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  • 1
    Publication Date: 2024-04-24
    Description: The dataset comprises stable water isotopes and conductitities of a lead case study during leg 5 of the MOSAiC campaign. Samples have been taken from different water and ice types for this lead case study. Discrete water samples were taken using a peristaltic pump (Masterflex E/S Portable Sampler, Masterflex, USA) through a 2 m long PTFE tube (L/S Pump Tubing, Masterflex, USA). Water samples for measurement of stable water isotopes (δ18O, δD,) were collected in 50-mL glass screw-cap narrow-neck vials (VWR international LLC, Germany). Snow on the sea ice was sampled with a polyethylene shovel (GL Science Inc., Tokyo, Japan) and placed into a polyethylene zip-loc bag. Ice in the lead was collected and a 0.25 m ' 0.25 m ice block was cut with a hand saw and placed into a zip-lock bag. Ice temperature at the surface was measured with a needle-type temperature sensor (Testo 110 NTC, Brandt Instruments, Inc., USA). Two ice cores from the bottom of a melt pond were collected, using an ice corer with an inner diameter of 0.09 m (Mark II coring system, KOVACS Enterprises, Inc., USA). The cores were cut with a stainless steel saw into 0.1 m thick sections and stored in plastic bags for subsequent salinity and δ18O measurements. Snow and ice samples were immediately placed in a cooler box along with refrigerants to keep their temperature low and to minimize brine drainage. Onboard Polarstern, ice samples were transferred into ice melting bags (Smart bags PA, AAK 5L, GL Sciences Inc., Japan) and melted in the dark at +4°C. After the ice melted, the meltwater was placed in a 30-mL glass screw-cap vial for later stable water isotope measurement and into a 100-mL polypropylene bottle (I-Boy, AS ONE Corporation, Japan) for later salinity measurement. These samples were stored at +4°C in the dark until analysis. Under-ice water samples (from about 10 m depth) were collected via R/V Polarstern's underway water sampling system during leg 5. Samples were placed into 250-mL glass vials (Duran Co. Ltd, Germany) for later δ18O and salinity measurements. Salinity of collected samples was determined with a same conductivity sensor used on sea ice (Cond 315i, WTW GmbH, Germany). Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at AWI Potsdam (hdl:10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): hdl:10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 and hdl:10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values were given in per mil (‰) vs. Vienna standard mean ocean water (V-SMOW) as the standard. The second order parameter d excess was computed according to: d excess = δD-8 δ18O (Dansgaard, 1964).
    Keywords: Arctic Ocean; AWI_Envi; AWI_Perma; Calculated after Dansgaard (1964); Chamber for gas sampling; CHAMGAS; Comment; Conductivity sensor Cond 315i, WTW GmbH, Germany; DATE/TIME; DEPTH, ice/snow; DEPTH, water; Deuterium excess; Event label; freshwater; IC; Ice corer; Latitude of event; leads; Leg 5; Longitude of event; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); Mosaic; MOSAiC; MOSAiC20192020; Multidisciplinary drifting Observatory for the Study of Arctic Climate; Permafrost Research; Polarstern; Polar Terrestrial Environmental Systems @ AWI; PS122/5; PS122/5_59-343; PS122/5_59-389; PS122/5_59-392; PS122/5_59-446; PS122/5_59-447; PS122/5_60-130; PS122/5_60-133; PS122/5_60-146; PS122/5_60-16; PS122/5_60-260; PS122/5_60-61; PS122/5_61-126; PS122/5_61-205; PS122/5_61-206; PS122/5_62-117; PS122/5_62-120; PS122/5_62-35; PS122/5_62-40; PS122/5_62-42; PS122/5_62-5; Salinity; Sample code/label; Sample ID; Sample type; Sea ice; snow; SNOW; Snow/ice sample; Station label; Water sample; WS; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 838 data points
    Location Call Number Expected Availability
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  • 2
    Publication Date: 2024-04-24
    Description: Snow samples were collected from several locations on the main MOSAiC ice floe on weekly basis. Snow samples for measurement of stable water isotopes (δ18O, δD,) were collected in three different layers (top, middle, bottom) using a metal density cutter. At first, samples were stored in sealed plastic bags and the air was squeezed out before closing the bags. At later stages of the expedition, samples were stored in plastic cups with lids. Later the samples were thawed completely at room temperature and poured into 20 ml glass vials and sealed with parafilm tape and stored at 4°C. Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at AWI Potsdam (https://hdl.handle.net/10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): https://hdl.handle.net/10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 https://hdl.handle.net/10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c. employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values were given in per mil (‰) vs. Vienna standard mean ocean water (V-SMOW) as the standard. The second order parameter d excess was computed according to: d excess = δD-8 δ18O (Dansgaard, 1964).
