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  • 1
    Publication Date: 2024-02-07
    Description: Highlights • A mechanistic explanation is provided for the observed CO2 loss in the sediments. • Reactions of CO2 with the sediment lead to significant heating. • The observations were modeled including reactions and losses due to lateral transport. • CO2 leakage will lead to very local effects. Abstract We investigated the effect of an artificial CO2 vent (0.0015−0.037 mol s−1), simulating a leak from a reservoir for carbon capture and storage (CCS), on the sediment geochemistry. CO2 was injected 3 m deep into the seafloor at 120 m depth. With increasing mass flow an increasing number of vents were observed, distributed over an area of approximately 3 m. In situ profiling with microsensors for pH, T, O2 and ORP showed the geochemical effects are localized in a small area around the vents and highly variable. In measurements remote from the vent, the pH reached a value of 7.6 at a depth of 0.06 m. In a CO2 venting channel, pH reduced to below 5. Steep temperature profiles were indicative of a heat source inside the sediment. Elevated total alkalinity and Ca2+ levels showed calcite dissolution. Venting decreased sulfate reduction rates, but not aerobic respiration. A transport-reaction model confirmed that a large fraction of the injected CO2 is transported laterally into the sediment and that the reactions between CO2 and sediment generate enough heat to elevate the temperature significantly. A CO2 leak will have only local consequences for sediment biogeochemistry, and only a small fraction of the escaped CO2 will reach the sediment surface.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
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  • 2
    Publication Date: 2023-03-03
    Description: The Guaymas Basin hydrothermal vents in the Gulf of California (Mexico) were visited with the research vessel RV Atlantis in November to December 2018 (mission AT 42-05). Due to its proximity to land, this area is covered with thick organic-rich sediments. In the subsurface heated fluids enrich in hydrocarbons gases, leading to complex biogeochemical reactions in surface sediments (Teske et al., 2016; doi:10.3389/fmicb.2016.00075). We used the submarine ALVIN to collect sediments with push cores at sites covered with different mat types and surrounding areas. Aim of this effort was to describe the biogeochemistry and the fluxes of dissolved species in these sediments. We collected porewater from these push cores using Rhizon technology (Seeberg-Elverfeldt et al., 2005; doi:10.4319/lom.2005.3.361). Porewater sampling was performed in anoxic tents to preserve oxygen-sensitive dissolved metal species. Samples were preserved according to established protocols. In the home laboratory we measured concentrations of dissolved inorganic carbon, chloride, sulfate, sulfide, dissolved inorganic carbon, nitrate, nitrite, ammonium, phosphate and silicate and concentrations of dissolved iron using two approaches and manganese were assessed. Sediment cores is the direct vicinity of these cores were taken as replicates for the measurement of dissolved gases. Cores were sectioned and 2 ml sediments were sampled into glass-vials filled with 5 ml sodium hydroxide solutions and were sealed gas-tight. Concentrations of the hydrocarbon gases methane, ethane, propane, i-butane and butane were measured using gas chromatography coupled to flame ionization detection.
    Keywords: Ammonia; AT42-05; AT42-05_4991-13; AT42-05_4991-14; AT42-05_4991-17; AT42-05_4992-6; AT42-05_4992-7; AT42-05_4993-20; AT42-05_4995-10; AT42-05_4995-12; AT42-05_4995-15; AT42-05_4995-19; AT42-05_4995-20; AT42-05_4995-7; AT42-05_4997-1; AT42-05_4997-35; AT42-05_4999-13; AT42-05_4999-15; AT42-05_5000-10; AT42-05_5000-15; AT42-05_5000-25; AT42-05_5000-27; AT42-05_5000-5; AT42-05_5000-6; Atlantis (1997); Atomic absorption spectrometry (AAS) (Thermo iCE3000); brown area; butane; Carbon, inorganic, dissolved; Chloride; cold sediment; Continuous Segmented Flow Analyzer, SEAL Analytical, QuAAtro39; Date/Time of event; DEPTH, sediment/rock; Elevation of event; Ethane; Event label; Flow injection analysis (Hall and Aller 1992); Gas chromatography - Flame Ionization Detection (GC-FID); Guaymas Basin; hydrothermal vent; Ion chromatography (Metrohm 930 Compact IC); Iron 2+; Isobutane; Latitude of event; Longitude of event; Manganese; Methane; n-Butane; orange mat; Phosphate; porewater; propane; Propane; PUC; Push corer; RULER; Ruler stick; Sample ID; sediment; Silicate; Spectrophotometry; Station label; Sulfate; Sulfide, total; white area; white-grey area; white mat; yellow area; yellow mat
    Type: Dataset
    Format: text/tab-separated-values, 1238 data points
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  • 3
    Publication Date: 2023-02-24
    Keywords: AGE; Arabian Sea; Biomarker; Calibration de Bar et al., 2020; Deglaciation; Long chain diol index; NIOP_905; paleotemperature proxy; Sea surface temperature; SST; Upwelling
    Type: Dataset
    Format: text/tab-separated-values, 234 data points
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  • 4
    Publication Date: 2023-02-24
    Keywords: AGE; Biomarker; Calibration de Bar et al., 2020; Deglaciation; Long chain diol index; paleotemperature proxy; PASOM_03; PASOM3; Sea surface temperature; SST; Upwelling
    Type: Dataset
    Format: text/tab-separated-values, 106 data points
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  • 5
    Publication Date: 2023-06-27
    Keywords: AGE; Biomarker; Deglaciation; KAL; Kasten corer; Long chain diol index; MAKRAN 2; paleotemperature proxy; Sea surface temperature; SO130; SO130_289KL; Sonne; SST; Upwelling
    Type: Dataset
    Format: text/tab-separated-values, 118 data points
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  • 6
    Publication Date: 2023-10-05
    Description: This dataset includes ages, long-chain diol index (LDI), and estimated sea surface temperature (SST) based on calibration de Bar et al., 2020. Sediment cores; NIOP905, SO47-74KL, PASOM3, and SO130-289KL, were obtained from the north and the western Arabian Sea, covering the last 25 kyr and 35 kyr respectively.
