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  • 1
    ISSN: 0003-5599
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The effect of different kind of pigments on the corrosion resistance properties of an epoxy paint has been investigated using electrochemical impedance spectroscopy and open circuit potential measurements. Painted naval steel samples were studied during the exposure to artificial sea water. The epoxy paint coatings were prepared employing red lead, zinc, red iron oxide or titanium dioxide as pigment with 0.8 of PVC/CPVC ratio. From the EIS and corrosion potential data analyis was found that the anticorrosive protection given by an anticorrosive (pigmented with red lead) and a top coat (pigmented with red iron oxide) epoxy painting scheme was both more lasting and more effective. This was attributed to the fact that both the effective adhesion provided by the chemical bonding between the steel surface and the epoxy paint groups and the constant high barrier effect afforded by this type of top coat were a perfect complement for the high corrosion inhibitive capacity of the red lead pigment.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Bingley : Emerald
    Pigment & resin technology 29 (2000), S. 16-22 
    ISSN: 0369-9420
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Health and safety legislation has forced changes in the type of anticorrosive pigments used in paint formulations, mainly focused on their substitution with different phosphates. The zinc phosphate pigment used with different types of binders has provided contradictory experimental results. In this paper, waterborne anticorrosive paints pigmented with zinc phosphates were studied. The main variables considered were PVC and the anticorrosive pigment content. Accelerated tests (salt spray, humidity chamber, and electrochemical tests) were performed to evaluate the paints' anticorrosive performance. Good correlation was found using salt spray and impedance tests. From analysis of the time dependence of all the experimental results it was concluded that an efficient steel protection could be obtained using a waterborne epoxy primer pigmented with zinc phosphate. Such protection is attained through the barrier effect afforded by the paint film as well as the precipitation of a pretty stable ferric phosphate layer under the intact and damaged coating areas.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0369-9420
    Source: Emerald Fulltext Archive Database 1994-2005
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The effect of different kind of pigments on the corrosion resistance properties of an epoxy paint has been investigated using electrochemical impedance spectroscopy and open circuit potential measurements. Painted naval steel samples were studied during the exposure to artificial sea water. The epoxy paint coatings were prepared employing red lead, zinc, red iron oxide or titanium dioxide as pigment with 0.8 of PVC/CPVC ratio. From the EIS and corrosion potential data analyis was found that the anticorrosive protection given by an anticorrosive (pigmented with red lead) and a top coat (pigmented with red iron oxide) epoxy painting scheme was both more lasting and more effective. This was attributed to the fact that both the effective adhesion provided by the chemical bonding between the steel surface and the epoxy paint groups and the constant high barrier effect afforded by this type of top coat were a perfect complement for the high corrosion inhibitive capacity of the red lead pigment.
    Type of Medium: Electronic Resource
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