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  • 1
    Publication Date: 2024-05-30
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The interpretation of stalagmite δ〈sup〉18〈/sup〉O in terms of reflecting Asian summer monsoon (ASM) precipitation is still elusive. Here, we present high‐resolution stalagmite trace element ratios (X/Ca, X = Mg, Sr, Ba) records from southwest China covering 116.09 to 4.07 ka BP. δ〈sup〉18〈/sup〉O, δ〈sup〉13〈/sup〉C, and X/Ca values exhibit clear precessional cycles, with δ〈sup〉18〈/sup〉O values reflecting ASM circulation/intensity, while X/Ca ratios capture local precipitation or evapotranspiration variations. Our results show that Northern Hemisphere summer insolation (NHSI) is the main driver of ASM intensity and precipitation phase variation, but global ice volume modulates the response magnitude of summer precipitation to insolation. During the Last Glacial Maximum, high ice volumes caused significant monsoon precipitation to decrease. In contrast to modern observations of the tripolar distribution of precipitation in China, our record is consistent with paleo‐precipitation records in southern and northern China.〈/p〉
    Description: Plain Language Summary: While it is well known that global changes have led to variations in the intensity and spatial distribution of Asian monsoon precipitation, the mechanisms behind this are not well understood. Paleoclimate records are essential for revealing the drivers behind monsoon variation. However, speleothem records from the Asian monsoon region rarely provide direct information on the amount of rainfall. Here we report on multiple indicator data sets from a stalagmite in southwestern China. It could help explore the variation of monsoon precipitation over the last ∼100,000 years. We find that the increase/decrease of Northern Hemisphere summer insolation controls the increase/decrease of Asian summer monsoon rainfall. In addition, global ice volume moderates the magnitude of rainfall response to insolation, and precipitation decreases significantly during high ice volume periods. Based on the present paleo‐precipitation records evidence, the existence of the spatial pattern of increasing/decreasing rainfall in central China corresponding to decreasing/increasing rainfall in northern and southern China remains ambiguous on the orbital scales, although the feature has been captured by some of the model simulations.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Stalagmite trace elements are indicators of regional hydrological environmental variations in Southwestern China〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Northern Hemisphere summer insolation and global ice volume modulate the phase and amplitude variations of regional hydrological environment〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉The meridional tripolar spatial pattern of precipitation in monsoon region in China on the orbital scale remains ambiguous〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: German Science Grant
    Description: Structure and Innovation Fund of the Region of Baden Württemberg
    Description: China Scholarship Council http://dx.doi.org/10.13039/501100004543
    Description: National Nature Science Foundation of China
    Description: Yunnan Fundamental Research Projects
    Description: Young and Middle‐age Academic and Technical Leader in Yunnan Province
    Description: https://doi.org/10.5281/zenodo.10072475
    Keywords: ddc:551 ; stalagmite ; trace elements ; Asian summer monsoon ; Northern Hemisphere summer insolation ; global ice volume ; regional hydrological environment
    Language: English
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  • 2
    Publication Date: 2024-04-19
    Description: The stable water isotopic composition in firn and ice cores provides valuable information on past climatic conditions. Because of uneven accumulation and post‐depositional modifications on local spatial scales up to hundreds of meters, time series derived from adjacent cores differ significantly and do not directly reflect the temporal evolution of the precipitated snow isotopic signal. Hence, a characterization of how the isotopic profile in the snow develops is needed to reliably interpret the isotopic variability in firn and ice cores. By combining digital elevation models of the snow surface and repeated high‐resolution snow sampling for stable water isotope measurements of a transect at the East Greenland Ice‐core Project campsite on the Greenland Ice Sheet, we are able to visualize the buildup and post‐depositional changes of the upper snowpack across one summer season. To this end, 30 cm deep snow profiles were sampled on six dates at 20 adjacent locations along a 40 m transect. Near‐daily photogrammetry provided snow height information for the same transect. Our data shows that erosion and redeposition of the original snowfall lead to a complex stratification in the δ〈sup〉18〈/sup〉O signature. Post‐depositional processes through vapor‐snow exchange affect the near surface snow with d‐excess showing a decrease in surface and near‐surface layers. Our data suggests that the interplay of stratigraphic noise, accumulation intermittency, and local post‐depositional processes form the proxy signal in the upper snowpack.
