongue of 79 North Glacier, a major outlet glacier of the Northeast Greenland Ice Stream, has thinned by 30% since 1999. Earlier studies have indicated that long‐term warming of Atlantic Intermediate Water (AIW) is likely driving increased basal melt, causing the observed thinning. Still, limited ocean measurements in 79 North Fjord beneath the ice tongue have made it difficult to test this hypothesis. Here we use data from an Ice Tethered Mooring (ITM) deployed in a rift in the ice tongue from August 2016 to July 2017 to show that the subannual AIW temperature variability is smaller than the observed interannual variability, supporting the conclusion that AIW has warmed over the period of ice tongue thinning. In July 2017, the AIW at 500 m depth in the ice tongue cavity reached a maximum recorded temperature of 1.5°C. Velocity measurements reveal weak tides and a mean overturning circulation, which is likely seasonally enhanced by subglacial runoff discharged at the grounding line. Deep inflow of AIW and shallow export of melt‐modified water persist throughout the record, indicating year‐round basal melting of the ice tongue. Comparison with a mooring outside of the cavity suggests a rapid exchange between the cavity and continental shelf. Warming observed during 2016–2017 is estimated to drive a 33 ± 20% increase in basal melt rate near the ice tongue terminus and a 14 ± 2% increase near the grounding line if sustained.
    Description: Funding for the ITM was provided by the Grossman Family Foundation through the WHOI Development Office. M. R. L. is supported by a National Defense Science and Engineering Graduate Fellowship. N. L. B. is supported by a grant from the National Science Foundation (NSF OCE‐1536856).
    Description: 2021-02-10
    Keywords: 79 North ; Basal melt ; Fjord ; Greenland ; Ice ocean interaction ; Ice shelf
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  • 79
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Atmospheres 125(18), (2020): e2019JD032368, doi:10.1029/2019JD032368.
    Description: Hurricane Irma (2017) underwent rapid intensification (RI) while passing over the Amazon‐Orinoco River plume in the tropical Atlantic. The freshwater discharge from the plume creates a vertical salinity gradient that suppresses turbulent heat flux from the cool, ocean subsurface. The stability within the plume reduces sea surface temperature (SST) cooling and promotes energetic air‐sea fluxes. Hence, it is hypothesized that this ocean feature may have facilitated Irma's RI through favorable upper ocean conditions. This hypothesis is validated using a collection of atmospheric and oceanic observations to quantify how the ocean response influences surface flux and atmospheric boundary layer thermodynamics during Hurricane Irma's RI over the river plume. Novel aircraft‐deployed oceanic profiling floats highlight the detailed evolution of the ocean response during Irma's passage over the river plume. Analyses include quantifying the ocean response and identifying how it influenced atmospheric boundary layer temperature, moisture, and equivalent potential temperature (θE). An atmospheric boundary layer recovery analysis indicates that surface fluxes were sufficient to support the enhanced boundary layer θE (moist entropy) observed, which promotes inner‐core convection and facilitates TC intensification. The implicit influence of salinity stratification on Irma's intensity during RI is assessed using theoretical intensity frameworks. Overall, the findings suggest that the salinity stratification sustained SST during Irma's passage, which promoted energetic air‐sea fluxes that aided in boundary layer recovery and facilitated Irma's intensity during RI. Examination of the air‐sea coupling over this river plume, corresponding atmospheric boundary layer response, and feedback on TC intensity was previously absent in literature.
    Description: This research was performed while the corresponding author held an NRC Research Associateship Award at the U.S. Naval Research Lab, Monterey. Chen is supported by Office of Naval Research (ONR) grant N0001416WX00470. Sanabia is sponsored by ONR grants N0001416WX01384 and N0001416WX01262. Jayne is supported by National Oceanic and Atmospheric Administration (NOAA) grant NA13OAR4830233.The authors gratefully acknowledge the HRD scientists, NOAA AOC crews, U.S. Air Force crews, and U.S. Navy crews who were involved in the collection of both atmospheric and oceanic data. This research would not be possible without your efforts. We are thankful for helpful discussion and pre‐RI AXBT data provided by Jun Zhang (NOAA/HRD).
    Description: 2020-12-12
    Keywords: Hurricane Irma ; Air-sea interaction ; Atmospheric boundary layer ; River plume ; Tropical cyclone ; Upper ocean response
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  • 80
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Reviews of Geophysics 58(3), (2020): e2019RG000672, doi:10.1029/2019RG000672.
    Description: Global sea level provides an important indicator of the state of the warming climate, but changes in regional sea level are most relevant for coastal communities around the world. With improvements to the sea‐level observing system, the knowledge of regional sea‐level change has advanced dramatically in recent years. Satellite measurements coupled with in situ observations have allowed for comprehensive study and improved understanding of the diverse set of drivers that lead to variations in sea level in space and time. Despite the advances, gaps in the understanding of contemporary sea‐level change remain and inhibit the ability to predict how the relevant processes may lead to future change. These gaps arise in part due to the complexity of the linkages between the drivers of sea‐level change. Here we review the individual processes which lead to sea‐level change and then describe how they combine and vary regionally. The intent of the paper is to provide an overview of the current state of understanding of the processes that cause regional sea‐level change and to identify and discuss limitations and uncertainty in our understanding of these processes. Areas where the lack of understanding or gaps in knowledge inhibit the ability to provide the needed information for comprehensive planning efforts are of particular focus. Finally, a goal of this paper is to highlight the role of the expanded sea‐level observation network—particularly as related to satellite observations—in the improved scientific understanding of the contributors to regional sea‐level change.
    Description: The research was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration. The authors acknowledge support from the National Aeronautics and Space Administration under Grants 80NSSC17K0565, 80NSSC170567, 80NSSC17K0566, 80NSSC17K0564, and NNX17AB27G. A. A. acknowledges support under GRACE/GRACEFO Science Team Grant (NNH15ZDA001N‐GRACE). T. W. acknowledges support by the National Aeronautics and Space Administration (NASA) under the New (Early Career) Investigator Program in Earth Science (Grant: 80NSSC18K0743). C. G. P was supported by the J. Lamar Worzel Assistant Scientist Fund and the Penzance Endowed Fund in Support of Assistant Scientists at the Woods Hole Oceanographic Institution.
