ALBERT

Description: Gas chimneys and gas clouds in the subsurface media are known as one of the indications of possible petroleum reservoirs. Investigations of their properties are mostly initiated by seismic attribute interpretation on reflection seismic data. However, due to the complexity of their behavior and their difficult interpretation of seismic attributes, state-of-the-art methods are mostly required to be applied on the seismic data to prevent any misinterpretation. This is mostly done through attribute integration and multi-attribute analysis. This research presents a study on seismic attributes and integration on several 2D seismic reflection lines from the Gorgan Plain. It is located in Northeast Iran, on the western border of the region’s well-known Kopeh-Dagh fold and thrust belt, and southeastern border of the South Caspian Basin. Hydrocarbon systems of the Gorgan Plain are poorly known and have not been widely studied, but according to preliminary investigations, this region has the potential for hydrocarbon occurrences. The aim of this study is to investigate presence and then delaminate the affected area of possible gas chimneys that are related to possible hydrocarbon reservoirs. Gas chimneys are assumed to be created due to the routes, mostly made by faults, that provoke light hydrocarbons components to migrate toward the surface. Preliminary interpretations of seismic reflection data in this study revealed that at least two gas chimneys occurred within the Gorgan Plain. As it was mentioned, since they are mostly due to the faulting above the hydrocarbon reservoir, gas chimney and heavy faulting might exhibit the same effects on the seismic data and then on its attributes, which are amplitude reduction and high damping on energies, distortion of the waveshape and seismic velocity reduction. Thus, care should be taken in separation of these two different geologic phenomena on seismic attributes. This also was done in this study through utilized integration of the most relevant seismic attributes such as Instantaneous-phase, Chaos, Variance and Remove-bias attributes. Based on the result of interpretations and according to the evolution of the basin and its structural reconstruction on other studies, gas chimneys of the Gorgan Plain, are in relation to the operation of fault zones in Cenozoic erathem in the region. These fault zones which cut the entire Cenozoic erathem, create the pathway for vertical migration of hydrocarbons through Cheleken formation (reservoir rock) and its overburden sedimentary sequences. In other words, operation of fault zones within Cenozoic sedimentary sequence, is the main reason for gas seepage in the Gorgan Plain, which is also shown in seismic data.

Description: Highlights • δ13C and δ18O profiles increase from exterior to interior until reaching a plateau. • Primary Layer δ13C reflects the δ13C of the Dissolved Inorganic Carbon. • In high pCO2 experiments, δ13C and δ18O closer to equilibrium fields. • Brachiopods grow according to an incremental growth model. Abstract Brachiopod shells are ubiquitous since the Early Cambrian up to now. As they secrete a shell made of low-magnesium calcite, more resistant to diagenesis than biocarbonates richer in Mg, their geochemical signatures are generally considered a powerful tool for paleo-environmental and paleo-climatic reconstructions. However, gaps in knowledge still remain on the underlying controls of the shell chemistry, in particular at a high spatial resolution. In this study, in situ oxygen and carbon isotope measurements by SIMS (Secondary Ion Mass Spectrometry) were performed in brachiopod shells of the cold-temperate water species Magellania venosa, constituted of a primary and a secondary layer. The individual specimens studied here grew under controlled conditions mimicking the natural environment and in experiments under low-pH (high pCO2) and high-temperature conditions. Transversal carbon and oxygen profiles showed a “brachiopod pattern” typical of extant two-layered brachiopods, with the primary layer depleted in 18O and 13C relative to equilibrium and the secondary layer showing a gradual increasing trend until reaching a near-equilibrium plateau. Overall, shells cultured at low pH were found to have δ18O and δ13C values closer to equilibrium when compared to shells from the control experiment. These near-equilibrium values may reflect a decrease in shell precipitation rate, leading to less kinetic effects, and/or a more rapid kinetics for the equilibration between DIC species and water. By close pairing of seawater δ18O and δ13C to that of shell microstructure, our study enables us to derive layer-specific C and O enrichment factors, which show the extent of pH and temperature effects superimposed on the seawater δ18O and DIC δ13C signal inherited. Finally, we show that during brachiopod shell growth, newly precipitated calcite is added to the calcite already existing, thus empirically validating the conceptual accretionary growth model proposed by Ackerly (1989).

Description: The Earth's magnetic field can provide reliable directional information, allowing migrating animals to orient themselves using a magnetic compass or estimate their position relative to a target using map-based orientation. Here we show for the first time that young, inexperienced herring (Clupea harengus, Ch) have a magnetic compass when they migrate hundreds of kilometres to their feeding grounds. In birds, such as the European robin (Erithacus rubecula), radical pair-based magnetoreception involving cryptochrome 4 (ErCRY4) was demonstrated; the molecular basis of magnetoreception in fish is still elusive. We show that cry4 expression in the eye of herring is upregulated during the migratory season, but not before, indicating a possible use for migration. The amino acid structure of herring ChCRY4 shows four tryptophans and a flavin adenine dinucleotide-binding site, a prerequisite for a magnetic receptor. Using homology modelling, we successfully reconstructed ChCRY4 of herring, DrCRY4 of zebrafish (Danio rerio) and StCRY4 of brown trout (Salmo trutta) and showed that ChCRY4, DrCRY4 and ErCRY4a, but not StCRY4, exhibit very comparable dynamic behaviour. The electron transfer could take place in ChCRY4 in a similar way to ErCRY4a. The combined behavioural, transcriptomic and simulation experiments provide evidence that CRY4 could act as a magnetoreceptor in Atlantic herring.

Description: The spectral composition of light is an important factor for the metabolism of photosynthetic organisms. Several blue light-regulated metabolic processes have already been identified in the industrially relevant microalga Monoraphidium braunii. However, little is known about the spectral impact on this species' growth, fatty acid (FA), and pigment composition. In this study, M. braunii was cultivated under different light spectra (white light: 400–700 nm, blue light: 400–550 nm, green light: 450–600 nm, and red light: 580–700 nm) at 25°C for 96 h. The growth was monitored daily. Additionally, the FA composition, and pigment concentration was analyzed after 96 h. The highest biomass production was observed upon white light and red light irradiation. However, green light also led to comparably high biomass production, fueling the scientific debate about the contribution of weakly absorbed light wavelengths to microalgal biomass production. All light spectra (white, blue, and green) that comprised blue-green light (450–550 nm) led to a higher degree of FA unsaturation and a greater concentration of all identified pigments than red light. These results further contribute to the growing understanding that blue-green light is an essential trigger for maximized pigment concentration and FA unsaturation in green microalgae.

Description: The addition of carbonate minerals to seawater through an artificial ocean alkalinity enhancement (OAE) process increases the concentrations of hydroxide, bicarbonate, and carbonate ions. This leads to changes in the pH and the buffering capacity of the seawater. Consequently, OAE could have relevant effects on marine organisms and in the speciation and concentration of trace metals that are essential for their physiology. During September and October 2021, a mesocosm experiment was carried out in the coastal waters of Gran Canaria (Spain), consisting on the controlled variation of total alkalinity (TA). Different concentrations of carbonate salts (NaHCO3 and Na2CO3) previously homogenized were added to each mesocosm to achieve an alkalinity gradient between Δ0 to Δ2400 µmol L−1. The lowest point of the gradient was 2400 µmol kg−1, being the natural alkalinity of the medium, and the highest point was 4800 µmol kg−1. Iron (Fe) speciation was monitored during this experiment to analyse total dissolved iron (TdFe, unfiltered samples), dissolved iron (dFe, filtered through a 0.2 µm pore size filter), soluble iron (sFe, filtered through a 0.02 µm pore size filter), dissolved labile iron (dFe′), iron-binding ligands (LFe), and their conditional stability constants () because of change due to OAE and the experimental conditions in each mesocosm. Observed iron concentrations were within the expected range for coastal waters, with no significant increases due to OAE. However, there were variations in Fe size fractionation during the experiment. This could potentially be due to chemical changes caused by OAE, but such an effect is masked by the stronger biological interactions. In terms of size fractionation, sFe was below 1.0 nmol L−1, dFe concentrations were within 0.5–4.0 nmol L−1, and TdFe was within 1.5–7.5 nmol L−1. Our results show that over 99 % of Fe was complexed, mainly by L1 and L2 ligands with ranging between 10.92 ± 0.11 and 12.68 ± 0.32, with LFe ranging from 1.51 ± 0.18 to 12.3 ± 1.8 nmol L−1. Our data on iron size fractionation, concentration, and iron-binding ligands substantiate that the introduction of sodium salts in this mesocosm experiment did not modify iron dynamics. As a consequence, phytoplankton remained unaffected by alterations in this crucial element.

Description: This article presents risk factors that are associated with the handling of unexploded ordnance (UXO) during explosive ordnance disposal (EOD) operations in German waters. The construction of offshore wind parks and the German immediate action program are expected to increase the number of EOD operations. Existing literature and guidelines do not offer a structured and reproducible framework for assessing EOD risk. To fill this gap, a network of EOD risk factors was developed by means of a literature review and validation via expert consultation. The study was scoped to “personnel and equipment at the EOD location” as the risk receptor and “undesired detonation” as the undesired event under investigation. Factors are subdivided into UXO factors that depend on the object that should be handled and factors that describe the object's surrounding environment. While the former can be researched by an EOD expert, the latter must be measured on site or acquired from a model. Each of these factors contributes to risk, some directly and others indirectly via other factors. The complexity of the resulting network, with its 33 factors, demonstrates the need for a reliable and reproducible model to quantify EOD risk. Its purpose is not to replace EOD experts but to aid them in their decision‐making process. Such a tool can provide valuable support for the high‐cost and high‐risk EOD operations.

Description: The mesopelagic or ocean twilight zone (OTZ) in the ocean contains huge numbers of fish in a relatively pristine environment and may therefore attract interest as a commercial fishery. In this study we evaluate in economic terms, the likely trade-offs between the different services provided by the mesopelagic layer in the Bay of Biscay and the societal benefits of its commercial exploitation. Benefits arise mainly from the likely use of this group of species as raw material for producing fishmeal and fish oil. Costs are derived from the loss in climate regulating and cultural, services, but also from the loss in the provisioning service of other commercial species. To do so we compare the current non-exploited status with a situation in where mesopelagic fishes are harvested at levels capable of producing the Maximum Sustainable Yield. Results suggest that if mesopelagic fishes are harvested, a mean value of 1.2 million Euro loss in a year will be created in the Bay of Biscay, although in a range between 42 million Euro loss and 48 Euro million benefits. This uncertainty comes, mainly, from the limited existing knowledge of the mesopelagic fishes’ biomass but also from the uncertainty on the biomass of the rest of the species of the studied ecosystem. The large range indicates that a better understanding of the mesopelagic ecosystem is needed, however, results also show that ecosystem services under no exploitation provided by the OTZ could be more valuable than the fishmeal and fish oil that potentially could be obtained from the fishes harvested in this sea layer.

Description: Infections by filamentous phages, which are usually nonlethal to the bacterial cells, influence bacterial fitness in various ways. While phage-encoded accessory genes, for example virulence genes, can be highly beneficial, the production of viral particles is energetically costly and often reduces bacterial growth. Consequently, if costs outweigh benefits, bacteria evolve resistance, which can shorten phage epidemics. Abiotic conditions are known to influence the net-fitness effect for infected bacteria. Their impact on the dynamics and trajectories of host resistance evolution, however, remains yet unknown. To address this, we experimentally evolved the bacterium Vibrio alginolyticus in the presence of a filamentous phage at three different salinity levels, that is (1) ambient, (2) 50% reduction and (3) fluctuations between reduced and ambient. In all three salinities, bacteria rapidly acquired resistance through super infection exclusion (SIE), whereby phage-infected cells acquired immunity at the cost of reduced growth. Over time, SIE was gradually replaced by evolutionary fitter surface receptor mutants (SRM). This replacement was significantly faster at ambient and fluctuating conditions compared with the low saline environment. Our experimentally parameterized mathematical model explains that suboptimal environmental conditions, in which bacterial growth is slower, slow down phage resistance evolution ultimately prolonging phage epidemics. Our results may explain the high prevalence of filamentous phages in natural environments where bacteria are frequently exposed to suboptimal conditions and constantly shifting selections regimes. Thus, our future ocean may favour the emergence of phage-born pathogenic bacteria and impose a greater risk for disease outbreaks, impacting not only marine animals but also humans.

Description: Key Points: - We reconstruct the temporal evolution of seawater isotope ratios of boron, strontium, lithium, and osmium over the last 65 million years - The evolution of seawater boron isotope ratio shows similarity to the evolution of strontium, lithium and osmium isotope ratios - Randomly drawn, smooth time series are provided for use in uncertainty propagation in calculation of palaeo pH The boron isotope ratio of seawater (δ11Bsw) is a parameter which must be known to reconstruct palaeo pH and CO2 from boron isotope measurements of marine carbonates. Beyond a few million years ago, δ11Bsw is likely to have been different to modern. Palaeo δ11Bsw can be estimated by simultaneously constraining the vertical gradients in foraminiferal δ11B (Δδ11B) and pH (ΔpH). A number of subtly different techniques have been used to estimate ΔpH in the past, all broadly based on assumptions about vertical gradients in oxygen, and/or carbon, or other carbonate system constraints. In this work we pull together existing data from previous studies, alongside a constraint on the rate of change of δ11Bsw from modeling. We combine this information in an overarching statistical framework called a Gaussian Process. The Gaussian Process technique allows us to bring together data and constraints on the rate of change in δ11Bsw to generate random plausible evolutions of δ11Bsw. We reconstruct δ11Bsw, and by extension palaeo pH, across the last 65Myr using this novel methodology. Reconstructed δ11Bsw is compared to other seawater isotope ratios, namely ,87/86 Sr, 187/188 Os , and δ7Li, which we also reconstruct with Gaussian Processes. Our method provides a template for incorporation of future δ11Bsw constraints, and a mechanism for propagation of uncertainty in δ11Bsw into future studies.