    Keywords: Arctic Ocean; Calculated after Dansgaard (1964); Comment; DATE/TIME; DEPTH, water; Deuterium excess; Event label; Height, relative, from ice/snow line, maximum; Height, relative, from ice/snow line, minimum; IC; Ice corer; isotopes; Layer description; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); Mosaic; MOSAiC; MOSAiC20192020; Multidisciplinary drifting Observatory for the Study of Arctic Climate; Polarstern; PS122/1; PS122/1_10-35; PS122/1_10-38; PS122/1_10-5; PS122/1_11-23; PS122/1_4-10; PS122/1_5-5; PS122/1_5-92; PS122/1_5-93; PS122/1_5-95; PS122/1_6-10; PS122/1_6-136; PS122/1_6-140; PS122/1_6-34; PS122/1_6-6; PS122/1_6-61; PS122/1_7-105; PS122/1_7-106; PS122/1_7-12; PS122/1_7-89; PS122/1_8-110; PS122/1_8-24; PS122/1_8-33; PS122/1_8-79; PS122/1_9-23; PS122/1_9-31; PS122/1_9-39; PS122/1_9-65; PS122/2; PS122/2_16-9; PS122/2_17-109; PS122/2_17-16; PS122/2_18-17; PS122/2_18-66; PS122/2_19-144; PS122/2_19-28; PS122/2_19-9; PS122/2_19-92; PS122/2_20-36; PS122/2_20-4; PS122/2_20-80; PS122/2_20-83; PS122/2_21-14; PS122/2_21-15; PS122/2_21-96; PS122/2_22-5; PS122/2_22-6; PS122/2_22-73; PS122/2_23-2; PS122/2_23-34; PS122/2_23-73; PS122/2_23-74; PS122/2_23-9; PS122/2_24-14; PS122/2_24-15; PS122/2_24-35; PS122/2_24-86; PS122/2_25-22; PS122/2_25-80; PS122/2_25-81; PS122/3; PS122/3_29-28; PS122/3_29-29; PS122/3_29-9; PS122/3_30-17; PS122/3_30-25; PS122/3_31-44; PS122/3_31-55; PS122/3_31-64; PS122/3_31-65; PS122/3_31-91; PS122/3_32-5; PS122/3_32-88; PS122/3_32-92; PS122/3_33-53; PS122/3_33-65; PS122/3_33-66; PS122/3_34-34; PS122/3_34-45; PS122/3_35-23; PS122/3_35-53; PS122/3_35-56; PS122/3_36-14; PS122/3_36-178; PS122/3_36-35; PS122/3_36-99; PS122/3_37-129; PS122/3_37-41; PS122/3_37-57; PS122/3_38-1; PS122/3_38-141; PS122/3_38-4; PS122/3_38-51; PS122/3_39-46; PS122/3_39-48; PS122/3_39-88; PS122/3_39-92; PS122/4; PS122/4_44-157; PS122/4_44-215; PS122/4_44-216; PS122/4_44-47; PS122/4_46-32; PS122/4_46-50; PS122/4_47-23; PS122/4_48-142; PS122/4_48-143; PS122/4_48-144; PS122/4_48-145; PS122/4_48-146; PS122/5; PS122/5_59-204; PS122/5_59-313; PS122/5_60-2; PS122/5_60-91; PS122/5_61-25; PS122/5_62-124; PS122/5_62-44; Sample code/label; Sample ID; Sample type; snow; SNOWPIT; Snow pit; Snow sampler metal; SSM; Station label; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 2717 data points
    Location Call Number Expected Availability
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  • 3
    Publication Date: 2024-04-24
    Description: Underway seawater samples have been taken from underneath the research vessel Polarstern through a pipe installed on the ship. The valve had been open for about 2 minutes before collecting the samples to avoid possible contaminations. Water samples for measurement of stable water isotopes (δ18O, δD,) were collected in narrow-mouth low-density polyethylene 20- or 30-mL plastic bottles (VWR international LLC, Germany), sealed with Parafilm M and stored at +4 °C from the end of the expedition until the measurement. Average daily salinity values were extracted from dship portal (https://dship.awi.de/). Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at AWI Potsdam (https://hdl.handle.net/10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): https://hdl.handle.net/10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 https://hdl.handle.net/10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values were given in per mil (‰) vs. Vienna standard mean ocean water (V-SMOW) as the standard. The second order parameter d excess was computed according to: d excess = δD-8 δ18O (Dansgaard, 1964).