    Description: Plain Language Summary: We study the process of the formation of the stable water isotope signal in surface snow on the Greenland Ice Sheet to better understand temperature information which is stored as a climate proxy in snow and ice. Our data consist of high‐resolution surface topography information illustrating the timing and location of snowfall, erosion, and redeposition along a transect of 40 m, as well as stable water isotope records of the upper 30 cm of the snowpack sampled biweekly on 20 positions at the same 40 m long transect. The data cover a 2‐month period during the summer of 2019. We find that the isotopic composition shows spatial variability of layers with low and high values, presumably winter and summer layers. We further observe that prevailing surface structures, such as dunes, influence the snow deposition and contribute to the found variable structure of the climatic information. Eventually, snow accumulation alone cannot explain all of the observed patterns in the isotopic data which is likely related to exchange processes between the snow and the atmosphere which modify the signal in the snow column after deposition.
    Description: Key Points: Combining digital elevation models and repeated snow sampling reveals the heterogeneous buildup of δ〈sup〉18〈/sup〉O signal in the snow column. Surface structures (stratigraphic noise) substantially contribute to internal heterogeneity in δ〈sup〉18〈/sup〉O signature in the upper snowpack. Proxy signals are formed in the surface layer by local processes, advected downwards with limited post‐depositional influences below 10 cm.
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: A. P. Møller Foundation, University of Copenhagen
    Description: US National Science Foundation, Office of Polar Programs
    Description: Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research
    Description: National Institute of Polar Research and Arctic Challenge for Sustainability
    Description: University of Bergen
    Description: Trond Mohn Foundation
    Description: Swiss National Science Foundation
    Description: French Polar Institute Paul‐Emile Victor, Institute for Geosciences and Environmental Research
    Description: University of Manitoba
    Description: Chinese Academy of Sciences
    Description: Beijing Normal University
    Description: https://doi.org/10.1594/PANGAEA.954944
    Description: https://doi.org/10.1594/PANGAEA.954945
    Description: https://doi.org/10.1594/PANGAEA.951583
    Description: https://doi.org/10.1594/PANGAEA.925618
    Description: https://doi.org/10.1594/PANGAEA.928827
    Description: https://www.agisoft.com/downloads/installer/
    Keywords: ddc:551 ; proxy ; Greenland ; isotopes ; structure‐from‐motion ; snow accumulation ; ice core
    Language: English
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  • 3
    Publication Date: 2024-02-21
    Description: Emergent constraints on carbon cycle feedbacks in response to warming and increasing atmospheric CO〈sub〉2 〈/sub〉 concentration have previously been identified in Earth system models participating in the Coupled Model Intercomparison Project (CMIP) Phase 5. Here, we examine whether two of these emergent constraints also hold for CMIP6. The spread of the sensitivity of tropical land carbon uptake to tropical warming in an idealized simulation with a 1% per year increase of atmospheric CO〈sub〉2 〈/sub〉 shows only a slight decrease in CMIP6 (−52 ± 35 GtC/K) compared to CMIP5 (−49 ± 40 GtC/K). For both model generations, the observed interannual variability in the growth rate of atmospheric CO〈sub〉2 〈/sub〉 yields a consistent emergent constraint on the sensitivity of tropical land carbon uptake with a constrained range of −37 ± 14 GtC/K for the combined ensemble (i.e., a reduction of ∼30% in the best estimate and 60% in the uncertainty range relative to the multimodel mean of the combined ensemble). A further emergent constraint is based on a relationship between CO〈sub〉2 〈/sub〉 fertilization and the historical increase in the CO〈sub〉2 〈/sub〉 seasonal cycle amplitude in high latitudes. However, this emergent constraint is not evident in CMIP6. This is in part because the historical increase in the amplitude of the CO〈sub〉2 〈/sub〉 seasonal cycle is more accurately simulated in CMIP6, such that the models are all now close to the observational constraint.