Description: Open data, as an essential element in the sustainable development of the digital economy, is highly valued by many relevant sectors in the implementation process. However, most studies suppose that there are only data providers and users in the open data process and ignore the existence of data regulators. In order to establish long-term green supply relationships between multistakeholders, we hereby introduce data regulators and propose an evolutionary game model to observe the cooperation tendency of multistakeholders (data providers, users, and regulators). The newly proposed game model enables us to intensively study the trading behavior which can be realized as strategies and payoff functions of the data providers, users, and regulators. Besides, a replicator dynamic system is built to study evolutionary stable strategies of multistakeholders. In simulations, we investigate the evolution of the cooperation ratio as time progresses under different parameters, which is proved to be in agreement with our theoretical analysis. Furthermore, we explore the influence of the cost of data users to acquire data, the value of open data, the reward (penalty) from the regulators, and the data mining capability of data users to group strategies and uncover some regular patterns. Some meaningful results are also obtained through simulations, which can guide stakeholders to make better decisions in the future.

Description: The article evidences to what extent rights-based climate litigation is applied as a strategy to enhance the recognition and protection of climate-induced migrants. Adopting a deduc- tive approach and desk review, the study, illustrates how climate-induced migration has been addressed by International Human Rights Law, with some attention also paid to the growing application of the right to a safe climate and climate justice. The study highlights the duties of both States and private actors in tackling the emerging climate crisis under the human rights agenda. Relevant responsibilities are framed in particular within the scope of rights-based litiga- tion dealing with the topic. We present an analysis of litigation linked to climate-induced migration that was filed before distinct international, regional, and national jurisdictions and, in doing so, propose a chronology of cases—structured in three generations—of how population movements as a result of climate change have been discussed by judicial means. The first generation relates to cases that consider the issue from the perspective of protection—in both national, regional, and international jurisdictions. The second generation emerges within general climate litigation claims, involving commitments linked to the climate agenda. In addition to raising (forced) pop- ulation movements as one of the expected impacts of climate change, such cases frequently call upon a rights-based approach. The third generation encompasses rights-based cases cen- tred on climate-induced migrants per se. The strengths and limitations of rights-based litigation to respond to the topic are finally highlighted: we conclude that litigation remains a blunt but not unpromising tool to respond to climate-induced migration. Generic references to the risk of (forced) population movements largely prevail; nevertheless, strategic rights-based litigation can facilitate the visibility of climate-induced migrants to the international community, fostering the development of legal solutions in the longer term.

Description: The complex phase interactions of the two-phase flow are a key factor in understanding the flow pattern evolutional mechanisms, yet these complex flow behaviors have not been well understood. In this paper, we employ a series of gas–liquid two-phase flow multivariate fluctuation signals as observations and propose a novel interconnected ordinal pattern network to investigate the spatial coupling behaviors of the gas–liquid two-phase flow patterns. In addition, we use two network indices, which are the global subnetwork mutual information (⁠ ⁠) and the global subnetwork clustering coefficient (⁠ ⁠), to quantitatively measure the spatial coupling strength of different gas–liquid flow patterns. The gas–liquid two-phase flow pattern evolutionary behaviors are further characterized by calculating the two proposed coupling indices under different flow conditions. The proposed interconnected ordinal pattern network provides a novel tool for a deeper understanding of the evolutional mechanisms of the multi-phase flow system, and it can also be used to investigate the coupling behaviors of other complex systems with multiple observations.

Description: Global hydrological models (GHMs) are widely used to assess the impact of climate change on streamflow, floods, and hydrological droughts. For the 'model evaluation and impact attribution' part of the current round of the Inter-Sectoral Impact Model Intercomparison Project (ISIMIP3a), modelling teams generated historical simulations based on observed climate and direct human forcings with updated model versions. Here we provide a comprehensive evaluation of daily and maximum annual discharge based on ISIMIP3a simulations from nine GHMs by comparing the simulations to observational data from 644 river gauge stations. We also assess low flows and the effects of different river routing schemes. We find that models can reproduce variability in daily and maximum annual discharge, but tend to overestimate both quantities, as well as low flows. Models perform better at stations in wetter areas and at lower elevations. Discharge routed with the river routing model CaMa-Flood can improve the performance of some models, but for others, variability is overestimated, leading to reduced model performance. This study indicates that areas for future model development include improving the simulation of processes in arid regions and cold dynamics at high elevations. We further suggest that studies attributing observed changes in discharge to historical climate change using the current model ensemble will be most meaningful in humid areas, at low elevations, and in places with a regular seasonal discharge as these are the regions where the underlying dynamics seem to be best represented.

Description: Urban agriculture, including peri-urban farming, can nourish around one billion city dwellers and provide multiple social, economic, and environmental benefits. However, these benefits depend on various factors and are debated. Therefore, we used machine learning to semi-automate a systematic review of the existing literature on urban agriculture. It started with around 76,000 records for initial screening based on a broad keyword search strategy. We applied the topic modeling approach to systematically understand various aspects of urban agriculture based on the full text of around 1450 relevant publications. Urban agriculture literature covers 14 topics, clustered into 11 themes related to urban agriculture forms, their multi-functionalities, and their underlying challenges. These forms are small-scale ground-based and building-integrated systems. The multifunctionalities include food, livelihoods, health benefits, social space, green infrastructure, biodiversity, and ecosystem services. Therefore, promoting urban agriculture requires accounting for its multi-functionalities, besides food provisioning,and encouraging efficient and sustainable practices.

Description: Having experienced low prices for about a decade, the European Union Emissions Trading System has been supplemented with the market stability reserve (MSR) that adjusts the supply of allowances to market outcomes. We critically review the literature assessing the performance of the MSR against several policy objectives. In doing so, we cover both conceptual aspects and quantitative assessments. We conclude by pointing out important policy implications and open issues for further research.

Description: Carbon prices in the EU emissions trading system are a key instrument driving Europe’s decarbonization. Between 2017 and 2021, they surged tenfold, exceeding €80 tCO2−1 and reshaping investment decisions across the electricity and industry sectors. What has driven this increase is an open question. While it coincided with two significant reforms tightening the cap (‘MSR reform’ and ‘Fit for 55’), we argue that a reduced supply of allowances alone cannot fully explain the price rise. A further crucial aspect is that actors must have become more farsighted as the reform signalled policymakers’ credible long-term commitment to climate targets. This is consistent with model results that show historic prices can be better explained with myopic actors, whereas explaining prices after the reforms requires actors to be farsighted. To underline the role of credibility, we test what would happen if a crisis undermines policy credibility such that actors become myopic again, demonstrating that carbon prices could plummet and endanger the energy transition.

Description: In diesem Positionspapier zur Neubewertung der DGE-Position zu veganer Ernährung werden neben neuen Daten zur Gesundheit auch die weiteren Zieldimensionen einer nachhaltigeren Ernährung (Umwelt, Tierwohl und Soziales) betrachtet. Zur Identifizierung relevanter Publikationen wurden ein Umbrella Review und ein ergänzendes systematisches Review durchgeführt sowie weitere Publikationen berücksichtigt. Die Betrachtung der Zieldimensionen Tierwohl und Soziales zeigt, dass die bisherigen Ansätze zur Bewertung der Auswirkung von Ernährungsweisen in diesem Zusammenhang noch nicht ausreichend etabliert sind und nicht umfassend angewendet werden. Daher werden nur die Zieldimensionen Gesundheit und Umwelt in die Position einbezogen. Gegenüber anderen Ernährungsweisen wurden bei einer veganen Ernährung potenzielle Vor- und Nachteile für die Gesundheit identifiziert. Für die gesunde erwachsene Allgemeinbevölkerung kann neben anderen Ernährungsweisen auch eine vegane Ernährung, unter der Voraussetzung der Einnahme eines Vitamin-B12- Präparats, einer ausgewogenen, gut geplanten Lebensmittelauswahl sowie einer bedarfsdeckenden Zufuhr der potenziell kritischen Nährstoffe (ggf. auch durch weitere Nährstoffpräparate), eine gesundheitsfördernde Ernährung darstellen. Für die vulnerablen Gruppen Kinder, Jugendliche, Schwangere, Stillende und Senior*innen kann die DGE aufgrund der weiterhin eingeschränkten Datenlage weder eine eindeutige Empfehlung für noch gegen eine vegane Ernährung aussprechen. Aufgrund des Risikos für potenzielle, teilweise irreversible Konsequenzen bei inadäquater Durchführung müssen für eine vegane Ernährung in vulnerablen Gruppen besonders fundierte Ernährungskompetenzen vorliegen. Eine Ernährungsberatung durch qualifizierte Fachkräfte ist daher für diese Gruppen dringend angeraten. Eine vegane Ernährung ist als äußerst umweltfreundlich anzusehen, sie stellt eine empfehlenswerte Maßnahme zur Verringerung der Umweltbelastungen des Ernährungssystems dar. Unter Berücksichtigung sowohl gesundheits- als auch umweltrelevanter Aspekte ist eine Ernährungsweise mit einer deutlichen Reduktion tierischer Lebensmittel zu empfehlen.

Description: The exchange of trace gases across the ocean/atmosphere interface, as well as the deposition of atmospheric pollutants and aerosols, are key processes linking the biogeochemical cycles and biological processes in the ocean with atmospheric chemistry and climate. Here we summarize our knowledge about the distributions of long-lived trace gases (CO2, CH4, N2O), short-lived trace gases, and pollutants (dimethyl sulfide (DMS), isoprene, halocarbons, NOx, SO2, O3, and others), and aerosols in the Indian Ocean. In general, dissolved trace gases show a pronounced temporal and spatial variability, which is caused by the variability of both physical processes (e.g., coastal upwelling) and biological productivity. The distributions of pollutants and aerosols and their depositions to the sea surface are mainly driven by the monsoon system and the variability of their land sources. Nitrogen and iron-containing aerosols can significantly affect biological production in the surface layer of the open Indian Ocean.

Description: Neomphaloidean gastropods are endemic to chemosynthesis-based ecosystems ranging from hot vents to organic falls, and their diversity and evolutionary history remain poorly understood. In the southwestern Pacific, deep-sea hydrothermal vents on back-arc basins and volcanic arcs are found in three geographically secluded regions: a western region around Manus Basin, an eastern region around North Fiji and Lau Basins, and the intermediate Woodlark Basin where active venting was confirmed only recently, on the 2019 R/V L’Atalante CHUBACARC expedition. Although various lineages of neomphaloidean snails have been detected, typically restricted to one of the three regions, some of these have remained without names. Here, we use integrative taxonomy to describe three of these species: the neomphalid Symmetromphalus mithril sp. nov. from Woodlark Basin and the peltospirids Symmetriapelta becki sp. nov. from the eastern region and Symmetriapelta radiata sp. nov. from Woodlark Basin. A combination of shell sculpture and radular characters allow the morphological separation of these new species from their described congeners. A molecular phylogeny reconstructed from 570 bp of the mitochondrial cytochrome c oxidase subunit I gene confirmed the placement of the three new species in their respective genera and the superfamily Neomphaloidea. The finding of these new gastropods, particularly the ones from the Woodlark Basin, provides insights and implications on the historical role of Woodlark as a dispersing centre, in addition to highlighting the uniqueness of the Woodlark faunal community.

Description: The Indian Ocean is an important conduit for the exchange of physical and biogeochemical properties through many distinct interbasin oceanic connections. The Indonesian archipelago provides a gappy pathway for warm tropical waters to enter the Indian Ocean from the Pacific. South of Australia, a complex circulation transports cooler subtropical waters from the Pacific while Indian Ocean waters from within the Leeuwin Current feed a series of currents along the southern Australian continental margin. Southern Ocean waters source both the deep and shallow overturning circulations into the Indian Ocean. The westward leakage of eddies spawned from the Agulhas Current off South Africa returns warm and salty Indian Ocean waters into the Atlantic and plays a significant role in the upper branch of the global meridional overturning circulation. This chapter discusses these pathways and highlights how they change with time and influence the circulation and properties of the Indian and global oceans.