    Keywords: Arctic Ocean; Calculated after Dansgaard (1964); Comment; DATE/TIME; DEPTH, water; Deuterium excess; Event label; isotopes; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); MOSAiC; MOSAiC20192020; MOSAiC expedition; Multidisciplinary drifting Observatory for the Study of Arctic Climate; North Greenland Sea; Polarstern; PS122/1; PS122/1_10-111; PS122/1_10-2; PS122/1_10-25; PS122/1_10-32; PS122/1_10-52; PS122/1_10-77; PS122/1_10-93; PS122/1_11-15; PS122/1_11-28; PS122/1_11-4; PS122/1_11-42; PS122/1_7-111; PS122/1_7-95; PS122/1_8-100; PS122/1_8-119; PS122/1_8-15; PS122/1_8-26; PS122/1_8-4; PS122/1_8-84; PS122/1_9-103; PS122/1_9-15; PS122/1_9-29; PS122/1_9-45; PS122/1_9-56; PS122/1_9-92; PS122/2; PS122/2_15-6; PS122/2_15-8; PS122/2_16-14; PS122/2_16-29; PS122/2_16-37; PS122/2_16-53; PS122/2_16-61; PS122/2_16-8; PS122/2_17-17; PS122/2_17-2; PS122/2_17-25; PS122/2_17-42; PS122/2_17-67; PS122/2_17-75; PS122/2_17-97; PS122/2_18-15; PS122/2_18-2; PS122/2_18-23; PS122/2_18-39; PS122/2_18-58; PS122/2_18-75; PS122/2_18-90; PS122/2_19-114; PS122/2_19-17; PS122/2_19-2; PS122/2_19-33; PS122/2_19-58; PS122/2_19-80; PS122/2_19-90; PS122/2_20-1; PS122/2_20-111; PS122/2_20-13; PS122/2_20-29; PS122/2_20-50; PS122/2_20-75; PS122/2_20-99; PS122/2_21-11; PS122/2_21-112; PS122/2_21-123; PS122/2_21-50; PS122/2_21-69; PS122/2_21-85; PS122/2_22-14; PS122/2_22-2; PS122/2_22-31; PS122/2_22-64; PS122/2_22-84; PS122/2_22-95; PS122/2_23-1; PS122/2_23-11; PS122/2_23-33; PS122/2_23-49; PS122/2_23-66; PS122/2_23-86; PS122/2_24-20; PS122/2_24-30; PS122/2_24-41; PS122/2_24-48; PS122/2_24-5; PS122/2_24-71; PS122/2_24-82; PS122/2_25-101; PS122/2_25-29; PS122/2_25-43; PS122/2_25-5; PS122/2_25-56; PS122/2_25-75; PS122/2_25-88; PS122/3; PS122/3_29-21; PS122/3_29-36; PS122/3_29-51; PS122/3_29-6; PS122/3_29-60; PS122/3_29-7; PS122/3_29-81; PS122/3_30-18; PS122/3_30-23; PS122/3_30-35; PS122/3_30-52; PS122/3_30-6; PS122/3_30-66; PS122/3_30-83; PS122/3_31-13; PS122/3_31-16; PS122/3_31-28; PS122/3_31-46; PS122/3_31-54; PS122/3_31-60; PS122/3_31-78; PS122/3_32-1; PS122/3_32-21; PS122/3_32-37; PS122/3_32-48; PS122/3_32-60; PS122/3_32-72; PS122/3_33-15; PS122/3_33-35; PS122/3_33-50; PS122/3_33-64; PS122/3_33-79; PS122/3_33-8; PS122/3_33-93; PS122/3_34-1; PS122/3_34-12; PS122/3_34-26; PS122/3_34-35; PS122/3_34-47; PS122/3_34-61; PS122/3_34-74; PS122/3_35-103; PS122/3_35-17; PS122/3_35-3; PS122/3_35-35; PS122/3_35-52; PS122/3_35-75; PS122/3_35-89; PS122/3_36-1; PS122/3_36-110; PS122/3_36-13; PS122/3_36-135; PS122/3_36-34; PS122/3_36-55; PS122/3_36-72; PS122/3_37-112; PS122/3_37-12; PS122/3_37-2; PS122/3_37-23; PS122/3_37-42; PS122/3_37-67; PS122/3_37-90; PS122/3_38-113; PS122/3_38-22; PS122/3_38-26; PS122/3_38-37; PS122/3_38-48; PS122/3_38-67; PS122/3_38-88; PS122/3_39-1; PS122/3_39-14; PS122/3_39-29; PS122/3_39-49; PS122/3_39-68; PS122/3_39-76; PS122/3_39-85; PS122/3_40-1; PS122