    Keywords: Sea level ; Satellite observations ; Remote sensing
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  • 81
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 47(22), (2020): e2020GL090431, doi:10.1029/2020GL090431.
    Description: Vast quantities of solid CO2 reside in topographic basins of the south polar layered deposits (SPLD) on Mars and exhibit morphological features indicative of glacial flow. Previous experimental studies showed that CO2 ice is 1–2 orders of magnitude weaker than water ice under Martian polar conditions. Here we present data from deformation experiments on pure, fine‐grained CO2 ice, over a broader range of temperatures than previously explored (158–213 K). The experiments confirm previous observations of highly nonlinear power law creep at larger stresses, but also show a transition to a previously unseen linear‐viscous creep regime at lower stresses. We examine the viscosity of CO2 within the SPLD and predict that the CO2‐rich deposits are modestly stronger than previously thought. Nevertheless, CO2 ice flows much more readily than H2O ice, particularly on the steep flanks of SPLD topographic basins, allowing the CO2 to pond as observed.
    Description: This work was funded by NASA grant NNH16ZDA001N‐SSW awarded to Smith and Goldsby. Additional salary support for Cross was provided by the WHOI Investment in Science Fund.
    Description: 2021-04-29
    Keywords: SPLD ; Mars ; Glacier ; Carbon dioxide ; Flow law ; Creep
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  • 82
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(5), (2020): e2019JC015377, doi:10.1029/2019JC015377.
    Description: Internal waves strongly influence the physical and chemical environment of coastal ecosystems worldwide. We report novel observations from a distributed temperature sensing (DTS) system that tracked the transformation of internal waves from the shelf break to the surf zone over a narrow shelf slope region in the South China Sea. The spatially continuous view of temperature fields provides a perspective of physical processes commonly available only in laboratory settings or numerical models, including internal wave reflection off a natural slope, shoreward transport of dense fluid within trapped cores, and observations of internal rundown (near‐bed, offshore‐directed jets of water preceding a breaking internal wave). Analysis shows that the fate of internal waves on this shelf—whether transmitted into shallow waters or reflected back offshore—is mediated by local water column density structure and background currents set by the previous shoaling internal waves, highlighting the importance of wave‐wave interactions in nearshore internal wave dynamics.
    Description: We are grateful for the support of the Dongsha Atoll Research Station (DARS) and the Dongsha Atoll Marine National Park, whose efforts made this research possible. The authors would also like to thank A. Hall, S. Tyler, and J. Selker from the Center for Transformative Environmental Monitoring Programs (CTEMPs) funded by the National Science Foundation (EAR awards 1440596 and 1440506), G. Lohmann from WHOI, A. Safaie from UC Irvine, G. Wong, L. Hou, F. Shiah, and K. Lee from Academia Sinica for providing logistical and field support, as well as E. Pawlak, S. Lentz, B. Sanders, and S. Grant for equipment, and B. Raubenheimer, S. Elgar, R. Walter and D. Lucas for informative discussions that improved this work. We acknowledge the US Army Research Laboratory DoD Supercomputing Resource Center for computer time on Excalibur, which was used for the numerical simulations in this work. Funding for this work supported by Academia Sinica and for K.D. and E.R. from NSF‐OCE 1753317 and for O.F., J.R., and R.A. from ONR Grant 1182789‐1‐TDZZM. A portion of this work (R.A.) was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE‐AC52‐07NA27344.
    Description: 2020-10-21
    Keywords: Internal waves ; Distributed temperature sensing ; Coral reef ; Internal wave reflection
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  • 83
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Kirkels, F. M. S. A., Ponton, C., Galy, V., West, A. J., Feakins, S. J., & Peterse, F. From Andes to Amazon: assessing branched tetraether lipids as tracers for soil organic carbon in the Madre de Dios River system. Journal of Geophysical Research-Biogeosciences, 125(1), (2020): e2019JG005270, doi:10.1029/2019JG005270.
    Description: We investigate the implications of upstream processes and hydrological seasonality on the transfer of soil organic carbon (OC) from the Andes mountains to the Amazon lowlands by the Madre de Dios River (Peru), using branched glycerol dialkyl glycerol tetraether (brGDGT) lipids. The brGDGT signal in Andean soils (0.5 to 3.5 km elevation) reflects air temperature, with a lapse rate of −6.0 °C/km elevation (r 2 = 0.89, p 〈 0.001) and −5.6 °C/km elevation (r 2 = 0.89, p 〈 0.001) for organic and mineral horizons, respectively. The same compounds are present in river suspended particulate matter (SPM) with a lapse rate of −4.1 °C/km elevation (r 2 = 0.82, p 〈 0.001) during the wet season, where the offset in intercept between the temperature lapse rates for soils and SPM indicates upstream sourcing of brGDGTs. The lapse rate for SPM appears insensitive to an increasing relative contribution of 6‐methyl isomer brGDGTs produced within the river. River depth profiles show that brGDGTs are well mixed in the river and are not affected by hydrodynamic sorting. The brGDGTs accumulate relative to OC downstream, likely due to the transition of particulate OC to the dissolved phase and input of weathered soils toward the lowlands. The temperature‐altitude correlation of brGDGTs in Madre de Dios SPM contrasts with the Lower Amazon River, where the initial soil signature is altered by changes in seasonal in‐river production and variable provenance of brGDGTs. Our study indicates that brGDGTs in the Madre de Dios River system are initially soil derived and highlights their use to study OC sourcing in mountainous river systems.