    Description: Plain Language Summary: The statistical model of so‐called emergent constraints help to better understand the sensitivity of Earth system processes in a changing climate. Here, we analyze the robustness of two previously found emergent constraints on carbon cycle feedbacks, using models from the Coupled Model Intercomparison Project (CMIP) of Phases 5 and 6. First the decrease of carbon storage in the tropics due to increasing near‐surface air temperatures, which is found to be robust on the choise of model ensemble. Giving a constraint estimate of −52 ± 35 GtC/K for CMIP6 models, being within the range of uncertainty for the previously estimated result for CMIP5. Second, the increase of carbon storage in high latitudes due to CO〈sub〉2 〈/sub〉 fertilization effect, which is found to be not evident among CMIP6 models. This is in part because the historical increase in the amplitude of the CO〈sub〉2 〈/sub〉 seasonal cycle is more accurately simulated in CMIP6, such that the models are all now close to the observational constraint.
    Description: Key Points: An emergent constraint on the sensitivity of tropical land carbon to global warming, originally derived from Coupled Model Intercomparison Project Phase 5 (CMIP5), also holds for CMIP6. The combined CMIP5 + CMIP6 ensemble gives an emergent constraint on the sensitivity of tropical land carbon to global warming of −37 ± 14 GtC/K. An emergent constraint on the fertilization feedback due to rising CO〈sub〉2 〈/sub〉 levels, previously derived, is not evident in CMIP6.
    Description: Horizon 2020 Framework Programme http://dx.doi.org/10.13039/100010661
    Description: ERC
    Description: https://doi.org/10.5281/zenodo.6900341
    Description: https://doi.org/10.5281/zenodo.3387139
    Description: https://github.com/ESMValGroup
    Description: https://docs.esmvaltool.org/
    Keywords: ddc:551 ; carbon cycle ; emergent constraint ; CMIP5 ; CMIP6 ; fertilization effect ; temperature warming
    Language: English
    Type: doc-type:article
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  • 4
    Publication Date: 2024-02-14
    Description: Modelling soil erosion and sediment transport are vital to assess the impact of the flash floods. However, limited research works have studied sediment transport, especially in Egypt. This paper employs the HEC-HMS lumped hydrological model to predict the sediment load due to the flood event of 9th March 2014 in Wadi Billi, Egypt. The Modified USLE model has been used to calculate the total upland erosion, while Laursen-Copeland has been used to simulate load streams’ sediment transport potential. The Normalized Difference Vegetation Index (NDVI) has been applied over Landsat 8 image captured on 20th February 2014 using ArcMap 10.5 to determine the vegetation cover based on its spectral footprint. The resulted sedigraph showed accumulation of more than five thousand tons of sediments at the Wadi’s outlet. The results are crucial to design a suitable stormwater management system to protect the downstream urban area and to use flood water for groundwater recharge.
    Description: Technische Universität Berlin (3136)
    Description: https://www.hec.usace.army.mil/software/hec-hms/
    Keywords: ddc:551 ; MUSLE model ; HEC-HMS ; Wadi system ; Remote sensing ; Sedigraph ; Egypt
    Language: English
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  • 5
    Publication Date: 2024-02-09
    Description: Tracing pathways and transformations of particulate organic carbon from landscape sources to oceanic sinks is commonly done using the isotopic composition or biomarker content of particulate organic matter (POM). However, similarity of source characteristics and complex mixing in rivers often preclude a robust deconvolution of individual contributions. Moreover, these approaches are limited in detecting organic matter transformations. This impedes understanding of carbon cycling. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT‐ICR‐MS) can simultaneously identify many molecular formulas from mixtures of organic matter, and provide direct information on its compositional variability. Here, we investigate how FT‐ICR‐MS can give insight into POM dynamics on a landscape scale, focusing on the trans‐Himalayan Kali Gandaki River, Nepal. Using molecular information, we identify source tracers in the solvent extractable lipid fraction of riverine POM, finding up to 102 indicative molecular formulas for individual sources. Further, we assess molecular transformations of the lipid fraction of POM during its transfer from litter into topsoil, and onwards into the river. A large number of shared mass formulas and a well‐preserved isoprenoidal patterns suggest efficient incorporation of litter into topsoil. In contrast, we observe a selective loss of mass formulas and a preferential export of formulas with low double bond equivalents and a low nominal oxidation state of carbon after organic matter entrainment in the river. Our results demonstrate the potential of FT‐ICR‐MS for source‐to‐sink studies, allowing detailed organic matter source characterization and discrimination, and tracking of molecular transformations along organic matter pathways spanning different spatial and temporal scales.