/3_40-13; PS122/3_40-22; PS122/3_40-30; PS122/3_40-35; PS122/3_40-45; PS122/3_40-7; PS122/3_41-13; PS122/3_41-20; PS122/3_41-27; PS122/3_41-38; PS122/3_41-4; PS122/3_41-42; PS122/3_41-48; PS122/3_42-1; PS122/3_42-12; PS122/3_42-21; PS122/3_42-27; PS122/3_42-33; PS122/3_42-43; PS122/3_42-52; PS122/3_42-58; PS122/3_42-6; PS122/3_42-67; PS122/4; PS122/4_44-123; PS122/4_44-131; PS122/4_44-146; PS122/4_44-160; PS122/4_44-175; PS122/4_44-19; PS122/4_44-194; PS122/4_44-28; PS122/4_44-34; PS122/4_44-54; PS122/4_44-64; PS122/4_44-80; PS122/4_44-85; PS122/4_44-96; PS122/4_45-111; PS122/4_45-133; PS122/4_45-14; PS122/4_45-6; PS122/4_45-65; PS122/4_45-90; PS122/4_46-124; PS122/4_46-22; PS122/4_46-5; PS122/4_46-51; PS122/4_46-67; PS122/4_46-96; PS122/4_47-105; PS122/4_47-118; PS122/4_47-24; PS122/4_47-37; PS122/4_47-5; PS122/4_47-70; PS122/4_47-88; PS122/4_48-119; PS122/4_48-149; PS122/4_48-156; PS122/4_48-18; PS122/4_48-48; PS122/4_48-68; PS122/4_49-23; PS122/4_49-24; PS122/4_49-28; PS122/4_49-58; PS122/4_49-67; PS122/4_49-82; PS122/4_49-96; PS122/4_50-12; PS122/4_50-22; PS122/4_50-3; PS122/4_50-34; PS122/4_50-44; PS122/4_50-53; PS122/4_50-59; PS122/4_50-62; PS122/5; PS122/5_59-11; PS122/5_59-133; PS122/5_59-151; PS122/5_59-167; PS122/5_59-179; PS122/5_59-199; PS122/5_59-220; PS122/5_59-247; PS122/5_59-26; PS122/5_59-266; PS122/5_59-287; PS122/5_59-323; PS122/5_59-341; PS122/5_59-36; PS122/5_59-361; PS122/5_59-379; PS122/5_59-4; PS122/5_59-59; PS122/5_59-65; PS122/5_60-11; PS122/5_60-116; PS122/5_60-140; PS122/5_60-169; PS122/5_60-35; PS122/5_60-50; PS122/5_60-73; PS122/5_61-106; PS122/5_61-141; PS122/5_61-184; PS122/5_61-208; PS122/5_61-244; PS122/5_61-3; PS122/5_61-34; PS122/5_62-111; PS122/5_62-133; PS122/5_62-150; PS122/5_62-171; PS122/5_62-63; PS122/5_62-8; PS122/5_62-86; PS122/5_63-115; PS122/5_63-123; PS122/5_63-134; PS122/5_63-144; PS122/5_63-27; PS122/5_63-52; PS122/5_63-6; PS122/5_63-66; PS122/5_63-7; PS122/5_63-78; PS122/5_63-93; Salinity; Sample code/label; Sample ID; Sample type; seawater; see abstract; Station label; Surface water sample; SWS; Tap; TAP; Water sample; WS; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 2375 data points
    Location Call Number Expected Availability
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  • 4
    Publication Date: 2024-04-24
    Description: The dataset compiles water isotope measurements of 66 lakes, sampled in Central and Eastern Yakutia during a summer field campaign in August and September 2021 (RU-Land_2021_Yakutia). Additionally, there are isotope data of a single rain event, received during the campaign. The investigated lakes are located in four different study areas in the Sakha Republic, Russia: in the mountainous region of the Verkhoyansk Range within the Oymyakonsky and Tomponsky District (EN21401 - EN21415), and in three lowland regions of Central Yakutia within the