    Description: The brGDGT analyses were supported by NWO‐Veni grant 863.13.016 to F.P. This material is based upon work supported by the US National Science Foundation under grant EAR‐1227192 to A. J. W. and S. J. F. for the river fieldwork and lipid purification. In Perú, we thank the Servicio Nacional de Áreas Naturales Protegidas por el Estado (SERNANP) and personnel of Manu and Tambopata National Parks for logistical assistance and permission to work in the protected areas. We thank the Explorers' Inn and the Pontifical Catholic University of Perú (PUCP), as well as the Amazon Conservation Association for the use of the Tambopata and Wayqecha Research Stations, respectively. For river fieldwork assistance, we thank M. Torres, A. Robles, and A. Cachuana. Soil samples were contributed by Andrew Nottingham and Patrick Meir. Logistical support was provided by Y. Malhi, J. Huaman, W. Huaraca Huasco, and other collaborators as part of the Andes Biodiversity and Ecosystems Research Group ABERG (www.andesresearch.org). We thank Dominika Kasjaniuk for technical support at Utrecht. Two anonymous reviewers have provided valuable comments that have helped to improve this manuscript. Geochemical and brGDGT data are available in the PANGAEA Data Repository (Kirkels et al., 2019) and can be accessed at https://doi.pangaea.de/10.1594/PANGAEA.906170
    Keywords: Bacterial membrane lipids (brGDGTs) ; Altitude‐temperature relations ; Amazon headwaters ; Soil‐river connectivity ; Riverine organic carbon transport, brGDGT proxy signal
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  • 84
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125 (2020): e2020JB020323, doi: 10.1029/2020JB020323.
    Description: Ultramylonites—intensely deformed rocks with fine grain sizes and well‐mixed mineral phases—are thought to be a key component of Earth‐like plate tectonics, because coupled phase mixing and grain boundary pinning enable rocks to deform by grain‐size‐sensitive, self‐softening creep mechanisms over long geologic timescales. In isoviscous two‐phase composites, “geometric” phase mixing occurs via the sequential formation, attenuation (stretching), and disaggregation of compositional layering. However, the effects of viscosity contrast on the mechanisms and timescales for geometric mixing are poorly understood. Here, we describe a series of high‐strain torsion experiments on nonisoviscous calcite‐fluorite composites (viscosity contrast, ηca/ηfl ≈ 200) at 500°C, 0.75 GPa confining pressure, and 10−6–10−4 s−1 shear strain rate. At low to intermediate shear strains (γ ≤ 10), polycrystalline domains of the individual phases become sheared and form compositional layering. As layering develops, strain localizes into the weaker phase, fluorite. Strain partitioning impedes mixing by reducing the rate at which the stronger (calcite) layers deform, attenuate, and disaggregate. Even at very large shear strains (γ ≥ 50), grain‐scale mixing is limited, and thick compositional layers are preserved. Our experiments (1) demonstrate that viscosity contrasts impede mechanical phase mixing and (2) highlight the relative inefficiency of mechanical mixing. Nevertheless, by employing laboratory flow laws, we show that “ideal” conditions for mechanical phase mixing may be found in the wet middle to lower continental crust and in the dry mantle lithosphere, where quartz‐feldspar and olivine‐pyroxene viscosity contrasts are minimized, respectively.
    Description: This work was funded through a National Science Foundation grant (EAR‐1352306) awarded to P. S., with additional support for A. J. C. provided by the McDonnell Center for the Space Sciences (Washington University in St. Louis), the J. Lamar Worzel Assistant Scientist Fund (WHOI), and the Penzance Endowed Fund in Support of Assistant Scientists (WHOI). Partial support for electron microscopy was provided by the Institute of Materials Science and Engineering (Washington University in St. Louis).
    Description: 2021-02-04
    Keywords: Ultramylonite ; Geometric mixing ; Strain partitioning ; Shear zone ; Calcite ; Torsion
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  • 85
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in DeGrandpre, M., Evans, W., Timmermans, M., Krishfield, R., Williams, B., & Steele, M. Changes in the arctic ocean carbon cycle with diminishing ice cover. Geophysical Research Letters, 47(12), (2020): e2020GL088051, doi:10.1029/2020GL088051.
    Description: Less than three decades ago only a small fraction of the Arctic Ocean (AO) was ice free and then only for short periods. The ice cover kept sea surface pCO2 at levels lower relative to other ocean basins that have been exposed year round to ever increasing atmospheric levels. In this study, we evaluate sea surface pCO2 measurements collected over a 6‐year period along a fixed cruise track in the Canada Basin. The measurements show that mean pCO2 levels are significantly higher during low ice years. The pCO2 increase is likely driven by ocean surface heating and uptake of atmospheric CO2 with large interannual variability in the contributions of these processes. These findings suggest that increased ice‐free periods will further increase sea surface pCO2, reducing the Canada Basin's current role as a net sink of atmospheric CO2.
    Description: This research was made possible by grants from the NSF Arctic Observing Network program (ARC‐1107346, PLR‐1302884, PLR‐1504410, and OPP‐1723308). In addition, M. S. was supported by ONR (Grant 00014‐17‐1‐2545), NASA (Grant NNX16AK43G), and NSF (Grants PLR‐1503298 and OPP‐1751363).
    Keywords: Arctic Ocean ; Ice concentration ; Seawater CO2 ; Interannual variability ; Canada Basin ; Shipboard CO2 measurements
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  • 86
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(7), (2020): e2019JC015676, doi:10.1029/2019JC015676.
    Description: The temperature‐salinity (T‐S) diagram is widely used in water mass analysis, but the boundaries between water masses are vaguely distinguished by conventional T‐S‐based methods. Herein, we propose a new method based on the potential density‐potential spicity (sigma‐pi) diagram. The new method has been applied to the conductivity‐temperature‐depth data collected in the northern South China Sea during a spring cruise in 2011. The water masses in the study region are classified into 13 types according to both the standard deviation of potential spicity in each potential density layer and the water volumetric distribution in the sigma‐pi space. The results suggest that this new method is reasonable and robust for classifying water masses in the sigma‐pi space as compared to previous methods based on the traditional T‐S space. In addition, the westward intrusion of the West Pacific Ocean water to the northern South China Sea can be clearly detected by the tongue‐like potential spicity structure and relatively high potential spicity patches on potential density layers, further verifying the robustness and efficiency of our method in the water mass analysis.
    Description: This work was supported by the National Natural Science Foundation of China (91958203, 41776027, and 11732010) and the National Basic Research Program of China (2015CB954004 and 2009CB421208). Funding of Y.G.'s cotutelle doctoral research project by Région Hauts‐de‐France and Xiamen University is acknowledged. All the cruise participants are appreciated. We also thank the editor and anonymous reviewers for their valuable comments.
