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  • 1
    Electronic Resource
    Electronic Resource
    Photochemical pathways of water on palladium (111) at 6.4 eV (1991)
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 95 (1991), S. 8393-8402 
    Details
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/j100174a065
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  • 2
    Electronic Resource
    Electronic Resource
    Laser-induced interaction of ammonia with GaAs(100). II. Desorption dynamics (1992)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 5868-5875 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: UV laser irradiation of ammonia adsorbed on GaAs(100) leads to molecular desorption, with a mean translational temperature of 〈Etrans/2k(approximately-greater-than)=300 K, independent of photon energy and isotope substitution. However, the photodesorption cross section depends strongly on isotope substitution: σNH3/σND3=4.1 at hν=6.4 eV. This isotope effect is too large to be accounted for by the mass difference in the leaving particles (NH3 vs ND3), but can be successfully explained in terms of an isotope effect in the internal N–H(D) coordinates. We take this as evidence for uv-driven photodesorption from electronically quenched, but vibrationally hot ground state ammonia.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.463746
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  • 3
    Electronic Resource
    Electronic Resource
    Laser-induced interaction of ammonia with GaAs(100). I. Dissociation and nitridation (1992)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 5856-5867 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: UV laser irradiation of ammonia adsorbed on GaAs(100) leads to molecular desorption and dissociation. A nitride passivation layer can be formed on the GaAs surface at 100 K by simultaneous exposure to ammonia and uv photons in a UHV environment. The nitride layer consists of a mixture of Ga and As nitrides. While the dominating GaN surface species is thermally stable, AsN desorbs below 800 K. Surface NH2 is identified as an intermediate. The implication of this study for selective area passivation and GaN growth is discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.463745
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  • 4
    Electronic Resource
    Electronic Resource
    Surface plasmon enhanced photochemistry: Mo(CO)6–Al–quartz (1992)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 7015-7016 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We demonstrate that surface plasmon oscillations excited at an adsorbate covered metal–vacuum interface can effectively couple to the electronic system of the adsorbed molecule. Using p-polarized light (hν=3.5 eV) incident at the surface plasmon resonant angle in Kretschmann's attenuated-total-reflection (ATR) configuration, we observe a strong enhancement of the photodissociation rate of Mo(CO)6 from a 180 A(ring) Al film, evaporated on a quartz prism in UHV.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.463211
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  • 5
    Electronic Resource
    Electronic Resource
    The adsorbate state specific photochemistry of dioxygen on Pd(111) (1990)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 5327-5336 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The ultraviolet-photochemistry of molecularly adsorbed oxygen on Pd(111) has been studied using pulsed laser light with 6.4 eV photon energy. Three processes occur upon irradiation: desorption of molecular oxygen, conversion between adsorption states, and dissociation to form adsorbed atomic oxygen. By using time-of-flight spectroscopy to detect the desorbing molecular oxygen and post-irradiation thermal desorption spectroscopy (TDS) to characterize the adsorbate state, a detailed picture of the photochemical processes is obtained. The data indicate that the O2 molecules desorbing with low translational energies from the saturated surface as well as the conversion of adsorbed molecules between binding states are induced by the photoinduced build-up of atomic oxygen on the surface. Analysis of a proposed reaction model reproduces the observed data and yields detailed rates. Polarization analysis indicates that the photochemical processes are initiated by electronic excitations of the substrate.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.459652
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  • 6
    Electronic Resource
    Electronic Resource