    Description: Plain Language Summary: The transfer of organic matter (OM) by rivers from landscape sources into the ocean followed by its burial in marine sediments is an important carbon sink. Therefore, OM is often traced along this journey using its isotopic or biomarker composition. But contributions of OM sources to river sediments can be difficult to estimate because of similar source characteristics, mixing of many sources and changes of the molecular composition along the way. Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT‐ICR‐MS) is a novel method able to identify many molecular formulas from OM mixtures at once providing direct information about their molecular composition. Here, we investigate how FT‐ICR‐MS contributes to understanding the transport and transformation of particulate OM focusing on a Himalayan river in Nepal. We use the molecular information to identify tracers for individual OM sources in the landscape. We then assess molecular transformations during the transfer of litter into topsoil, and onwards into the river. Our data suggest efficient incorporation of litter into topsoil, but we observe a selective loss of molecular formulas upon entrainment of sources into the river. Our results reveal that FT‐ICR‐MS is useful for detailed source characterization and tracking of molecular transformations along OM pathways.
    Description: Key Points: Organic matter sourcing and transformations in a Himalayan river studied by FT‐ICR‐MS measurements of solvent extractable lipids. Identification of up to 102 indicator mass formulas for different organic matter sources in the landscape using indicator species analysis. Mass formulas preserved during incorporation of litter into topsoil but selectively lost during entrainment of sources into the river.
    Description: Helmholtz Impuls und Vernetzungsfond
    Description: GFZ expedition funding
    Description: http://doi.org/10.5880/GFZ.4.6.2022.002
    Keywords: ddc:551 ; particulate organic carbon ; solvent extractable lipids ; FT‐ICR‐MS ; Himalaya ; carbon cycling ; indicator species analysis
    Language: English
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  • 6
    Publication Date: 2024-01-19
    Description: While timing and ice extent of the last glacial maximum are generally well known, the courses of earlier glaciations have remained poorly constrained, with one of the main reasons being the scarcity of sedimentary archives. This study introduces a new palaeolake record from a Mid‐Pleistocene glaciofluvial channel system in the Lower Aare Valley (Northern Switzerland). The record of Rinikerfeld comprises a 〉40 m long succession of Quaternary deposits that are targeted by multi‐method sedimentological analysis. Sedimentary facies together with geochemical and geotechnical parameters, pollen content, as well as luminescence ages allow the reconstruction of the establishment, evolution and infilling of the early Marine Isotope Stage 6‐aged Rinikerfeld Palaeolake. A drastic change in lake sediment composition and structure indicates cessation of the initial glacially derived input, which is explained by landscape modification and drainage rerouting during the Penultimate (Beringen) Glaciation. Geochemical and palynological data further reveal cold, initially periglacial but slightly ameliorating, climate conditions, while the lake was progressively filled up by local runoff, before being buried by periglacial colluvial diamicts, and potentially overridden by ice. It is therefore concluded that the onset of the Beringen Glaciation was an environmentally as well as geomorphically dynamic time period in the Northern Alpine Foreland.
    Description: NATIONALE GENOSSENSCHAFT FÜR DIE LAGERUNG RADIOAKTIVER ABFÄLLE
    Keywords: ddc:551 ; Northern Alpine foreland ; palaeolake ; penultimate glaciation ; periglacial lake ; sedimentary archive
    Language: English
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  • 7
    Publication Date: 2024-01-19
    Description: The transport of dissolved organic carbon (DOC) from the soils to inland waters plays an important role in the global carbon cycle. Widespread increases in DOC concentrations have been observed in surface waters over the last few decades, affecting carbon balances, ecosystem functioning and drinking water treatment. However, the primary hydrological controls on DOC mobilization are still uncertain. The aim of this study was to investigate the role of microtopography in the riparian zone for DOC export and DOM quality. DOC concentration and DOM quality in the shallow groundwater of a riparian zone and in streamflow in a forested headwater catchment was investigated using fluorescence and absorbance characteristics. We found higher DOC concentrations with a higher aromaticity in the microtopographical depressions, which were influenced by highly dynamic shallow groundwater levels, than in the flat forest soil. As a result of the frequent wet‐dry cycles in the upper soil layers, aromatic DOC accumulated in the shallow groundwater within and below the microtopographical depressions. Rising groundwater levels during precipitation events led to the connection of the microtopographical depressions to the stream, resulting in a change toward more aromatic DOC in the stream. Increasing stream DOC concentrations were accompanied by increasing concentrations of iron and aluminum, suggesting the coupled release of these metals with DOC from the riparian zone. Our results highlight the importance of the interplay between microtopography and groundwater level dynamics in the riparian zone for DOC export from headwater catchments.