Churapchinsky, Tattinsky and the Megino-Kangalassky District (Event EN21416 - EN21467). One lake (EN21160) is centrally located in the city of Yakutsk, the capital of the Sakha Republic. Baisheva et al. (2022) gives an overview of the lakes studied and the corresponding hydrochemistry. Surface water samples (0 – 0.5 m) for measurement of stable water isotopes (δ18O, δD) have been taken for all lakes. If the lakes were deeper than five meters (≥ 5 m), water samples of the middle and bottom water (MW, BW) of the lake were taken, too. Where it was available and reachable, there are also water isotope data from in- or outflow (IF, OF). For two greater lakes, there are one or even more depth profiles composed of several isotope samples from different depths (EN21112, EN21116, EN21124¸ EN21160; numbers at the end indicate different sampling depths). There were two different methods of sampling: Either water for isotope measurements was directly sampled from the lake into 30 ml narrow-mouth PE bottles, filled to the top and closed tightly. Otherwise water samples were taken with an UWITEC water sampler (2 L), filled into a larger sample container (2 L Whirl-Pak®) and subsampled in 30 ml narrow-mouth PE bottles as soon as possible afterwards. The single rain event was sampled on the 22nd of August 2021 at one of the field camp sites, close to the lake EN21427. A dry, clean plastic container was placed outside for receiving the rain. The subsampling was done immediately after the event by rinsing it into 30 ml narrow-mouth PE bottles, filled to the top and closed tightly. All samples were stored cool and dark as soon as possible until analysis. All data were collected and processed by scientists from the Alfred Wegener Institute, Helmholtz Centre for Polar and Marine Research (AWI), Germany, the University of Potsdam, Germany, and the North-Eastern Federal University of Yakutsk (NEFU), Russia. Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at Alfred Wegener Institute in Potsdam (hdl:10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): hdl:10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 and hdl:10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values are given in per mill (‰) vs. Vienna Standard Mean Ocean Water (VSMOW) as the standard. N indicates the number of measurements per sample. If N 〉 1, the mean isotope value of the sample was calculated from the individual measurement results. The standard deviation includes all measurements of the individual sample, which is generally better than the external (or machine) error. The external errors of long-term standard measurements for hydrogen and oxygen are better than 0.8‰ and 0.10‰, respectively (Meyer et al., 2000). The second order parameter d excess was computed according to: d excess = δD – 8 * δ18O (Dansgaard, 1964). For the calculation of d excess, the respective mean values were used.