Description: The cruise took place from 14.8.2005 (Akureyri) – 22.8.2005 (Akureyri) Research subject: ROV studies, mapping and sampling of the Tjörnes Offset (Storagrunn, Hollinn, Nafir) Chief Scientist: Prof. Dr. Colin W. Devey, IFM-GEOMAR, Kiel Number of Scientists: 10 Project: DFG De572/13-1 Fracture Zone

Description: Air-sea interaction in late boreal winter is studied over the extratropical North Atlantic (NA) during 1960–2020 by examining the relationship between sea-surface temperature (SST) and total turbulent heat flux (THF). The two quantities are positively correlated on interannual timescales over the central-midlatitude and subpolar NA, suggesting the atmosphere on average drives SST and THF variability is independent of SST. On decadal timescales and over the central-midlatitude NA the correlation is negative, suggesting ocean processes on average drive SST and THF variability is sensitive to SST. The correlation is positive over the subpolar NA. There, interannual and decadal THF variability is governed by the North Atlantic Oscillation (NAO). During the major late 20th and early 21st century SST increase in the subpolar NA diminishing oceanic heat loss associated with a weakening NAO was observed. This study suggests that the atmosphere is more sensitive to SST over the central-midlatitude than subpolar NA. Key Points: - Regional variation in the nature of air-sea interaction over the extratropical North Atlantic (NA) north of 35°N - Timescale dependence in relationship between sea-surface temperature (SST) and turbulent heat flux over the central-midlatitude NA - The atmosphere is more sensitive to SST variability over the central-midlatitude than subpolar NA

Description: The eastern boundary regions of the Atlantic and Pacific oceans host highly productive ecosystems. These upwelling systems play a key role in supporting marine biodiversity, local and global fisheries, and biogeochemical cycles. Consequently, it is of high interest to understand the processes driving these systems. This thesis focuses on one of these highly productive ecosystems - the tropical Angolan upwelling system (tAUS). Conditions in the tAUS undergo strong seasonal modulations, where many characteristics exhibit variability on semi-annual and annual time scales. The lowest sea surface temperature (SST), highest primary productivity, and lowest along-shore wind are found in austral winter during the main upwelling season. Interestingly, and in contrast to other upwelling systems, the productivity signal cannot be explained by local wind-driven upwelling. Possible forcing mechanisms of the productivity signal are connected to equatorial dynamics via the propagation of coastal trapped waves (CTWs). The tAUS is thus an ecosystem influenced by both remote and local processes. This thesis focuses on understanding the physical drivers of the seasonal and interannual variability in the tAUS, particularly in SST and primary productivity. The analyses conducted within this thesis are mostly based on observational datasets. Additionally, the results are compared with output of a regional ocean model. The observational data includes shipboard measurements as well as satellite products. The shipboard measurements comprise an extensive ocean turbulence dataset. This dataset provides, for the first time, insights into turbulent heat and nitrate fluxes in the tAUS. In the tAUS, waters are colder directly at the coast than further offshore. Both SST and the crossshore SST gradient exhibit a seasonal cycle. A seasonal mixed layer heat budget is calculated to identify atmospheric and oceanic causes for heat content variability. The results show that the seasonal cycle in SST is mainly controlled by surface heat fluxes and turbulent heat loss at the base of the mixed layer. The net surface heat flux warms the coastal ocean more strongly than the offshore region and thus acts to dampen cross-shore SST differences. Ocean turbulence data shows that turbulent mixing across the base of the mixed layer is an important cooling term. This turbulent cooling, being strongest in the shallow shelf regions, explains the observed negative cross-shore temperature gradient. The seasonal cycle of the cross-shore SST gradient exhibits semi-annual variability, likely linked to tidal mixing acting on changing background stratification associated with the passage of CTWs. The primary productivity in the tAUS peaks in late austral winter. Analyses of observational data and the output of a regional ocean model reveal that the seasonal productivity maximum is due to the combined effect of CTWs and elevated tidal mixing on the shelf. During austral winter, the passage of an upwelling CTW displaces the nitracline upward by more than 50 m. Thereby, nitrate-rich waters spread onto the shelf, where elevated vertical mixing causes a nitrate flux into the surface mixed layer. High-mode CTWs play an important role in the upward and onshore transport of nitrate-rich waters. The interannual variability of the productivity maximum in the tAUS is strongly correlated with the amplitude of the upwelling CTW. Consequently, it is of high interest to investigate dynamical factors controlling the characteristics of the CTW as their strength controls the amount of primary production in the tAUS. Regression analyses suggest that the timing and amplitude of the austral winter upwelling CTW in tAUS are influenced by variability in different regions. The timing of the CTW is mostly influenced by variability in the equatorial region and along the southern African coast. Here. weaker equatorial easterlies from April to July lead to a late arrival of the upwelling CTW. The amplitude of the CTW is influenced by variability in the eastern equatorial Atlantic and in the central South Atlantic, a region characterizing the strength of the South Atlantic anticyclone. A cooling in the eastern equatorial Atlantic four to three months before the arrival of the CTW causes stronger zonal winds, leading to a stronger austral winter upwelling CTW. In general, the results suggest that the timing and amplitude of the upwelling CTW in the tAUS during austral winter are predictable on seasonal time scales. Overall, this thesis enhances our understanding of the seasonal to interannaul dynamics in the tAUS. The results of this thesis show that CTWs, near-coastal mixing, and surface heat fluxes are essential processes to explain the seasonal variability of SST and productivity in the tAUS. A key result is the proposed mechanism explaining the austral winter productivity peak, based on the combined effect of CTWs and near-coastal mixing. This result not only advances process understanding in the tAUS but also suggests a potential predictability of productivity in the region.

Description: A stratigraphic complex composed of mass transport deposits (MTDs), where the gas occurrence allows for the formation of a gas chimney and pipe structure, is identified based on seismic interpretation in the QiongDongNan area of the northern South China Sea. During the Fifth Gas Hydrate Drilling Expedition of the Guangzhou Marine Geological Survey, this type of complex morphology that has close interaction with local gas hydrate (GH) distribution was eventually confirmed. A flow-reaction model is built to explore the spatial–temporal matching evolution process of massive GH reservoirs since 30 kyr before the present (BP). Five time snapshots, including 30, 20, 10, and 5 kyr BP, as well as the present, have been selected to exhibit key strata-evolving information. The results of in situ tensile estimation imply fracturing emergence occurs mostly at 5 kyr BP. Six other environmental scenarios and three cases of paleo-hydrate existence have been compared. The results almost coincide with field GH distribution below the bottom MTD from drilling reports, and state layer fracturing behaviors always feed and probably propagate in shallow sediments. It can be concluded that this complex system with 10% pre-existing hydrates results in the exact distribution and occurrence in local fine-grained silty clay layers adjacent to upper MTDs.

Description: Highlights • Statistically different gas geochemistry was observed in two adjacent springs. • About 74% of helium was contributed by the mantle. • Excess N2 relative to Ar was attributed to subducted materials and seawater mixing. • Magmatic CO2 has been largely removed by calcite precipitation in the reaction zone. • The residual CO2 may also be supplied by microbial oxidation of alkanes. Gas emissions from hydrothermal systems can serve as indicators of subsurface activity. In addition to gas sources, hydrothermal gas geochemistry is strongly influenced by secondary processes that occur during/after hydrothermal circulation. Here, we observed statistically significant differences in the geochemical characteristics (except for helium isotopes) of bubbling gases discharged from two adjacent vents in the Northern Luzon Arc. Helium (3He/4He = 4.25–7.09 Ra) in both vents was controlled by mixing between mantle and crustal components, where about 74% of helium was contributed by the mantle. Differences in N2/Ar ratios (∼ 300–330) of the two neighboring springs are attributed to subducted materials and seawater mixing (contributing ∼2.5% N2 and Ar), rather than phase separation in the reaction zone. Specifically, Ar was mainly supplied by atmospheric components that dissolved in the percolated seawater with only 8%–9% contributed by the excess radiogenic 40Ar. Excess N2 relative to Ar was mainly supplied by the decomposition of subducted materials (83%–92%) of the South China Sea plate beneath the Philippine Sea Plate. The Lutao gases showed low CO2 concentrations (0.07–22.2 mmol/mol), despite the high 3He/4He ratios indicating a significant contribution of magmatic components. Magmatic CO2 may have been largely consumed by the high Ca Lutao vent fluids via carbonate precipitation in the reaction zone. Alternatively, stable carbon isotope compositions (δ13C) indicate that Lutao CO2 may be supplied by microbial oxidation of alkanes (e.g., CH4 with concentrations of 14.6–173 mmol/mol in the samples), with fractionation factor ΔCO2–CH4 ranging from −15‰ to −25‰ and conversion rates of 〈10%. Up to 65% of the CO2 in the 2016 samples experienced secondary calcite precipitation in the discharge zone. Our results indicate that recycled subducted materials could potentially affect the geochemical characteristics of gases discharged from arc-volcanic systems. In addition, the influence of secondary processes needs to be considered before tracing the sources of hydrothermal fluids and/or gases, especially in shallow-water hydrothermal systems.

Description: The crises of climate change and biodiversity loss are interlinked and must be addressed jointly. A proposed solution for reducing reliance on fossil fuels, and thus mitigating climate change, is the transition from conventional combustion-engine to electric vehicles. This transition currently requires additional mineral resources, such as nickel and cobalt used in car batteries, presently obtained from land-based mines. Most options to meet this demand are associated with some biodiversity loss. One proposal is to mine the deep seabed, a vast, relatively pristine and mostly unexplored region of our planet. Few comparisons of environmental impacts of solely expanding land-based mining versus extending mining to the deep seabed for the additional resources exist and for biodiversity only qualitative. Here, we present a framework that facilitates a holistic comparison of relative ecosystem impacts by mining, using empirical data from relevant environmental metrics. This framework (Environmental Impact Wheel) includes a suite of physicochemical and biological components, rather than a few selected metrics, surrogates, or proxies. It is modified from the “recovery wheel” presented in the International Standards for the Practice of Ecological Restoration to address impacts rather than recovery. The wheel includes six attributes (physical condition, community composition, structural diversity, ecosystem function, external exchanges and absence of threats). Each has 3–5 sub attributes, in turn measured with several indicators. The framework includes five steps: (1) identifying geographic scope; (2) identifying relevant spatiotemporal scales; (3) selecting relevant indicators for each sub-attribute; (4) aggregating changes in indicators to scores; and (5) generating Environmental Impact Wheels for targeted comparisons. To move forward comparisons of land-based with deep seabed mining, thresholds of the indicators that reflect the range in severity of environmental impacts are needed. Indicators should be based on clearly articulated environmental goals, with objectives and targets that are specific, measurable, achievable, relevant, and time bound.

Description: Scientists are using a variety of geochemical, geophysical, and numerical methods to study offshore freshened groundwater and better understand its role in the global water cycle.

Description: The deep-sea water column below 200 m is a vast three-dimensional habitat with an enormous but largely unexplored biodiversity (Robison, 2009). Cephalopod mollusks are abundant in the deep sea and are important prey for many kinds of predators. Still, most deep-sea cephalopods have never been observed alive in their natural habitat and their reproductive biology remains poorly documented. In March of 2015, at a depth of 2566 m, we observed a female squid of an undescribed species but likely belonging to the Gonatidae, carrying few but exceptionally large eggs in her arms. This raises questions as to how these and other related animals reproduce in the deep sea, an environment that is generally characterized by darkness, low temperature, reduced oxygen, limited food availability, and low population densities. The authors were conducting dives with deep-sea robots (remotely operated vehicles or ROVs) equipped with cameras in the deep basins of the Gulf of California, to investigate how deep-sea fauna are distributed in relation to the extensive low-oxygen zones in the region (Gilly et al., 2013). The squid (Individual 1, Table 1) we observed with an ROV at 2566 m in the Gulf of California in 2015 was carrying 30–40 large eggs (average maximum diameter 11.2 mm, n = 5; measured eggs were 11.4, 10.4, 11.5, 11.7 and 11 mm maximum diameter) embedded in a small external egg sheet that did not extend beyond the arm tips. The size of the eggs was similar to those of two squid (Individuals 2 and 3, Table 1) that were observed close to the seafloor during earlier expeditions in the same region.

Description: Abstract Robust chronologies and time equivalent tephra markers are essential to better understand spatial palaeoenvironmental response to past abrupt climatic changes. Identification of well-dated and widely dispersed volcanic ash by tephra and cryptotephra (microscopic volcanic ash) provide time synchronous tie-points and strongly reduce chronological uncertainties. Here, we present the major, minor and trace element analyses of cryptotephra shards in the Dead Sea Deep Drilling sedimentary record (DSDDP 5017-1A) matching the Campanian Ignimbrite (CI). This geochemical identification expands the know dispersal range of the CI to the southeastern Mediterranean, over 2,300 km from the volcanic source. Due to the CI eruption occurring near-synchronous with North Atlantic ice surge of Heinrich Event 4 (HE4), this tephra provides insights into regional responses to large-scale climatic change in the Mediterranean. In the Dead Sea, the CI layer is associated with wetter climatic conditions. This contrasts with the contemporaneous occurrence of the CI deposition and dry conditions in the northern and western Mediterranean suggesting a possible climate time-transgressive expansion of HE4. Our finding underscores the temporal and spatial complexity of regional climate responses and emphasises the importance of tephra as a time marker for studying large-scale climatic changes verses regional variations.

Description: As a consequence of on-going global warming, the ocean is losing oxygen, which has implications not only in terms of marine resources management and food supply but also in terms of the potentially important feedback on the global carbon cycle and climate. Of particular scrutiny are the extended zones of already low levels of oxygen called the oxygen minimum zones (OMZs) embedded in the subsurface waters of the productive Eastern Boundary Upwelling Systems (EBUS). These OMZs are currently diversely simulated by state-of-the-art Earth System Models (ESM) hampering a reliable projection of ocean deoxygenation on marine ecosystem services in these regions. Here we focus on the most emblematic EBUS OMZs of the planet, that of the South Eastern Pacific (SEP), which is under the direct influence of the El Ni & ntilde;o Southern Oscillation (ENSO), the main climate mode on interannual timescales at global scale. We show that, despite the low consensus among ESM long-term projections of oxygen levels, the sensitivity of the depth of the upper margin (oxycline) of the SEP OMZ to El Ni & ntilde;o events in an ensemble of ESMs can be used as a predictor of its long-term trend, which establishes an emergent constraint for the SEP OMZ. Because the oxycline along the coast of Peru and Chile deepens during El Ni & ntilde;o events, the upper bound of the SEP OMZ is thus likely to deepen in the future climate, therefore oxygenating the SEP OMZ. This has implications not only for understanding the nitrogen and carbon cycles at global scale but also for designing adaptation strategies for regional upper-ocean ecosystem services. The upper bound of the southeast Pacific oxygen minimum zone deepens during El Ni & ntilde;o events across an ensemble of Earth system models and is therefore projected to likely contract in the future climate, according to an analysis of multiple Earth System Models.