    Description: Plain Language Summary: Dissolved organic carbon (DOC) is the result of the continuous breakdown of organic material, such as leaves. It accumulates in the soil and is transported to streams mainly during precipitation events. In this study, we analyzed the shallow groundwater of two differing sites in the Bavarian Forest National Park. Both sites were located close to the stream, but one was characterized by typical forest soil and one by small ponds, which were occasionally filled with water. The site with ponds showed much higher DOC concentrations and the DOC was chemically different from the other site. During a precipitation event, we observed a shift in chemical composition of stream water parameters toward the chemical characteristics found at the site with ponds. Therefore, we conclude that the ponds contribute substantially to DOC mobilization, once they fill with water and get connected to the stream.
    Description: Key Points: This study found small‐scale differences in dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) quality in the riparian zone. Microtopographical depressions were characterized by high DOC concentrations and aromatic DOC. In‐stream DOC concentrations and DOM quality during a precipitation event resembled shallow groundwater below microtopographical depressions.
    Description: Stifterverband http://dx.doi.org/10.13039/501100008384
    Description: Helmholtz Association http://dx.doi.org/10.13039/501100009318
    Description: Rudolf and Helene Glaser Foundation
    Description: European Regional Development Funds
    Description: https://doi.org/10.6084/m9.figshare.19086455
    Description: https://doi.org/10.48758/ufz.12908
    Keywords: ddc:551 ; dissolved organic carbon ; hydrology ; microtopography ; DOM quality
    Language: English
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  • 8
    Publication Date: 2023-12-16
    Description: Temperature and dissolved oxygen concentration are critical factors affecting the exchange of solutes between sediment and water; both factors will be affected by warming of lakes and thereby influence water quality. Temperature and oxygen responses of single solute fluxes are well known; however, not much is known about the interaction of temperature and oxygen in regulating the balance of different fluxes in the benthic environment. We analyzed benthic flux (mobilization and immobilization) data of various solutes (dissolved organic carbon (DOC), CH〈sub〉4〈/sub〉, NO〈sub〉3〈/sub〉〈sup〉−〈/sup〉‐N, NH〈sub〉4〈/sub〉+〈/sup〉‐N, SRP, SO〈sub〉4〈/sub〉〈sup〉−〈/sup〉, Fe, Mn, and O〈sub〉2〈/sub〉) collected from laboratory incubations of 142 sediment cores from 5 different reservoirs incubated under varying in situ temperature and oxygen conditions. Oxygen was the primary driver of benthic fluxes, while temperature and total organic content were secondary. Temperature effects on benthic fluxes were stronger under anoxic conditions which imply that warming will substantially increase the benthic fluxes if the sediment surface becomes anoxic. The varying temperature response of processes underlying the studied fluxes will result in a shift of their relative importance in the benthic environment, especially in shallow lakes that are more vulnerable to warming. For example, more anoxic conditions will shift the equilibrium between net sulfate reduction and methane release toward the latter. We also predict that physical effects of warming leading to hypolimnetic oxygen depletion, that is, stronger stratification and longer hypolimnetic confinement will increase the benthic mobilization of phosphorus, DOC, and methane into water and immobilization of sulfate by the sediments even in deep lakes.
    Description: Plain Language Summary: Temperature and dissolved oxygen concentration control the release of undesirable components buried in lake or reservoir sediments, that is, nutrients, metals, and organic matter, which can cause water quality problems. We investigated the effects of rising temperature and levels of oxygen on the release of undesirable components by performing experiments using sediments and water from five different reservoirs. The sediments with a layer of water on top were incubated under different in situ temperature (low and high) and oxygen conditions (with and without). Our results show that the absence of oxygen was the main cause of the release of nutrients and metals. When there was no oxygen in the sediment and water, nutrients and metals were released from the sediment into the water and this effect increased when temperature was high. There is higher possibility that phosphorus, dissolved organic carbon, and methane will be released from sediments in some reservoirs as a result of global warming.