    Description: 2020-12-20
    Keywords: Water mass ; Spicity ; Northern South China Sea
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  • 87
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Earth Surface 125 (2020): e2019JF005446, doi: 10.1029/2019JF005446.
    Description: Atoll reef islands primarily consist of unconsolidated sediment, and their ocean‐facing shorelines are maintained by sediment produced and transported across their reefs. Changes in incident waves can alter cross‐shore sediment exchange and, thus, affect the sediment budget and morphology of atoll reef islands. Here we investigate the influence of sea level rise and projected wave climate change on wave characteristics and cross‐shore sediment transport across an atoll reef at Kwajalein Island, Republic of the Marshall Islands. Using a phase‐resolving model, we quantify the influence on sediment transport of quantities not well captured by wave‐averaged models, namely, wave asymmetry and skewness and flow acceleration. Model results suggest that for current reef geometry, sea level, and wave climate, potential bedload transport is directed onshore, decreases from the fore reef to the beach, and is sensitive to the influence of flow acceleration. We find that a projected 12% decrease in annual wave energy by 2100 CE has negligible influence on reef flat hydrodynamics. However, 0.5–2.0 m of sea level rise increases wave heights, skewness, and shear stress on the reef flat and decreases wave skewness and shear stress on the fore reef. These hydrodynamic changes decrease potential sediment inputs onshore from the fore reef where coral production is greatest but increase potential cross‐reef sediment transport from the outer reef flat to the beach. Assuming sediment production on the fore reef remains constant or decreases due to increasing ocean temperatures and acidification, these processes have the potential to decrease net sediment delivery to atoll islands, causing erosion.
    Description: This study was supported by the Strategic Environmental Research and Development Program through awards SERDP: RC‐2334, and RC‐2336. Any use of trade, firm, or product names is for descriptive purposes only and does not imply endorsement by the U.S. Government.
    Description: 2021-03-25
    Keywords: Coral atolls ; Fringing reefs ; Sediment transport ; Wave model ; Wave climate ; Sea level rise
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  • 88
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Mankin, J. S., Lehner, F., Coats, S., & McKinnon, K. A. The value of initial condition large ensembles to robust adaptation decision-making. Earth's Future, 8(10), (2020): e2012EF001610, doi:10.1029/2020EF001610.
    Description: The origins of uncertainty in climate projections have major consequences for the scientific and policy decisions made in response to climate change. Internal climate variability, for example, is an inherent uncertainty in the climate system that is undersampled by the multimodel ensembles used in most climate impacts research. Because of this, decision makers are left with the question of whether the range of climate projections across models is due to structural model choices, thus requiring more scientific investment to constrain, or instead is a set of equally plausible outcomes consistent with the same warming world. Similarly, many questions faced by scientists require a clear separation of model uncertainty and that arising from internal variability. With this as motivation and the renewed attention to large ensembles given planning for Phase 7 of the Coupled Model Intercomparison Project (CMIP7), we illustrate the scientific and policy value of the attribution and quantification of uncertainty from initial condition large ensembles, particularly when analyzed in conjunction with multimodel ensembles. We focus on how large ensembles can support regional‐scale robust adaptation decision‐making in ways multimodel ensembles alone cannot. We also acknowledge several recently identified problems associated with large ensembles, namely, that they are (1) resource intensive, (2) redundant, and (3) biased. Despite these challenges, we show, using examples from hydroclimate, how large ensembles provide unique information for the scientific and policy communities and can be analyzed appropriately for regional‐scale climate impacts research to help inform risk management in a warming world.
    Description: F. L. has been supported by the Swiss NSF (grant no. PZ00P2_174128), the NSF Division of Atmospheric and Geospace Sciences (grant no. AGS‐0856145, Amendment 87), and the Regional and Global Model Analysis (RGMA) component of the Earth and Environmental System Modeling Program of the U.S.Department of Energy’s Office of Biological & Environmental Research (BER) via NSF IA 1844590. This is SOEST publication no. 11115.
    Keywords: Large ensembles ; Robust decision‐making ; Internal variability ; Initial conditions ; Climate adaptation
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  • 89
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Global Biogeochemical Cycles 35(4), (2021): e2020GB006887, https://doi.org/10.1029/2020GB006887.
    Description: In this study we report full-depth water column profiles for nitrogen and oxygen isotopic composition (δ15N and δ18O) of nitrate (NO3−) during the GEOTRACES GA01 cruise (2014). This transect intersects the double gyre system of the subtropical and subpolar regions of the North Atlantic separated by a strong transition zone, the North Atlantic Current. The distribution of NO3− δ15N and δ18O shows that assimilation by phytoplankton is the main process controlling the NO3− isotopic composition in the upper 150 m, with values increasing in a NO3− δ18O versus δ15N space along a line with a slope of one toward the surface. In the subpolar gyre, a single relationship between the degree of NO3− consumption and residual NO3− δ15N supports the view that NO3− is supplied via Ekman upwelling and deep winter convection, and progressively consumed during the Ekman transport of surface water southward. The co-occurrence of partial NO3− assimilation and nitrification in the deep mixed layer of the subpolar gyre elevates subsurface NO3− δ18O in comparison to deep oceanic values. This signal propagates through isopycnal exchanges to greater depths at lower latitudes. With recirculation in the subtropical gyre, cycles of quantitative consumption-nitrification progressively decrease subsurface NO3− δ18O toward the δ18O of regenerated NO3−. The low NO3− δ15N observed south of the Subarctic Front is mostly explained by N2 fixation, although a contribution from the Mediterranean outflow is required to explain the lower NO3− δ15N signal observed between 600 and 1500 m depth close to the Iberian margin.
    Description: The GEOVIDE project was co-funded by the French national program LEFE/INSU (GEOVIDE), ANR Blanc (GEOVIDE) and RPDOC, LabEX MER and IFREMER. F. Deman was supported by the Belgian Federal Science Policy Office (Belspo contract BL/12/C63) while writing the manuscript. This work was financed by Flanders Research Foundation (FWO contract G0715.12N) and Vrije Universiteit Brussel, R&D, Strategic Research Plan “Tracers of Past & Present Global Changes”. During the preparation of the manuscript, Debany Fonseca-Batista was supported by funding from the Canada First Research Excellence Fund, through an International Postdoctoral Fellowship of the Ocean Frontier Institute (OFI) at Dalhousie University.
