ISSN:
1572-9567
Keywords:
acrylonitrile
;
alkyl acetate
;
binary liquid mixtures
;
correlating equations
;
dimethylformamide
;
dimethylacetamide
;
dimethyl sulphoxide
;
Gibbs energy of activation
;
molecular interactions
;
viscosities
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract The measurements of viscosity η are reported for seven binary mixtures of acrylonitrile (AN) with ethanenitrile (EN), methyl acetate (MA), ethyl acetate (EA), n-butyl acetate (BA), dimethylformamide (DMF), dimethylacetamide (DMA), and dimethyl sulphoxide (DMSO) at 303.15 K temperature. The viscosity data have been correlated with the equations of Grunberg and Nissan; Hind, McLaughlin, and Ubbelohde; Tamura and Kurata; Katti and Chaudhri; McAllister; Heric and Brewer; and of Auslaender. The relations between the viscosity deviations Δη, excess Gibbs energy of activation ΔG*E of viscous flow, and the intermolecular interaction in these mixtures are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1026485618495
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