    Keywords: AWI_Envi; AWI Arctic Land Expedition; Calculated after Dansgaard (1964); Central Yakutia; Churapchinsky District; Comment; DATE/TIME; Depth, bathymetric; DEPTH, water; Deuterium excess; d excess; ELEVATION; EN21160; EN21401; EN21402; EN21403; EN21404; EN21405; EN21406; EN21407; EN21408; EN21409; EN21410; EN21411; EN21412; EN21413; EN21414; EN21415; EN21416; EN21417; EN21418; EN21419; EN21420; EN21421; EN21422; EN21423; EN21424; EN21425; EN21426; EN21427; EN21428; EN21429; EN21430; EN21431; EN21432; EN21433; EN21434; EN21435; EN21436; EN21437; EN21438; EN21439; EN21440; EN21441; EN21442; EN21443; EN21444; EN21445; EN21446; EN21447; EN21448; EN21449; EN21450; EN21451; EN21452; EN21453; EN21454; EN21455; EN21456; EN21457; EN21458; EN21459; EN21462; EN21463; EN21464; EN21465; EN21466; EN21467; Event label; lake; LAKE; Landform; LATITUDE; Location; LONGITUDE; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); Megino-Kangalassky District; Number of observations; Oymyakonsky District; Polar Terrestrial Environmental Systems @ AWI; RU-Land_2021_Yakutia; Russia; Sample ID; Sampling lake; Siberia; stabe isotopes; stable oxygen and hydrogen isotopes; Tattinsky District; thermokarst lakes; Tomponsky District; Type; water isotopes; Yakutia; Yakutsk; δ18O, water; δ18O, water, standard deviation; δ Deuterium, water; δ Deuterium, water, standard deviation
    Type: Dataset
    Format: text/tab-separated-values, 1480 data points
    Location Call Number Expected Availability
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  • 5
    Publication Date: 2024-04-24
    Description: The dataset comprises the main geochemical characteristics of purified lake sediment samples from Lake Bolshoye Shchuchye, in the Polar Ural based on EDS and stable isotope data. Moreover, core segment (column A), composite depth (in cm; column B); calibrated age (in cal ka BP; column C) are given. Details on coring and age model are given in Lenz et al. (2021) Energy-Dispersive X-ray Spectroscopy (EDS) was carried out with a scanning electron microscope (SEM) at the German Research Centre for Geosciences (GFZ Potsdam, Germany) to assess contamination of all diatom samples (following Chapligin et al., 2012). Three replicate analyses were carried out with an excited-area size with a radius of ~200 μm at an acceleration voltage of 20.0 kV. All detectable elements were normalized to 100% weight. The results were expressed as weight percentages (in %) and displayed as oxides: SiO2 content (%); Al2O3 content (%); Na2O content (%); MgO content (%); K2O content (%); CaO content (%); MnO content (%); FeO content (%): Total sum (%) of the purified sediment sample (columns D to L). Details are given in Meyer et al. (2022) The diatom oxygen isotope composition (δ18Odiatom) from lacustrine sediments helps tracing the hydrological and climate dynamics in individual lake catchments. The oxygen isotope data has been generated in the ISOLAB Facility Potsdam including all d18Odiatom values (all in ‰ vs. VSMOW). The measured δ18O values (δ18Omeas), the standard deviation (SD) and number of replicates (N) are given (columns M to O), as well as the calculated contamination (ccont; in %) and δ18O values corrected for contamination (δ18Ocorr) (columns P to Q). The details of the contamination correction and isotope analytics are given in Meyer et al. (2022)
    Keywords: AGE; Aluminium oxide; biogenic silica; Calcium oxide; chironomid-inferred temperature reconstructions; Climate change; Co1321; Contamination; Core; Corrected; DEPTH, sediment/rock; Diatom; Diatoms, δ18O; Diatoms, δ18O, standard deviation; hydrological fluctuations; Iron oxide, FeO; Isotope ratio mass spectrometry; Lake Bolshoye Shchuchye, Polar Urals, Russia; Lake sediment; Magnesium oxide; Manganese oxide; oxygen isotopes; Paleolimnological Transect; PCUWI; Piston corer, UWITEC; PLOT; Potassium oxide; Replicates; Scanning electron microscope (SEM) equipped with electron-dispersive x-ray spectroscopy (EDX); Silicon dioxide; Sodium oxide; Total; δ18O, adjusted/corrected
    Type: Dataset
    Format: text/tab-separated-values, 720 data points
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  • 6
    Publication Date: 2024-04-24
    Description: Seawater samples have been taken from the station Ocean City on the main MOSAiC ice floe on legs 1, 2, and 3. Water samples for measurement of stable water isotopes (δ18O, δD) were collected in 50-mL glass screw-cap narrow-neck vials (VWR international LLC, Germany), sealed with Parafilm M and stored at +4 °C from the end of the expedition until the measurement. Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at AWI Potsdam (https://hdl.handle.net/10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): https://hdl.handle.net/10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 https://hdl.handle.net/10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values were given in per mil (‰) vs. Vienna standard mean ocean water (V-SMOW) as the standard. The second order parameter d excess was computed according to: d excess = δD-8 δ18O (Dansgaard, 1964).
