ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
α,ω-Dipiperazino polybutadiene (PBD) was complexed with the hydrated forms of copper chloride, iron chloride, and nickel chloride in methanol. The polymers were recovered and compression molded into films and properties investigated. In particular, the tensile stress-strain behavior as well as stress relaxation behavior were monitored with time at ambient conditions. It was observed that the polybutadiene material showed a strong association with copper providing a pseudo network behavior. The association for the iron and nickel components were considerably weaker than that of copper. Comparisons of the data obtained from these systems were also made with earlier data obtained from the same laboratory on carboxylated or sulfonated telechelic ionomers based on polyisoprene and polyisobutylene. It was concluded that the copper complex with the α,ω-dipiperazino polybutadiene has comparable or better behavior than some of the carboxylate systems. © 1992 John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1992.070461217
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