Description: Low-level jets (LLJs), vertical profiles with a wind speed maxima in the lowest hundred meters of the troposphere, have multiple impacts in the Earth system, but a global present-day climatology based on contemporary data does not exist. We use the spatially and temporally complete data set from ERA5 reanalysis to compile a global climatology of LLJs for studying the formation mechanisms, characteristics, and trends during the period of 1992–2021. In the global mean, LLJs are detected 21% of the time with more cases over land (32%) than over the ocean (15%). We classified the LLJs into three categories: non-polar land (LLLJ), polar land (PLLJ), and coastal (CLLJ) LLJs. For LLLJ, the averaged frequency of occurrence is 20% and 75% of them are associated with a near-surface temperature inversion as a prerequisite for an inertial oscillation. PLLJs are also associated with a temperature inversion and occur even more frequently with 59% of the time. These are also the lowest and the strongest LLJs among the three categories. CLLJs are particularly frequent in some marine hotspots, situated along the west coast of continents, with neutral to unstable stratification close to the surfaces and a stably stratified layer aloft. We found distinct regional trends in both the frequency and intensity of LLJs over the past decades, which can have implications for the emission and transport of aerosols, and the transport of atmospheric moisture. Future studies could address changes in LLJs and the associated implications in more detail, based on the here released ERA5-based LLJ data. Key Points: - First global comprehensive low-level jet (LLJ) climatology using ERA5 - Polar LLJs are the strongest and most frequent among the detected types - Distinct past trends in regional LLJ frequency and intensity

Description: Phytoplankton form the base of the marine food web by transforming CO2 into organic carbon via photosynthesis. Despite the importance of phytoplankton for marine ecosystems and global carbon cycling, projections of phytoplankton biomass in response to climate change differ strongly across Earth system models, illustrating uncertainty in our understanding of the underlying processes. Differences are especially large in the Southern Ocean, a region that is notoriously difficult to represent in models. Here, we argue that total (depth-integrated) phytoplankton biomass in the Southern Ocean is projected to largely remain unchanged under climate change by the Coupled Model Intercomparison Project Phase 6 (CMIP6) multi-model ensemble because of a shifting balance of bottom-up and top-down processes driven by a shoaling mixed-layer depth. A shallower mixed layer is projected on average to improve growth conditions, consequently weaken bottom-up control, and confine phytoplankton closer to the surface. An increase in the phytoplankton concentration promotes zooplankton grazing efficiency, thus intensifying top-down control. However, large differences across the model ensemble exist, with some models simulating a decrease in surface phytoplankton concentrations. To reduce uncertainties in projections of surface phytoplankton concentrations, we employ an emergent constraint approach using the observed sensitivity of surface chlorophyll concentration, taken as an observable proxy for phytoplankton, to seasonal changes in the mixed-layer depth as an indicator for future changes in surface phytoplankton concentrations. The emergent constraint reduces uncertainties in surface phytoplankton concentration projections by around one-third and increases confidence that surface phytoplankton concentrations will indeed rise due to shoaling mixed layers under global warming, thus favouring intensified top-down control. Overall, our results suggest that while changes in bottom-up conditions stimulate enhanced growth, intensified top-down control opposes an increase in phytoplankton and becomes increasingly important for the phytoplankton response to climate change in the Southern Ocean.

Description: Highlights: • A cyclonic frontal eddy emerged near the South Java Coast (SJC) in 2019. • The cyclonic eddy induces filaments of Chl-a, cold water, and nutrients. • Anti-cyclonic eddies distribute the filaments further offshore. • The role of wind can't be ignored in distributing filaments in the SJC. • We propose a three-stage mechanism for Chl-a distribution in the offshore SJC. Intense mesoscale eddy activity has been observed off the southern Java coast (SJC), yet its impact on local ecosystems remains largely unknown. To investigate this, we examined remotely sensed altimetry, chlorophyll-a (Chl-a), and sea surface temperature (SST) data, focusing on their response to eddies in the region. Our eddy detection and tracking analysis revealed a unique cyclonic frontal eddy near the SJC coast and a large anticyclonic eddy offshore, active from July to September 2019. The cyclonic frontal eddy induced water transport through eddy filaments, upwelled subsurface cold water, and enhanced Chl-a concentrations by horizontally entraining Chl-a-rich shelf water offshore. The anticyclonic eddy then contributed to further distributing this enriched water southward. The mean cross-shelf transport associated with the frontal eddy was estimated at 1.80–2.33 Sv offshore, exporting approximately 1.87–2.40 × 103 tons of Chl-a to the Indian Ocean during its lifetime. Additionally, the spatial cross-correlation analysis of zonal and meridional wind stress with Chl-a revealed relatively high correlation values (0.6–1) and short lag times (〈5 days) in offshore areas, indicating that the role of wind in the Chl-a advection cannot be ignored. We propose a three-stage mechanism to explain the presence of high Chl-a offshore:1) Wind-driven upwelling intensifies coastal nutrients, elevating Chl-a concentrations in coastal waters, 2) Frontal cyclonic eddy facilitates the retention and offshore export of these upwelling-enriched waters. and 3) Anticyclonic eddy advects these nutrient-rich waters further south. The combination of enhanced coastal upwelling and eddies can explain nutrient-rich coastal waters in offshore regions

Description: Reef-building corals live in highly hydrodynamic environments, where water flow largely controls the complex chemical microenvironments surrounding them—the concentration boundary layer (CBL). The CBL may be key to alleviate ocean acidification (OA) effects on coral colonies by partially isolating them. However, OA effects on coral CBL remain poorly understood, particularly under different flow velocities. Here, we investigated these effects on the reef-building corals Acropora cytherea, Pocillopora verrucosa, and Porites cylindrica. We preconditioned corals to a control (pH 8.0) and OA (pH 7.8) treatment for four months and tested how low flow (2 cm s−1) and moderate flow (6 cm s−1) affected O2 and H+ CBL traits (thickness, surface concentrations, and flux) inside a unidirectional-flow chamber. We found that CBL traits differed between species and flow velocities. Under OA, traits remained generally stable across flows, except surface pH. In all species, the H+ CBL was thin and led to lower surface pH. Still, low flow thickened H+ CBLs and increased light elevation of surface pH. In general, our findings reveal a weak to null OA modulation of the CBL. Moreover, the OA-buffering capacity by the H+ CBL may be limited in coral species, though low flow could enhance CBL sheltering.

Description: Turbulent mixing in the ocean, lakes and reservoirs facilitates the transport of momentum, heat, nutrients, and other passive tracers. Turbulent fluxes are proportional to the rate of turbulent kinetic energy dissipation per unit mass, ε. A common method for ε measurements is using microstructure profilers with shear probes. Such measurements are now widespread, and a non-expert practitioner will benefit from best practice guidelines and benchmark datasets. As a part of the Scientific Committee on Oceanographic Research (SCOR) working group on “Analysing ocean turbulence observations to quantify mixing” (ATOMIX), we compiled a collection of five benchmark data of ε from measurements of turbulence shear using shear probes. The datasets are processed using the ATOMIX recommendations for best practices documented separately. Here, we describe and validate the datasets. The benchmark collection is from different types of instruments and covers a wide range of environmental conditions. These datasets serve to guide the users to test their ε estimation methods and quality-assurance metrics, and to standardize their data for archiving.

Description: Oceanic intraplate volcanoes sometimes experience late-stage eruptive activity known as rejuvenated volcanism, and contrasting interpretations for its petrogenesis depend on the compositional characteristics. In the Juan Fernández Ridge (JFR), a volcanic chain approximately 800 km in length emplaced on the Nazca Plate, some subaerial occurrences of rejuvenated volcanism have been recognized on the Robinson Crusoe and Santa Clara Islands, both part of the same deeply eroded shield volcano complex. This study aims to understand the origin and magmatic evolution of rejuvenated volcanism on Santa Clara Island, emplaced after ~2.15 Ma of quiescence above the shield sequence, mainly via the analysis of unpublished geochemical and isotopic data. Field reconnaissance identified two nearly coeval rejuvenated sequences on Santa Clara Island: Bahía W (BW) and Morro Spartan (MS), both formed by basanitic and picro-basaltic lava flows with brecciated levels and local intercalations of sedimentary and pyroclastic deposits. In comparison to the chemical signature of the preceding shield-building stage (comprised mainly of basalts and picrites), the two rejuvenated sequences exhibit a notable enrichment in incompatible elements, but the Sr, Nd, and Pb isotopes are very similar to the FOZO mantle endmember, with an apparent additional contribution of HIMU and EM1 components. The geochemistry of lavas revealed the involvement of various processes, including contamination by ultramafic xenoliths, high-pressure fractional crystallization of olivine and clinopyroxene, and potential partial assimilation of oceanic lithospheric components. While the oceanic lithosphere has been considered as a potential source, the isotopic data from Santa Clara lies outside of the mixing curve between depleted mantle (DM, here represented by the North Chile Rise and the East Pacific Rise) and the previous shield stage, suggesting that a lithospheric mantle is not the primary source for the rejuvenated stage volcanism. Therefore, we favor an origin of the rejuvenated volcanism from the mantle plume forming the JFR, supported by similarities in isotopic signatures with the shield stage and high values of 208Pb/204Pb (only comparable to San Félix—San Ambrosio in the vicinity of JFR), implying the presence of a regional source with radiogenic 208Pb/204Pb isotope ratios. In addition, isotopic variations are subparallel to the mixing line between HIMU and EM1 components, whose participation in different proportions might explain the observed trends. In conclusion, we propose that the source of the rejuvenated volcanism on Santa Clara Island is a heterogeneous mantle plume, the same one that fed the shield stage. The rejuvenated volcanism is derived from a secondary melting zone away from the main axis of the plume.

Description: What role do socio-demographic and local environmental factors play in the perception of climate change? The article of Landwehr et al. to be discussed here presents interdisciplinary findings on this question, which are particularly interesting regarding the group of farmers. However, the findings also raise questions about the degree of abstraction of climate perception, the rigidity of social identity, the role of the media and the strategy of targeting. In the context of recent “farmer protests” and populist narratives, the author of this response concludes that future interdisciplinary research projects on climate perceptions should also analyse political variables and the relevance of populist discourses.

Description: Welche Rolle spielen sozio-demografische und lokale Umweltfaktoren für die Klimawandelwahrnehmung? Der hier besprochene Artikel von Landwehr et al. stellt interdisziplinäre Befunde zu dieser Frage vor, die besonders mit Blick auf die Gruppe der Landwirt(inn)e(n) interessant sind. Die Befunde werfen aber auch Fragen zum Abstraktionsgrad der Klimawahrnehmung, der Rigidität sozialer Identität, der Rolle der Medien und der Zielgruppenstrategie auf. Im Kontext der jüngsten ,,Bauernproteste“ und populistischer Narrative folgert der Autor dieser Reaktion, dass in künftigen interdisziplinären Forschungsprojekten zur Klimawahrnehmung auch politische Variablen und die Relevanz populistischer Diskurse untersucht werden sollten.

Description: Climate change poses a threat to the agricultural sector, increasing the risk of crop failures, food insecurity and poverty. Given the need for an efficient allocation of scarce adaptation finance, scientific evidence can help to guide the prioritization of adaptation options. This article offers reflections on lessons learned from the AGRICA project, a collaboration between the Potsdam Institute for Climate Impact Research (PIK) and Deutsche Gesellschaft für Internationale Zusammenarbeit (GIZ) on behalf of the German Federal Ministry for Economic Cooperation and Development (BMZ). Running from 2018 to 2024, AGRICA aimed to provide scientific evidence on climate risks, related impacts and suitable adaptation strategies for the agricultural sector in sub-Saharan Africa. Bringing together insights from science, development cooperation and policy, we argue for the need to produce and use rigorous scientific evidence for adaptation policy and planning, including for the formulation and implementation of ambitious National Adaptation Plans (NAPs) and Nationally Determined Contributions (NDCs). This is motivated by assessments such as from the IPCC (2022), which deems current NDC efforts in the agricultural sector insufficient for achieving the Paris Agreement. We discuss lessons learned with a focus on trade-offs between in-depth and standardized assessments, data availability and spatial resolution, modelling uncertainty and methodological pluralism to bridge the science-policy gap.

Description: This chapter provides an overview of the transhumanist movement, its origins, its main figures and its main positions. It then highlights the fact that transhumanism shows little concern for environmental issues, as it is mostly focused on individual bodies, health and longevity. Finally, this chapter examines how transhumanists activists or related academics address contemporary ecological disasters, focusing on the human engineering hypothesis first, and then the “good Anthropocene” and its connections with some aspects of the debate on solar geoengineering.

Description: Today, populism is widely understood to entail an exclusionary conception of “the people” that threatens climate change action. While this threat is real, I argue that populism itself can be understood as a response to perceived exclusion and marginalization, making it possible to conceptualize a more heterogeneous conception of populism’s “people.” Examining two approaches to climate change action rooted in contrasting conceptions of the people and the elite, I argue that climate justice organizing offers a promising effort to construct a heterogeneous people and offers a powerful critique of the elite representation of climate change action in which “we are all in this together.” Yet along with this promise, climate justice organizing must navigate tensions that are inescapable within any populist formation. One neglected thread of populist history and theory offers resources for doing so; in the final section of this paper, I explore its relevance to climate justice today.