    Keywords: Biomarker; Deglaciation; paleotemperature proxy; SST; Upwelling
    Type: Dataset
    Format: application/zip, 4 datasets
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  • 7
    Publication Date: 2024-02-13
    Keywords: AGE; Arabian Sea; Biomarker; Deglaciation; KAL; Kasten corer; KL-74, AS-12; Long chain diol index; paleotemperature proxy; Sea surface temperature; SO42; SO42-74KL; Sonne; SST; Upwelling
    Type: Dataset
    Format: text/tab-separated-values, 154 data points
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  • 8
    Publication Date: 2024-04-20
    Description: This data set was collected from incubations of sediment collected from the intertidal sandbank Janssand, behind the back barrier island Spiekeroog, in the German Wadden Sea. The rate of oxygen consumption (microsensor), hydrogen accumulation (GC), iron accumulation (ferrozine, chlorometric), and sulfate reduction (35S sulfate + acid-chromium distillation) were all measured in constantly mixed slurries, with and without the ROS-removing enzymes superoxide dismutase and catalase. It additionally includes depth profiles of oxygen and hydrogen peroxide in cores, determined with amperometric microsensors.
    Keywords: File content; H2O2; intertidal permeable sediments; Iron reduction; Jans1-5; MULT; Multiple investigations; Office Open XML Workbook; Reactive Oxygen Species; sand flat; sulfate reduction; Wadden Sea
    Type: Dataset
    Format: text/tab-separated-values, 2 data points
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  • 9
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    AMER SOC LIMNOLOGY OCEANOGRAPHY
    In:  EPIC3Limnology and Oceanography, AMER SOC LIMNOLOGY OCEANOGRAPHY, ISSN: 0024-3590
    Publication Date: 2020-09-07
    Description: We investigated the impact of kelp deposition on the geochemistry and microbial community composition of beach sands on the island of Helgoland (North Sea). The composition of the microbial community at a beach with regular kelp deposition appeared shaped by this regular input of organic material, as indicated by significantly higher proportions of aerobic degraders, fermenters, and sulfur cycling microorganisms. Rapid degradation of deposited kelp by this community leads to high levels of dissolved organic and inorganic carbon and nutrients, a lower pH and anoxia. Aerobic respiration, fermentation, Fe- and SO42- reduction and methanogenesis were strongly enhanced, with SO42- reduction being the main process in kelp degradation. SO42- reduction rates increased 20 to 25-fold upon addition of kelp. The main route of electrons from kelp to SO42- was not via CO and H2, as expected, but via organic fermentation products. O2 supply by the tides was not sufficient and reduced intermediates escaped from the sediment with tidal water retraction. The resulting extremely high levels of free sulfide (〉10 mmol L-1) lead to abundant filamentous growth of sulfur-oxidizing bacteria largely composed of a rare O2-adapted Sulfurovum lacking the expected denitrification genes. Our results show that regular kelp deposition strongly enhances the thermodynamic disequilibrium in the beach sand habitat, leading to a dramatic enhancement of the sulfur cycle.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 10
    Publication Date: 2021-12-15
    Description: We investigated the effect of an artificial CO2 vent (0.0015−0.037 mol s−1), simulating a leak from a reservoir for carbon capture and storage (CCS), on the sediment geochemistry. CO2 was injected 3 m deep into the seafloor at 120 m depth. With increasing mass flow an increasing number of vents were observed, distributed over an area of approximately 3 m. In situ profiling with microsensors for pH, T, O2 and ORP showed the geochemical effects are localized in a small area around the vents and highly variable. In measurements remote from the vent, the pH reached a value of 7.6 at a depth of 0.06 m. In a CO2 venting channel, pH reduced to below 5. Steep temperature profiles were indicative of a heat source inside the sediment. Elevated total alkalinity and Ca2+ levels showed calcite dissolution. Venting decreased sulfate reduction rates, but not aerobic respiration. A transport-reaction model confirmed that a large fraction of the injected CO2 is transported laterally into the sediment and that the reactions between CO2 and sediment generate enough heat to elevate the temperature significantly. A CO2 leak will have only local consequences for sediment biogeochemistry, and only a small fraction of the escaped CO2 will reach the sediment surface.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev , info:eu-repo/semantics/article
    Format: application/pdf
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