    Description: 2021-10-02
    Keywords: Atlantic ; Isotopy ; Nitrate
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  • 90
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Tectonics 39(11), (2020): e2020TC006409, doi:10.1029/2020TC006409.
    Description: The dynamics of continental breakup at convergent margins has been described as the results of backarc opening caused by slab rollback or drag force induced by subduction direction reversal. Although the rollback hypothesis has been intensively studied, our understanding of the consequence of subduction direction reversal remains limited. Using thermo‐mechanical modeling based on constraints from the South China Sea (SCS) region, we investigate how subduction direction reversal controls the breakup of convergent margins. The numerical results show that two distinct breakup modes, namely, continental interior and edge breakup (“edge” refers to continent above the plate boundary interface), may develop depending on the “maturity” of the convergent margin and the age of the oceanic lithosphere. For a slab age of ~15 to ~45 Ma, increasing the duration of subduction promotes the continental interior breakup mode, where a large block of the continental material is separated from the overriding plate. In contrast, the continental edge breakup mode develops when the subduction is a short‐duration event, and in this mode, a wide zone of less continuous continental fragments and tearing of the subducted slab occur. These two modes are consistent with the interior (relic late Mesozoic arc) and edge (relic forearc) rifting characteristics in the western and eastern SCS margin, suggesting that variation in the northwest‐directed subduction duration of the Proto‐SCS might be a reason for the differential breakup locus along the strike of the SCS margin. Besides, a two‐segment trench associated with the northwest‐directed subduction is implied in the present‐day SCS region.
    Description: This research was supported by the Guangdong NSF research team project (2017A030312002), the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou) (GML2019ZD0205), the K. C. Wong Education Foundation (GJTD‐2018‐13), the Strategic Priority Research Program of the Chinese Academy of Science (XDA13010303), the Chinese Academy of Sciences (Y4SL021001, QYZDY‐SSWDQC005, 133244KYSB20180029, and ISEE2019ZR01), the NSFC project (41606073, 41890813, and 41576070), the IODP‐China Foundation, the OMG Visiting Fellowship (OMG18‐15), and the Hong Kong Research Grant Council Grants (Nos. 14313816 and 14304820).
    Description: 2021-04-06
    Keywords: Continental breakup ; Convergent margins ; Edge breakup ; Subduction direction reversal ; Proto‐South China Sea ; Numerical modeling
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  • 91
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 125(12),(2020): e2020JB020040, https://doi.org/10.1029/2020JB020040.
    Description: We model the magnetic signature of rift‐related volcanism to understand the distribution and volume of magmatic activity that occurred during the breakup of Pangaea and early Atlantic opening at the Eastern North American Margin (ENAM). Along‐strike variations in the amplitude and character of the prominent East Coast Magnetic Anomaly (ECMA) suggest that the emplacement of the volcanic layers producing this anomaly similarly varied along the margin. We use three‐dimensional magnetic forward modeling constrained by seismic interpretations to identify along‐margin variations in volcanic thickness and width that can explain the observed amplitude and character of the ECMA. Our model results suggest that the ECMA is produced by a combination of both first‐order (~600–1,000 km) and second‐order (~50–100 km) magmatic segmentation. The first‐order magmatic segmentation could have resulted from preexisting variations in crustal thickness and rheology developed during the tectonic amalgamation of Pangaea. The second‐order magmatic segmentation developed during continental breakup and likely influenced the segmentation and transform fault spacing of the initial, and modern, Mid‐Atlantic Ridge. These variations in magmatism show how extension and thermal weakening was distributed at the ENAM during continental breakup and how this breakup magmatism was related to both previous and subsequent Wilson cycle stages.
    Description: Thanks to Anne Bécel, Dan Lizarralde, Collin Brandl, Brandon Shuck, and Mark Everett for beneficial discussion and assistance in compiling the archived data used in this study. We thank Debbie Hutchinson (USGS Woods Hole Coastal and Marine Science Center) for passing along her vast breadth of knowledge on the ENAM through numerous constructive suggestions to greatly strengthen our manuscript. We greatly appreciate the insightful comments from two reviewers, the Associate Editor, and the Editor that significantly improved the manuscript. Thanks to Maurice Tivey for providing codes that aided our magnetic modeling efforts. Project completed as part of J.A.G.'s Ph.D. dissertation at Texas A&M University.
    Description: 2021-05-16
    Keywords: ENAM ; Rifted margin ; Breakup magmatism ; Magnetic modeling ; Continental breakup ; Atlantic Ocean
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  • 92
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(12), (2020): e2020JC016543, https://doi.org/10.1029/2020JC016543.
    Description: On coral reefs, flow determines residence time of water influencing physical and chemical environments and creating observable microclimates within the reef structure. Understanding the physical mechanisms driving environmental variability on shallow reefs, which distinguishes them from the open ocean, is important for understanding what contributes to thermal resilience of coral communities and predicting their response to future anomalies. In June 2014, a field experiment conducted at Dongsha Atoll in the northern South China Sea investigated the physical forces that drive flow over a broad shallow reef flat. Instrumentation included current and pressure sensors and a distributed temperature sensing system, which resolved spatially and temporally continuous temperature measurements over a 3‐km cross‐reef section from the lagoon to reef crest. Spectral analysis shows that while diurnal variability was significant across the reef flat—a result expected from daily solar heating—temperature also varied at higher frequencies near the reef crest. These spatially variable temperature regimes, or thermal microclimates, are influenced by circulation on the wide reef flat, with spatially and temporally variable contributions from tides, wind, and waves. Through particle tracking simulations, we find the residence time of water is shorter near the reef crest (3.6 h) than near the lagoon (8.6 h). Tidal variability in flow direction on the reef flat leads to patterns in residence time that are different than what would be predicted from unidirectional flow. Circulation on the reef also determines the source (originating from offshore vs. the lagoon) of the water present on the reef flat.