    Keywords: Arctic Ocean; Calculated after Dansgaard (1964); CTD/Rosette; CTD-RO; DATE/TIME; DEPTH, water; Deuterium excess; Event label; isotopes; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); Mosaic; MOSAiC; MOSAiC20192020; Multidisciplinary drifting Observatory for the Study of Arctic Climate; Polarstern; PS122/1; PS122/1_10-45; PS122/1_11-40; PS122/1_2-68; PS122/1_4-37; PS122/1_5-46; PS122/1_6-38; PS122/1_7-40; PS122/1_8-16; PS122/1_9-28; PS122/2; PS122/2_18-16; PS122/2_19-4; PS122/2_20-17; PS122/2_21-101; PS122/2_21-114; PS122/2_21-128; PS122/2_21-26; PS122/2_22-18; PS122/2_22-3; PS122/2_22-71; PS122/2_23-17; PS122/2_23-4; PS122/2_23-70; PS122/2_24-47; PS122/2_25-4; PS122/3; PS122/3_29-74; PS122/3_29-8; PS122/3_30-38; PS122/3_30-9; PS122/3_31-18; PS122/3_31-81; PS122/3_32-12; PS122/3_32-77; PS122/3_33-82; PS122/3_34-17; PS122/3_34-76; PS122/3_35-25; PS122/3_35-92; PS122/3_36-115; PS122/3_36-19; PS122/3_37-116; PS122/3_37-15; PS122/3_38-100; PS122/3_38-31; PS122/3_39-16; Sample code/label; Sample ID; Sample type; seawater; Station label; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 762 data points
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  • 7
    Publication Date: 2024-04-24
    Description: Sea ice cores were collected from the Biogeochemistry (BGC) team at different stations located on the main ice floe of MOSAiC expedition. Flat sea ice on the floe was categorized into three types based on the age: sea ice which grew during the same winter referred to as First-Year-Ice (FYI); sea ice which had survived one or more summer melting periods referred to as Second-Year-Ice (SYI). Sea ice cores were collected using a Kovacs Mark II 9 cm diameter corer. The core was extracted and placed in an aluminum holder equipped with a metric ruler. Using a standard Kovacs ice thickness gauge, the freeboard was taken and the length of the core was measured. The snow on top of the sea ice was brushed off the top of the cores to minimize the snow affecting the ice surface. Onboard RV Polarstern, the cores were cut in 10 cm sections using a handsaw at 4° C (leg 1) or an electric saw at -20° C (legs 2 and 3). Each section was transferred into a gas-tight TedlarTM bag. The closed bags were carefully degassed with a vacuum pump (NKF Neuberger, type N035). Melting occurred within 12 to 15 hours in a water bath in the dark. After shaking the melted ice within the TedlarTM bags, discrete sampling started by first rising the melt water carefully through a Tygon tube connected with the opened valves of the gas tide bags and then into prepared sample vials. Here we present the data from samples collected at Main Core Site (MCS) at the Dark Sector (DS). Oxygen and hydrogen isotope analyses were carried out at the ISOLAB Facility at AWI Potsdam (https://hdl.handle.net/10013/sensor.ddc92f54-4c63-492d-81c7-696260694001) with mass spectrometers (DELTA-S Finnigan MAT, USA): https://hdl.handle.net/10013/sensor.af148dea-fe65-4c87-9744-50dc4c81f7c9 https://hdl.handle.net/10013/sensor.62e86761-9fae-4f12-9c10-9b245028ea4c employing the equilibration method (details in Meyer et al., 2000). δ18O and δD values were given in per mil (‰) vs. Vienna standard mean ocean water (V-SMOW) as the standard. The second order parameter d excess was computed according to: d excess = δD-8 δ18O (Dansgaard, 1964).