Description: The debate on how to evaluate and manage risks focuses on three major strategies: (Renn O. EMBO Rep 8:303–305, 2007, Renn O. Risk governance. Coping with uncertainty in a complex world. Earthscan, London, 2008a; Stirling A. On ‘Science’ and ‘Precaution’ in the management of technological risk. Volume I: synthesis study, report to the eu forward studies unit by European Science and Technology Observatory (ESTO), EUR19056EN. IPTS, Sevilla. Available at: ftp://ftp.jrc.es/pub/EURdoc/eur19056IIen.pdf, 1999): (1) risk-based approaches, including, numerical thresholds (NOEL standards, performance standards, etc.); (2) reduction activities derived from the application of the precautionary principle (examples are ALARA, i.e., as low as reasonably achievable, BACT, i.e., best available control technology, containment in time and space, or constant monitoring of potential side-effects); and (3) standards derived from discursive processes such as roundtables, deliberative rulemaking, mediation or citizen panels. Experience demonstrates that there is no simple recipe for assessing, evaluating and managing risks. In view of complex cause-effect relationships, diverse attitudes and preferences as well as variations in interests and values, risks must be considered as physically as well as socially heterogeneous phenomena that preclude standardized evaluation and handling. Therefore, a coherent concept for evaluation and management is needed that ensures the integration of social diversity and multidisciplinary approaches into institutional routines and standardized practices. The main objective of this paper is to explore the potentials and the limitations of an approach to risk assessment and management that has been labelled the “precautionary principle”. In its most simple version, precaution requires risk managers to err on the safe side. This includes rather accepting false negative (that risks are less severe than assumed) than false positive assessments (that risk are more severe than assumed). However, such a simple definition does not specify to what degree false negatives are socially tolerable, nor does it allow a discussion about future benefits that could potentially compensate for uncertain risks. The following sections will review main positions on precaution and point out the present practice in the European Union, which has adopted the precautionary principle as a major legal guideline for its risk management practice. The paper concludes with suggestions for aligning the precautionary principle and the concept of responsible innovation.

Description: Policy advice for dealing with major crises has focussed on two concepts: resilience and sustainability. The article introduces the term resilience and explains its application in different disciplines. Furthermore, it explores the relationship between resilience and sustainability, illustrates the various concepts that are associated with each term and suggests an integrative approach that is based on the ideal of maintaining critical services for reaching humane living conditions for present and future generations based on fair distribution rules and inclusive governance processes.

Description: FS METEOR Expedition M201 VebVolc, 09.06. – 18.07.2024 | Reykjavik – Praia da Vitoria

Description: The Banda Sea is of crucial importance for the circulation of the world's oceans, as it is part of the connection between the Pacific to the Indian Ocean. One peculiarity of the upper ocean hydrography in the Banda Sea is the occurrence of barrier layers. The regionality and temporal variability of barrier layer thickness (BLT) in the Banda Sea are examined in this study utilizing in-situ observations and ocean reanalysis output. It is found that a barrier layer occurs in over 90 % of the observational data profiles, and in over 72 % of those profiles, the BLT is shallower than 10 m. Furthermore, we find a seasonal cycle in BLT with a maximum thickness of about 60 m occurring during austral autumn and winter and coinciding with the presence of low saline waters fed by the regional river discharge and rainfall from the Java Sea and Makassar Strait. In addition, we identify the existence of a quasi-permanent anticyclonic circulation cell in the Banda Sea that may support the trapping of surface freshwater by retention. The anticyclonic circulation is most likely wind-driven because it coincides with the regional Ekman pumping pattern. Modulation of the anticyclone is via seasonal variability in the wind stress curl which in turn may explain the efficiency of freshwater retention and thus the BLT. The annual mean BLT distribution in the Banda Sea shows a preferential region of thickened barrier layers around 6o-8oS and 124o-126oE and resampling the pattern of the monthly mean climatology. Key Points: - First study estimating barrier layer thickness (BLT) in the Banda Sea using comprehensive observations - A quasi-permanent barrier layer exists in the Banda Sea with seasonal variation in occurrence and thickness - The intrusion of low saline waters and anticyclonic circulation are identified as the main mechanisms for creating and modulating the local BLT

Description: In 2015, the United Nations agreed on 17 Sustainable Development Goals as the central normative framework for sustainable development worldwide. The effectiveness of governing by such broad global goals, however, remains uncertain, and we lack comprehensive meta-studies that assess the political impact of the goals across countries and globally. We present here condensed evidence from an analysis of over 3,000 scientific studies on the Sustainable Development Goals published between 2016 and April 2021. Our findings suggests that the goals have had some political impact on institutions and policies, from local to global governance. This impact has been largely discursive, affecting the way actors understand and communicate about sustainable development. More profound normative and institutional impact, from legislative action to changing resource allocation, remains rare. We conclude that the scientific evidence suggests only limited transformative political impact of the Sustainable Development Goals thus far.

Description: The disturbance of marine organism phenology due to climate change and the subsequent effects on recruitment success are still poorly understood, especially in migratory fish species, such as the Atlantic herring (Clupea harengus; Clupeidae). Here we used the commercial catch data from a local fisher over a 50-year period (1971–2020) to estimate western Baltic spring-spawning (WBSS) herring mean arrival time Q50 (i.e., the week when 50% of the total fish catches had been made) at their spawning ground within the Kiel Fjord, southwest Baltic Sea, and the duration of the spawning season for each year. The relationship between the seawater temperature in the Kiel Bight and other environmental parameters (such as water salinity, North Atlantic and Atlantic multidecadal oscillations) and Q50 was evaluated using a general linear model to test the hypothesis that fish arrived earlier after warm than cold winters. We also estimated the accumulated thermal time to Q50 during gonadal development to estimate the effects of seawater temperature on the variations of Q50. The results of this study revealed a dramatic decrease in herring catches within the Kiel Fjord since the mid-1990s, as documented for the whole southwestern Baltic Sea. Warmer winter seawater temperature was the only factor related to an earlier arrival (1 week for one January seawater temperature degree increase) of herring at their spawning ground. The relationship was found for the first time on week 52 of the year prior to spawning and was the strongest (50% of the variability explained) from the fourth week of January (8 weeks before the mean Q50 among the studied years). A thermal constant to Q50 (~316°C day) was found when temperatures were integrated from the 49th week of the year prior to spawning. These results indicate that seawater temperature enhanced the speed of gonadal maturation during the latest phases of gametogenesis, leading to an early fish arrival under warm conditions. The duration of the spawning season was elongated during warmer years, therefore potentially mitigating the effects of trophic mismatch when fish spawn early. The results of this study highlight the altering effects of climate change on the spawning activity of a migratory fish species in the Baltic Sea where fast global changes presage that in other coastal areas worldwide

Description: FS Maria S Merian – MSM129/2 07.06.2024 – 06.07.2024 St. John’s (Kanada) – Reykjavik (Island) 1st Wochenbericht (07.06. – 09.06.2024)

Description: Events of extreme precipitation pose a hazard to many parts of Europe but are typically not well represented in climate models. Here, we evaluate daily extreme precipitation over Europe during 1982–2019 in observations (GPCC), reanalysis (ERA5) and a set of atmosphere-only simulations at low- (100 km), medium- (50 km) and high- (25 km) horizontal resolution with identical vertical resolutions using OpenIFS (version 43r3). We find that both OpenIFS simulations and reanalysis underestimate the rates of extreme precipitation compared to observations. The biases are largest for the lowest resolution (100 km) and decrease with increasing horizontal resolution (50 and 25 km) simulations in all seasons. The sensitivity to horizontal resolution is particularly high in mountain regions (such as the Alps, Scandinavia, Iberian Peninsula), likely linked to the sensitivity of vertical velocity to the representation of topography. The sensitivity of precipitation to model resolution increases dramatically with increasing percentiles, with modest biases in the 70th–80thpercentile range and large biases above the 99th percentile range. We also find that precipitation above the 99th percentile mostly consists of large-scale precipitation (~80 %) in winter, while in summer it is mostly large-scale precipitation in Northern Europe (~70 %) and convective precipitation in Southern Europe (~70 %). Compared to ERA5, the OpenIFS overestimates large-scale precipitation extremes in winter, but underestimates in summer. The discrepancy between OpenIFS and ERA5 decreases with increasing horizontal resolutions. We also examine the sensitivity of extreme precipitation to model time step and find that the convective contribution to extreme precipitation is more sensitive to the model time step than the horizontal resolution. This is likely due to the sensitivity of convective activity to model time step. On the other hand, the large-scale contribution to extreme precipitation is more sensitive to horizontal resolution than the model time step, which may be due to sharper fronts and steeper topography at higher horizontal resolution.

Description: Little is known about the Paleocene in the southern Pacific Ocean due to scarce marine records. Here, we present a systematic geochemical investigation using biomarkers, carbonate content, and carbon isotopes of a set of early Paleocene deep-sea cores from International Ocean Discovery Program Expedition 378 Site U1553. The results provide a new and complete biomarker profile of the Campbell Plateau, New Zealand over the Paleocene. The occurrence and distribution of a series of hopenes, ββ hopanes, sterenes and biomarker-based maturity parameters indicate that these organically-lean sediments are in an early diagenetic stage, with an equivalent vitrinite reflectance of approximately 0.4%. Redox properties of the Paleocene southern Pacific Ocean change from an oxidising-anoxic transition zone to a more reducing marine environment (water depth 〉 1000 m). The sources of the organic matter are diverse, including algae, bacteria, archaea, diatoms, dinoflagellates, and higher plants, but are dominated by aquatic organisms. Our new biomarker record bridges the knowledge gap of Paleocene biosphere in the high latitude South Pacific.

Description: 1. The expansion of scientific image data holds great promise to quantify individuals, size distributions and traits. Computer vision tools are especially powerful to automate data mining of images and thus have been applied widely across studies in aquatic and terrestrial ecology. Yet marine benthic communities, especially infauna, remain understudied despite their dominance of marine biomass, biodiversity and playing critical roles in ecosystem functioning. 2. Here, we disaggregated infauna from sediment cores taken throughout the spring transition (April-June) from a near-natural mesocosm setup under experimental warming (Ambient, +1.5 degrees C, +3.0 degrees C). Numerically abundant mudsnails were imaged in batches under stereomicroscopy, from which we automatically counted and sized individuals using a superpixel-based segmentation algorithm. Our segmentation approach was based on clustering superpixels, which naturally partition images by low-level properties (e.g., colour, shape and edges) and allow instance-based segmentation to extract all individuals from each image. 3. We demonstrate high accuracy and precision for counting and sizing individuals, through a procedure that is robust to the number of individuals per image (5-65) and to size ranges spanning an order of magnitude (〈750 mu m to 7.4 mm). The segmentation routine provided at least a fivefold increase in efficiency compared with manual measurements. Scaling this approach to a larger dataset tallied 〉40k individuals and revealed overall growth in response to springtime warming. 4. We illustrate that image processing and segmentation workflows can be built upon existing open-access R packages, underlining the potential for wider adoption of computer vision tools among ecologists. The image-based approach also generated reproducible data products that, alongside our scripts, we have made freely available. This work reinforces the need for next-generation monitoring of benthic communities, especially infauna, which can display differential responses to average warming.

Description: Abundant mineral resources in the deep sea are prospected for mining for the global metal market. Seafloor massive sulphide (SMS) deposits along the Mid-Atlantic Ridge are one of the potential sources for these metals. The extraction of SMS deposits will expose adjacent marine ecosystems to suspended particle plumes charged with elevated concentrations of heavy metals and other potentially toxic compounds. Up to date there is no information about the impact of mining activities on deep-sea benthic ecosystems such as abundant deep-sea sponge grounds in the North Atlantic Ocean. Sponge grounds play a major role in benthic-pelagic coupling and represent an important habitat for a diversity of vertebrates, invertebrates and microorganisms. To simulate the effects of mining plumes on benthic life in the deep sea, we exposed Geodia barretti, a dominant sponge species in the North Atlantic Ocean, and an associated brittle star species from the genus Ophiura spp. to a field-relevant concentration of 30 mg L−1 suspended particles of crushed SMS deposits. Three weeks of exposure to suspended particles of crushed SMS resulted in a tenfold higher rate of tissue necrosis in sponges. All brittle stars in the experiment perished within ten days of exposure. SMS particles were evidently accumulated in the sponge's mesohyl and concentrations of iron and copper were 10 times elevated in SMS exposed individuals. Oxygen consumption and clearance rates were significantly retarded after the exposure to SMS particles, hampering the physiological performance of G. barretti. These adverse effects of crushed SMS deposits on G. barretti and its associated brittle star species potentially cascade in disruptions of benthic-pelagic coupling processes in the deep sea. More elaborate studies are advisable to identify threshold levels, management concepts and mitigation measures to minimize the impact of deep-sea mining plumes on benthic life.

Description: In the Andaman Sea internal waves of extraordinary amplitudes and frequencies break at the continental shelf and periodically introduce cold, nutrient-rich, hypoxic deep-sea water into the surface layer. The islands of the Andaman Sea shelter coral reefs from the effects of these large amplitude internal waves (LAIW) on eastern shores and separate them from the exposed reefs on western shores. Exposed reefs harbor corals with increased heat resistance, but which processes facilitate this resistance is not yet clear. As heterotrophic feeding has been shown to play an important role in warm water coral bleaching resilience and recovery, a shift in trophic strategy through LAIW-enriched organic matter flux may contribute to thermal resistance. In this thesis I utilized modern stable isotope and fatty acid analytics on separated coral host and Symbiodinium fractions to assess the trophic strategy of two coral species Porites lutea and Pocillopora verrucosa from both shore sites of two islands in the Andaman Sea (Miang and Racha). The results reveal a complex picture, with island and species-specific effects. Pocillopora does not show large differences in fatty acid trophic and health markers, with trophic markers indicating marginal higher heterotrophy on Rachas LAIW exposed but also on Miangs sheltered site. SIBER analysis on Pocillopora signals consistent trophic strategy on both sides. Porites do show a tendency of increased heterotrophy on Miangs LAIW exposed site and a smaller increase on Rachas exposed reefs. However, SIBER analysis of both islands pooled does not support this and instead indicates higher autotrophy. Health markers in LAIW exposed Porites are slightly elevated, in concert with higher biomass and fatty acids per surface they suggest a healthier phenotype. However, Pocillopora does not demonstrate this enhanced health status with LAIW exposure. As shift towards more heterotrophy seems to be nuanced and context-dependent it is most likely not the driving factor for the elevated heating resistance observed in LAIW exposed corals.

