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  • 1
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    American Chemical Society
    In:  EPIC3Environmental Science & Technology, American Chemical Society, 53, pp. 8747-8756, ISSN: 1520-5851
    Publication Date: 2020-06-04
    Description: Recent studies pointed to a high ice nucleating activity (INA) in the Arctic sea surface microlayer (SML). However, related chemical information is still sparse. In the present study, INA and free glucose concentrations were quantified in Arctic SML and bulk water samples from the marginal ice zone, the ice-free ocean, melt ponds, and open waters within the ice pack. T50 (defining INA) ranged from −17.4 to −26.8 °C. Glucose concentrations varied from 0.6 to 51 μg/L with highest values in the SML from the marginal ice zone and melt ponds (median 16.3 and 13.5 μg/L) and lower values in the SML from the ice pack and the ice-free ocean (median 3.9 and 4.0 μg/L). Enrichment factors between the SML and the bulk ranged from 0.4 to 17. A positive correlation was observed between free glucose concentration and INA in Arctic water samples (T50(°C) = (−25.6 ± 0.6) + (0.15 ± 0.04)·Glucose(μg/L), RP = 0.66, n = 74). Clustering water samples based on phytoplankton pigment composition resulted in robust but different correlations within the four clusters (RP between 0.67 and 0.96), indicating a strong link to phytoplankton-related processes. Since glucose did not show significant INA itself, free glucose may serve as a potential tracer for INA in Arctic water samples.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 2
    Publication Date: 2023-04-26
    Description: Mechanisms behind the phenomenon of Arctic amplification are widely discussed. To contribute to this debate, the (AC)3 project was established in 2016 (www.ac3-tr.de/). It comprises modeling and data analysis efforts as well as observational elements. The project has assembled a wealth of ground-based, airborne, shipborne, and satellite data of physical, chemical, and meteorological properties of the Arctic atmosphere, cryosphere, and upper ocean that are available for the Arctic climate research community. Short-term changes and indications of long-term trends in Arctic climate parameters have been detected using existing and new data. For example, a distinct atmospheric moistening, an increase of regional storm activities, an amplified winter warming in the Svalbard and North Pole regions, and a decrease of sea ice thickness in the Fram Strait and of snow depth on sea ice have been identified. A positive trend of tropospheric bromine monoxide (BrO) column densities during polar spring was verified. Local marine/biogenic sources for cloud condensation nuclei and ice nucleating particles were found. Atmospheric–ocean and radiative transfer models were advanced by applying new parameterizations of surface albedo, cloud droplet activation, convective plumes and related processes over leads, and turbulent transfer coefficients for stable surface layers. Four modes of the surface radiative energy budget were explored and reproduced by simulations. To advance the future synthesis of the results, cross-cutting activities are being developed aiming to answer key questions in four focus areas: lapse rate feedback, surface processes, Arctic mixed-phase clouds, and airmass transport and transformation.
    Repository Name: EPIC Alfred Wegener Institut
    Type: Article , isiRev
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  • 3
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    In:  XXVIII General Assembly of the International Union of Geodesy and Geophysics (IUGG)
    Publication Date: 2023-08-16
    Description: Marine carbohydrates are produced by microbes in the ocean and contribute significantly to dissolved and particulate organic carbon in the seawater. Recent studies showed that the carbohydrates released by Arctic microorganisms exhibit an extraordinarily high ice nucleating activity making them potentially important ice nucleating particles (INP). These carbohydrates enter the atmosphere as part of sea spray aerosol (SSA) through wind-driven processes and eventually contribute to cloud formation processes. However, the emission processes of marine carbohydrates and their atmospheric aging are still not well understood. Here, we present marine carbohydrates found in bulk seawater (at 1 m depth), the sea surface microlayer (SML), size-resolved aerosol particles and fog water collected in the Arctic during the PASCAL/SiPCA cruise (May-July 2017). Chemical and statistical analyses revealed a chemo-selective transfer of carbohydrates towards sodium during the sea-air transfer. Additionally, strong evidence could be found for bacterial modifications of the aerosolized carbohydrates in the atmosphere after their oceanic emission causing quick aging. Finally, we present the influence of sea ice on the sea-air transfer by forming different sea ice related environments, such as the marginal ice zone, open leads, melt ponds and the ice-free ocean with different biological activities and wind conditions. As a consequence of the retreat of sea ice enhanced by Arctic amplification, these processes may lead to a changing availability of potential INP influencing the cloud formation and their microphysical properties.
    Language: English
    Type: info:eu-repo/semantics/conferenceObject
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