    Keywords: Arctic Ocean; Calculated after Dansgaard (1964); DATE/TIME; DEPTH, ice/snow; Deuterium excess; Event label; IC; Ice corer; Mass spectrometer Finnigan MAT Delta-S (ISOLAB); Mosaic; MOSAiC; MOSAiC20192020; Multidisciplinary drifting Observatory for the Study of Arctic Climate; Polarstern; PS122/1; PS122/1_10-16; PS122/1_10-19; PS122/1_5-3; PS122/1_5-78; PS122/1_5-81; PS122/1_6-10; PS122/1_7-6; PS122/1_7-9; PS122/1_8-2; PS122/1_9-30; PS122/1_9-6; PS122/2; PS122/2_17-3; PS122/2_19-7; PS122/2_20-5; PS122/2_21-13; PS122/2_22-7; PS122/2_23-3; PS122/3; PS122/3_32-63; PS122/3_33-18; PS122/3_35-11; PS122/3_36-21; PS122/3_36-4; PS122/3_38-16; PS122/3_38-24; PS122/3_39-18; PS122/3_39-7; Salinity; Sample code/label; Sample ID; Sample type; Sea ice; Station label; δ18O, water; δ Deuterium, water
    Type: Dataset
    Format: text/tab-separated-values, 2179 data points
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  • 8
    Publication Date: 2024-05-01
    Description: Radiocarbon dating performed on the total organic carbon content of 40 bulk sediments, measured at the MICADAS (Mini Carbon Dating System) Laboratory of AWI in Bremerhaven.
    Keywords: Accelerator mass spectrometry, Ionplus, Mini Carbon Dating System (MiCaDaS AWI); Age, 14C calibrated; Age, dated; Age, dated material; Age, dated standard deviation; AWI Arctic Land Expedition; Calendar age, maximum/old; Calendar age, minimum/young; DEPTH, sediment/rock; EN21103; Laboratory code/label; Lake sediment core; Lake Ulu; Oymyakon; Piston coring system, UWITEC Niederreiter, HYBRID 90 mm UHP 30450; radiocarbon age; RU-Land_2021_Yakutia; Siberia; Yakutsk
    Type: Dataset
    Format: text/tab-separated-values, 240 data points
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  • 9
    Publication Date: 2024-05-01
    Description: Element composition including total carbon (TC), total organic carbon (TOC), total inorganic carbon (TIC), and total nitrogen (TN), measured with a soli TOC cube (Elementar) and a rapid MAX N exceed (Elementar) at the Carbon and Nitrogen Laboratory of AWI in Potsdam. The minimum detectable concentration for natural sediment samples is 0.1% for both machines.
    Keywords: AGE; AWI Arctic Land Expedition; Carbon, inorganic, total; Carbon, organic, total; Carbon, total; Carbon Analyzer, Elementar, soli TOC cube; DEPTH, sediment/rock; EN21103; Geochemical proxies; Lake sediment core; Lake Ulu; Nitrogen, total; Nitrogen Analyzer, Elementar, rapid MAX N exceed; Oymyakon; Piston coring system, UWITEC Niederreiter, HYBRID 90 mm UHP 30450; radiocarbon age; RU-Land_2021_Yakutia; Siberia; TC; TIC; TN; TOC; Yakutsk
    Type: Dataset
    Format: text/tab-separated-values, 288 data points
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  • 10
    Publication Date: 2024-05-01
    Description: This model was established based on the Bayesian method with a hiatus at 138 cm and calibrated using the IntCal20 dataset via the Bacon function in the R-package rbacon. A reservoir effect of approximately 351 ± 24 radiocarbon years has been determined by the dated surface sample (0−0.5 cm). We assumed a constant reservoir effect over time and therefore subtracted a value of 351 years from all radiocarbon ages.
    Keywords: Age model, Bacon (Blaauw & Christen, 2011); AWI Arctic Land Expedition; Calendar age; DEPTH, sediment/rock; EN21103; Geochemical proxies; Lake sediment core; Lake Ulu; Oymyakon; Piston coring system, UWITEC Niederreiter, HYBRID 90 mm UHP 30450; radiocarbon age; RU-Land_2021_Yakutia; Siberia; Yakutsk
    Type: Dataset
    Format: text/tab-separated-values, 2184 data points
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