Description: Biological invasions pose a rapidly expanding threat to the persistence, functioning and service provisioning of ecosystems globally, and to socio-economic interests. The stages of successful invasions are driven by the same mechanism that underlies adaptive changes across species in general-via natural selection on intraspecific variation in traits that influence survival and reproductive performance (i.e., fitness). Surprisingly, however, the rapid progress in the field of invasion science has resulted in a predominance of species-level approaches (such as deny lists), often irrespective of natural selection theory, local adaptation and other population-level processes that govern successful invasions. To address these issues, we analyse non-native species dynamics at the population level by employing a database of European freshwater macroinvertebrate time series, to investigate spreading speed, abundance dynamics and impact assessments among populations. Our findings reveal substantial variability in spreading speed and abundance trends within and between macroinvertebrate species across biogeographic regions, indicating that levels of invasiveness and impact differ markedly. Discrepancies and inconsistencies among species-level risk screenings and real population-level data were also identified, highlighting the inherent challenges in accurately assessing population-level effects through species-level assessments. In recognition of the importance of population-level assessments, we urge a shift in invasive species management frameworks, which should account for the dynamics of different populations and their environmental context. Adopting an adaptive, region-specific and population-focused approach is imperative, considering the diverse ecological contexts and varying degrees of susceptibility. Such an approach could improve and refine risk assessments while promoting mechanistic understandings of risks and impacts, thereby enabling the development of more effective conservation and management strategies. Biological invasions increasingly threaten global ecosystems and socio-economic interests, advancing through mechanisms like natural selection that enhance survival and reproductive traits. Our study focuses on population-level analyses of non-native European freshwater macroinvertebrates to better understand their spread and impact. We found significant variability in invasion dynamics across populations and regions, suggesting that current species-level risk assessments may overlook crucial population-specific factors.image

Description: Forest ecosystems, their products and services play an important role in achieving ambitious climate change mitigation objectives at the same time requiring profound adaptation to climate change. Forest management schemes to support climate action have to be developed within their regional context but also have to be aligned with national or EU-level climate, forest and sustainability policies.The conference on “Managing forests in the 21st century” is the final conference of the FORMASAM, REFORCEand FOREXCLIMresearch projects. The conference bringstogether scientific experts on forest management from all over Europe facing very specific management challenges. The aim isto discuss and improve the understanding therole of forests and forest management in the context of climate change. The conference addressesclimate change impacts, as well as needs for mitigation and adaptation especially with regard to the following scientific questions:1.What are the impacts of climate extremes and disturbances?2.What are the management challenges (and options) for resilient forests?3.What can we do to increase the contribution of forest management to climate change mitigation?

Description: Zur Unterstützung einer lithostratigraphischen Neugliederung der Rotliegend- Sedimente der Saar-Nahe-Senke wurden im Donnersberg-Raum zwei Bohrungen niedergebracht. Durch diese konnten Aufbau und Mächtigkeiten mehrerer lithostratigraphisch wichtiger Einheiten aus dem mittleren Teil der Nahe-Gruppe erfaßt werden.

Description: Abstract: Two 300 and 392 m deep holes where drilled to gain detailed Information on the Rotliegend-stratigraphy in the Donnersberg-area, which is part of the Permocarboniferous Saar-Nahe-Basin (SW-Germany). The results lead to a better knowledge of lithostratigraphic important units from the upper part of the Rotliegend (the Nahe-Group).

Description: research

Description: Observations of spatio-temporal variability of the deep ocean are rare and little is known about occurrence of deep ocean mesoscale dynamics. Here, we make use of 2.5 years of time series data from three distributed sensor arrays, which acquired high-resolution temperature, pressure and sound speed data of the bottom layer offshore northern Chile. Estimating salinity and density from the direct observations enable access to the full spectrum of hydrographic variability from a multi-hourly to annual time scale and with average inter-station distances of less than 1 km. Analyses revealed interannual warming over the continental slope of 0.002 °C yr−1–0.003 °C yr−1, and could trace periodic hydrographic anomalies, likely related to coastal-trapped waves, as far as to the lower continental slope. A concurrent change in the shape of the warm anomalies and the rate of deep-sea warming that occurs with the crossing of the deep-sea trench suggests that the abyssal part of the eastern boundary current system off Chile does not extend past the deep sea trench. Furthermore, the comparison of anomaly timing and shape in between stations implies southwards flow over the mid to lower continental slope, centred closer to the trench.

Description: Weather causes extremes in photovoltaic and wind power production. Here we present a comprehensive climatology of anomalies in photovoltaic and wind power production associated with weather patterns in Europe considering the 2019 and potential 2050 installations, and hourly to ten-day events. To that end, we performed kilometer-scale numerical simulations of hourly power production for 23 years and paired the output with a weather classification which allows a detailed assessment of weather-driven spatio-temporal production anomalies. Our results highlight the dependency of low-power production events on the installed capacities and the event duration. South-shifted Westerlies (Anticyclonic South-Easterlies) are associated with the lowest hourly (ten-day) extremes for the 2050 (both) installations. Regional power production anomalies can differ from the ones in the European mean. Our findings suggest that weather patterns can serve as indicators for expected photovoltaic and wind power production anomalies and may be useful for early warnings in the energy sector.

Description: The Peruvian Upwelling System hosts an extremely high productive marine ecosystem. Observations show that the Peruvian Upwelling System is the only Eastern Boundary Upwelling Systems (EBUS) with an out-of-phase relationship of seasonal surface chlorophyll concentrations and upwelling intensity. This "seasonal paradox" triggers the questions: (1) what is the uniqueness of the Peruvian Upwelling System compared with other EBUS that leads to the out of phase relationship; (2) how does this uniqueness lead to low phytoplankton biomass in austral winter despite strong upwelling and ample nutrients? Using observational climatologies for four EBUS we diagnose that the Peruvian Upwelling System is unique in that intense upwelling coincides with deep mixed layers. We then apply a coupled regional ocean circulation-biogeochemical model (CROCO-BioEBUS) to assess how the interplay between mixed layer and upwelling is regulating the seasonality of surface chlorophyll in the Peruvian Upwelling System. The model recreates the "seasonal paradox" within 200 km off the Peruvian coast. We confirm previous findings that deep mixed layers, which cause vertical dilution and stronger light limitation, mostly drive the diametrical seasonality of chlorophyll relative to upwelling. In contrast to previous studies, reduced phytoplankton growth due to enhanced upwelling of cold waters and lateral advection are second-order drivers of low surface chlorophyll concentrations. This impact of deep mixed layers and upwelling propagates up the ecosystem, from primary production to export efficiency. Our findings emphasize the crucial role of the interplay of the mixed layer and upwelling and suggest that surface chlorophyll may increase along with a weakened seasonal paradox in response to shoaling mixed layers under climate change.

Description: Marine ecosystems, particularly productive marine ecosystems, substantially impact global fisheries and are considerably influenced by climate change as an integral component of the earth system. Modelling is an essential tool to understand marine ecosystems and project their possible response to climate change. However, current ecosystem modelling projections have significant uncertainties, which are partially caused by a lack of overall understanding of the underlying physical-biological interactions. This thesis seeks to identify the driving mechanisms of the trophodynamics in productive marine ecosystems in the contemporary climate, which is key to improve future ecosystem projections under climate change.

Description: Emission inventories are a critical basis for air quality and climate modeling, as well as policy decisions. Non-methane volatile organic compounds (NMVOCs) are key precursor compounds in ozone and secondary organic aerosol formation. Accurately representing NMVOCs in emission inventories is crucial for understanding atmospheric chemistry, the impact of policy measures, and climate projections. Improving NMVOC representation in emission inventories is fraught with challenges, ranging from the lack of (long-term) NMVOC measurements, limited efforts in updating emission factors, to the diversity of NMVOC species reactivity. Here we take an initial step to evaluate the representation of urban NMVOC speciation in an emission inventory (EDGARv4.3.2 and EDGARv6.1) at the global level. To compare the urban measurements of NMVOCs to the emission inventory estimates, ratios of individual NMVOCs to acetylene are used. Owing to limitations in measurement data and grouping of NMVOCs in emission inventories, the comparison includes only a limited number of alkanes, alkenes, and aromatics. Results show little to no agreement between the ratios in the observations and those in the global emission inventory for the species compared (r2 0.01–0.20). This could be related to incorrect speciation profiles and/or spatial allocation of NMVOCs to urban areas. Regional emission inventories show better agreement among the ratios (r2 0.43–0.70). The inclusion of oxygenated species in NMVOC measurements, as well as greater global coverage of measurements could improve representation of NMVOC species in emission inventories, and a mosaic of regional inventories may be a better approach.

Description: The international UN Climate Change conferences known as “Conferences of the Parties (COPs)” have an enormous convening power and are attended annually by tens of thousands of actors working on climate change topics from a wide range of perspectives. In the COP spaces outside of the formal negotiations, the communication culture is dominated by “side events,” a format that relies heavily on conventional presentations and panels that can be informative, but is generally not conducive to mutual engagement, reflection, or dialogue. There is an urgent need for new dialogue formats that can better foster learning and community-building and thereby harness the enormous latent potential for climate action represented by the diverse stakeholders that gather at the COP. Against this backdrop, and drawing on our experience with the development and implementation of the Co-Creative Reflection and Dialogue Spaces at COP25, COP26, and COP27, we make recommendations for further developing the communication culture of the COPs. At the level of individual sessions, we provide recommendations for designing participatory dialogues that can better support reflection, interconnection, and action orientation. In addition, we offer guidance for scaling up these practices, for instance through networks and communities of practice to support a shift of the overall communication culture of the COPs. Our recommendations focus on interactions and exchanges that unfold outside of the formal negotiation sessions, with a view toward enabling and accelerating transformative action by non-state actors.

Description: The simulation of deep-sea conditions in laboratories is technically challenging but necessary for experiments that aim at a deeper understanding of physiological mechanisms or host-symbiont interactions of deep-sea organisms. In a proof-of-concept study, we designed a recirculating system for long-term culture (〉2 yr) of deep-sea mussels Gigantidas childressi (previously Bathymodiolus childressi). Mussels were automatically (and safely) supplied with a maximum stable level of ~60 μmol L−1 methane in seawater using a novel methane–air mixing system. Experimental animals also received daily doses of live microalgae. Condition indices of cultured G. childressi remained high over the years, and low shell growth rates could be detected, too, which is indicative of positive energy budgets. Using stable isotope data, we demonstrate that G. childressi in our culture system gained energy, both, from the digestion of methane-oxidizing endosymbionts and from digesting particulate food (microalgae). Limitations of the system, as well as opportunities for future experimental approaches involving deep-sea mussels, are discussed.

Description: Seagrass meadows have a disproportionally high organic carbon (Corg) storage potential within their sediments and thus can play a role in climate change mitigation via their conservation and restoration. However, high spatial heterogeneity is observed in Corg, with wide differences seen globally, regionally, and even locally (within a seagrass meadow). Consequently, it is difficult to determine their contributions to the national remaining carbon dioxide (CO2) budget without introducing a large degree of uncertainty. To address this spatial heterogeneity, we sampled 20 locations across the German Baltic Sea to quantify Corg stocks and sources in Zostera marina seagrass-vegetated and adjacent unvegetated sediments. To predict and integrate the Corg inventory in space, we measured the physical (seawater depth, sediment grain size, current velocity at the seafloor, anthropogenic inputs) and biological (seagrass complexity) environments to determine regional and local drivers of Corg variation. Here, we show that seagrass meadows in Germany constitute a significant Corg stock, storing on average 7,785 g C/m2, 13 times greater than meadows from other parts of the Baltic Sea, and fourfold richer than adjacent unvegetated sediments. Stocks were highly heterogenous; they differed widely between (by 10-fold) and even within (by 3- to 55-fold) sites. Regionally, Corg was controlled by seagrass complexity, fine sediment fraction, and seawater depth. Autochthonous material contributed to 78% of the total Corg in seagrass-vegetated sediments, and the remaining 22% originated from allochthonous sources (phytoplankton and macroalgae). However, relic terrestrial peatland material, deposited approximately 6,000 years BP during the last deglaciation, was an unexpected and significant source of Corg. Collectively, German seagrasses in the Baltic Sea are preventing 8.14 Mt of future CO2 emissions. Because Corg is mostly produced on-site and not imported from outside the meadow boundaries, the richness of this pool may be contingent on seagrass habitat health. Disturbance of this Corg stock could act as a source of CO2 emissions. However, the high spatial heterogeneity warrants site-specific investigations to obtain accurate estimates of blue carbon and a need to consider millennial timescale deposits of Corg beneath seagrass meadows in Germany and potentially other parts of the southwestern Baltic Sea.

Description: Seit über einem halben Jahrhundert wissen wir um die erschreckenden Auswirkungen von Umweltzerstörung und Klimawandel. Zwar häufen sich internationale Umwelt- und Klimakonferenzen, doch warum handeln wir nicht konsequent gegen die verheerenden Bedrohungen? Mojib Latif wendet sich in diesem Buch der Frage zu, warum unsere Welt trotz besseren Wissens weiterhin auf gefährliche Weise den Ast absägt, auf dem sie sitzt. Latif stellt die unbequemen Fragen nach dem Versagen der Politik und den Interessen weniger mächtiger Konzerne, die von dieser fatalen Entwicklung profitieren. Die zentrale These dieses Buches ist ebenso klar wie dringlich: Der Klimawandel ist zum verhängnisvollen Verhandlungsobjekt geworden. Nur wenige dabei gewinnen – zahllose verlieren. Doch es gibt Hoffnung, und Latif zeigt den Weg: Die Zukunft nachfolgender Generationen kann gerettet werden, wenn wir uns auf globale Zusammenarbeit besinnen sowie Wohlstand und Nachhaltigkeit in Einklang bringen.

