ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
The title complex, [Ru(C2H3N)2(C6H6N2)(C18H15P)2](PF6)2.CH4O, is the third of a series of ruthenium complexes containing two triphenylphosphine groups in a trans arrangement, o-benzoquinone diimine and two other non-redox active ligands to been characterized. The effect of electron donor–acceptor properties of the two non-redox active ligands does not change the quinone arrangement for the o-benzoquinone diimine ligand, as can be seen from the bond distances of the quinone ring. The asymmetric unit contains half a molecule of complex cation (on a twofold rotation axis), one hexafluorophosphate anion and half a molecule of methanol in a general position close to a twofold rotation axis.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100007654
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