    Description: Key Points: Solute fluxes from benthic lake sediments varied in response to temperature, with oxygen fluxes responding most strongly. Temperature effects on the magnitude of benthic fluxes were stronger under anoxic than oxic conditions. Direct temperature effects on reservoir water quality will be small compared to indirect effects through anoxia facilitation.
    Description: German Federal Ministry of Education and Research
    Description: MINECO
    Description: https://doi.pangaea.de/10.1594/PANGAEA.928570
    Keywords: ddc:551 ; temperature dependency ; oxygen ; benthic fluxes ; reservoirs ; anoxia ; activation energy
    Language: English
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  • 9
    Publication Date: 2023-12-16
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉Three volcanic arcs have been the source of New Zealand's volcanic activity since the Neogene: Northland arc, Coromandel Volcanic Zone (CVZ) and Taupō Volcanic Zone (TVZ). The eruption chronology for the Quaternary, sourced by the TVZ, is well studied and established, whereas the volcanic evolution of the precursor arc systems, like the CVZ (central activity c. 18 to 2 Ma), is poorly known due to limited accessibility to, or identification of, onshore volcanic deposits and their sources. Here, we investigate the marine tephra record of the Neogene, mostly sourced by the CVZ, of cores from IODP Exp. 375 (Sites U1520 and U1526), ODP Leg 181 (Sites 1123, 1124 and 1125), IODP Leg 329 (Site U1371) and DSDP Leg 90 (Site 594) offshore of New Zealand. In total, we identify 306 primary tephra layers in the marine sediments. Multi‐approach age models (e.g. biostratigraphy, zircon ages) are used in combination with geochemical fingerprinting (major and trace element compositions) and the stratigraphic context of each marine tephra layer to establish 168 tie‐lines between marine tephra layers from different holes and sites. Following this approach, we identify 208 explosive volcanic events in the Neogene between c. 17.5 and 2.6 Ma. This is the first comprehensive study of New Zealand's Neogene explosive volcanism established from tephrochronostratigraphic studies, which reveals continuous volcanic activity between c. 12 and 2.6 Ma with an abrupt compositional change at c. 4.5 Ma, potentially associated with the transition from CVZ to TVZ.〈/p〉
    Description: Plain Language Summary: Since 18 Ma, volcanic activity in New Zealand is dominantly sourced by the Coromandel Volcanic Zone (CVZ). Most caldera systems of the CVZ identified so far are located on Coromandel Peninsula in the NW of North Island, New Zealand, but studies of the CVZ are rare mainly due to the limited accessibility of its volcanic deposits, as well as missing stratigraphic continuity between different outcrops and the volcanic source. Here, our ocean drilling tephra record—mainly volcanic ash from explosive eruptions, distributed and falling out over the ocean—has a great potential to reveal the eruption history of the CVZ because it is preserved in marine sediments in a nearly undisturbed stratigraphic context. We analyzed ∼400 marine tephra layers from multiple ocean sediment cores off the coast of New Zealand for their geochemical glass compositions and identified 306 as largely undisturbed ash deposits. These primary ash deposits correspond to a total number of 208 Neogene volcanic events. Different dating methods result in a continuous marine tephra record for the last 12 Ma, equivalent to a unique and most complete eruptive history for the CVZ. This enables us to further unravel changes in the composition of the associated magmas with time.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉New Zealand's Neogene explosive volcanism based on the marine tephra record〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Geochemical fingerprinting of marine tephra layers across the study area to establish volcanic events〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Insights into geochemical variations with time, repose times and spatiotemporal distribution〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: DFG
    Description: Marsden project
    Description: https://doi.org/10.14379/iodp.proc.372B375.210.2023
    Keywords: ddc:551 ; marine tephrochronostratigraphy ; geochemical fingerprinting ; correlations of marine tephras between individual drill sites ; IODP ; ODP and DSDP drill sites ; neogene eruption record of New Zealand
