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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    International journal of fracture 21 (1983), S. 107-114 
    ISSN: 1573-2673
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Beschreibung / Inhaltsverzeichnis: Résumé La spectroscopie électronique à résonnance de spin (ESR), qui est à même d'annoncer des ruptures de liaisons covalentes au cours de la rupture d'un polymère, a fourni une base expérimentale permettant d'élaborer un modèle atomique de la rupture, qui prenne en compte la distribution des contraintes dans la structure interne du matériau. A l'aide d'un modèle de calcul mis au point par De Vries et Lloyd, on a obtenu des estimations des durées à rupture dans le cas de températures, de contraintes et de vitesses de sollicitation différentes. Les durées à rupture prévues sont en accord avec les observations de l'expérience, ce qui indique l'utilité pratique du modèle basé sur l'ESR. En outre, les paramètres d'activation effective qui découlent d'une mise en corrélation du modèle de rupture macroscopique de rupture de Zhurkov avec les prédictions de l'ESR fournissent un éélairage sur la manière dont la distribution des contraintes intervient dans la détermination de la cinétique du processus de rupture.
    Notizen: Abstract Electron spin resonance (ESR) spectroscopy, which is able to monitor covalent bond rupture during polymer fracture, has provided an experimental basis on which to construct an atomistic fracture model which takes proper cognizance of the distribution of stress over the material's internal structure. Using a computer model developed by DeVries and Lloyd, estimations of times to fracture were obtained for several different temperatures, stresses, and stress rates. The predicted rupture times agreed satisfactorily with experimental observations, which indicates the practical utility of the ESR-based model. Further, the effective activation parameters which result when the Zhurkov macroscopic fracture model is correlated with the ESR predictions provide an insight as to the role of the internal stress distribution in determining the kinetics of the fracture process.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of materials science 18 (1983), S. 652-656 
    ISSN: 1573-4803
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Maschinenbau
    Notizen: Abstract Transverse tensile properties of Kevlar 49 aramid/Fiberite 934 epoxy composites have been measured as a function of moisture content. Moisture effects are substantial: losses of 14% in stiffness, 35% in strength and 27% in elongation were observed at 25
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 372-376 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: This paper presents a method for analyzing the cure of multilayer circuit boards containing chemically reactive adhesive interlayers. The cure kinetics of the adhesive are first quantified by differential scanning calorimetry, using the method of Freeman and Carroll to obtain the numerical kinetic parameters. These parameters are then used in a finite-element model of the circuit board which solves the heat and species transfer equations simultaneously. It is then possible to predict the temperature and extent of reaction at any time and position within the laminate, enabling the curing program to be optimized.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 409-414 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A series of bismaleimide resin systems has been examined in order to identify the molecular features responsible for the mechanical response of these materials. A range of network structures was produced both by formulation of resins with different ratios of N,N′-bismaleimido-4,4′-diphenylmethane (BMI) and methylene dianiline (MDA), and by the use of different thermal processing cycles. Spectrographic and chromatographic techniques were used to study the reactions that occurred during the cure. Two principal reactions were confirmed: a Michael addition reaction which provides linear chain growth, and an addition reaction which produces crosslinking through the double bonds of the maleimide group. In general, curing at a lower temperature or increasing the MDA content served to favor chain extension over crosslinking, which might be expected to increase molecular mobility in the resin.
    Zusätzliches Material: 12 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 5
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 32 (1992), S. 415-420 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A range of bismaleimide resins of differing network structure was produced both by varying the ratios of N,N′-bismaleimido-4,4′-diphenylmethane (BMI) and methylene dianiline (MDA), and also by the use of different thermal processing cycles. Characterization of the resins by a variety of mechanical, physical, and micrographic techniques showed that properties such as modulus and yield strength varied directly with crosslink density and its associated free volume. Fracture toughness was found to increase as the crosslink density decreased, and microscopic investigation of the resin fracture surfaces identified characteristics which correlated with the resin fracture toughness.
    Zusätzliches Material: 14 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 6
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 27 (1987), S. 131-140 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: We have studied the failure of a urethane elastomer due to cyclic compressive loading, using loading frequencies and specimen sizes for which internal heat generation is an important factor. The eventual failures were generally manifest by internal cracks growing transverse to the loading direction. A variety of experimental analyses indicate that this failure is primarily thermal, in that the temperature rise due to viscous dissipation eventually leads to a melting of the hard segment domains which act to reinforce the material. No strong indication of thermal or thermomechanical bond scission was obtained, although a progressive reduction in the rubbery modulus was noted.
    Zusätzliches Material: 13 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 7
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 828-833 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The mechanism underlying fracture of many oriented semicrystalline polymers is hypothesized to be a thermally activated, stress-aided rate process in which the tie chains connecting crystalline units suffer thermomechanical dissociation. Some previous numerical models based on this concept have assumed a Gaussian distribution of tie chain contour lengths which are ruptured progressively by successively higher specimen strains, and have used electron spin resonance (ESR) spectroscopy to obtain the numerical parameters of the distribution. The distribution of tie chain lengths in the intererystalline region is calculated theoretically in this paper, based on minimization of free energy. Our results, although in basic agreement with earlier models, suggest a reinterpretation of some of the ESR findings with regard to molecular fracture processes.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Biomaterials 4 (1993), S. 289-301 
    ISSN: 1045-4861
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Medizin , Technik allgemein
    Notizen: The „tail string“ that extends from a contraceptive intrauterine device (IUD) into the vagina is an illustrative case in materials engineering design. The strings must satisfy certain criteria for strength and other properties in order to fulfill the function of providing a means of insuring that the IUD has not been ejected, and eventually of helping remove the IUD. This must be done without contributing to an additional risk of unwanted medical side effects beyond those that may be inherent in any such device. Oriented monofilament olefins appear to satisfy these criteria, and have been used successfully in several IUD designs. This article describes a study of two such monofilaments taken from new IUDs, showing how the material's processing, structure, and properties lead to effective performance as tail strings. Several types of used IUDs were also studied, to insure that nothing occurred during use that would alter the conclusions drawn from the study of new strings. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 15 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 9
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 1068-1072 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A numerical simulation of ballistic impact and penetration on woven textile panels is described which can easily incorporate a wide variety of realistic constitutive and fracture models. The use of this model in assessing Viscoelastic relaxation effects is illustrated, and is further extended to include non-linear Viscoelastic effects. Since a variety of non-linear models is presently available and there is insufficient evidence to indicate the superiority of any single one in this instance, the Eyring non-linear model was chosen arbitrarily to indicate the ease with which these models may be implemented into the numerical treatment. The results obtained using the non-linear model are compared with comparable computer experiments using linear elastic and linear Viscoelastic models.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 10
    Digitale Medien
    Digitale Medien
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 18 (1978), S. 249-254 
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Unless suitably stabilized and coated, fiber-reinforced composites are subject to photoinitiated oxidation which results in a degradation of the resin surface and an eventual reduction in the composite's mechanical properties. The photo-oxidation, which is initiated by UV-absorbing oxidation products created during cure, is relatively amenable to detection by techniques of analytical chemistry. Mechanical test results, which reflect a wide range of material properties, are more subject to variability and misinterpretation.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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