    Description: We thank S. Tyler, and J. Selker from the Center for Transformative Environmental Monitoring Programs (CTEMPs), funded by the National Science Foundation (EAR awards 1440596 and 1440506), for timely and effective provision of experimental design support, logistical support and equipment for the project. Support for S. Lentz is from NSF Grant No. OCE‐1558343. Support for A. Cohen from NSF Grant No. 1220529, by the Academia Sinica (Taiwan) through a thematic project grant to G. Wong and A. Cohen. Support for E. Reid and K. Davis is from National Science Foundation (NSF) Grant No. OCE‐1753317, and support to E. Reid from the Environmental Engineering Henry Samueli Endowed Fellowship and the UCI Oceans Graduate Fellowship.
    Description: 2021-05-23
    Keywords: Coral reef ; Distributed temperature sensing ; Temperature variability
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  • 93
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography and Paleoclimatology 35(12), (2020): e2020PA003853, https://doi.org/10.1029/2020PA003853.
    Description: During the middle Miocene, Earth's climate changed from a global warm period (Miocene Climatic Optimum) into a colder one with the expansion of the Antarctic ice sheet. This prominent climate transition was also a period of drastic changes in global atmospheric circulation. The development of the South Asian monsoon is not well understood and mainly derived from proxy records of wind strength. Data for middle Miocene changes in rainfall are virtually non‐existent for India and the Arabian Sea prior to 11 Ma. This study presents planktic foraminiferal trace element (Mg/Ca and Ba/Ca) and stable oxygen isotope records from NGHP‐01 Site 01A off the coast of West India in the Eastern Arabian Sea (EAS) to reconstruct the regional surface hydrography and hydroclimate in the South Asian monsoon (SAM) region during the middle Miocene. The Ba/Ca and local seawater δ18O (δ18Osw) changes reveal a notable gradual increase in SAM rainfall intensity during the middle Miocene. Additionally to this long‐term increase in precipitation, the seawater δ18O is punctuated by a prominent decrease, i.e. freshening, at ~14 Ma contemporary with Antarctic glaciation. This suggests that Southern Ocean Intermediate Waters (SOIW) transmitted Antarctic salinity changes into the Arabian Sea via an “oceanic tunnel” mechanism. The middle Miocene increase in SAM rainfall is consistent with climate model simulations of an overall strengthening Asian monsoon from the Eocene to the middle/late Miocene with a further acceleration after the middle Miocene climate transition.
    Description: This study has been funded by the National Natural Science Foundation of China through a grant to S. Steinke (NSFC grant No. 41776055) and Z. Jian and S. Steinke (NSFC grant No. 919582080). We express our gratitude to H. Kuhnert (MARUM, University of Bremen) and his team for stable isotope analyses. We thank P. Qiao (Tongji University Shanghai) for technical and analytical support with the ICP‐MS analyses, A. Dolman (Alfred‐Wegener‐Institute, Helmholtz Centre for Polar and Marine Research, Potsdam, Germany) for statistical analyses, and B. Wang (State Key Laboratory of Marine Environmental Science, Xiamen University) and his team for the SEM‐EDAX Energy Dispersive X‐ray Spectroscopy (EDS) analyses. L. Giosan acknowledges funding from USSP and WHOI and thanks colleagues and crew from the NGHP‐01 expedition for intellectual interactions leading to long‐standing interests in the fluvial‐continental margin systems of Peninsular India. J. Groeneveld thanks the State Key Laboratory of Marine Environmental Science (Xiamen University) for a MEL Senior Visiting Fellowship (Project No. MELRS1915).
    Description: 2021-05-27
    Keywords: Middle Miocene ; South Asian monsoon ; Arabian Sea ; Stable isotopes ; Trace elements
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  • 94
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry, Geophysics, Geosystems 21(12), (2020): e2020GC008914, https://doi.org/10.1029/2020GC008914.
    Description: Rarely have small seamounts on the flanks of hotspot derived ocean‐island volcanoes been the targets of sampling, due to sparse high‐resolution mapping near ocean islands. In the Galápagos Archipelago, for instance, sampling has primarily targeted the subaerial volcanic edifices, with only a few studies focusing on large‐volume submarine features. Sampling restricted to these large volcanic features may present a selection bias, potentially resulting in a skewed view of magmatic and source processes because mature magmatic systems support mixing and volcanic accretion that overprints early magmatic stages. We demonstrate how finer‐scale sampling of satellite seamounts surrounding the volcanic islands in the Galápagos can be used to lessen this bias and thus, better constrain the evolution of these volcanoes. Seamounts were targeted in the vicinity of Floreana and Fernandina Islands, and between Santiago and Santa Cruz. In all regions, individual seamounts are typically monogenetic, but each seamount field requires multigenerational magmatic episodes to account for their geochemical variability. This study demonstrates that in the southern and eastern regions the seamounts are characterized by greater geochemical variability than the islands they surround but all three regions have (Sr‐Nd‐He) isotopic signatures that resemble neighboring islands. Variations in seamount chemistry from alkalic to tholeiitic near Fernandina support the concept that islands along the center of the hotspot track undergo greater mean depths of melting, as predicted by plume theory. Patterns of geochemical and isotopic enrichment of seamounts within each region support fine‐scale mantle heterogeneities in the mantle plume sourcing the Galápagos hotspot.
    Description: This work was carried out with funding from National Science Foundation Division of Ocean Sciences (OCE‐1634952 to V. D. Wanless, OCE‐1634685 to S. A. Soule). The authors have no competing interests to declare. We thank Sally Gibson and three anonymous reviewers for providing detailed and critical feedback on this manuscript.
    Description: 2021-05-06
    Keywords: Basalt ; Hotspot ; Mantle ; Ocean island ; Radiogenic isotope ; Trace element
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  • 95
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2021. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Solid Earth 126(1),(2021): e2020JB020982, https://doi.org/10.1029/2020JB020982.