    Language: English
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  • 10
    Publication Date: 2023-12-14
    Description: 〈title xmlns:mml="http://www.w3.org/1998/Math/MathML"〉Abstract〈/title〉〈p xmlns:mml="http://www.w3.org/1998/Math/MathML" xml:lang="en"〉The reconstruction of accurate sea‐surface temperatures (SST) is of utmost importance due to the ocean's central role in the global climate system. Yet, a number of environmental processes might bias reliable SST estimations. Here, we investigate the fidelity of SST reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5, utilizing a core collected off eastern Brazil at ∼20°S. This interval was selected as previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a peculiar pooling of warm surface waters in the WTSA during MIS 6 despite glacial boundary conditions. To ground‐truth the Mg/Ca‐based SST data we generated SST reconstructions on the same core material using the alkenone and TEX〈sub〉86〈/sub〉 paleothermometers. Comparison with alkenone‐based temperature estimates corroborate the previous Mg/Ca‐based SST reconstructions, supporting the suggestion of a warm‐water anomaly during MIS 6. In contrast, TEX〈sub〉86〈/sub〉‐derived temperatures, albeit representing annual mean SST in recent core top samples, are up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. We interpret the periods of anomalously cold TEX〈sub〉86〈/sub〉‐temperatures as a result of a vertical migration of the TEX〈sub〉86〈/sub〉 producers (heterotrophic marine Thaumarchaeota) toward greater water depths, following food availability during phases of enhanced fluvial suspension input. Likewise, the data suggest that alkenone‐based SST are, albeit to a minor degree when compared to TEX〈sub〉86〈/sub〉, affected by river run‐off and/or a seasonal bias in the growth season of haptophyte algae.〈/p〉
    Description: Plain Language Summary: In this study, we investigate the accuracy of sea‐surface temperature (SST) reconstructions for the western tropical South Atlantic (WTSA) for the interval covered by Marine Isotope Stages (MIS) 6–5—the penultimate glacial‐interglacial cycle (ca. 190,000 to 70,00 years before present). This time interval was selected because previous SST estimates based on Mg/Ca ratios of planktic foraminifera suggested a pooling of warm surface waters in the WTSA during late MIS 6 despite the cold glacial conditions. To verify the Mg/Ca‐based SST data, we generated temperature reconstructions from a core located off Eastern Brazil using two common paleothermometers that based on lipid biomarkers: alkenone and TEX〈sub〉86〈/sub〉. The alkenone‐based temperature estimates agree with previous Mg/Ca‐based SST reconstructions, supporting the existence of a warm‐water anomaly in the WTSA during MIS 6. On the other hand, TEX〈sub〉86〈/sub〉‐derived temperatures were up to 6°C colder than Mg/Ca‐ and alkenone‐based SST reconstructions. This discrepancy might be a result of a vertical migration of the TEX86 producers toward greater water depths where they feed on particles of organic matter. These migrations into deeper waters occurred during phases of increased river run‐off fluvial suspension input which enhanced surface primary productivity and facilitated vertical particle flux through the water column.〈/p〉
    Description: Key Points: 〈list list-type="bullet"〉 〈list-item〉 〈p xml:lang="en"〉Parallel Mg/Ca (〈italic〉Globigerinoides ruber〈/italic〉), alkenone and TEX〈sub〉86〈/sub〉‐based temperature estimates in the western tropical South Atlantic (WTSA) across Marine Isotope Stages (MIS) 6–5〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Mg/Ca and alkenones represent annual mean sea surface temperatures, but most TEX〈sub〉86〈/sub〉‐based temperatures deviate to colder values〈/p〉〈/list-item〉 〈list-item〉 〈p xml:lang="en"〉Anomalous sea surface warming in the WTSA during late MIS 6 appears as a robust signal〈/p〉〈/list-item〉 〈/list〉 〈/p〉
    Description: R/V METEOR
    Description: DFG
    Description: CNPq
    Description: FAPESP
    Description: Alexander von Humboldt‐Stiftung http://dx.doi.org/10.13039/100005156
    Description: https://doi.org/10.1594/PANGAEA.956207
    Keywords: ddc:551 ; Mg/Ca ; alkenones ; TEX86 ; MIS 6 ; Brazilian Margin ; MIS 5
    Language: English
    Type: doc-type:article
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