Description: Persistently high marine temperatures are escalating and threating marine biodiversity. The Baltic Sea, warming faster than other seas, is a good model to study the impact of increasing sea surface temperatures. Zostera marina, a key player in the Baltic ecosystem, faces susceptibility to disturbances, especially under chronic high temperatures. Despite the increasing number of studies on the impact of global warming on seagrasses, little attention has been paid to the role of the holobiont. Using an outdoor benthocosm to replicate near-natural conditions, this study explores the repercussions of persistent warming on the microbiome of Z. marina and its implications for holobiont function. Results show that both seasonal warming and chronic warming, impact Z. marina roots and sediment microbiome. Compared with roots, sediments demonstrate higher diversity and stability throughout the study, but temperature effects manifest earlier in both compartments, possibly linked to premature Z. marina die-offs under chronic warming. Shifts in microbial composition, such as an increase in organic matter-degrading and sulfur-related bacteria, accompany chronic warming. A higher ratio of sulfate-reducing bacteria compared to sulfide oxidizers was found in the warming treatment which may result in the collapse of the seagrasses, due to toxic levels of sulfide. Differentiating predicted pathways for warmest temperatures were related to sulfur and nitrogen cycles, suggest an increase of the microbial metabolism, and possible seagrass protection strategies through the production of isoprene. These structural and compositional variations in the associated microbiome offer early insights into the ecological status of seagrasses. Certain taxa/genes/pathways may serve as markers for specific stresses. Monitoring programs should integrate this aspect to identify early indicators of seagrass health. Understanding microbiome changes under stress is crucial for the use of potential probiotic taxa to mitigate climate change effects. Broader-scale examination of seagrass–microorganism interactions is needed to leverage knowledge on host–microbe interactions in seagrasses.

Description: We contend that ocean turbulent fluxes should be included in the list of Essential Ocean Variables (EOVs) created by the Global Ocean Observing System. This list aims to identify variables that are essential to observe to inform policy and maintain a healthy and resilient ocean. Diapycnal turbulent fluxes quantify the rates of exchange of tracers (such as temperature, salinity, density or nutrients, all of which are already EOVs) across a density layer. Measuring them is necessary to close the tracer concentration budgets of these quantities. Measuring turbulent fluxes of buoyancy (Jb), heat (Jq), salinity (JS) or any other tracer requires either synchronous microscale (a few centimeters) measurements of both the vector velocity and the scalar (e.g., temperature) to produce time series of the highly correlated perturbations of the two variables, or microscale measurements of turbulent dissipation rates of kinetic energy (ϵ) and of thermal/salinity/tracer variance (χ), from which fluxes can be derived. Unlike isopycnal turbulent fluxes, which are dominated by the mesoscale (tens of kilometers), microscale diapycnal fluxes cannot be derived as the product of existing EOVs, but rather require observations at the appropriate scales. The instrumentation, standardization of measurement practices, and data coordination of turbulence observations have advanced greatly in the past decade and are becoming increasingly robust. With more routine measurements, we can begin to unravel the relationships between physical mixing processes and ecosystem health. In addition to laying out the scientific relevance of the turbulent diapycnal fluxes, this review also compiles the current developments steering the community toward such routine measurements, strengthening the case for registering the turbulent diapycnal fluxes as an pilot Essential Ocean Variable.

Description: The 2015 Paris Agreement aims to strengthen the global response to climate change, and to maintain an average global temperature well below 2 °C, with aspirations towards 1.5 °C, by means of balancing sources and sinks of greenhouse gas emissions. Following this, the importance of carbon dioxide removal in global emission pathways has been further emphasized, and Negative Emissions Technologies (NETs) that capture carbon from the atmosphere and remove it from the system have been put in the spotlight. NETs range from innovative, engineered technologies, to well-known approaches like afforestation/reforestation. These technologies essentially compensate for a shrinking carbon budget coupled with hard-to-abate future emissions, and a historical lack of action. However, none has been deployed at scales close to what is envisioned in emission pathways in line with the Paris Agreement goals. To understand the potential contribution of NETs to meet global emission goals, we need to better understand opportunities and constraints for deploying NETs on a national level. We examine 17 Long-Term Low Greenhouse Gas Emission Development Strategies (LT-LEDS), and discuss them in the context of available NETs feasibility assessments. Our mapping shows that most countries include NETs in their long-term strategies, and that enhancement of natural sinks is the most dominating type of NET in these strategies. In line with many feasibility assessments, LT-LEDS focus on technical and biophysical considerations, and neglect socio-cultural dimensions. We suggest that feasibility assessments at the national level need to be more holistic; context-specific and comprehensive in terms of aspects assessed.

Description: Deep convection in the Subpolar Gyre (SPG) forms a link between the upper and lower limbs of the Atlantic Meridional Overturning Circulation (AMOC). The intensity of convection in ocean studies is usually estimated using mixed layer depth (MLD). Here MLD is derived using vertical profiles of potential density from the gridded ARMOR3D dataset and from in situ observations of the EN4 dataset. Given limited areas of convective chimneys, the robustness of the estimates from an available set of vertical profiles needs to be verified before accessing mechanisms of interannual variability of deep convection. For reaching this goal, we first outlined three convection domains in the SPG with a high frequency of deep convection events: the southwestern Labrador Sea (L-DC), the central Irminger Sea (I-DC), and the area south of Cape Farewell (F-DC). The minimum number of randomly scattered casts, required to be executed from January to April for a robust estimate of the maximum MLD, depends on the typical area of the convective regions within the domain and forms 50 casts for L-DC, 40 casts for I-DC and 10 casts for F-DC. For the investigated convection domains, a sufficient number of casts were collected for several standalone winters of the late 1990s, while continuous time series of the convection intensity can be obtained only since the mid-2000s.

Description: We characterize and decipher the resistome and the virulence factors of Shewanella algae MARS 14, a multidrug-resistant clinical strain using the whole genome sequencing (WGS) strategy. The bacteria were isolated from the bronchoalveolar lavage of a hospitalized patient in the Timone Hospital in Marseille, France who developed pneumonia after plunging into the Mediterranean Sea. Results: The genome size of S. algae MARS 14 was 5,005,710 bp with 52.8% guanine cytosine content. The resistome includes members of class C and D beta-lactamases and numerous multidrug-efflux pumps. We also found the presence of several hemolysins genes, a complete flagellum system gene cluster and genes responsible for biofilm formation. Moreover, we reported for the first time in a clinical strain of Shewanella spp. the presence of a bacteriocin (marinocin). Conclusion: The WGS analysis of this pathogen provides insight into its virulence factors and resistance to antibiotics.

Description: A novel strain, MA3_2.13T, was isolated from deep-sea sediment of Madeira Archipelago, Portugal, and characterized using a polyphasic approach. This strain produced dark brown soluble pigments, bronwish black substrate mycelia and an aerial mycelium with yellowish white spores, when grown on GYM 50SW agar. The main respiratory quinones were MK-10(H4), MK-10(H6) and MK-10(H8). Diphosphatidylglycerol, phosphatidylethanolamine, three unidentified phospholipids and two glycophospholipids were identified as the main phospholipids. The major cellular fatty acids were iso-C16: 1, iso-C16: 0, anteiso-C17: 1 and anteisoC17: 0 . Phylogenetic analyses based on 16S rRNA gene showed that strain MA3_2.13T is a member of the genus Streptomyces and was most closely related to Streptomyces triticirhizae NEAU-YY642T (NR_180032.1; 16S rRNA gene similarity 97.9 %), Streptomyces sedi YIM 65188T (NR_044582.1; 16S rRNA gene similarity 97.4 %), Streptomyces mimosae 3MP-10T (NR_170412.1; 16S rRNA gene similarity 97.3 %) and Streptomyces zhaozhouensis NEAU-LZS-5T (NR_133874.1; 16S rRNA gene similarity 97.0 %). Genome pairwise comparisons with closest related type strains retrieved values below the threshold for species delineation suggesting that strain MA3_2.13T represents a new branch within the genus Streptomyces. Based on these results, strain MA3_2.13T (=DSM 115980T=LMG 33094T) is proposed as the type strain of a novel species of the genus Streptomyces, for which the name Streptomyces profundus sp. nov. is proposed.

Description: The recent severe European summer heat waves of 2015 and 2018 co-occurred with cold subpolar North Atlantic (NA) sea surface temperatures (SSTs). However, a significant connection between this oceanic state and European heat waves was not yet established. We performed two AMIP-like model experiments: (a) employing daily 2018 SSTs as observed and (b) applying a novel approach to remove the negative NA SST anomaly, while keeping SST daily and small-scale variability. Comparing these experiments, we find that cold subpolar NA SSTs significantly increase heat wave duration and magnitude downstream over the European continent. Surface temperature and circulation anomalies are connected by the upper-tropospheric summer wave pattern of meridional winds over the North Atlantic European sector, which is enhanced with cold NA SSTs. Our results highlight the relevance of the subpolar NA region for European summer conditions, a region that is marked by large biases in current coupled climate model simulations. Key Points: - Model study designed to investigate the ocean impact on European heat waves by prescribing observed and realistic ocean surface conditions - Cold subpolar North Atlantic sea surface temperatures significantly enhance heat wave intensity and duration over the European continent - North Atlantic ocean and European surface temperature and circulation anomalies are bridged by the upper-tropospheric summer mean wave

Description: The impact of oxygen on the preservation of organic matter in marine surface sediments is still controversial. We revisited this long-standing debate by determining the burial efficiency of sedimentary organic matter in the Black Sea, the largest anoxic and euxinic basin in the modern ocean. Surface sediments were sampled in the Danube paleodelta on the northwestern margin of the Black Sea at 420–1550 m water depth. Steady-state modeling of solid species (particulate organic carbon and nitrogen) and solutes (ammonium, sulfate, and total alkalinity) in sediments was performed to quantify rates of mass accumulation, particulate organic matter (POM) degradation, and POM burial. We develop a novel analytical model to quantify these rates applying an inverse modelling approach to down core data accounting for molecular diffusion, sediment burial and compaction. Our model results indicate that 56.7 ± 6.6 % of the particulate organic matter deposited in the study area is not degraded in surface sediments but accumulates below 10 cm sediment depth. This burial efficiency is substantially higher than those previously derived for seafloor areas underlying oxygenated bottom waters. Hence, our study confirms previous studies showing that euxinic bottom water conditions promote the preservation of particulate organic matter in marine sediments.

Description: The western Andean belt of Argentina displays a comprehensive record of the Carboniferous and earliest Permian rocks so extensive that it allows an exceptional reconstruction of the Late Paleozoic Ice Age of the southwestern margin of the South American Gondwana area. Severe endemism of the Gondwana biota during this period makes it difficult to achieve a precise correlation of these glacially influenced deposits with the coeval sequences of the palaeoequatorial belt, where the subdivisions of the International Chronostratigraphic Chart (ICC) are currently defined. The abundant palaeontological record available from the Upper Paleozoic deposits of central-western Argentina, central Patagonia and eastern Argentina makes it possible to recognize five successive faunal stages that allow a proper ordering of the sequences of this period. The proposed regional stages, and their assumed chronological position regarding the standards of the current ICC, are: the Malimanian (late Tournaisian), Barrealian (Mid-Carboniferous or Serpukhovian–Bashkirian), Aguanegrian (Upper Pennsylvanian), Uspallatian (Asselian–Tastubian?) and Bonetian (Sakmarian). This paper aims to reiterate former recommendations about the convenience of having regional reference units and suggests the consideration of the available faunal stages as possible chronostratigraphic subdivisions for the Carboniferous–early Permian of the southeastern margin of Gondwana.

Description: Marine sponges and other sessile macro-organisms were collected at a shallow water hydrothermal site in Eyjafjörður, Iceland. Bacteria were isolated from the organisms using selective media for actinomycetes, and the isolates were screened for antimicrobial activity. A total of 111 isolates revealed antimicrobial activity displaying different antimicrobial patterns which indicates production of various compounds. Known test strains were grown in the presence of ethyl acetate extracts from one selected isolate, and a clear growth inhibition of Staphylococcus aureus was observed down to 0.1 % extract concentration in the medium. Identification of isolates shows different species of Actinobacteria with Streptomyces sp. playing the largest role, but also members of Bacilli, Alphaproteobacteria and Gammaproteobacteria. Sponges have an excellent record regarding production of bioactive compounds, often involving microbial symbionts. At the hydrothermal vents, however, the majority of active isolates originated from other invertebrates such as sea anemones or algae. The results indicate that antimicrobial assays involving isolates in full growth can detect activity not visible by other methods. The macro-organisms inhabiting the Eyjafjörður hydrothermal vent area host diverse microbial species in the phylum Actinobacteria with antimicrobial activity, and the compounds responsible for the activity will be subject to further research.

Description: In its latest assessment report the IPCC stresses the need for carbon dioxide removal (CDR) to counterbalance residual emissions to achieve net zero carbon dioxide or greenhouse gas emissions. There are currently a wide variety of CDR measures available. Their potential and feasibility, however, depends on context specific conditions, as among others biophysical site characteristics, or availability of infrastructure and resources. In our study, we selected 13 CDR concepts which we present in the form of exemplary CDR units described in dedicated fact sheets. They cover technical CO2 removal (two concepts of direct air carbon capture), hybrid solutions (six bioenergy with carbon capture technologies) and five options for natural sink enhancement. Our estimates for their CO2 removal potentials in 2050 range from 0.06 to 30 million tons of CO2, depending on the option. Ten of the 13 CDR concepts provide technical removal potentials higher than 1 million tons of CO2 per year. To better understand the potential contribution of analyzed CDR options to reaching net-zero CO2 emissions, we compare our results with the current CO2 emissions and potential residual CO2 emissions in 2050 in Germany. To complement the necessary information on technology-based and hybrid options, we also provide an overview on possible solutions for CO2 storage for Germany. Taking biophysical conditions and infrastructure into account, northern Germany seems a preferable area for deployment of many concepts. However, for their successful implementation further socio-economic analysis, clear regulations, and policy incentives are necessary.