    Photochemical decomposition of AsH3 on GaAs(100) (1992)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 97 (1992), S. 605-615 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Molecular AsH3, adsorbed on Ga-rich GaAs(100) at 115 K, dissociates readily upon uv irradiation with 193, 248, and 351 nm excimer laser light. In the initial photodissociation step one As–H bond cleaves, leaving all the AsH2, and a large fraction of the H, adsorbed to As. The AsH2 further photodissociates to give As–H and Ga–H. The final steps, photochemical removal of hydrogen from Ga–H and As–H, lead to As deposition. The photodissociation cross section decreases sharply with the extent of photolysis. The wavelength dependence, compared to the gas-phase absorption cross section, extends to much lower photon energies and indicates that substrate-mediated excitation dominates the observed chemistry. There are strong isotope effects in all the cross sections; these are related to mass-dependent substrate-mediated quenching of the excited states. Implications for photon-assisted organometallic chemical vapor deposition are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.463556
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  • 7
    Electronic Resource
    Electronic Resource
    Dynamics of the ultraviolet photochemistry of water adsorbed on Pd(111) (1991)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 94 (1991), S. 4609-4619 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: UV-laser irradiation (hν=6.4 eV and 5.0 eV) of the water bilayer adsorbed on a Pd(111) surface leads to molecular desorption and to conversion of the adsorbed state as manifested in thermal desorption spectra. The latter effect is attributed to photodissociation of water on the surface. Time-of-flight measurements show that water molecules desorb with a translational energy of about 600 K for both photon energies indicating a nonthermal process. While desorption is largely suppressed with adsorbed multilayers, conversion within the first layer still proceeds. The dependence of the desorption yield on angle of incidence and polarization of the light reveals substrate excitations as the dominant primary step. A strong variation of cross sections with isotopic substitution is observed. This is interpreted as evidence for the operation of a mechanism involving excitation onto an isotope-independent excited potential energy surface followed by rapid deexcitation to the ground state so that, of the total number of species excited, only a small mass dependent fraction actually fragments or desorbs.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.460589
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  • 8
    Electronic Resource
    Electronic Resource
    Cross sections and NO product state distributions resulting from substrate mediated photodissociation of NO2 adsorbed on Pd(111) (1990)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 3154-3169 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Ultraviolet irradiation of NO2 adsorbed on top of a NO saturated Pd(111) surface causes the photodissociation of NO2/N2O4 and results in the desorption of NO molecules. This process has been studied using excitation energies between 3.5 and 6.4 eV. At a photon energy of 6.4 eV, a cross section of 3×10−18 cm2 is found. Using laser-induced fluorescence to detect the desorbed NO molecules, fully state-resolved data detailing the energy channeling into different degrees of freedom has been obtained. Two desorption channels are found, one characterized by nonthermal state populations, and one showing accommodation to the surface. The yield of the fast channel shows a marked increase above 4 eV photon energy. The slow channel is interpreted as being due to NO molecules which, after formation, undergo a trapping–desorption process. A polarization experiment indicates that the photodissociation is initiated by excitation of metal electrons rather than direct absorption by the adsorbate.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.457913
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  • 9
    Electronic Resource
    Electronic Resource
    Ultraviolet-laser induced dissociation and desorption of water adsorbed on Pd(111) (1990)
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 1509-1510 
    Details
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Ultraviolet-laser irradiation (6.4 eV and 5.0 eV) of the first layer of water adsorbed on a Pd(111) surface at 90 K leads to desorption of H2O and to conversion of the adsorbed state as manifested in the thermal desorption spectra. The latter effect is attributed to photodissociation of water on the surface. Time-of-flight measurements show that water molecules desorb with the same translational energy of about 600 K for both photon energies. While desorption is suppressed with adsorbed multilayers, conversion within the first layer still proceeds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.458111
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  • 10
    Electronic Resource
    Electronic Resource
    Ultraviolet photochemical nitridation of GaAs (1992)
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 61 (1992), S. 3175-3177 
    Details
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Monolayer nitridation of Ga-rich GaAs(100) is achieved at 100 K by simultaneous exposure to ammonia and 6.4 eV photons in a vacuum environment. This process is a result of nonthermal photodissociation of adsorbed ammonia. Surface NH2 is identified as an important intermediate in nitridation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1063/1.107950
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