ISSN:
1572-8870
Keywords:
Anionic polymerization
;
block copolymer
;
ring-opening polymerization
;
poly(ferrocene)
;
nanostructures
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Living anionic ring-opening polymerization methodology for silicon-bridged [1]ferrocenophanes has been extended to unsymmetrically substituted monomers. This permits access to well-defined amorphous poly(ferrocene) homopolymers and organometallic block copolymers, such as polystyrene-b-poly(ferrocenylmethylphenylsilane), with an amorphous poly(ferrocenylsilane) block. This allows phase separation to occur at lower temperatures, which should facilitate applications in which organometallic nanodomains are desirable.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1021793622713
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