Description: We present a detailed field and petrological study of charnockites and ultra-high temperature (UHT) granulites from the Gruf Complex, eastern Central Alps. Charnockites occur as up to 0.5 km wide and 8 km long, internally boudinaged, opx-bearing sheet-like bodies within the regionally dominant migmatitic biotite-orthogneisses. Granulites occur as garnet–orthopyroxene–biotite–alkali feldspar-bearing schlieren (± sapphirine, sillimanite, cordierite, corundum, spinel, plagioclase, and quartz) within charnockites and as residual enclaves both in the charnockites and the migmatitic orthogneisses. Thermobarometric calculations, P–T pseudosections and orthopyroxene Al content, show that both charnockites and granulites equilibrated at metamorphic peak conditions of T = 920–940 °C and P = 8.5–9.5 kbar. Peak assemblages were subsequently overprinted by intergrowth, symplectite and corona textures involving orthopyroxene, sapphirine, cordierite and spinel at T = 720–740 °C and P = 7–7.5 kbar. We suggest that granulites and charnockites are lower crustal relicts preserved in the migmatitic orthogneisses. Garnet diffusion modelling shows that metamorphic garnet–opx ± sapphirine ± sillimanite peak assemblages and post-peak reaction textures always involving cordierite developed during two separate metamorphic cycles. Peak assemblages reflect UHT metamorphism related to post-Varican Permian extension, but post-peak coronae and symplectites formed during the mid-Tertiary, upper amphibolite facies, Alpine regional metamorphism. Fluid-absent partial melting of pelitic and psammitic sediments during the Permian UHT event lead to the formation of charnockitic magmas and granulitic residues. Intense melt loss and thorough dehydration of the granulites (although retaining biotite) favoured the partial preservation of peak mineral assemblages during Alpine metamorphism.

Description: In geoscience and other fields, researchers use models as a simplified representation of reality. The models include processes that often rely on uncertain parameters that reduce model performance in reflecting real-world processes. The problem is commonly addressed by adapting parameter values to reach a good match between model simulations and corresponding observations. Different optimization tools have been successfully applied to address this task of model calibration. However, seeking one best value for every single model parameter might not always be optimal. For example, if model equations integrate over multiple real-world processes which cannot be fully resolved, it might be preferable to consider associated model parameters as random parameters. In this paper, a random parameter is drawn from a wide probability distribution for every singe model simulation. We developed an optimization approach that allows us to declare certain parameters random while optimizing those that are assumed to take fixed values. We designed a corresponding variant of the well known Covariance Matrix Adaption Evolution Strategy (CMA-ES). The new algorithm was applied to a global biogeochemical circulation model to quantify the impact of zooplankton mortality on the underlying biogeochemistry. Compared to the deterministic CMA-ES, our new method converges to a solution that better suits the credible range of the corresponding random parameter with less computational effort.

Description: Sea spray aerosols (SSA) greatly affect the climate system by scattering solar radiation and acting as seeds for cloud droplet formation. The ecosystems in the Arctic Ocean are rapidly changing due to global warming, and the effects these changes have on the generation of SSA, and thereby clouds and fog formation in this region, are unknown. During the ship-based Arctic Century Expedition, we examined the dependency of forced SSA production on the biogeochemical characteristics of seawater using an on-board temperature-controlled aerosol generation chamber with a plunging jet system. Our results indicate that mainly seawater salinity and organic content influence the production and size distribution of SSA. However, we observed a 2-fold higher SSA production from waters with similar salinity collected north of 81°N compared to samples collected south of this latitude. This variability was not explained by phytoplankton and bacterial abundances or Chlorophyll-a concentration but by the presence of glucose in seawater. The synergic action of sea salt (essential component) and glucose or glucose-rich saccharides (enhancer) accounts for 〉80% of SSA predictability throughout the cruise. Our results suggest that besides wind speed and salinity, SSA production in Arctic waters is also affected by specific organics released by the microbiota.

Description: The University of Victoria Earth system climate model of intermediate complexity has been a useful tool in recent assessments of long-term climate changes including paleo-climate modelling. Since the last official release of the UVic ESCM 2.9, and the two official updates during the last decade, a lot of model development has taken place in multiple groups. The new version 2.10 of the University of Victoria Earth System Climate Model (UVic ESCM), to be used in the 6th phase of the coupled model intercomparison project (CMIP6), presented here combines and brings together multiple model developments and new components that have taken place since the last official release of the model. To set the foundation of its use, we here describe the UVic ESCM 2.10 and evaluate results from transient historical simulations against observational data. We find that the UVic ESCM 2.10 is capable of reproducing well changes in historical temperature and carbon fluxes, as well as the spatial distribution of many ocean tracers, including temperature, salinity, phosphate and nitrate. This is connected to a good representation of ocean physical properties. For the moment, there remain biases in ocean alkalinity and dissolved inorganic carbon, which will be addressed in the next updates to the model.

Description: Highlights • Development of an autonomous DIC analyzer based on Conductometric technique using a cell with 4 hollow brass electrodes. • CO2 extraction from seawater using a gas diffusion cell with a “Tube In A Tube” configuration and a gas permeable membrane. • Formulation of mathematical temperature and salinity correction to determine accurate DIC concentration. • Demonstration of the analyzer performance in the southwest Baltic Sea. Abstract Background The increase in anthropogenic CO2 concentrations in the Earth's atmosphere since the industrial revolution has resulted in an increased uptake of CO2 by the oceans, leading to ocean acidification. Dissolved Inorganic Carbon (DIC) is one of the key variables to characterize the seawater carbonate system. High quality DIC observations at a high spatial-temporal resolution is required to improve our understanding of the marine carbonate system. To meet the requirements, autonomous DIC analyzers are needed which offer a high sampling frequency, are cost-effective and have a low reagent and power consumption. Results We present the development and validation of a novel analyzer for autonomous measurements of DIC in seawater using conductometric detection. The analyzer employs a gas diffusion sequential injection approach in a “Tube In A Tube” configuration that facilitates diffusion of gaseous CO2 from an acidified sample through a gas permeable membrane into a stream of an alkaline solution. The change in conductivity in the alkaline medium is proportional to the DIC concentration of the sample and is measured using a detection cell constructed of 4 hollow brass electrodes. Physical and chemical optimizations of the analyzer yielded a sampling frequency of 4 samples h−1 using sub mL reagent volumes for each measurement. Temperature and salinity effects on DIC measurements were mathematically corrected to increase accuracy. Analytical precision of ±4.9 μmol kg−1 and ±9.7 μmol kg−1 were achieved from measurements of a DIC reference material in the laboratory and during a field deployment in the southwest Baltic Sea, respectively. Significance This study describes a simple, cost-effective, autonomous, on-site benchtop DIC analyzer capable of measuring DIC in seawater at a high temporal resolution as a step towards an underwater DIC sensor. The analyzer is able to measure a wide range of DIC concentrations in both fresh and marine waters. The achieved accuracy and precision offer an excellent opportunity to employ the analyzer for ocean acidification studies and CO2 leakage detection in the context of Carbon Capture and Storage operations.

Description: Following several small-scale benthic disturbance experiments, an industrial polymetallic nodule collector trial was conducted by the company Global Sea mineral Resources (GSR) in their exploration contract area in the Clarion-Clipperton Zone using the pre-prototype vehicle Patania II (PATII). In this study, meiofaunal (i.e., nematode abundance, ASV diversity and genus composition) and environmental (i.e., grain size, total organic carbon/total nitrogen and pigment) properties are compared between disturbance categories (i.e., Pre-impact, Collector Impact and Plume Impact). One week after the trial, proxies for food availability within the Collector Impact sediments were altered with lower total organic carbon (TOC) and pigment (i.e., CPE: sum of Chlorophyll a and phaeopigments) values. Albeit not significant, the observed decrease of nematode abundance and ASV diversity, further indicate the consequences of the removal of the ecologically important surface sediment layer within the PATII tracks. Next to sediment removal, exposed sediments were modified in different ways (e.g., central strips, parallel caterpillar imprints with alternating bands of depressions/ripples and interface patches) and were also subject to heavy collector-induced sediment blanketing. We propose that these cumulative impacts have led to intricate seabed modifications with various levels of disturbance intensity which resulted in the high meiofaunal variability observed. Adjacent nodule-rich areas (i.e., Plume Impact) received considerable levels of sediment deposition (2-3 cm) and were defined by significantly lower food sources (CPE, TOC, carbon to nitrogen ratio) and an observation of meiofaunal enrichment (i.e., higher average nematode abundance and ASV diversity; although statistically non-significant), but mechanisms behind these ecological changes (e.g., suspended material-surface fluxes, passive dispersal of fauna in the plume vs. active upward migration and “viability” of redeposited fauna) remain unresolved. We conclude that complex benthic pressure-response relationships associated with the PATII trial, combined with the high degree of natural spatial and temporal variability in abyssal meiofaunal communities and sedimentary parameters, complicates the quantitative assessment of deep-sea mining associated disturbances.

Description: Flow of dense shelf water provide an efficient mechanism for pumping CO 2 to the deep ocean along the continental shelf slope, particularly around the Antarctic bottom water (AABW) formation areas where much of the global bottom water is formed. However, the contribution of the formation of AABW to sequestering anthropogenic carbon ( C ant ) and its consequences remain unclear. Here, we show prominent transport of C ant (25.0 ± 4.7 Tg C yr −1 ) into the deep ocean (〉2,000 m) in four AABW formation regions around Antarctica based on an integrated observational data set (1974–2018). This maintains a lower C ant in the upper waters than that of other open oceans to sustain a stronger CO 2 uptake capacity (16.9 ± 3.8 Tg C yr −1 ). Nevertheless, the accumulation of C ant can further trigger acidification of AABW at a rate of −0.0006 ± 0.0001 pH unit yr −1 . Our findings elucidate the prominent role of AABW in controlling the Southern Ocean carbon uptake and storage to mitigate climate change, whereas its side effects (e.g., acidification) could also spread to other ocean basins via the global ocean conveyor belt. Plain Language Summary The Southern Ocean is thought to uptake and store a large amount of anthropogenic CO 2 ( C ant ), but little attention has been paid to the Antarctic coastal regions in the south of 60°S, mainly due to the lack of observations. Based on an integrated data set, we discovered the deep penetration of C ant and a visible pattern of relatively high concentration of C ant along the AABW formation pathway, and the concentration of C ant along the shelf‐slope is higher than that of other marginal seas at low‐mid latitudes, implying a highly effective C ant transport in AABW formation areas. We also found strong upper‐layer CO 2 uptake and a significant acidification rate in the deep waters of the Southern Ocean due to the AABW‐driven CO 2 transport, which is 3 times faster than those in other deep oceans. It is therefore crucial to understand how the Antarctic shelf regions affect the global carbon cycle through the uptake and transport of anthropogenic CO 2 , which also drives acidification in the other ocean basins. Key Points We show evidence for the accumulation of C ant along the Antarctic shelf‐slope into the deep ocean The process of AABW formation drives C ant downward transport at 25.0 ± 4.7 Tg C yr −1 , sustaining the CO 2 uptake in the surface ocean This further triggers acidification of AABW at a rate of −0.0006 ± 0.0001 pH unit yr −1 , which is faster than in other deep oceans

Description: The ocean region along the latitude of 40oS in the South Atlantic, characterized by enhanced primary productivity, forms a transition zone between the nutrient replete but iron depleted Southern Ocean, and the nitrate and iron depleted Subtropical Gyre. Here, we present distributions of nutrient-type dissolved and particulate trace metals (dTMs and pTMs) including cadmium (Cd), nickel (Ni), copper (Cu), and zinc (Zn) in the South Atlantic from the GEOTRACES GA10 cruises. Phytoplankton uptake, riverine and atmospheric inputs shaped dTM and pTM concentrations in surface waters (dCd 27.8±36.0 pmol kg-1, n=222; dCu 0.732±0.429 nmol kg-1, n=222; dNi 3.38±0.52 nmol kg-1, n=219; dZn 0.332±0.398 nmol kg-1, n=214). Subsurface nutrients and dTMs (dCd 563±184 pmol kg-1, n=335; dCu 1.819±0.773 nmol kg-1, n=334; dNi 6.19±1.06 nmol kg-1, n=330; dZn 3.71±2.10 nmol kg-1, n=333) were controlled by the mixing of Antarctic origin waters and North Atlantic Deep Waters (NADW) with negligible contributions from local remineralization. Dissolved and particulate TMs in the Argentine Basin showed elevated concentrations towards the seafloor because of benthic inputs. Direct hydrothermal inputs of dTMs and pTMs to deep waters were not observed along the transect. The Cd-Cu-Zn-phosphate stoichiometries of Antarctic origin waters were set by a combination of dynamic physical circulation and preferential uptake of Cd, Cu, and Zn relative to phosphate in surface waters because of a dominance by diatoms in the Southern Ocean. Water mass mixing subsequently produced convoluted dCu-P and dZn-P relationships and apparent linear dCd-P and dNi-P relationships in the South Atlantic. More importantly, endmember characteristics of Antarctic waters and NADW are largely fixed in their formation regions in high latitude oceans. Therefore, the highly dynamic high latitude oceans are key regions that supply nutrients and TMs at specific ratios to low latitude oceans via the thermohaline circulation. Changes to processes in the high latitude oceans may have consequences for marine primary productivity downstream, and hence the global carbon cycle.