    Description: Seismic anisotropy measurements show that upper mantle hydration at the Middle America Trench (MAT) is limited to serpentinization and/or water in fault zones, rather than distributed uniformly. Subduction of hydrated oceanic lithosphere recycles water back into the deep mantle, drives arc volcanism, and affects seismicity at subduction zones. Constraining the extent of upper mantle hydration is an important part of understanding many fundamental processes on Earth. Substantially reduced seismic velocities in tomography suggest that outer rise plate‐bending faults provide a pathway for seawater to rehydrate the slab mantle just prior to subduction. Estimates of outer‐rise hydration based on tomograms vary significantly, with some large enough to imply that, globally, subduction has consumed more than two oceans worth of water during the Phanerozoic. We found that, while the mean upper mantle wavespeed is reduced at the MAT outer rise, the amplitude and orientation of inherited anisotropy are preserved at depths 〉1 km below the Moho. At shallower depths, relict anisotropy is replaced by slowing in the fault‐normal direction. These observations are incompatible with pervasive hydration but consistent with models of wave propagation through serpentinized fault zones that thin to 〈100‐m in width at depths 〉1 km below Moho. Confining hydration to fault zones reduces water storage estimates for the MAT upper mantle from ∼3.5 wt% to 〈0.9 wt% H20. Since the intermediate thermal structure in the ∼24 Myr‐old MAT slab favors serpentinization, limited hydration suggests that fault mechanics are the limiting factor, not temperatures. Subducting mantle may be similarly dry globally.
    Description: National Science Foundation. Grant Numbers: OCE-0625178, OCE-0841063
    Description: 2021-06-15
    Keywords: Outer‐rise hydration ; Upper mantle anisotropy ; Upper mantle hydration
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  • 96
    Publication Date: 2022-10-26
    Description: Author Posting. © American Geophysical Union, 2020. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 125(10),(2020): e2020JC016507, https://doi.org/10.1029/2020JC016507.
    Description: Survival of Gulf Stream (GS) warm core rings (WCRs) was investigated using a census consisting of a total of 961 rings formed during the period 1980–2017. Kaplan‐Meier survival probability and Cox hazard proportional models were used for the analysis. The survival analysis was performed for rings formed in four 5° zones between 75° W and 55° W. The radius, latitude, and distance from the shelf‐break of a WCR at formation all had a significant effect on the survival of WCRs. A pattern of higher survival was observed in WCRs formed in Zone 2 (70°–65° W) or Zone 3 (65°–60° W) and then demised in Zone 1 (75°–70° W). Survival probability of the WCRs increased to more than 70% for those formed within a latitude band from 39.5° to 41.5° N. Survival probability is reduced when the WCRs are formed near the New England Seamounts.
    Description: We are grateful for financial supports from NOAA (NA11NOS0120038), NSF (OCE‐1851242), SMAST, and UMass Dartmouth. G. G. was supported by NSF under grant OCE‐1851261.
    Description: 2021-04-14
    Keywords: Gulf Stream ; Warm core rings ; Survival analysis
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  • 97
    Publication Date: 2022-10-26
    Description: © The Author(s), 2021. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Anderson, M., Wanless, V. D., Perfit, M., Conrad, E., Gregg, P., Fornari, D., & Ridley, W. I. Extreme heterogeneity in mid-ocean ridge mantle revealed in lavas from the 8 degrees 20 ' N near-axis seamount chain. Geochemistry Geophysics Geosystems, 22(1), (2021): e2020GC009322, https://doi.org/10.1029/2020GC009322.
    Description: Lavas that have erupted at near‐axis seamounts provide windows into mid‐ocean ridge mantle heterogeneity and melting systematics which are not easily observed on‐axis at fast‐spreading centers. Beneath ridges, most heterogeneity is obscured as magmas aggregate toward the ridge, where they efficiently mix and homogenize during transit and within shallow magma chambers prior to eruption. To understand the deeper magmatic processes contributing to oceanic crustal formation, we examine the compositions of lavas erupted along a chain of near‐axis seamounts and volcanic ridges perpendicular to the East Pacific Rise. We assess the chemistry of near‐ridge mantle using a ∼200 km‐long chain at ∼8°20′N. High‐resolution bathymetric maps are used with geochemical analyses of ∼300 basalts to evaluate the petrogenesis of lavas and the heterogeneity of mantle feeding these near‐axis eruptions. Major and trace element concentrations and radiogenic isotope ratios are highly variable on 〈1 km scales, and reveal a continuum of depleted, normal, and enriched basalts spanning the full range of ridge and seamount compositions in the northeast Pacific. There is no systematic compositional variability along the chain. Modeling suggests that depleted mid‐ocean ridge basalt (DMORB) lavas are produced by ∼5%–15% melting of a depleted mid‐ocean ridge (MOR) mantle. Normal mid‐ocean ridge basalts (NMORB) form from 5% to 15% melting of a slightly enriched MOR mantle. Enriched mid‐ocean ridge basalts (EMORB) range from 〈1% melting of 10% enriched mantle to 〉15% melting of 100% enriched mantle. The presence of all three lava types along the seamount chain, and on a single seamount closest to the ridge axis, confirms that the sub‐ridge mantle is much more heterogeneous than is commonly observed on‐axis and heterogeneity exists over small spatial scales.
    Description: This work was supported by NSF OCE‐MGG 1356610 (Romano and Gregg), NSF OCE‐MGG 1356822 (Fornari), NSF OCE‐MGG 1357150 (Perfit), NSF OCE‐MGG 2001314 (Perfit and Wanless), the Burnham Research Grant at Boise State University, and the Graduate School Funding Fellowship at University of Florida.
    Keywords: East Pacific Rise ; Mantle heterogeneity ; Mantle melting ; Mid‐ocean ridge basalt ; Near‐axis seamounts ; Seamount volcanism
    Repository Name: Woods Hole Open Access Server
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  • 98
    Publication Date: 2022-10-26
    Description: © The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Sutherland, K. M., Grabb, K. C., Karolewski, J. S., Plummer, S., Farfan, G. A., Wankel, S. D., Diaz, J. M., Lamborg, C. H., & Hansel, C. M. Spatial heterogeneity in particle-associated, light-independent superoxide production within productive coastal waters. Journal of Geophysical Research: Oceans, 125(10), (2020): e2020JC016747, https://doi.org/10.1029/2020JC016747.
