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  • 1
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Ltd
    Global change biology 7 (2001), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: Because biological and physical processes alter the stable isotopic composition of atmospheric CO2, variations in isotopic content can be used to investigate those processes. Isotopic flux measurements of 13CO2 above terrestrial ecosystems can potentially be used to separate net ecosystem CO2 exchange (NEE) into its component fluxes, net photosynthetic assimilation (FA) and ecosystem respiration (FR). In this paper theory is developed to partition measured NEE into FA and FR, using measurements of fluxes of CO2 and 13CO2, and isotopic composition of respired CO2 and forest air. The theory is then applied to fluxes measured (or estimated, for 13CO2) in a temperate deciduous forest in eastern Tennessee (Walker Branch Watershed). It appears that there is indeed enough additional information in 13CO2 fluxes to partition NEE into its photosynthetic and respiratory components. Diurnal patterns in FA and FR were obtained, which are consistent in magnitude and shape with patterns obtained from NEE measurements and an exponential regression between night-time NEE and temperature (a standard technique which provides alternate estimates of FR and FA). The light response curve for photosynthesis (FA vs. PAR) was weakly nonlinear, indicating potential for saturation at high light intensities. Assimilation-weighted discrimination against 13CO2 for this forest during July 1999 was 16.8–17.1‰, depending on canopy conductance. The greatest uncertainties in this approach lie in the evaluation of canopy conductance and its effect on whole-canopy photosynthetic discrimination, and thus the indirect methods used to estimate isotopic fluxes. Direct eddy covariance measurements of 13CO2 flux are needed to assess the validity of the assumptions used and provide defensible isotope-based estimates of the component fluxes of net ecosystem exchange.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Global change biology 2 (1996), S. 0 
    ISSN: 1365-2486
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Biology , Energy, Environment Protection, Nuclear Power Engineering , Geography
    Notes: A design is presented to continuously monitor the transfers of carbon between the atmosphere and the terrestrial biosphere and oceans on large spatial scales. A consideration of the expected signal-to-noise suggests that a very cost effective method is to perform repeated measurements of the mixing ratios of trace gases in the atmospheric column at an increased number of sites compared to the present geographical coverage. This can be accomplished with existing technology, provided that more automation is applied to the sampling process as well as to the analytical procedures. The resulting data will be crucial to test extrapolations based on direct flux measurements to regional and global scales.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: We have developed and tested an inexpensive ion detector with dark-count rates below 10−4 s−1 and excellent background rejection. Each 40-keV ion that strikes a grazing-incidence Al2O3 conversion dynode ejects a few tens of secondary electrons, which enter separate pores of a microchannel plate and are independently multiplied to saturated pulse height. The pulses are summed to produce an output signal that is proportional to the number of secondary electrons. This permits pulse-height discrimination against backgrounds of low-energy ions, electrons, and photons. We have successfully tested the detector with C+, Na+, K+, Rb+, and Cs+ at 5–40 keV, and with 36-keV C− and CH−. It should detect ions and neutrals of all species, at energies above 5–10 keV, with good efficiency and excellent background discrimination. Counting efficiency and background discrimination improve with higher ion energy. The detector can be operated at pressures up to at least 2×10−7 Torr and be exposed to air repeatedly without requiring reactivation. The maximum ion count rate is 3×106 s−1 in pulse-counting mode and 6×109 s−1 in current-integrating mode. Detection of 40-keV ions at rates below 10−2 s−1 was required in development of a 10-cm radius 40-keV cyclotron dedicated to high-sensitivity radioisotope dating by accelerator mass spectrometry (AMS). In the cyclotron, the detector suppresses to 6×10−4 s−1 the background count rate from the presence of low-energy ions, photons, and electrons.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 327 (1987), S. 495-497 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Sampling sites have been chosen for their access to large well-mixed air masses, remote from human influence. Monthly flask sample pairs have been collected in clean air conditions. Filling a flask involves venting off clean, dry, storage air, flushing for 15-20 min at 5-101 min"1 with a metal ...
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 277 (1979), S. 121-123 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The new isotopic measurements are plotted in Fig. 1 as the per mil variation, 〈513C, of the 13C/12C ratio from the historic standard PDB. Also plotted are isotopic data for 1955 and 1956 for those sites and times of day of the original study having minimal local disturbance to the CO2 ...
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Climatic change 37 (1997), S. 487-490 
    ISSN: 1573-1480
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    Publication Date: 2024-02-17
    Keywords: 31AR19610131-track; Algorithm; Argo; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); LATITUDE; LONGITUDE; MONS01AR-MONS08AR; MONSOON; Pressure, atmospheric; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 9931 data points
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  • 8
    Publication Date: 2024-02-17
    Keywords: 31HO19571021-track; Algorithm; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; DOWNWIND-H; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); Horizon; LATITUDE; LONGITUDE; Pressure, atmospheric; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 9742 data points
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  • 9
    Publication Date: 2024-02-17
    Keywords: 31AR19630216-track; Algorithm; Argo; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); LATITUDE; LONGITUDE; LSDA; LUSIAD-A; Pressure, atmospheric; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 29070 data points
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  • 10
    Publication Date: 2024-02-17
    Keywords: 31AR19620519-track; Algorithm; Argo; CT; DATE/TIME; Depth, bathymetric, interpolated/gridded; DEPTH, water; Distance; extracted from the 2-Minute Gridded Global Relief Data (ETOPO2); extracted from the World Ocean Atlas 2005; Fugacity of carbon dioxide (water) at sea surface temperature (wet air); LATITUDE; LONGITUDE; LSDA; LUSIAD-A; Pressure, atmospheric; Quality flag; Recomputed after SOCAT (Pfeil et al., 2013); Salinity, interpolated; SOCAT; Surface Ocean CO2 Atlas Project; Temperature, water; Underway cruise track measurements; xCO2 (water) at sea surface temperature (dry air)
    Type: Dataset
    Format: text/tab-separated-values, 32486 data points
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