    Description: In the marine environment, the reactive oxygen species (ROS) superoxide is produced through a diverse array of light‐dependent and light‐independent reactions, the latter of which is thought to be primarily controlled by microorganisms. Marine superoxide production influences organic matter remineralization, metal redox cycling, and dissolved oxygen concentrations, yet the relative contributions of different sources to total superoxide production remain poorly constrained. Here we investigate the production, steady‐state concentration, and particle‐associated nature of light‐independent superoxide in productive waters off the northeast coast of North America. We find exceptionally high levels of light‐independent superoxide in the marine water column, with concentrations ranging from 10 pM to in excess of 2,000 pM. The highest superoxide concentrations were particle associated in surface seawater and in aphotic seawater collected meters off the seafloor. Filtration of seawater overlying the continental shelf lowered the light‐independent, steady‐state superoxide concentration by an average of 84%. We identify eukaryotic phytoplankton as the dominant particle‐associated source of superoxide to these coastal waters. We contrast these measurements with those collected at an off‐shelf station, where superoxide concentrations did not exceed 100 pM, and particles account for an average of 40% of the steady‐state superoxide concentration. This study demonstrates the primary role of particles in the production of superoxide in seawater overlying the continental shelf and highlights the importance of light‐independent, dissolved‐phase reactions in marine ROS production.
    Description: This work was funded by grants from the Chemical Oceanography program of the National Science Foundation (OCE‐1355720 to C. M. H. and C. H. L.), NASA Earth and Space Science Fellowship (Grant NNX15AR62H to K. M. S.), Agouron Institute Postdoctoral Fellowship (K. M. S.), NSF GRFPs (2016230268 to K. C. G. and 2017250547 to S. P.), and a Sloan Research Fellowship (J. M. D.). The Guava flow cytometer was purchased through an NSF equipment improvement grant (1624593).
    Keywords: reactive oxygen species ; Extracellular superoxide ; Light‐independent ROS
    Repository Name: Woods Hole Open Access Server
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  • 99
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Chandanpurkar, H. A., Lee, T., Wang, X., Zhang, H., Fournier, S., Fenty, I., Fukumori, I., Menemenlis, D., Piecuch, C. G., Reager, J. T., Wang, O., & Worden, J. Influence of nonseasonal river discharge on sea surface salinity and height. Journal of Advances in Modeling Earth Systems, 14(2), (2022): e2021MS002715, https://doi.org/10.1029/2021MS002715.
    Description: River discharge influences ocean dynamics and biogeochemistry. Due to the lack of a systematic, up-to-date global measurement network for river discharge, global ocean models typically use seasonal discharge climatology as forcing. This compromises the simulated nonseasonal variation (the deviation from seasonal climatology) of the ocean near river plumes and undermines their usefulness for interdisciplinary research. Recently, a reanalysis-based daily varying global discharge data set was developed, providing the first opportunity to quantify nonseasonal discharge effects on global ocean models. Here we use this data set to force a global ocean model for the 1992–2017 period. We contrast this experiment with another experiment (with identical atmospheric forcings) forced by seasonal climatology from the same discharge data set to isolate nonseasonal discharge effects, focusing on sea surface salinity (SSS) and sea surface height (SSH). Near major river mouths, nonseasonal discharge causes standard deviations in SSS (SSH) of 1.3–3 practical salinity unit (1–2.7 cm). The inclusion of nonseasonal discharge results in notable improvement of model SSS against satellite SSS near most of the tropical-to-midlatitude river mouths and minor improvement of model SSH against satellite or in-situ SSH near some of the river mouths. SSH changes associated with nonseasonal discharge can be explained by salinity effects on halosteric height and estimated accurately through the associated SSS changes. A recent theory predicting river discharge impact on SSH is found to perform reasonably well overall but underestimates the impact on SSH around the global ocean and has limited skill when applied to rivers near the equator and in the Arctic Ocean.
    Description: This research was carried out in part at the Jet Propulsion Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004) with support from the Physical Oceanography (PO) and Modeling, Analysis, and Prediction (MAP) Programs. High-end computing resources for the numerical simulation were provided by the NASA Advanced Supercomputing Division at the Ames Research Center.
    Keywords: River discharge ; Sea surface salinity ; Sea surface height
    Repository Name: Woods Hole Open Access Server
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  • 100
    Publication Date: 2022-10-26
    Description: © The Author(s), 2022. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in German, C., Baumberger, T., Lilley, M., Lupton, J., Noble, A., Saito, M., Thurber, A., & Blackman, D. Hydrothermal exploration of the southern Chile Rise: sediment‐hosted venting at the Chile Triple Junction. Geochemistry Geophysics Geosystems, 23(3), (2022): e2021GC010317, https://doi.org/10.1029/2021gc010317.
    Description: We report results from a hydrothermal plume survey along the southernmost Chile Rise from the Guamblin Fracture Zone to the Chile Triple Junction (CTJ) encompassing two segments (93 km cumulative length) of intermediate spreading-rate mid-ocean ridge axis. Our approach used in situ water column sensing (CTD, optical clarity, redox disequilibrium) coupled with sampling for shipboard and shore based geochemical analyses (δ3He, CH4, total dissolvable iron (TDFe) and manganese, (TDMn)) to explore for evidence of seafloor hydrothermal venting. Across the entire survey, the only location at which evidence for submarine venting was detected was at the southernmost limit to the survey. There, the source of a dispersing hydrothermal plume was located at 46°16.5’S, 75°47.9’W, coincident with the CTJ itself. The plume exhibits anomalies in both δ3He and dissolved CH4 but no enrichments in TDFe or TDMn beyond what can be attributed to resuspension of sediments covering the seafloor where the ridge intersects the Chile margin. These results are indicative of sediment-hosted venting at the CTJ.
    Description: We acknowledge University of California Ship Funds for their support of that shiptime and the NOAA Ocean Exploration and Research Grant NA08OAR4600757 which supported the research presented here. Finally, we thank two anonymous reviewers whose important contributions helped to improve the final version of this paper. This is PMEL contribution number 5341.
    Keywords: Hydrothermal ; Geochemistry ; Chile Rise ; Chile Triple Junction ; Sediment hosted
    Repository Name: Woods Hole Open Access Server
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